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1. 发明公开

KR1020060086361A 지지체로서의 이온성 액체 无效
标题翻译：离子液体作为支持
公开(公告)号：KR1020060086361A
公开(公告)日：2006-07-31
申请号：KR1020067005492
申请日：2004-09-23
申请人： 토탈 리서치 앤드 테크놀로지 펠루이 , 쌍뜨르 나시오날 드 라 르셰르쉬 시앙띠피끄
发明人： 라바스뜨르올리비에 , 본네뜨파비앙 , 라자비압바스
IPC分类号： B01J31/02 , B01J23/755 , B01J31/22 , C08F10/00
CPC分类号： B01J31/143 , B01J31/0284 , B01J31/1805 , B01J2231/12 , B01J2231/20 , B01J2531/824 , B01J2531/847 , C08F110/02 , C08F4/7006
摘要： The present invention discloses a method for preparing a supported catalyst component comprising the steps of: a) providing a halogenated bisimine precursor component of formula (I); b) reacting the halogenated bisimine precursor with an ionic liquid precursor in a solvent to prepare an ionic liquid; c) reacting the ionic liquid prepared in step b) with a metallic complex of formula (II) L2MY2; wherein L is a labile ligand, M is a metal selected from Ni or Pd and Y is a halogen; d) retrieving a single site catalyst component dissolved in an ionic liquid. It also discloses an active catalyst system dissolved in an ionic liquid and its use in the polymerisation of olefins.
摘要翻译：本发明公开了一种制备载体催化剂组分的方法，包括以下步骤：a）提供式（I）的卤化双亚胺前体组分; b）使卤化双亚胺前体与离子液体前体在溶剂中反应以制备离子液体; c）使步骤b）中制备的离子液体与式（II）的金属络合物L2MY2反应; 其中L是不稳定的配体，M是选自Ni或Pd的金属，Y是卤素; d）回收溶解在离子液体中的单一位点催化剂组分。它还公开了溶解在离子液体中的活性催化剂体系及其在烯烃聚合中的用途。

2. 发明公开

KR1020070003788A 이온성 액체에 의한 중합 촉매의 불균질화 无效
标题翻译：离子液体聚合催化剂的异构化
公开(公告)号：KR1020070003788A
公开(公告)日：2007-01-05
申请号：KR1020067011524
申请日：2004-11-05
申请人： 토탈 리서치 앤드 테크놀로지 펠루이 , 쌍뜨르 나시오날 드 라 르셰르쉬 시앙띠피끄
发明人： 라바스뜨르올리비에 , 본넷뜨파비엥 , 라자비압바스
IPC分类号： C08F4/70 , C08F4/00 , C08F110/00 , C08F110/02
CPC分类号： B01J31/143 , B01J31/0284 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2531/0241 , B01J2531/824 , B01J2531/842 , B01J2531/847 , C08F10/00 , C08F110/02 , C08F2500/20 , C08F2500/24 , C08F4/7042 , C08F4/7006
摘要： The present invention discloses a method for preparing a dissolved catalyst component comprising the steps of: a) providing a halogenated precursor component of formula (I) X-([CH2-]- b) reacting the halogenated bisimine precursor with an ionic liquid precursor in a solvent to prepare an ionic liquid; c) mixing in a solvent one equivalent of the ionic liquid prepared in step b) with a metallic complex of formula (II) L2MY2 wherein L is a coordinating ligand for the metallic site, said coordination being achieved by phosphorus, nitrogen or oxygen; d) evaporating the solvent; and e) retrieving a hybrid single site catalyst component/ionic liquid system. It also discloses an active catalyst system heterogenised by an ionic liquid and its use in the polymerisation of olefins. ® KIPO & WIPO 2007
摘要翻译：本发明公开了一种制备溶解的催化剂组分的方法，包括以下步骤：a）提供式（I）的卤化前体组分，X - （[CH 2 - ] - b）使卤代双亚胺前体与离子液体前体反应制备离子液体的溶剂; c）在溶剂中将一当量的步骤b）中制备的离子液体与式（II）L2MY2的金属络合物混合，其中L是金属位点的配位配体，所述配位通过磷，氮或氧来实现; d）蒸发溶剂; 和e）检索混合单位点催化剂组分/离子液体体系。它还公开了由离子液体异源化的活性催化剂体系及其在烯烃聚合中的用途。 ®KIPO＆WIPO 2007

