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1. 发明授权

KR101680049B1 건식 개질 촉매 및 제조방법, 해당 촉매를 이용한 건식 개질 방법 有权
标题翻译：干重整催化剂的制造方法和使用该催化剂的干重整方法
公开(公告)号：KR101680049B1
公开(公告)日：2016-11-28
申请号：KR1020150002191
申请日：2015-01-07
申请人： 한국과학기술연구원
发明人： 남석우 , 윤창원 , 김영천 , 김용민 , 한종희 , 윤성필 , 함형철 , 정지훈 , 고석근
IPC分类号： H01M4/90 , H01M8/02 , B01J37/08 , H01M8/12
CPC分类号： B01J37/08 , H01M4/90 , H01M8/02 , H01M8/12 , Y02P70/56
摘要： 니켈이트리아안정화지르코니아복합체(Ni/YSZ)에귀금속(M)이도핑된것이되, 니켈이트리아안정화지르코니아(YSZ)의표면의니켈사이트(Ni sites)에귀금속(M)과니켈의합금(M-Ni alloy)이형성된건식개질촉매및 이를귀금속/글루코스를이용하여제조하는방법, 상기촉매를이용하여건식개질을수행하는방법이제공된다. 이에따르면, Ni/YSZ 촉매와대비하여훨씬높은건식개질활성을보여줄수 있다. 또한, 열화가억제또는방지되어장기성능도향상할수 있다. 또한, 상기제조방법은 Ni/YSZ 표면의 Ni 사이트에서의귀금속-Ni의합금화를수행하는데유용하고, 또한제조공정을단순화할수 있어대량생산에적합하다.
摘要翻译：提供：其中在镍氧化钇稳定的氧化锆络合物（Ni / YSZ）中掺杂贵金属（M）的干重整催化剂和贵金属（M）和镍的合金（M-Ni合金）形成在镍氧化钇稳定氧化锆（YSZ）表面的Ni位置; 使用贵金属/葡萄糖制造干重整催化剂的方法; 以及使用该催化剂进行干重整的方法。与Ni / YSZ催化剂相比，本发明可以表现出显着更高的干重整活性。此外，通过抑制或防止劣化，本发明可以具有改善的长期性能。此外，该制备方法可用于在Ni / YSZ表面上的Ni位置处进行贵金属Ni的合金化，并且可以简化制备工艺，因此适合批量生产。

2. 发明授权

KR100307807B1 이온빔을이용하여표면개질된고분자배양접시및그표면개질방법 有权
标题翻译：离子束表面改性聚合物培养皿及其表面改性方法
公开(公告)号：KR100307807B1
公开(公告)日：2001-11-30
申请号：KR1019980054847
申请日：1998-12-14
申请人： 주식회사 삼양홀딩스 , 한국과학기술연구원
发明人： 고석근 , 정형진 , 최원국 , 최성창 , 윤영수 , 유영숙 , 정봉철
IPC分类号： C08J7/00
摘要： 본 발명은 이온빔을 이용하여 친수성으로 표면개질된 고분자 배양접시 및 그 표면 개질방법에 관한 것으로, 고분자 배양접시 표면으로, 반응성 기체를 유입시키면서 2000 eV 이하의 에너지를 가진 이온빔을 조사시킴으로써 상기 이온빔으로 고분자 배양접시의 표면을 활성화시키면서 활성화된 고분자 배양접시 표면과 상기 반응성 기체를 반응시켜 그 표면에 친수성기를 형성시키는 고분자 배양접시의 표면개질방법과 그에 의해 표면개질된 고분자 배양접시를 제공한다.

3. 发明授权

KR100287362B1 이온빔을이용한산화물기판표면의전처리방법및이를이용한질화물박막형성방법 失效
标题翻译：使用离子束的氧化物基板表面的预处理方法和使用其的氮化物膜形成方法
公开(公告)号：KR100287362B1
公开(公告)日：2001-05-02
申请号：KR1019970061766
申请日：1997-11-21
申请人： 한국과학기술연구원
发明人： 고석근 , 최원국 , 금동화 , 정형진 , 변동진
IPC分类号： H01J37/00

