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1. 发明公开

KR1020020096342A 자동차 휠커버용 폴리올레핀 수지 조성물 无效
标题翻译：汽车车轮盖的聚烯烃树脂组合物
公开(公告)号：KR1020020096342A
公开(公告)日：2002-12-31
申请号：KR1020010034743
申请日：2001-06-19
申请人： 현대자동차주식회사 , 한화종합화학 주식회사
发明人： 박봉현 , 이성준 , 정원범 , 채경석
IPC分类号： C08L23/00
CPC分类号： C08L23/142 , C08L23/16 , C08L53/02 , C08L2666/24 , C08L2666/04
摘要： PURPOSE: A polyolefin resin composition for the wheel cover of a car is provided, which has the strength, the impact strength, the heat resistance and the hardness applicable to the wheel cover of a car and the improved coating property and does not generate the projection in the weld line generation part. CONSTITUTION: The polyolefin resin composition comprises 40-75 wt% of a super high crystalline olefin-based resin; 3-25 wt% of a polyolefin-based elastomer; and 5-30 wt% of an inorganic filler. Preferably the super high crystalline olefin-based resin has a melt index of 10-80 g/10 min and the isotactic peptide fraction of the homopolymer part of 96% or more, and is a copolymer the α-olefin selected from isotactic polypropylene, propylene-ethylene copolymer, propylene-1-butene copolymer, propylene-1-hexene copolymer and propylene-4-methyl-1-pentene copolymer, and propylene; a random copolymer; or their mixture.
摘要翻译：目的：提供一种用于汽车车轮罩的聚烯烃树脂组合物，其具有强度，冲击强度，耐热性和适用于汽车车轮罩的硬度和改善的涂覆性能，并且不产生突起在焊线生成部分。构成：聚烯烃树脂组合物包含40-75wt％的超高结晶烯烃基树脂; 3-25重量％的聚烯烃类弹性体; 和5-30重量％的无机填料。优选超高结晶性烯烃类树脂的熔融指数为10-80g / 10min，均聚物部分的全同立构肽部分为96％以上，是选自全同立构聚丙烯，丙烯乙烯共聚物，丙烯-1-丁烯共聚物，丙烯-1-己烯共聚物和丙烯-4-甲基-1-戊烯共聚物和丙烯; 无规共聚物; 或它们的混合物。

2. 发明授权

KR100389474B1 폴리프로필렌계 매트성 복합필름 失效
标题翻译：聚丙烯基哑光复合膜
公开(公告)号：KR100389474B1
公开(公告)日：2004-02-05
申请号：KR1019960018046
申请日：1996-05-27
申请人： 한화종합화학 주식회사
发明人： 전승호 , 정원범
IPC分类号： B32B27/32 , B32B27/18
摘要： PURPOSE: A polypropylene based film combination having matting property and improved mechanical property suitable for producing adhesive tape material, cover paper or case for stationery, fashionable bag, food packages, etc. is provided. CONSTITUTION: The film comprises a matting surface layer with a thickness ranging of 2-50% and a supporting layer with a thickness ranging of 50-98% based on total thickness of the film. The matting surface layer is made of metallocene catalytic propylene copolymer resin in 0.1-50 weight parts based on 100 weight parts of a resin composition comprising 30-70 weight % of polypropylene resin and 30-70 weight % of high density polyethylene resin with 0.94-0.97g/cm¬3 density. The supporting layer is formed of polypropylene resin.

3. 发明公开

KR1020020007588A 난연성이 우수한 폴리프로필렌-유기점토 복합체 및 이의제조방법 失效
标题翻译：具有优异阻燃剂的聚丙烯有机粘土复合材料及其生产方法
公开(公告)号：KR1020020007588A
公开(公告)日：2002-01-29
申请号：KR1020000040961
申请日：2000-07-18
申请人： 한화종합화학 주식회사
发明人： 이윤환 , 정원범 , 양준호
IPC分类号： C08K3/00
CPC分类号： C08L51/06 , C08F255/02 , C08K3/346 , C08K7/00 , C08K9/04 , C08L23/0815 , C08L23/10 , C08L23/12 , C08L53/00 , C08L23/02 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： PURPOSE: Provided is a polypropylene-organic clay composite with excellent flame retardant as well as mechanical properties and heat resistance improved by substituting an inorganic material with a flame retardant agent and modifying a polymeric resin with a certain material so that a chemical bond is made between inorganic material substituted with a flame retardant agent and the polymeric resin matrix. Also, a method for producing the composite is provided. CONSTITUTION: The polypropylene-organic clay composite comprises 1.0 to 30 wt% of a modified polypropylene containing a functional group (A component); 1.0 to 20 wt% of layered clay minerals organized with a free-halogen amine flame retardant agent bonded to the functional group of the A component or with a combination of a free-halogen amine flame retardant agent and an alkyl ammonium compound; and 50 to 98 wt% of polyolefin resin matrix in which the A component and the B component are dispersed.
摘要翻译：目的：提供通过用阻燃剂代替无机材料并用某种材料改性聚合物树脂，从而在具有优异的阻燃性和机械性能和耐热性的聚丙烯 - 有机粘土复合材料之间形成化学键，被阻燃剂和聚合物树脂基质取代的无机材料。另外，提供了一种复合体的制造方法。构成：聚丙烯 - 有机粘土复合体含有1.0〜30重量％的含有官能团（A成分）的改性聚丙烯; 以与A成分的官能团结合的自由卤素胺阻燃剂或与自由卤素胺阻燃剂和烷基铵化合物的组合结合的层状粘土矿物为1.0〜20重量％和50〜98重量％的分散有A成分和B成分的聚烯烃树脂基体。