3. 发明公开

KR1020070004648A 지지체 상에 전이금속 착물의 그래프팅 无效
标题翻译：过渡金属复合材料在支撑物上的应用
公开(公告)号：KR1020070004648A
公开(公告)日：2007-01-09
申请号：KR1020067017275
申请日：2005-01-20
申请人： 토탈 리서치 앤드 테크놀로지 펠루이 , 쌍뜨르 나시오날 드 라 르셰르쉬 시앙띠피끄
发明人： 바네필리쁘 , 브뤼넬다니엘 , 파쥘라프랑수아 , 레르네당 , 라자비압바스
IPC分类号： C08F4/16 , B01J31/00 , C08F4/00 , C08F10/00
CPC分类号： C08F10/00 , C08F4/64058 , C08F4/025 , C08F4/7042 , C08F4/7006
摘要： The present invention discloses a method for supporting a transition metal complex and the resulting supported catalyst component which is characterised in that the metallic sites are kept away from one another and kept away from the surface of the support. ® KIPO & WIPO 2007
摘要翻译：本发明公开了一种负载过渡金属络合物的方法及所得到的负载型催化剂成分，其特征在于金属部位彼此远离并远离支持体表面。 ®KIPO＆WIPO 2007

4. 发明公开

KR1020060128844A 2 모드 폴리에틸렌 无效
标题翻译：双模聚乙烯
公开(公告)号：KR1020060128844A
公开(公告)日：2006-12-14
申请号：KR1020067005524
申请日：2004-09-23
申请人： 토탈 리서치 앤드 테크놀로지 펠루이 , 쌍뜨르 나시오날 드 라 르셰르쉬 시앙띠피끄
发明人： 라바스트르올리비에 , 갈라르로랑 , 라자비압바스
IPC分类号： C08F10/02 , C08F110/02 , C08F10/00 , C07F15/02
CPC分类号： C08F110/02 , C07B2200/11 , C07F15/025 , C08F10/00 , C08F4/027 , C08F2/001 , C08F2500/05 , C08F4/7042
摘要： The present invention discloses a method for preparing a catalyst component suitable for the preparation of bimodal polymers that comprises the steps of: a) providing hollow beads of polyethylene of controlled morphology and size; b) drying the hollow beads under vacuum; c) impregnating the dried hollow beads with a concentrated solution of the desired catalyst component under vacuum; d) submitting the impregnated hollow beads to atmospheric pressure; e) draining excess liquid; f) drying under inert gas at atmospheric pressure. It also discloses a method for preparing bimodal polymers that uses the new catalyst component catalyst.
摘要翻译：本发明公开了一种制备适于制备双峰聚合物的催化剂组分的方法，包括以下步骤：a）提供具有受控形态和尺寸的聚乙烯空心珠; b）真空干燥空心珠; c）在真空下用所需催化剂组分的浓缩溶液浸渍干燥的中空珠粒; d）将浸渍的空心珠粒提供到大气压; e）排出多余的液体; f）在大气压下在惰性气体下干燥。它还公开了一种使用新的催化剂组分催化剂制备双峰聚合物的方法。

