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1. 发明授权

KR101778407B1 코크스로 배가스 전처리 및 SCR을 이용한 질소산화물의 제거 방법 有权
标题翻译：用焦炭和SCR预处理烟气脱除氮氧化物
公开(公告)号：KR101778407B1
公开(公告)日：2017-09-26
申请号：KR1020150186059
申请日：2015-12-24
申请人： 주식회사 포스코 , 재단법인 포항산업과학연구원
发明人： 신동남 , 변영철 , 김병억 , 양희정 , 정운식 , 최길은
IPC分类号： B01D53/86 , B01D53/56 , B01D53/75 , B01D53/04 , B01D51/00 , B01D46/00
摘要： 본발명은여과집진기전단부에흡착제를주입하여촉매피독물질및 다이옥신을제거하는단계; 및코크스로리버싱타임에맞추어 SCR 환원제의주입주기를제어하면서 NOx를제거하는단계를포함하는코크스로배가스전처리및 SCR을이용한질소산화물제거방법을제공한다.
摘要翻译：本发明涉及一种净化催化剂的方法，该方法包括以下步骤：在过滤除尘器的前端注入吸附剂以除去催化剂中毒物质和二恶英; 本发明还提供了一种利用焦炉煤气预处理和SCR去除氮氧化物的方法，该方法包括以下步骤：

2. 发明公开

KR1020170076150A 코크스로 배가스 전처리 및 SCR을 이용한 질소산화물의 제거 방법 有权
公开(公告)号：KR1020170076150A
公开(公告)日：2017-07-04
申请号：KR1020150186059
申请日：2015-12-24
申请人： 주식회사 포스코 , 재단법인 포항산업과학연구원
发明人： 신동남 , 변영철 , 김병억 , 양희정 , 정운식 , 최길은
IPC分类号： B01D53/86 , B01D53/56 , B01D53/75 , B01D53/04 , B01D51/00 , B01D46/00
摘要： 본발명은여과집진기전단부에흡착제를주입하여촉매피독물질및 다이옥신을제거하는단계; 및코크스로리버싱타임에맞추어 SCR 환원제의주입주기를제어하면서 NOx를제거하는단계를포함하는코크스로배가스전처리및 SCR을이용한질소산화물제거방법을제공한다.

3. 发明公开

KR1020100073390A 폐수 중에 함유된 중금속 저감장치 无效
标题翻译：在废水中去除重金属的装置
公开(公告)号：KR1020100073390A
公开(公告)日：2010-07-01
申请号：KR1020080132049
申请日：2008-12-23
申请人： 재단법인 포항산업과학연구원
发明人： 김민균 , 김병억
IPC分类号： C02F3/10 , B01D39/00 , B01D35/00 , C02F1/62
CPC分类号： Y02W10/15 , C02F1/283 , B09B3/00 , C02F1/62 , C02F2101/20
摘要： PURPOSE: A heavy metal reducing device is provided to remove heavy metals in wastewater, and to improve inconvenience for treating waste by using stainless steel-making slag which is a by-product for making slag to recycle the stainless steel-making slag. CONSTITUTION: A heavy metal reducing device fills stainless steel-making slag(11) in a filter as fillings to remove heavy metals contained in wastewater. The stainless steel-making slag is pulverized to a diameter of 1mm or less. The stainless steel-making slag is heat-treated after being processed with a sodium hydroxide solution. The stainless steel-making slag is heat-treated for 12 hours at 300 degrees.
摘要翻译：目的：提供一种重金属还原装置，用于去除废水中的重金属，并通过使用不锈钢制成的炉渣来改善处理废物的不便，而不锈钢制造炉渣是用于使炉渣回收不锈钢制造炉渣的副产物。构成：重金属还原装置在过滤器中填充不锈钢制成的渣（11）作为填充物，以除去废水中所含的重金属。将不锈钢制造的炉渣粉碎至1mm以下的直径。在用氢氧化钠溶液处理后对不锈钢制造的炉渣进行热处理。不锈钢制造渣在300度下热处理12小时。

4. 发明公开

KR1020090067670A 하수 슬러지에서 ＰＦＯＳ 또는 ＰＦＯＡ를 제거하는 방법 无效
标题翻译：废除污水中PFOS或PFOA的方法
公开(公告)号：KR1020090067670A
公开(公告)日：2009-06-25
申请号：KR1020070135409
申请日：2007-12-21
申请人： 재단법인 포항산업과학연구원
发明人： 김병억 , 김민균 , 사영삼
IPC分类号： C02F11/14 , C02F1/30 , C02F9/00
CPC分类号： C02F11/14 , C02F1/30 , C02F9/00 , C02F2201/002
摘要： A method for removing PFOS(Perfluorooctane Sulfonate) or PFOA(Perfluorooctanoic Acid) from sewage sludge inexpensively and safely is provided. A method for removing PFOS(Perfluorooctane Sulfonate) or PFOA(Perfluorooctanoic Acid) from sewage sludge comprises a step(S1) of adding an oxidizer to sewage sludge containing PFOS or PFOA and a step(S2) of irradiating electromagnetic waves to the sewage sludge. The oxidizer is hydrogen peroxide or superphosphate. The electromagnetic waves are irradiated to the sewage sludge at a frequency of 2000 to 2500 MHz and an output of 80 to 120W for 2 to 10 minutes.
摘要翻译：提供了从污水污泥中廉价，安全地去除PFOS（全氟辛烷磺酸盐）或PFOA（全氟辛酸）的方法。从污水污泥中除去PFOS（全氟辛烷磺酸盐）或PFOA（全氟辛酸）的方法包括向含有PFOS或PFOA的污水污泥添加氧化剂的步骤（S1）和向污水污泥照射电磁波的步骤（S2）。氧化剂是过氧化氢或过磷酸盐。电磁波以2000〜2500MHz的频率和80〜120W的输出照射到污水污泥2〜10分钟。

