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1. 发明公开

KR20120064933A Method for preparing polyketone fibers 审中-公开
标题翻译：制备聚酮纤维的方法
公开(公告)号：KR20120064933A
公开(公告)日：2012-06-20
申请号：KR20100126206
申请日：2010-12-10
申请人： HYOSUNG CORP
发明人： CHOI JONG IN , KIM HEON SU , CHOI SOO MYUNG
IPC分类号： D01F6/76 , D01D5/06
CPC分类号： D01F6/76 , D01D1/02 , D01D1/065 , D01D5/06 , D01D10/06 , D01F1/10 , D10B2401/063 , D10B2505/00 , D10B2505/022
摘要： PURPOSE: A polyketone fiber having 90 mole% of repetitive ketone units of -CH2 CH2 -CO- is provided to enhance polyketone fiber strength and to be used in an industrial fiber field. CONSTITUTION: A method for fabricating polyketone fiber comprises: a step of dissolving polyketone containing 90 mole% of more of ketone units in a metal salt solution containing zinc bromide to prepare a polyketone solution; a step of extruding/spinning the polyketone solution by a spinning nozzle and solidifying in an acidic solution to prepare a multi-filament; and a washing and drying the multi-filament and treating with emulsion for drawing. The strength, fineness, and extension of the polyketone fiber are 10-30 g/d, 500-30,000 denier, and 3-10%, respectively. The metal salt solution contains zinc bromide, calcium bromide, and lithium bromide.
摘要翻译：目的：提供具有90摩尔％的-CH 2 CH 2 -CO-重复酮单元的聚酮纤维，以增强聚酮纤维强度并用于工业纤维领域。构成：制造聚酮纤维的方法包括：将含有90摩尔％以上酮单元的聚酮溶解在含有溴化锌的金属盐溶液中制备聚酮溶液的步骤; 通过纺丝喷嘴挤出/纺丝聚酮溶液并在酸性溶液中固化以制备复丝的步骤; 并洗涤并干燥复丝并用乳液处理拉伸。聚酮纤维的强度，细度和伸长率分别为10-30克/分，500-300旦尼尔和3-10％。金属盐溶液含有溴化锌，溴化钙和溴化锂。

2. 发明公开

KR20090070648A A process of producing polyketone fiber and a polyketone fiber produced by the process 无效
标题翻译：生产聚酮纤维的方法和由该方法生产的聚酮纤维
公开(公告)号：KR20090070648A
公开(公告)日：2009-07-01
申请号：KR20070138734
申请日：2007-12-27
申请人： HYOSUNG CORP
发明人： KIM WUN GWI , KIM HEON SU
IPC分类号： D01F6/76
CPC分类号： D01F6/76 , D01F1/02 , D01F6/30 , D01F6/96 , D02G3/48
摘要： A manufacturing method of polyketone fiber and the polyketone fiber produced thererby are provided to offer excellent intensity by preventing adhesion of monofilaments, and to offer impact resistance and chemical resistance etc in low temperature. A manufacturing method of polyketone fiber comprises the following steps of: producing a polyketone solution by dissolving polyketone containing a ketone unit of 90 mole % or greater in a resorcinol aqueous solution; spinning the polyketone solution through a spinneret(S1); gaining multifilament by coagulating the solution in a solidification bath(S2); and spinning the multifilament through a washing, drying and an emulsion treatment processes. In a washing bath(S3), washing liquid is flowed to a counter current direction.
摘要翻译：提供聚酮纤维及其制造的聚酮纤维的制造方法，以通过防止单丝的粘附提供优异的强度，并且在低温下提供抗冲击性和耐化学性等。聚酮纤维的制造方法包括以下步骤：通过将含有90摩尔％以上的酮单元的聚酮溶解在间苯二酚水溶液中来制造聚酮溶液; 通过喷丝头纺丝聚酮溶液（S1）; 通过在固化浴中凝固溶液来获得复丝（S2）; 并通过洗涤，干燥和乳液处理工艺纺出复丝。在洗涤槽（S3）中，洗涤液体流向逆流方向。