5. 发明公开

KR1020050118275A 8 핵 니켈 클러스터계 소중합 촉매 无效
标题翻译：基于十二烷基镍聚合物的低聚物催化剂
公开(公告)号：KR1020050118275A
公开(公告)日：2005-12-16
申请号：KR1020057016527
申请日：2004-03-02
申请人： 토탈 리서치 앤드 테크놀로지 펠루이 , 쌍뜨르 나시오날 드 라 르셰르쉬 시앙띠피끄
发明人： 라바스트르올리비예 , 일라이레까롤린 , 라자비압바스
IPC分类号： B01J31/22 , B01J31/24 , C07C2/32
CPC分类号： B01J31/143 , B01J31/2208 , B01J31/2404 , B01J2231/12 , B01J2231/20 , B01J2531/0211 , B01J2531/847 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07C2531/30 , C08F110/02 , C08F110/06 , C08F110/08 , C07C11/02 , C08F2500/02
摘要： The present invention discloses a catalyst component based upon a Nib cluster made of two sheets each containing four nickel atoms and that is the reaction product of: a) a first component of the general formula (I) b) a second component based on complex, of the general formula (II) wherein in the first component, the benzene ring can be substituted in positions 3 and/or position 4 and/or position 5 and/or position 6, wherein R and R' are the same or different and can be selected from a phenyl, substituted or unsubstituted or a cycloalkyl or an alkyl having from 1 to 20 carbon atoms, wherein Q is a cation, and wherein, in the second component, R" is selected from a halogen or an acetate and wherein the two arrows mean that there are two vacant sites. It also discloses a catalyst system and a process for the oligomerisation of olefins.
摘要翻译：本发明公开了一种催化剂组分，该催化剂组分基于由两个片材制成的每个包含四个镍原子的Nib团簇，其是以下物质的反应产物：a）通式（I）的第一组分b）基于络合物的第二组分，通式（II）其中在第一组分中苯环可以在3位和/或4位和/或5位和/或6位上被取代，其中R和R'相同或不同，并且可以选自苯基，取代或未取代的或环烷基或具有1至20个碳原子的烷基，其中Q是阳离子，并且其中在第二组分中，R“选自卤素或乙酸酯，并且其中两个箭头表示有两个空位，还公开了一种催化剂体系和烯烃低聚方法。

6. 发明公开

KR1020060063871A 프로필렌-스티렌 공중합 방법 无效
标题翻译：丙烯 - 苯乙烯共聚物工艺
公开(公告)号：KR1020060063871A
公开(公告)日：2006-06-12
申请号：KR1020067000154
申请日：2004-06-28
申请人： 토탈 리서치 앤드 테크놀로지 펠루이
发明人： 라자비압바스 , 까르빵띠에장-프랑수아 , 키리로프에프구에니
IPC分类号： C08F210/06 , C08F212/08 , C08F210/00 , C08F212/00
CPC分类号： C08F212/08 , C08F210/06 , C08F2420/02 , C08F4/76 , C08F4/6592
摘要： Provided is a method for the production of a copolymer of styrene and propylene, which method comprises copolymerising styrene and propylene in the presence of a metallocene catalyst, wherein the metallocene catalyst comprises a metallocene having the either formula (I): R"(CpRm) (FluR'n)MQ2 wherein Cp comprises a cyclo pentad ienyl ring; Flu comprises a fluorenyl ring; R" comprises a structural bridge imparting stereorigidity to the component; each R is the same or different and is an organic group; m is an integer of from 0-4; each R' is the same or different and is an organic group; n is an integer of from 0-8; M is a metal atom from group IVB of the Periodic Table or is vanadium; and each Q is a hydrocarbon having from 1-20 carbon atoms or is a halogen; or formula (II): R"(FluR'n)XR$MQp (II) wherein R(FluR'n), R'', M and Q are as defied hcre-above; R$ is hydrogen or a hydrocarbyl group having from 1- 20 carbon atoms; X is a heteroatom from group 15 or 16 of the Periodic Table.
摘要翻译：提供了一种制备苯乙烯和丙烯的共聚物的方法，该方法包括在金属茂催化剂存在下使苯乙烯和丙烯共聚，其中茂金属催化剂包含具有式（I）的金属茂：R“（CpRm）（FluR'n）MQ2其中Cp包含环五烯基环; Flu包含芴基环; R“包括赋予组分立体刚性的结构桥; 每个R相同或不同，为有机基团; m为0-4的整数; 每个R'相同或不同，为有机基团; n为0-8的整数; M是元素周期表IVB族的金属原子，或是钒; 并且每个Q是具有1-20个碳原子的烃或是卤素; 或式（II）：R“（FluR'n）XR $ MQp（II）其中R（FluR'n），R”，M和Q如上所述; R $为氢或具有 1-20个碳原子; X是周期表第15或16族的杂原子。