4. 发明公开

KR1020010026171A 플라즈마로 친수성 표면 개질된 관을 이용한 흡수식 냉동기 无效
标题翻译：吸管式制冷机采用等离子体改性表面处理
公开(公告)号：KR1020010026171A
公开(公告)日：2001-04-06
申请号：KR1019990037380
申请日：1999-09-03
申请人： 한국과학기술연구원
发明人： 강병하 , 고석근 , 김서영 , 황규대 , 박노성 , 김기환
IPC分类号： F25B15/00
CPC分类号： F25B15/00 , F28F13/182 , F28F2245/02 , Y02A30/277 , Y02B30/62
摘要： PURPOSE: An absorbing refrigeration machine is provided to achieve an improved heat or substance transfer performance while reducing the size and weight of the machine, and installation cost, by allowing the heat transfer section with a plasma hydrophilic-reformed surface to be mounted in a heat exchanger. CONSTITUTION: In an absorbing refrigeration machine consisting of an evaporator, an absorber and a condenser, a heat transfer section has a plasma hydrophilic reformed surface which is a plasma polymer film having a receding contact angle of 30 degrees or lower. Since the pipe with plasma hydrophilic reformed surface has a thin water screen formed at the surface of the pipe, heat transfer performance is improved due to the increased heat transfer surface area and decreased heat resistance.
摘要翻译：目的：提供一种吸收式制冷机，通过将具有等离子体亲水重整表面的传热部分安装在热量中来实现改进的热或物质转移性能，同时减小机器的尺寸和重量以及安装成本器。构成：在由蒸发器，吸收体和冷凝器组成的吸收性制冷机中，传热部具有等离子体亲水性重整面，其为具有30度以下的后退接触角的等离子体聚合物膜。由于具有等离子体亲水性重整表面的管具有在管表面形成的薄水屏，由于传热表面积增加和耐热性降低，传热性能得到改善。

5. 发明公开

KR1020010013160A 플라즈마를 이용한 냉동 공조용 금속 재료 표면상의고분자 중합막 합성방법 失效
标题翻译：用于制冷和空调的金属表面的等离子体聚合增强
公开(公告)号：KR1020010013160A
公开(公告)日：2001-02-26
申请号：KR1019997011143
申请日：1998-12-03
申请人： 한국과학기술연구원 , 주식회사 엘지이아이
发明人： 고석근 , 정형진 , 최원국 , 강병하 , 김기환 , 하삼철 , 김철환 , 최성창
IPC分类号： C23C16/44
CPC分类号： C23C16/503 , B05D1/62 , B05D3/148 , B05D5/083 , C23C16/30 , C23C16/50 , C23C16/515 , C23C16/56 , F25B47/003 , F28F13/18 , F28F2245/02 , F28F2245/04
摘要： PURPOSE: Provided is a plasma polymerization for forming a polymer with hydrophilicity or hydrophobicity on a surface of a material by using a DC discharge plasma or an RF discharge plasma. CONSTITUTION: A method for surface processing by plasma polymerization of a surface of a metal, for enhancing its usefulness in a refrigerating and air-conditioning apparatus by using a DC discharge plasma, comprises the steps of: (a) positioning an anode electrode which is substantially of a metal to be surface-modified and a cathode electrode in a chamber; (b) maintaining a pressure in the chamber at a predetermined vacuum level; (c) blowing a reaction gas comprising an unsaturated aliphatic hydrocarbon monomer gas at a predetermined pressure and a non-polymerizable gas at a predetermined pressure into the chamber, the non-polymerizable gas being 50-90% of the entire reaction gas; and (d) applying a voltage to the electrodes in order to obtain a DC discharge, whereby to obtain a plasma consisting of positive and negative ions and radicals generated from the unsaturated aliphatic hydrocarbon monomer gas and the non-polymerizable gas, and then forming a polymer with hydrophilicity on the surface of the anode electrode by plasma deposition.
摘要翻译：目的：提供通过使用DC放电等离子体或RF放电等离子体在材料表面形成具有亲水性或疏水性的聚合物的等离子体聚合。构成：通过等离子体聚合金属表面处理方法，通过使用DC放电等离子体来提高其在制冷空调装置中的用途，包括以下步骤：（a）将阳极电极基本上待表面改性的金属和室中的阴极电极; （b）将腔室内的压力保持在预定的真空度; （c）将预定压力的不饱和脂族烃单体气体和预定压力的不可聚合气体的反应气体吹入室内，所述非可聚合气体为整个反应气体的50-90％; 和（d）向电极施加电压以获得DC放电，从而获得由不饱和脂族烃单体气体和非可聚合气体产生的正离子和负离子和自由基组成的等离子体，然后形成通过等离子体沉积在阳极电极的表面上具有亲水性的聚合物。