3. 发明公开

KR20120071806A Method of preparing polyketone fibers and the polyketone fibers prepared by the method 审中-公开
标题翻译：制备聚酮纤维的方法和方法制备的聚酮纤维
公开(公告)号：KR20120071806A
公开(公告)日：2012-07-03
申请号：KR20100133499
申请日：2010-12-23
申请人： HYOSUNG CORP
发明人： LEE HYO KYUNG , KIM HEON SU
IPC分类号： D01D5/06 , D01F6/76 , D02J1/22
CPC分类号： D01D5/06 , D01D1/02 , D01D4/02 , D01D10/06 , D01F1/10 , D01F6/76 , D02J1/22 , D10B2331/061 , D10B2401/063 , D10B2505/00 , D10B2505/022
摘要： PURPOSE: A method for fabricating a polyketone fiber of high strength is provided to quickly solidify the polyketone fiber and to manufacture a tire cord, belt, and rope. CONSTITUTION: A method for fabricating a polyketone fiber comprises: a step of dissolving polyketone having 90 mole% of ketone units in a resorcinol solution to prepare a polyketone solution; a step of dissolving the polyketone solution through two or more temperature rising stages; a step of extruding/spinning the polyketone solution through a spinning nozzle(S1) and solidifying the polyketone solution to prepare a multifilament; and a step of washing and drying the multifilament and drawing.
摘要翻译：目的：提供一种制造高强度聚酮纤维的方法，以快速固化聚酮纤维并制造轮胎帘线，带和绳。构成：制造聚酮纤维的方法包括：将具有90摩尔％酮单元的聚酮溶解在间苯二酚溶液中以制备聚酮溶液的步骤; 将聚酮溶液溶解在两个或多个升温阶段的步骤; 通过纺丝喷嘴（S1）挤出/纺丝聚酮溶液并固化聚酮溶液以制备复丝的步骤; 以及洗涤和干燥复丝和拉丝的步骤。

4. 发明公开

KR20100041305A Process for producing polyketone 审中-公开
标题翻译：生产聚酮的方法
公开(公告)号：KR20100041305A
公开(公告)日：2010-04-22
申请号：KR20080100429
申请日：2008-10-14
申请人： HYOSUNG CORP
发明人： KANG BYOUNG GOOK , KIM HEON SU
IPC分类号： C08G6/02 , C08G2/06 , C08G8/02
摘要： PURPOSE: A method for preparing polyketone is provided to improve catalyst activity and intrinsic viscosity by copolymerizing carbon monoxides and ethylenically unsaturated compounds using (R)-(+)-2,2'-bis(diphenylphospino)-6,6'-dimethoxy-1,1'-diphenyl in a liquid medium. CONSTITUTION: A method for preparing polyketone comprises a step for copolymerizing monoxides and ethylenically unsaturated compounds in a liquid medium in the presence of a organometallic complex catalyst consisting of (a) Group 9, 10 or 11 transition metal compounds and (b) Group 15 element ligands. (R)-(+)-2,2'-bis(diphenylphospino)-6,6'-dimethoxy-1,1'-diphenyl is used as Group 15 element ligands(b). The liquid medium is a mixed solvent consisting of methanol and water.
摘要翻译：目的：提供一种制备聚酮的方法，通过使用（R） - （+） - 2,2'-双（二苯基膦基）-6,6'-二甲氧基 - 1,1'-二苯基。构成：制备聚酮的方法包括在由（a）第9,10或11族过渡金属化合物和（b）第15族元素组成的有机金属配合物催化剂的存在下，在液体介质中共聚单氧化物和烯键式不饱和化合物的步骤配体。（R） - （+） - 2,2'-双（二苯基膦基）-6,6'-二甲氧基-1,1'-二苯基用作第15族元素配体（b）。液体介质是由甲醇和水组成的混合溶剂。

5. 发明公开

KR20120056090A Flame Retardant Polyketone Resin Composition 审中-公开
标题翻译：阻燃聚酮树脂组合物
公开(公告)号：KR20120056090A
公开(公告)日：2012-06-01
申请号：KR20100117620
申请日：2010-11-24
申请人： HYOSUNG CORP
发明人： LEE BOO YOUN , KIM HEON SU , CHOI SOO MYUNG
IPC分类号： C08L73/00 , C08K5/3492 , C08K5/52 , C09K21/12
CPC分类号： C08L73/00 , C08G67/02 , C08K5/3492 , C08K5/34922 , C08K5/52 , C09K21/12
摘要： PURPOSE: A polyketone resin composition is provided to improve flame retardance using specific additives, thereby being used in OA devices, electric/electronic components, housing components, vehicle components, machine components, etc. CONSTITUTION: A polyketone resin composition comprises 0.2-20 weight% of linear alternate polyketone polymer resin consisting of carbon monoxide and at least one kind of ethylene-based unsaturated hydrocarbon, on the basis of the total weight of the resin composition. The polyketone resin composition marks V-0 or V-1 class on the UK94 flame retardance test. The limiting oxygen index of the polyketone resin composition is 30-38%.
摘要翻译：目的：提供聚酮树脂组合物，以提高使用特定添加剂的阻燃性，从而用于OA设备，电气/电子部件，外壳部件，车辆部件，机器部件等。构成：聚酮树脂组合物包含0.2-20重量％的由一氧化碳和至少一种乙烯类不饱和烃组成的线性交替聚酮树脂，基于树脂组合物的总重量。聚酮树脂组合物在UK94阻燃试验中标记V-0或V-1级。聚酮树脂组合物的极限氧指数为30-38％。

