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1. 发明公开

KR1020120033367A 유동층접촉분해 배가스로부터 에틸렌의 회수방법 有权
标题翻译： FCC废气回收乙烯的方法和装置
公开(公告)号：KR1020120033367A
公开(公告)日：2012-04-09
申请号：KR1020100082772
申请日：2010-08-26
申请人： 한국에너지기술연구원 , 에스케이 주식회사
发明人： 박종호 , 김종남 , 범희태 , 이성준 , 이장재 , 김동욱 , 고창현 , 한상섭 , 조순행
IPC分类号： C07C7/12 , C07C11/04 , C10G70/04 , B01D53/047
CPC分类号： C07C7/12 , B01D53/047 , B01D2253/108 , B01D2256/24 , B01D2257/7022 , B01D2259/40073 , B01D2259/4063 , C07C7/13 , C10G70/046 , C10G2300/107 , C10G2300/4081 , C10G2400/20 , Y02C20/20 , Y02P30/464 , C07C11/04
摘要： PURPOSE: Process and apparatus for recovery of ethylene is provided to recollect ethylene from fluidized catalytic cracking(FCC) off-gas of heavy crudeoil like atmospheric residue generated in crude oil purification process with high purity and low cost. CONSTITUTION: Process for recovery of ethylene from fluidized catalytic cracking(FCC) off-gas comprises: a step of concentrating components of components containing C2 or more carbons in FCC off-gas by using pressure variable adsorption process; and a step of re-collecting ethylene of high concentration by introducing the mixed gas, in which concentrate the components containing C2 or more carbons, are concentrated, into substitution-desorption process. Apparatus for recover of ethylene from FCC off-gas comprises a device for pressure variable adsorption process in order to concentrate the components containing C2 or more carbons from the FCC off-gas of heavy crudeoil, and a device for ethylene substitution-desorption process in order to selectively separate ethylene from the components containing C2 or more carbons.
摘要翻译：目的：提供回收乙烯的方法和装置，用于从流化催化裂化（FCC）废气中回收乙烯，该废气是以粗纯油和低成本在原油纯化过程中产生的大气残留物。构成：从流化催化裂化（FCC）废气中回收乙烯的方法包括：通过使用压力可变吸附方法将含有C2或更多碳的组分的组分浓缩在FCC废气中的步骤; 以及将含有C2个或更多个碳的组分的浓缩物的浓缩的混合气体引入取代 - 脱附过程中，重新收集高浓度的乙烯的步骤。用于从FCC废气中回收乙烯的设备包括用于压力可变吸附过程的装置，以便将浓缩含有C2或更多碳的组分从来自重质焦油的FCC废气中浓缩，以及用于乙烯取代 - 脱附过程的装置从含有C2或更多个碳的组分中选择性地分离乙烯。

2. 发明授权

KR101040966B1 고산도 원유 중의 산성분 제거를 위한 촉매 및 그 제법 有权
标题翻译：用于去除高TAN粗品中酸性化合物的催化剂及其制备方法
公开(公告)号：KR101040966B1
公开(公告)日：2011-06-16
申请号：KR1020080110965
申请日：2008-11-10
申请人： 한국에너지기술연구원
发明人： 박종호 , 오현영 , 김종남 , 고창현 , 이광복 , 한상섭 , 조순행 , 노남선
IPC分类号： B01J21/14 , B01J21/12
CPC分类号： B01J21/10 , B01J21/14 , B01J37/031 , C10G25/00
摘要： 본 발명은 고산도 원유(High TAN crude) 중의 산 성분을 반응을 통하여 제거하기 위한 촉매와 그 제법에 관한 것이다. 고산도 원유는 공정 부식을 일으키는 산성분이 많이 함유되어 있는데, 이러한 산성분을 탈탄산 반응을 통하여 제거한다. 기존의 탈탄산 반응을 위한 촉매로는 알칼리 토금속 산화물이나 수화물이 이용되었는데 이들 촉매들은 촉매 반응환경하에서 원유에 나프텐염의 형태로 녹아들어가 이차적인 문제를 유발한다. 본 발명은 알칼리토금속 양이온 혹은 전이금속 양이온이 실리케이트 혹은 알루미네이트 등의 음이온과 결합한 형태의 탈탄산 촉매를 제공하며 이 촉매는 산성분위기 하에서도 안정하면서 우수한 탈탄산 활성을 보인다.
고산도 원유(High TAN crude), 나프텐산(Naphthenic acid), 탈탄산 반응(Decarboxylation), 염기성 촉매(Base catalyst), 내산성 촉매(acid resistance catalyst)