4. 发明公开

KR1020020002646A 방충필름 제조방법 失效
标题翻译：制造防护膜的方法
公开(公告)号：KR1020020002646A
公开(公告)日：2002-01-10
申请号：KR1020000036874
申请日：2000-06-30
申请人： 한화종합화학 주식회사
发明人： 양경선 , 정원범 , 홍종수 , 이상우
IPC分类号： B29D7/01
CPC分类号： B29C47/0004 , B29C47/0021 , B29C47/0057 , B29D7/01 , C08K3/013 , C08K5/0058 , C08K9/10 , C08K2201/014 , C08L23/00 , C08L101/00
摘要： PURPOSE: A method for manufacturing an insect proofing film, especially appropriate for fruit bags, is provided to maintain insect-proof effect for an extended period of time, and to improve moisture transpiration. CONSTITUTION: The method for manufacturing an insect proofing film is comprised of the steps of: mixing 20-80 wt.% of polyolefin resin, 20-80 wt.% of inorganic filling agent, and 0.01-10 wt.% of capsule containing an insecticide, and melting the mixture; performing an inflation or t-die casting process on a resulting film; and elongating the film uniaxially or biaxially, making the total area of the film be within a range of from 1.5 times to 36 times of elongation ratio, which varies depending on the moisture transpiration required after manufacturing an original plate sheet.
摘要翻译：目的：提供特别适用于水果袋的防虫膜的制造方法，以在更长的时间内保持防虫效果，并改善水分蒸发。构成：制造防虫膜的方法包括以下步骤：混合20-80重量％的聚烯烃树脂，20-80重量％的无机填充剂和0.01-10重量％的含有杀虫剂，并融化混合物; 对所得膜进行充气或t压铸过程; 并且单轴或双轴拉伸膜，使膜的总面积在伸长率的1.5倍至36倍的范围内，这取决于制造原版印刷版后所需的水分蒸腾。

5. 发明公开

KR1020010107429A 난연성 폴리프로필렌 수지조성물 有权
标题翻译：阻燃聚丙烯树脂组合物
公开(公告)号：KR1020010107429A
公开(公告)日：2001-12-07
申请号：KR1020000028965
申请日：2000-05-29
申请人： 한화종합화학 주식회사
发明人： 정인식 , 홍종수 , 허만생 , 정원범
IPC分类号： C08L23/12
CPC分类号： C08L53/025 , C08K5/053 , C08K5/523 , C08K2003/323 , C08L23/10 , C08L23/12 , C08L23/142 , C08L53/00 , C08L71/12 , C08L71/123 , C08L2205/03 , C08L2666/02 , C08L2666/22 , C08L2666/24 , C08L2666/18 , C08L2666/14 , C08L2666/04
摘要： 본 발명은 난연성 및 높은 기계적 물성을 나타내는 난연성 폴리프로필렌 수지조성물에 관한 것으로서, 더욱 상세하게는 폴리프로필렌 수지를 주성분으로 하여 특정 비율의 인계난연제와 폴리페닐렌 에테르계 수지 및 난연조제를 분산시켜 이루어진 난연성이 우수한 폴리프로필렌 수지조성물에 관한 것이다.
본 발명에 의하여 제조된 폴리프로필렌 수지조성물은 난연성이 우수하여 UL94 V-0의 난연성을 발휘하며, 성형시키거나 연소시킬 경우 어떤 부식 기체 또는 유독 기체도 발생되지 않고, 또한 충격강도, 내열변형성 등의 기계적 물성 및 치수안정성이 우수하여 이러한 성능이 요구되는 전기용품 및 자동차부품, 건축자재, 내부장식재 등을 제조하는데 사용하기에 바람직하다.