6. 发明公开

KR20090072471A Process for producing polyketone fibers 无效
标题翻译：生产聚酮纤维的方法
公开(公告)号：KR20090072471A
公开(公告)日：2009-07-02
申请号：KR20070140595
申请日：2007-12-28
申请人： HYOSUNG CORP
发明人： JANG YOUN WOOK , KIM HEON SU
IPC分类号： D01F6/78
CPC分类号： D01F6/78 , D01D5/08 , D01F6/74 , D02G3/48
摘要： A manufacturing method of polyketone fiber is provided to offer superior intensity by decreasing generation of a deterioration material through a bubble-removing process of materials at high temperature in a short time. A manufacturing method of polyketone fiber comprises the following steps of: producing a polyketone solution by dissolving polymetone containing a ketone unit of 90 mole % or greater in a resorcinol aqueous solution; performing a bubble-removing process in the polyketone solution; extruding the polyketone solution through a spinning nozzle; gaining multifilament through a coagulation process; and performing a washing(S3), a drying(S4), and an ointment(S6) processes with the multifilament. The content of the polyketone is 5 - 30 weight% about the resorcinol content. The bubble-removing process is performed under pressure of -650mmHg ~ -600mmHg with a thin film evaporation mode.
摘要翻译：提供聚酮纤维的制造方法，通过在短时间内通过高温下的材料的气泡除去工艺减少劣化材料的产生，提供优异的强度。聚酮纤维的制造方法包括以下步骤：通过将含有90摩尔％以上的酮单元的聚甲醛溶解在间苯二酚水溶液中来制造聚酮溶液; 在聚酮溶液中进行气泡去除工艺; 通过纺丝喷嘴挤出聚酮溶液; 通过凝结过程获得复丝; 并进行洗涤（S3），干燥（S4）和软膏（S6）。聚酮的含量相对于间苯二酚含量为5-30重量％。采用薄膜蒸发模式，在-650mmHg〜-600mmHg的压力下进行气泡去除处理。

7. 发明公开

KR20120077807A Blend comprising polyketone and abs and method for preparing the same 审中-公开
标题翻译：包含聚酮和ABS的混合物及其制备方法
公开(公告)号：KR20120077807A
公开(公告)日：2012-07-10
申请号：KR20100139893
申请日：2010-12-31
申请人： HYOSUNG CORP
发明人： CHO HAE SOUK , CHOI SOO MYUNG , KIM HEON SU
IPC分类号： C08L73/00 , C08F279/04 , C08G67/02 , C08L55/02
CPC分类号： C08L73/00 , C08F279/04 , C08G2/18 , C08G67/02 , C08G2261/124 , C08L55/02
摘要： PURPOSE: A polyketone blend is provided to have excellent impact resistance, and to be used for manufacturing vehicle components, etc. CONSTITUTION: A polyketone blend comprises a linear alternating polyketone polymer consisting of at least one kind of ethylene-based unsaturated hydrocarbon, and an acrylonitrile-butadiene-styrene(ABS) polymer resin. The comprised amount of the ABS polymer resin is 10-30 weight% based on total weight of the blend. The polyketone blend has the elongation at break of 35-190%, and the Charpy impact value of 18-30 KJ/m^2.
摘要翻译：目的：提供聚酮共混物以具有优异的抗冲击性，并用于制造载体组分等。构成：聚酮共混物包含由至少一种乙烯类不饱和烃组成的线性交替聚酮聚合物和丙烯腈 - 丁二烯 - 苯乙烯（ABS）聚合物树脂。 ABS聚合物树脂的含量相对于共混物的总重量为10-30重量％。聚酮共混物的断裂伸长率为35-190％，夏比冲击值为18-30KJ / m ^ 2。