3. 发明授权

KR100836707B1 올레핀/파라핀 혼합가스에서 고순도 부텐-1 분리 기술 有权
标题翻译：从C4油脂/ PARAFFINS混合气体生产高纯度的BUTENE-1
公开(公告)号：KR100836707B1
公开(公告)日：2008-06-10
申请号：KR1020070040366
申请日：2007-04-25
申请人： 한국에너지기술연구원 , 에스케이이노베이션 주식회사
发明人： 박종호 , 김종남 , 이성준 , 고민수 , 범희태 , 박종기 , 고창현 , 한상섭 , 조순행
IPC分类号： C07C7/12 , C07C7/20
CPC分类号： C07C7/12 , B01D3/143 , B01D53/04 , B01D2253/108 , B01D2256/24 , B01D2257/7022 , B01D2259/40086 , B01D2259/403 , C07C7/005 , C07C7/04 , C07C7/13 , C07C11/08
摘要： A method for separating butene-1 from a mixture gas comprising a C4 olefin and a paraffin, and its apparatus are provided to reduce the loss of butene-1 in case of the removing isobutane and to lower the concentration of n-butane. A method for separating butene-1 from a mixture gas comprising C4 olefins and paraffins comprises the steps of: introducing a mixture gas comprising C4 olefins and paraffins into an adsorption tower to adsorb olefins to separate paraffins; introducing the some part of the obtained C4 olefins of high purity to wash out the adsorbed paraffins of small quantity for improving the purity of olefins; introducing a desorber to desorb C4 olefins; and distilling C4 olefins to obtain butene-1, wherein the absorption, washing and desorption are carried out continuously and repeatedly at three adsorption towers and the three adsorption towers carry out the different processes at the identical point.
摘要翻译：提供了从包含C4烯烃和石蜡的混合气体中分离丁烯-1的方法及其装置，以减少在除去异丁烷的情况下的丁烯-1的损失并降低正丁烷的浓度。从包含C4烯烃和石蜡的混合气体中分离丁烯-1的方法包括以下步骤：将包含C4烯烃和链烷烃的混合气体引入吸附塔中以吸附烯烃以分离石蜡; 引入部分得到的高纯度C4烯烃洗出少量的吸附石蜡，以提高烯烃的纯度; 引入解吸器解吸C4烯烃; 并蒸馏出C4烯烃，得到丁烯-1，其中吸附，洗涤和解吸在三个吸附塔连续反复进行，三个吸附塔在同一点进行不同的过程。