6. 发明公开

KR1020000039496A 이온빔을이용하여표면개질된고분자배양접시및그표면개질방법 有权
标题翻译：聚合物培养皿表面改性利用离子束和表面改性方法
公开(公告)号：KR1020000039496A
公开(公告)日：2000-07-05
申请号：KR1019980054847
申请日：1998-12-14
申请人： 주식회사 삼양홀딩스 , 한국과학기술연구원
发明人： 고석근 , 정형진 , 최원국 , 최성창 , 윤영수 , 유영숙 , 정봉철
IPC分类号： C08J7/00
摘要： PURPOSE: A polymer culture dish having an improved hydrophilic property and surface adhesiveness is provided which a part of carbon of the activated surface is reacted with a reactive gas after activating the surface by irradiating less than 2,000 eV of ion-beam. CONSTITUTION: A surface modifying apparatus comprises a gas inlet part(20) introducing a reactive gas into a vacuum chamber(10), an ion source(30) producing ion beam, a substrate holder(40) and a vacuum pump(50). The polymer culture dish is built in the substrate holder(40) and the reactive gas is introduced into the vacuum chamber(10) through the gas inlet part(20). Ion-beam having less than 2,000 eV is irradiated to activate the surface of the polymer culture dish from the ion source(30). The surface of the polymer culture is reacted with the reactive gas such as oxygen, nitrogen, carbon dioxide, carbon monoxide, ozone and their mixed gas to produce a hydrophilic group on the surface.
摘要翻译：目的：提供具有改善的亲水性和表面粘合性的聚合物培养皿，其中活化表面的一部分碳通过照射小于2000eV的离子束而在活化表面后与反应性气体反应。构成：表面改性装置包括将反应性气体引入真空室（10）的气体入口部分（20），产生离子束的离子源（30），衬底保持器（40）和真空泵（50）。聚合物培养皿内置在基板保持件（40）中，反应气体通过气体入口部分（20）引入真空室（10）。照射小于2000eV的离子束从离子源（30）活化聚合物培养皿的表面。聚合物培养物的表面与氧，氮，二氧化碳，一氧化碳，臭氧及其混合气体等反应性气体反应，在表面产生亲水基团。

7. 发明公开

KR1019960016030A 이온 클러스터 빔을 이용한 레이저 거울의 제조방법 失效
标题翻译：离子束激光器的制造方法
公开(公告)号：KR1019960016030A
公开(公告)日：1996-05-22
申请号：KR1019940025241
申请日：1994-10-01
申请人： 한국과학기술연구원
发明人： 고석근 , 정형진 , 이지연 , 김철호
IPC分类号： H01S3/00 , H01L21/205 , H01S3/18
摘要： 본 발명은 레이저를 발생시키는 장비, 또는 레이저를 이용하는 장비에 필수적으로 장착되어야 하는 레이저 거울의 제조방법에 관한 것으로, 원자의 중착이 아닌 10
2 ∼10
3 개 원자들의 모임인 덩어리를 이온화시키고 고전압을 걸어 가속화시켜서 기판을 때림으로서 기판에서 퍼지는 현상이 일어나도록 함으로써 1. 고밀도 금속 박막, 2. 고 평탄성 금속 박막, 3. 기판과 금속간의 고 접착력, 4. 제조한 금속 박막과 기판간의 예리한 계면형성 등을 모두 만족하는 레이저 거울을 제작하도록 한 것이다.

8. 发明公开

KR1020020057507A 고분자 표면과 도금된 금속막의 접착력 향상방법 失效
标题翻译：改善聚合物和金属之间粘合力的方法
公开(公告)号：KR1020020057507A
公开(公告)日：2002-07-11
申请号：KR1020010000571
申请日：2001-01-05
申请人： 한국과학기술연구원
发明人： 고석근 , 한성 , 조준식 , 김기환
IPC分类号： C23C16/54
CPC分类号： C23C18/204 , C23C18/1641 , C23C18/2066 , H05K3/381 , H05K2203/072 , H05K2203/0723 , H05K2203/087 , H05K2203/092
摘要： PURPOSE: A method is provided to improve adhesion force between polymer and metal layer or easily form the metal layer on the polymer having low plating property without a metal seed layer, and simplify treating processes when forming the metal layer on the polymer by electroless or electrolytic plating. CONSTITUTION: The method for improving adhesion force between polymer and metal comprises the processes of partially breaking polymer bonds on the surface of the polymer by irradiating ion beams having an energy onto the polymer as injecting a reactive gas into a vacuum chamber; injecting the reactive gas into the vacuum chamber so that atoms on the surface of the bond broken polymer are reacted with the reactive gas, thereby changing the property of the surface of the polymer into hydrophilic property; and depositing a metal layer on the surface of the polymer changed into the hydrophilic property, wherein an acceleration voltage of the ion beams is 300 to 2000 V, the ion is an ionization gas such as argon, nitrogen, hydrogen, helium, oxygen, ammonia, or a mixture thereof, the reactive gas is oxygen, nitrogen, ammonia, hydrogen, or a mixture thereof, and the deposition of the metal layer is done by an electroless or electrolytic plating.
摘要翻译：目的：提供一种提高聚合物和金属层之间的粘合力或容易在不具有金属种子层的情况下形成具有低电镀性能的聚合物上的金属层的方法，并且简化在通过无电解或电解法在聚合物上形成金属层时的处理过程电镀。构成：提高聚合物和金属之间的粘合力的方法包括通过在聚合物中注入具有能量的离子束将反应性气体注入真空室来部分地破坏聚合物表面上的聚合物键的方法; 将反应性气体注入真空室中，使得断裂的聚合物表面上的原子与反应性气体反应，从而将聚合物表面的性能改变为亲水性; 并且在聚合物表面上沉积金属层变为亲水性，其中离子束的加速电压为300〜2000V，离子为氩，氮，氢，氦，氧，氨等离子化气体或其混合物，反应性气体是氧，氮，氨，氢或其混合物，并且金属层的沉积通过无电解或电解电镀进行。