6. 发明公开

KR1019950018201A 분해성 발포체 및 그 제조방법 失效
公开(公告)号：KR1019950018201A
公开(公告)日：1995-07-22
申请号：KR1019930027507
申请日：1993-12-13
申请人： 한화종합화학 주식회사
发明人： 황진택 , 전승호 , 정원범
IPC分类号： C08J9/04 , C08J9/00
摘要： 본 발명은 분해성 발포체 및 그의 제조방법에 관한 것이다. 종래 기술에 따른 생분해성 발포체는 생분해성은 우수하지만, 기계적 물성이 불량하거나, 비경제적인 단점이 있었다. 이러한 단점을 해결하기 위해 본 발명에 따른 분해성 발포체는 목분, 왕겨 등 폐자원인 리그노셀루로오즈를 사용하여, 리그노셀루로오즈 및/또는 그 유도체를 지방족계 디카르본산 및 케톤계 디카르본산으로 구성되는 디카르본산 또는 그 에스테르와 지방조계 글리콜의 통상의 축중합 반응으로 얻어지는 생/광분해성 지방족 폴리에스테르에 용해시킨 용해물과 통상의 경화제 및 발포제와 발포경화시켜 제조되며, 제조된 분해성 발포체는 분해성이 우수하고 기계적 물성 및 경제성이 양호함으로 스티로플 등 1회용 완충재를 대체하는데 적합하다.

7. 发明公开

KR1020020051000A 접착성이 우수한 올레핀계 열가소성 일래스토머 수지조성물 및 이의 제조방법 有权
标题翻译：基于烯烃的热塑性弹性体树脂组合物在粘合性能中的优异性能及其生产方法
公开(公告)号：KR1020020051000A
公开(公告)日：2002-06-28
申请号：KR1020000080321
申请日：2000-12-22
申请人： 한화종합화학 주식회사
发明人： 장욱진 , 김영환 , 이종대 , 정원범
IPC分类号： C08L23/16 , C08L23/26 , C08L51/00
CPC分类号： C08L51/06 , C08J2300/22 , C08L23/12 , C08L23/16 , C08L2205/02 , C08L2205/03 , C08L2207/04
摘要： PURPOSE: Provided are an olefin-based thermoplastic elastomer resin composition excellent in adhesive property, which can be used for impact-resistance of various composite materials, and a process for producing the olefin-based thermoplastic elastomer resin composition. CONSTITUTION: The olefin-based thermoplastic elastomer resin composition comprises: 1-40wt% of polypropylene copolymers obtained by grafting 0.25-5wt%(based on the polypropylene copolymers) of ethylene-based unsaturated carboxylic acid, ethylene-based unsaturated carboxylic anhydride or ester monomers; 60-99wt% of thermoplastic elastomer obtained by crosslinking EPDM, being a terpolymer comprising ethylene, propylene, and non-conjugated diene, and polypropylene. And the olefin-based thermoplastic elastomer resin composition is produced by mixing the grafted polypropylene copolymers and the thermoplastic elastomer, which are produced separately.
摘要翻译：目的：提供能够用于各种复合材料的耐冲击性的粘合性优异的烯烃系热塑性弹性体树脂组合物以及烯烃类热塑性弹性体树脂组合物的制造方法。构成：基于烯烃的热塑性弹性体树脂组合物包括：通过接枝0.25-5wt％（基于聚丙烯共聚物）乙烯类不饱和羧酸，乙烯类不饱和羧酸酐或酯单体得到的1-40wt％聚丙烯共聚物 ; 通过交联EPDM获得的热塑性弹性体的60-99重量％，其是包含乙烯，丙烯和非共轭二烯的三元共聚物和聚丙烯。烯烃类热塑性弹性体树脂组合物是通过混合分别制备的接枝聚丙烯共聚物和热塑性弹性体来制备的。