7. 发明公开

KR1020060063873A 2 개의 연속 교반 탱크 반응기를 사용하여 메탈로센 촉매로바이모달 폴리올레핀을 제조하는 방법 无效
标题翻译：使用两台连续搅拌的罐式反应器生产金属茂催化剂的二元聚合物的工艺
公开(公告)号：KR1020060063873A
公开(公告)日：2006-06-12
申请号：KR1020067000231
申请日：2004-07-06
申请人： 토탈 리서치 앤드 테크놀로지 펠루이
发明人： 라자비압바스
IPC分类号： C08F10/00 , C08F4/659 , C08F2/01 , C08F10/02
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08L23/0815 , C08L2205/02 , C08L2314/06 , C08F2/001 , C08F4/65927 , C08L2666/04 , C08F210/14 , C08F2500/12
摘要： This invention discloses a process for the preparation of polyolefi ns having a bi-or multimodal molecular weight distribution comprising the steps of: (i) contacting olefin monomer and a first co-reactant with a catalyst system in a first continuously stirred reactor under first polymerisation conditions to produce a product comprising a first polyolefin having a first molecular weight distribution; and (ii) contacting olefin monomer and a second co-reactant with a catalyst system in a second continuously stirred reactor under second polymerisation conditions to produce a product comprising a second polyolefin having a second molecular weight distribution that is different from the first molecular weight distribution; wherein the first and second continuously stirred reactors are connected in series, and the first and second polyolefins are mixed together, and wherein one of the co-reactants is hydrogen and the other is a comonomer, and wherein each catalyst system comprises (a) a bisindenyl catalyst component; and (b) an activating agent which activates the catalyst component.
摘要翻译：本发明公开了一种制备具有双分子或多峰分子量分布的聚烯烃的方法，包括以下步骤：（i）在第一次聚合下在第一连续搅拌的反应器中使烯烃单体和第一共反应物与催化剂体系接触产生包含具有第一分子量分布的第一聚烯烃的产品的条件; 和（ii）在第二聚合条件下在第二连续搅拌的反应器中将烯烃单体和第二共反应物与催化剂体系接触以产生包含具有不同于第一分子量分布的第二分子量分布的第二聚烯烃的产物 ; 其中所述第一和第二连续搅拌的反应器串联连接，并且所述第一和第二聚烯烃混合在一起，并且其中所述共反应物之一是氢，另一个是共聚单体，并且其中每个催化剂体系包含（a）双茚基催化剂组分; 和（b）活化催化剂组分的活化剂。

8. 发明公开

KR1020050094426A 시클로펜타디에닐-플루오레닐 리간드계 ＩＩＩ족 가교메탈로센 无效
标题翻译：基于环戊二烯基氟化物配体的III族桥联金属
公开(公告)号：KR1020050094426A
公开(公告)日：2005-09-27
申请号：KR1020057012622
申请日：2004-01-06
申请人： 토탈 리서치 앤드 테크놀로지 펠루이 , 상뜨로 나쇼날 드 라 러쉐르쉐 샹띠피크
发明人： 카르빵띠에장-프랑수아 , 끼릴로프예브게니 , 라자비압바스
IPC分类号： C08F4/52 , C08F112/08 , C08F120/06
CPC分类号： C08F4/52 , C07F17/00 , C08F10/00 , Y10S526/943
摘要： The present invention discloses a metallocene catalyst component of formula (Flu-R"-Cp)M(eta3-C3R'5) (ether)n (I) wherein Cp is a cyclopentadienyl, substituted or unsubstituted, Flu is a fluorenyl, substituted or unsubstitutted, R" is a structural bridge between Cp and Flu imparting stereorigidity to the component, M is a metal Group III of the Periodic Table, each R' is the same or different and is hydrogen or a hydrocarbyl having from 1 to 20 carbon atoms and n is 0, 1 or 2. It further discloses a process for preparing said catalyst component and its used in the controlled polymerisation of polar or non polar monomers.
摘要翻译：本发明公开了式（Flu-R“-Cp）M（eta3-C3R'5）（醚）n（I）的茂金属催化剂组分，其中Cp是环戊二烯基，取代或未取代的，Flu是芴基，取代或未构成的，R“是Cp和Flu赋予组分立体刚性之间的结构桥，M是周期表的金属III族，每个R'相同或不同，是氢或具有1至20个碳原子的烃基并且n为0,1或2.进一步公开了一种制备所述催化剂组分的方法及其用于极性或非极性单体的受控聚合。