9. 发明授权

KR100316586B1 재료표면의개질방법및이에의해표면개질된재료 失效
标题翻译：一种改变材料表面并由此改变表面 -
公开(公告)号：KR100316586B1
公开(公告)日：2002-02-28
申请号：KR1019960011994
申请日：1996-04-19
申请人： 한국과학기술연구원
发明人： 감직상 , 한경섭 , 최원국 , 고석근 , 정형진
IPC分类号： C08J7/00 , C03B29/00 , C08J7/12
摘要： PURPOSE: Provided are a method for modifying a polymer surface, which decrease a contact angle of the polymer surface, or increase adhesiveness of the polymer surface, and a material having surface modified by the method. CONSTITUTION: The method comprises directly blowing a reactive gas selected from oxygen, nitrogen, hydrogen, ammonia, carbon monooxide, and a mixture thereof on the polymer surface, and then irradiating an ion particle having energy of 0.5-2.5 KeV to the polymer surface to decrease a contact angle or increase an adhesion in the polymer surface. The amount of blown gas is 1-8 ml/min. The polymer is selected from polycarbonate, polymethylmethacrylate, polyimide, teflon, polyvinylidene fluoride, polyethylene terephthalate, polyethylene, and silicone rubber.

10. 发明公开

KR1020020007581A 고분자 연료전지의 제조방법 및 이 방법으로 제조된고분자 연료전지 有权
标题翻译：生产聚合物燃料电池的方法和生产的聚合物燃料电池
公开(公告)号：KR1020020007581A
公开(公告)日：2002-01-29
申请号：KR1020000040953
申请日：2000-07-18
申请人： 현대자동차주식회사 , 한국과학기술연구원
发明人： 이기춘 , 임태원 , 오인환 , 하흥용 , 최형준 , 조성아 , 홍성안 , 임태훈 , 남석우 , 고석근
IPC分类号： H01M8/10
摘要： PURPOSE: Provided is a method for producing a polymer fuel cell containing an electrolyte membrane having superior properties and a large surface area by an ion aid reaction method. CONSTITUTION: The method includes (a) irradiating an ion beam having an energy of 0.1 to 2.0 keV at 1 x 10¬13 to 1 x 10¬19 ions/cm¬2 to a polymer electrolyte membrane(11) to form concavo-convex on the surface of the polymer electrolyte membrane; (b) preparing a catalytic slurry in the presence of a solvent and a thickener; (c) coating the catalyst on both sides of the polymer electrolyte membrane to an anode electrode(12) and a cathode electrode(13); and (d) disposing a diffusion layer(14) made of carbon fibers to the outside of the produced electrodes(12,13).
摘要翻译：目的：提供一种含有电解质膜的高分子型燃料电池的制造方法，该电解质膜通过离子辅助反应法具有优异的性能和较大的表面积。方案：该方法包括（a）将具有0.1至2.0keV的能量的离子束以1×10 13至1×10 19离子/ cm 2照射到聚合物电解质膜（11）上以形成凹凸在聚合物电解质膜的表面上; （b）在溶剂和增稠剂的存在下制备催化浆料; （c）将聚合物电解质膜两侧的催化剂涂覆到阳极电极（12）和阴极电极（13）上; 和（d）将由碳纤维制成的扩散层（14）设置到所制作的电极（12,13）的外部。

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