4. 发明授权

KR100822847B1 올레핀/파라핀 혼합가스에서 올레핀 분리 기술 有权
标题翻译：来自烯烃/分散体混合气体的烯烃的分离
公开(公告)号：KR100822847B1
公开(公告)日：2008-04-16
申请号：KR1020070030970
申请日：2007-03-29
申请人： 한국에너지기술연구원 , 에스케이이노베이션 주식회사
发明人： 김종남 , 박종호 , 이성준 , 고민수 , 범희태 , 박종기 , 고창현 , 한상섭 , 조순행
IPC分类号： C07C7/12 , C07C7/00 , B01D53/02
CPC分类号： B01D53/047 , B01D2256/24 , B01D2257/7022 , B01D2259/40054 , B01D2259/4006 , B01D2259/40062 , B01D2259/40067 , B01D2259/403 , C07C7/13 , C07C11/08
摘要： A method for separating a C4 olefin from a mixture gas comprising C4 olefin and paraffin, and its apparatus are provided to minimize the concentration of isobutane in a C4 olefin and to increase the concentration of a C4 olefin. A method for separating a C4 olefin from a mixture gas comprising C4 olefin and paraffin comprises the steps of introducing a mixture gas comprising C4 olefin and paraffin into an adsorption tower to adsorb an olefin to separate paraffin and a desorbing agent; introducing some of the high purity C4 olefin into an adsorption tower to wash out a small amount of the paraffin adsorbed together with an olefin to increase the purity of olefin; and introducing a desorbing agent to the adsorption tower to desorb and separate an olefin, wherein the continuous adsorption, washing and desorption are carried out at three adsorption towers.
摘要翻译：提供了一种从含有C4烯烃和石蜡的混合气体中分离C4烯烃的方法及其装置，以使C4烯烃中异丁烷的浓度最小化并提高C4烯烃的浓度。从包含C4烯烃和石蜡的混合气体中分离C4烯烃的方法包括以下步骤：将包含C 4烯烃和石蜡的混合气体引入吸附塔中以吸附烯烃以分离石蜡和解吸剂; 将一些高纯度C 4烯烃引入到吸附塔中，以清洗少量与烯烃一起吸附的石蜡，以提高烯烃的纯度; 并将吸附剂引入吸附塔以解吸和分离烯烃，其中连续吸附，洗涤和解吸在三个吸附塔上进行。

5. 发明授权

KR100807730B1 기질과 촉매와의 접착력 증대방법 有权
标题翻译：微反应器表面与催化剂颗粒之间的附着力增强方法
公开(公告)号：KR100807730B1
公开(公告)日：2008-02-28
申请号：KR1020050075362
申请日：2005-08-17
申请人： 한국에너지기술연구원
发明人： 고창현 , 김종남 , 범희태 , 한상섭 , 조순행 , 정헌도
IPC分类号： B01J32/00 , B01J23/40 , B01J35/00 , B01J21/06
摘要： 본 발명은 기질과 촉매와의 접착력 증대방법에 관한 것으로서 보다 상세하게는 기질과 상이한 물질의 촉매를 기질에 부착함에 있어서, 기질 표면의 오염물질을 제거하는 단계, 기질에 부착되어지는 촉매와 기질의 계면사이에 촉매와 동일한 물질이 접착층으로 형성되는 단계를 포함하는 기질과 촉매와의 접착력 증대방법에 관한 것이다.
본 발명에서는 기질표면에 원자기상증착법(ALD) 또는 화학기상증착법(CVD)을 이용해서 기질-촉매간의 계면에 촉매와 동일한 물질 또는 촉매와 동일한 표면특성을 지닌 물질을 접착층으로 형성하여서 촉매-기질간의 접착을 증대시켜 기질의 종류나 모양에 상관없이 원하는 성분의 박막을 원하는 두께만큼 균일하게 형성할 수 있으므로 접착층 형성에 매우 유리하다.