9. 发明授权

KR101086603B1 단일 반응기에서 이정점 폴리올레핀의 제조를 위한하프노센 성분을 포함하는 두자리 촉매계 失效
标题翻译：包含用于在单反应器中生产双模聚合物的高分子组分的双界面催化剂体系
公开(公告)号：KR101086603B1
公开(公告)日：2011-11-23
申请号：KR1020057005317
申请日：2003-09-24
申请人： 토탈 리서치 앤드 테크놀로지 펠루이
发明人： 라자비압바스
IPC分类号： C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/941 , Y10S526/943 , C08F4/65904 , C08F4/70
摘要： 본 발명은
A. 폴리올레핀의 고분자량 분획을 제조하기에 적절한 하프노센계 촉매 성분;
B. 성분 A와 상이하고 폴리올레핀의 저분자량 분획을 제조하기에 적절한 1 이상의 메탈로센 또는 포스트-메탈로센 성분;
C. 배위능이 낮거나 전혀 없는 활성화제
를 포함하는, 폴리올레핀 제조용 메탈로센 촉매계에 관한 것이다.

10. 发明公开

KR1020050083899A 폴리올레핀 제조 无效
标题翻译：聚烯烃生产
公开(公告)号：KR1020050083899A
公开(公告)日：2005-08-26
申请号：KR1020057009044
申请日：2003-11-19
申请人： 토탈 리서치 앤드 테크놀로지 펠루이
发明人： 라자비압바스
IPC分类号： C08F4/64 , C08F10/00 , C08F4/642
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/65927 , C08F210/14
摘要： Provided is a catalyst component for producing a polyolefin, which catalyst component comprises a metallocene catalyst having a structure according to a formula (I): Cp1Cp2R"MQp wherein Cp1 and Cp2are each independently a cyclopentadienyl derivative which may be substituted or unsubstituted and are selected from cyclopentadienyl groups, indenyl groups and fluorenyl groups, provided that at least one of the cyclopentadienyl derivatives comprises an N atom or a P atom in it cyclopentadienyl ring; R" is a structural bridge to impart stereorigidity between Cp1 and Cp 2; and when only one of Cp1 and Cp2 comprises a P atom in its cyclopentadienyl ring, R" is attached to that phosphorous atom, or is attached to a carbon atom in the cylopentadienyl ring distal to that phosphorous atom; and when one of Cp1 or Cp2 comprises an indenyl group and the other of Cp1 and Cp2comprises an indolyl group, R" is attached either directly to the N atom of the indolyl group or to a carbon atom that is vicinal to the N atom; M is a metal from Group IIIB, IVB, VB or VIB; Q is a hydrocarbyl group having from 1-20 carbon atoms, or a halogen; and p is the valence of M minus 2.
摘要翻译：提供了一种用于制备聚烯烃的催化剂组分，该催化剂组分包括具有式（I）结构的茂金属催化剂：Cp1Cp2R“MQp其中Cp1和Cp2各自独立地为可取代或未取代的环戊二烯基衍生物，环戊二烯基，茚基和芴基，条件是至少一种环戊二烯基衍生物在其中包含N原子或P原子，环戊二烯基环; R“是赋予Cp1和Cp2之间立体刚性的结构桥; 当Cp1和Cp2中只有一个在其环戊二烯基环中包含一个P原子时，R“连接到该磷原子上，或连接到该磷原子远端的环戊二烯基环中的碳原子;当Cp1或Cp2之一包含茚基，Cp1和Cp2中的另一个包含吲哚基，R“直接连接到吲哚基的N原子或与N原子相邻的碳原子; M是IIIB，IVB，VB或VIB族的金属; Q是具有1-20个碳原子的烃基或卤素; 而p是M的价数减去2。

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