8. 发明公开

KR1020020046078A 난연성 폴리프로필렌 수지 조성물 有权
标题翻译：阻燃聚丙烯树脂组合物
公开(公告)号：KR1020020046078A
公开(公告)日：2002-06-20
申请号：KR1020000075578
申请日：2000-12-12
申请人： 한화종합화학 주식회사
发明人： 정인식 , 정원범 , 허만생
IPC分类号： C08L23/12 , C08K5/5399 , C08K5/521 , C08K5/3492
CPC分类号： C08K5/5399 , C08K5/34924 , C08K5/521 , C08L23/12 , C08L2201/02
摘要： PURPOSE: A flame retardant polypropylene resin composition is provided, which is improved in the flame retardancy and the mechanical strength and does not generate pollutant gases in combustion. CONSTITUTION: The flame retardant polypropylene resin composition comprises 46-80.5 wt% of a polypropylene-based resin; 16-27 wt% of a poly(ammonium phosphate); 1.5-12 wt% of a phenol-based aromatic phosphate ester compound; and 2-15 wt% of 1,3,5-triazine derivative. Preferably the polypropylene-based resin is a homopolymer, an impact copolymer or their mixture, and has a melting flow index of 0.1-40 g/10 min. The phenol-based aromatic phosphate ester compound is represented by the formula 1, wherein X is an allylene group; R1, R2, R3 and R4 are preferably an aryl group; and n is an integer of 1-5. The 1,3,5-triazine derivative is represented by the formula 2, wherein X is a morpholino group or a piperazino group; Y is a piperazine group; m is 1 or 2; and n is an integer of 1-50.
摘要翻译：目的：提供阻燃聚丙烯树脂组合物，其阻燃性和机械强度得到改善，并且不会在燃烧中产生污染气体。构成：阻燃聚丙烯树脂组合物包含46-80.5重量％的聚丙烯基树脂; 16-27重量％的聚（磷酸铵）; 1.5-12重量％的苯酚系芳族磷酸酯化合物; 和2-15重量％的1,3,5-三嗪衍生物。优选地，聚丙烯基树脂是均聚物，抗冲共聚物或其混合物，并且具有0.1-40g / 10min的熔融流动指数。酚系芳族磷酸酯化合物由式1表示，其中X为烯丙基; R1，R2，R3和R4优选为芳基; n为1-5的整数。 1,3,5-三嗪衍生物由式2表示，其中X是吗啉代基或哌嗪基; Y是哌嗪基; m为1或2; n为1-50的整数。

9. 发明公开

KR1020020002786A 폴리프로필렌-유기점토 복합체 및 이의 제조방법 无效
标题翻译：聚丙烯有机粘土复合材料及其制造方法
公开(公告)号：KR1020020002786A
公开(公告)日：2002-01-10
申请号：KR1020000037082
申请日：2000-06-30
申请人： 한화종합화학 주식회사
发明人： 이윤환 , 정원범 , 윤대영
IPC分类号： C08J5/00
CPC分类号： C08L51/06 , C08F255/02 , C08K3/346 , C08K9/08 , C08L23/10 , C08L23/12 , C08L53/00 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： PURPOSE: Provided is a polypropylene-organic clay composite excellent in rigidity, heat-resistance, impact-resistance, fire retardancy, transparency, and inhibition of gas- and liquid-permeation. CONSTITUTION: The polypropylene-organic clay composite comprises: 1.0-30wt% of a modified polypropylene(component A) having a functional group, which is formed by modifying polypropylene homopolymers, ethylene/propylene copolymers, or propylene/alpha-olefin nonconjugated compound copolymers by unsaturated carboxylic acid or derivatives thereof; 1.0-20wt% of an organized lamellar clay mineral(component B) bonded to the functional group of the component A, which is organized by an organic onium ion compound; 50-98wt% of a polyolefin resin matrix(component C) dispersing the component A and the component B.
摘要翻译：目的：提供刚性，耐热性，耐冲击性，阻燃性，透明性和气液渗透抑制性优异的聚丙烯 - 有机粘土复合材料。构成：聚丙烯 - 有机粘土复合材料包括：通过改性聚丙烯均聚物，乙烯/丙烯共聚物或丙烯/α-烯烃非共轭化合物共聚物形成的具有官能团的改性聚丙烯（组分A）为1.0-30重量％不饱和羧酸或其衍生物; 与有机鎓离子化合物组合的组分A的官能团键合的有机层状粘土矿物（组分B）为1.0-20重量％ 50〜98重量％的分散了组分A和组分B的聚烯烃树脂基质（组分C）。

10. 发明授权

KR100288053B1 분해성 폴리에스테르의 제조방법 失效
标题翻译：生产可降解聚酯的方法
公开(公告)号：KR100288053B1
公开(公告)日：2001-05-02
申请号：KR1019930029414
申请日：1993-12-23
申请人： 한화종합화학 주식회사
发明人： 정원범 , 육문수 , 황진택 , 전승호
IPC分类号： C08G63/91
摘要： PURPOSE: Provided is a method for producing degradable polyester, comprising ketone group imparting photodegradability and a number of aliphatic ester bonds excellent in biodegradability, as well as having high molecular weight and sufficient strength. CONSTITUTION: The method comprises the steps of (i) polycondensing a compound containing 0.01-5 mole% of ketone component, selected from a mixture of at least one dicarbonic acid selected from aliphatic dicarbonic acid having C8 or less and ketone dicarbonic acid of general formula 1, with at least one diol selected from aliphatic dicarbonic acid having C8 or less and keton dicarbonic acid of general formula 2, to form polyester having ketonic group with a number average molecular weight of 4,000 or more, and (ii) adding diisocyanate to the molten polyester and reacting them with each other to form polyester with a number average molecular weight of 10,000 or more.

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