8. 发明公开

KR20120077366A Blend comprising polyketone and nylong with high impact resistance 审中-公开
标题翻译：混合包含聚酮和尼龙具有高抗冲击性
公开(公告)号：KR20120077366A
公开(公告)日：2012-07-10
申请号：KR20100139301
申请日：2010-12-30
申请人： HYOSUNG CORP
发明人： KANG BYOUNG GOOK , CHOI SOO MYUNG , KIM HEON SU
IPC分类号： C08L73/00 , C08G67/02 , C08L23/16 , C08L77/02
CPC分类号： C08L73/00 , C08G67/02 , C08G2261/124 , C08L23/16 , C08L77/02
摘要： PURPOSE: A blend of polyketone and nylon with improved impact resistance is provided to be used for manufacturing molded product or vehicle components, and to have excellent dimensional stability. CONSTITUTION: A blend of polyketone and nylon comprises: a linear alternating polyketone polymer consisting of carbon monoxide, and at least one kind of ethylene-based unsaturated hydrocarbon; nylon 6,6; and ethylene-based octane rubber. Specifically, the polyketone polymer comprises 60-80 weight% of the linear alternating polyketone polymer, 10-40 weight% of nylon 6,6,, and 1-15 weight% of ethylene-based unsaturated octane rubber. The polyketone blend has impact strength of 25-93 KJ/m.
摘要翻译：目的：提供具有改善耐冲击性的聚酮和尼龙的混合物，用于制造模制产品或车辆部件，并且具有优异的尺寸稳定性。构成：聚酮和尼龙的共混物包括：由一氧化碳和至少一种乙烯类不饱和烃组成的线性交替聚酮聚合物; 尼龙6,6; 和乙烯基辛烷橡胶。具体地，聚酮聚合物包含60-80重量％的线性交替聚酮聚合物，10-40重量％的尼龙6,6，和1-15重量％的基于乙烯的不饱和辛烷橡胶。聚酮共混物的冲击强度为25-93KJ / m。

9. 发明公开

KR20120077365A Method for preparing polyketone fibers 审中-公开
标题翻译：制备聚酮纤维的方法
公开(公告)号：KR20120077365A
公开(公告)日：2012-07-10
申请号：KR20100139300
申请日：2010-12-30
申请人： HYOSUNG CORP
发明人： CHOI JONG IN , CHOI SOO MYUNG , KIM HEON SU
IPC分类号： D01F6/76 , D01D5/06 , D01D10/06
CPC分类号： D01F6/76 , D01D1/02 , D01D1/065 , D01D5/06 , D01D10/06 , D01F1/10 , D10B2401/063 , D10B2505/00 , D10B2505/022
摘要： PURPOSE: A method for fabricating polyketone fibers containing 90 mole% or more of ketone units is provided to ensure excellent strength of polyketone fibers and to be applied to industrial fiber fields. CONSTITUTION: A method for fabricating polyketone fibers comprises: a step of dissolving polyketone containing 90 mole% or more of repetitive ketone units in a metal salt solution containing zinc bromide to prepare a polyketone solution; a step of extruding/spinning the polyketone solution through a spinning nozzle and solidifying to prepare multifilaments; a step of washing and drying the multifilaments; and a step of treating with additive and emulsion and drawing the multifilaments. The additive is an acetone solution containing 100-500 ppm of calcium hydroxyl apatite.
摘要翻译：目的：提供一种制备含有90摩尔％以上酮单元的聚酮纤维的方法，以确保聚酮纤维的优异强度并适用于工业纤维领域。构成：制造聚酮纤维的方法包括：将含有90摩尔％以上的重复酮单元的聚酮溶解在含有溴化锌的金属盐溶液中制备聚酮溶液的步骤; 通过纺丝喷嘴挤出/纺丝聚酮溶液并固化以制备复丝的步骤; 洗涤和干燥复丝的步骤; 以及用添加剂和乳液处理并拉伸复丝的步骤。添加剂是含有100-500ppm羟基磷灰石钙的丙酮溶液。

10. 发明公开

KR20120071811A Process for preparing polyketon fiber 审中-公开
标题翻译：制备聚酮纤维的方法
公开(公告)号：KR20120071811A
公开(公告)日：2012-07-03
申请号：KR20100133507
申请日：2010-12-23
申请人： HYOSUNG CORP
发明人： JANG YOUN WOOK , CHOI SOO MYUNG , KIM HEON SU
IPC分类号： D01D5/06 , D01D10/06 , D01F6/76 , D02J1/22
CPC分类号： D01D5/06 , D01D1/02 , D01D4/02 , D01D10/06 , D01F1/10 , D01F6/76 , D02J1/22 , D10B2331/061 , D10B2401/063 , D10B2505/00 , D10B2505/022
摘要： PURPOSE: A method for fabricating a polyketone fiber is provided to shorten unnecessary drying time and to save installation cost. CONSTITUTION: A method for fabricating a polyketone fiber comprises: a step of solidifying and washing a polyketone spinning solution extruded from a spinning nozzle(S1); and a step of drawing the solution through a hot air dryer for 120-220 Deg. C for 2-9 min. The strength of the polyketone fiber is 20 g/d.
摘要翻译：目的：提供一种制造聚酮纤维的方法，以缩短不必要的干燥时间并节省安装成本。构成：制造聚酮纤维的方法包括：固化和洗涤从纺丝喷嘴挤出的聚酮纺丝溶液的步骤（S1）; 并通过热空气干燥器将溶液拉伸120-220度的步骤。 C 2-9分钟。聚酮纤维的强度为20g / d。

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