6. 发明公开

KR1020070095476A 기질과 촉매와의 접착력 증대방법 有权
标题翻译：微粒体表面和催化剂颗粒之间的粘合强化方法
公开(公告)号：KR1020070095476A
公开(公告)日：2007-10-01
申请号：KR1020050075362
申请日：2005-08-17
申请人： 한국에너지기술연구원
发明人： 고창현 , 김종남 , 범희태 , 한상섭 , 조순행 , 정헌도
IPC分类号： B01J32/00 , B01J23/40 , B01J35/00 , B01J21/06
CPC分类号： B01J21/063 , B01J23/40
摘要： A method for enhancement of adhesive force between a matrix and a catalyst by forming an adhesion layer on a surface of the matrix to which the catalyst is adhered using a catalyst, more preferably, the same material as a carrier of a catalyst onto which active components are doped or a material having the same surface characteristics as the catalyst is provided. In a method for adhering a catalyst of a material that is different from a matrix onto the matrix, a method for enhancement of adhesive force between the matrix and the catalyst comprises the step of forming the same material as a carrier of the catalyst or an adhesion layer having the same surface characteristics as the carrier of the catalyst between interfaces of a matrix and a carrier of a catalyst that is adhered onto a surface of a matrix. The matrix is a metal support formed from stainless steel, iron, aluminum, or alloys thereof. The matrix is an inorganic support selected from alumina, silica, titania, and zirconia. The catalyst is at least one selected from Pt/Al2O3, Cu/ZnO/Al2O3, Au/TiO2, Pt/SiO2, Pt-Ru/Al2O3, Pt-Ru/TiO2, Pt-Ru/SiO2, Pt-Pd/Al2O3, Pt-Pd/TiO2, and Pt-Pd/SiO2.
摘要翻译：一种通过在催化剂附着催化剂的基质的表面上形成粘合层来提高基质和催化剂之间的粘合力的方法，更优选使用与催化剂载体相同的材料，活性组分或者提供具有与催化剂相同的表面特性的材料。在将不同于基质的材料的催化剂粘附到基质上的方法中，用于增强基质和催化剂之间的粘合力的方法包括形成与催化剂的载体相同的材料或粘合剂的步骤层具有与基体的界面和粘附到基体表面上的催化剂的载体之间的催化剂载体相同的表面特性。基体是由不锈钢，铁，铝或其合金形成的金属支撑体。该基质是选自氧化铝，二氧化硅，二氧化钛和氧化锆的无机载体。催化剂为选自Pt / Al2O3，Cu / ZnO / Al2O3，Au / TiO2，Pt / SiO2，Pt-Ru / Al2O3，Pt-Ru / TiO2，Pt-Ru / SiO2，Pt-Pd / Pt-Pd / TiO2和Pt-Pd / SiO2。

7. 发明授权

KR100569884B1 Ｎ-메틸-2-피롤리돈의 액상 제조방법 有权
标题翻译：液相中N-甲基-2-吡咯烷酮诱导的过程
公开(公告)号：KR100569884B1
公开(公告)日：2006-04-11
申请号：KR1020030083717
申请日：2003-11-24
申请人： 한국에너지기술연구원
发明人： 조순행 , 김태환 , 김권일 , 조성철 , 박종기 , 정헌도
IPC分类号： C07D207/06
摘要： 본 발명은 감마 부티로락톤과 모노메틸아민을 반응물로 하는 N-메틸-2-피롤리돈의 제조방법에 관한 것으로, 감마 부티로락톤과 모노메틸아민을 제올라이트계 또는 점토광물계 촉매의 존재하에 액상 반응시켜 제조되는 N-메틸-2-피롤리돈의 제조방법을 제공한다.
N-메틸-2-피롤리돈, 감마 부티로락톤, 제올라이트

8. 发明授权

KR100266479B1 휘발성석유화합물의흡착식포집및회수장치 有权
标题翻译：空值
公开(公告)号：KR100266479B1
公开(公告)日：2000-09-15
申请号：KR1019980014769
申请日：1998-04-24
申请人： 한국에너지기술연구원
发明人： 주국택 , 조순행 , 조성철 , 김종남 , 한상섭 , 박종기 , 양정일 , 범희태
IPC分类号： B01D15/00
摘要： PURPOSE: Disclosed is a treatment method of volatile petrochemical compounds by adsorption. CONSTITUTION: The equipment for adsorption is composed of an adsorption tower (11) packed with silica gel and activated carbon, adsorption recovery tower (12,13), a heat exchanger (14), a storage (15), and a vacuum pump. In the adsorption tower (11), the silica gel adsorbs the stronger adsorbable compounds such as pentene, hexane, or heptane and activated carbon does the weaker adsorbable compound such as methane, ethane, propane, butane, or pentane. The adsorbing process operates at 15-50 deg.C and 30-100 mmHg. The adsorption recovery tower (12,13) is carried out by the one process period of compression, adsorption, decompression, and pressing-cleaning. The recovery tower is operated at pressure of between 30 and 1000 mmHg by operation of vacuum pump. And, the heat exchanger (14) is operated at 1200-1800 mmHg.
摘要翻译：目的：公开了通过吸附挥发性石化化合物的处理方法。构成：吸附设备由填充有硅胶和活性炭的吸附塔（11），吸附回收塔（12,13），热交换器（14），储存器（15）和真空泵组成。在吸附塔（11）中，硅胶吸附较强的可吸附化合物如戊烯，己烷或庚烷，而活性炭则较弱的可吸附化合物如甲烷，乙烷，丙烷，丁烷或戊烷。吸附过程在15-50℃和30-100mmHg下操作。吸附回收塔（12,13）通过压缩，吸附，减压和压制清洗的一个工艺周期进行。通过真空泵的操作，回收塔在30至1000mmHg的压力下运行。并且，热交换器（14）在1200-1800mmHg下运行。

9. 发明授权

KR100185288B1 연소배가스로부터 이산화탄소 회수용 2단식 흡착분리공정과 그 운전방법 失效
标题翻译：从燃烧气体中回收二氧化碳的两阶段吸附分离方法及其操作方法
公开(公告)号：KR100185288B1
公开(公告)日：1999-04-15
申请号：KR1019960047869
申请日：1996-10-24
申请人： 한국에너지기술연구원
发明人： 주국태 , 조순행 , 김종남 , 정순철
IPC分类号： B01D53/02
CPC分类号： Y02C10/04 , Y02C10/08 , Y02P20/152
摘要： PROBLEM TO BE SOLVED: To prevent a decrease in the productivity of an adsorbing and separating device due to moisture contamination at the time of using synthetic zeolite as an adsorbent to produce carbon dioxide from a waste combustion gas having a high content of moisture by connecting a predehumidifier to the carbon dioxide adsorbing and separating device and enhancing the dehumidifying effect of a dehumidification tower. SOLUTION: The adsorbing and separating device is provided with a regenerating gas- heating heat exchanger 21, a sprinkling dust removal tower 29, two tower-type dehumidifiers 23a and 23b, three tower-type one-stage adsorbing and separating devices 24a to 24c and three tower-type two-stage adsorbing and separating devices 25a to 25c to recover the carbon dioxide of >=95vol.% purity from the waste combustion gas of a steam supply and power generating plant, etc., contg. 8-15vol.% carbon dioxide. The waste gas from a cleaning stage is supplied to the adsorption tower having finished an adsorption stage among the one-stage adsorbing and separating devices 24a to 24c to recover carbon dioxide. Meanwhile, the whole amt. of the adsorbed waste gas of the two-stage adsorbing and separating devices 25a to 25c and the cleaned waste gas are heat-exchanged with the waste combustion gas to cool the waste combustion gas.

10. 发明授权

KR100124039B1 농축산소와 한외여과막을 사용한 고농도 활성슬러지 폐수처리방법 失效
标题翻译：使用超滤和浓缩氧气的活性污泥过程
公开(公告)号：KR100124039B1
公开(公告)日：1997-11-25
申请号：KR1019940026916
申请日：1994-10-21
申请人： 한국에너지기술연구원
发明人： 조순행 , 김권일 , 김종남 , 유윤종 , 장미숙
IPC分类号： C02F3/26
CPC分类号： Y02W10/15
摘要： preparing concentrated oxygens with 2-bed oxygens PSA charged with zeolite X at the oxygen concentration of 90-93% and a pressure of 0.7-1 kg/cm2; feeding the concentrated oxygens into a closed multistage active sludgy reactor to supply dissolved oxygens sufficient to maintain the high concentration of 3-15 g/l; and separating the active sludge with a tubular ultramicroscopic filter layer at a circulation linear rate of 1-3 m/s.
摘要翻译：用氧浓度为90-93％，压力为0.7-1kg / cm2的带沸石X的2-床氧PSA制备浓缩氧; 将浓缩的氧气输送到封闭的多级活性污泥反应器中以提供足以保持3-15g / l的高浓度的溶解氧; 并以1-3m / s的循环线性速率用管状超微过滤层分离活性污泥。

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