5. 发明公开

KR1020090067664A 토양에서 ＰＦＯＳ 또는 ＰＦＯＡ를 제거하는 방법 失效
标题翻译：在土壤中去除PFOS或PFOA的方法
公开(公告)号：KR1020090067664A
公开(公告)日：2009-06-25
申请号：KR1020070135403
申请日：2007-12-21
申请人： 재단법인 포항산업과학연구원
发明人： 김병억 , 김민균 , 사영삼
IPC分类号： B09C1/08
CPC分类号： B09C1/08 , A62D3/30
摘要： A method for removing PFOS(Perfluorooctane Sulfonate) and PFOA(Perfluorooctanoic Acid) from soil is provided to effectively remove the PFOS or PFOA contained in the soil and maintain a neutral pH suitable for the growth of the crops in the soil. A method for removing PFOS(Perfluorooctane Sulfonate) and PFOA(Perfluorooctanoic Acid) from soil comprises: a step(S1) of preparing soil contaminated with PFOS or PFOA; and a step of purifying the contaminated soil using iron oxides and sodium borohydride(NaBH4) as decomposition agents. The step of purifying the contaminated soil comprises a step(S2) of adding 1 to 100 parts by weight of the decomposition agents to 100 parts by weight of the contaminated soil and a step(S3) of leaving the decomposition agent-added soil alone for 5 days or more. The iron oxides including Fe2O3 and FeO are by-products of the pickling process in the ironmaking process. The iron oxides are formed in the form of a powder having an average particle diameter of 0.2 to 50 microns.
摘要翻译：提供从土壤中去除PFOS（全氟辛烷磺酸盐）和PFOA（全氟辛酸）的方法，以有效去除土壤中所含的全氟辛烷磺酸或PFOA，并保持适合土壤中作物生长的中性pH。从土壤中去除PFOS（全氟辛烷磺酸盐）和PFOA（全氟辛酸）的方法包括：制备受PFOS或PFOA污染的土壤的步骤（S1）; 以及使用氧化铁和硼氢化钠（NaBH4）作为分解剂来净化污染土壤的步骤。净化污染土壤的步骤包括向100重量份的污染土壤中加入1至100重量份的分解剂的步骤（S2）和将分解剂添加的土壤单独留下的步骤（S3） 5天以上。包括Fe2O3和FeO在内的铁氧化物是炼铁过程中酸洗工艺的副产物。铁氧化物以平均粒径为0.2至50微米的粉末的形式形成。

6. 发明公开

KR1020060071566A 기름에 함유된 폴리염화비페닐의 무해화 처리방법 无效
标题翻译：变压器油中PCBS的处理方法
公开(公告)号：KR1020060071566A
公开(公告)日：2006-06-27
申请号：KR1020040110186
申请日：2004-12-22
申请人： 재단법인 포항산업과학연구원
发明人： 김병억 , 김민균 , 사영삼
IPC分类号： A62D3/00 , A62D3/30 , B01J20/00 , B01D17/02
CPC分类号： A62D3/30 , B01D17/0202 , B01J20/00
摘要： 본 발명은 기름에 함유된 폴리염화비페닐의 무해화 처리방법을 제공하기 위한 것으로, 산화칼슘과 오일을 혼합하여 소수성의 산화칼슘을 제조하는 제 1 단계와; 상기 제 1 단계에서 제조된 소수성의 산화칼슘을 기름 분해제, 이온 교환성 다공체와 함께 변압기 오일에 혼합하여 방치하는 제 2 단계로 이루어진다.
상기의 본 발명에 의한 기름에 함유된 폴리염화비페닐의 무해화 처리방법은 기름이 첨착되고 소수성이 부여된 산화칼슘, 흡착과 이온 교환성이 있는 다공체, 폴리염화비페닐을 함유한 기름 및 상기 산화칼슘에 첨착한 기름을 분해하는 기름분해제를 사용하여 간단하게 저온에서 유분을 분해하여 분말화함과 동시에 이온 교환성에 의한 폴리염화비페닐의 염소를 유리시켜 무해한 염소화합물로 변화시킬수 있는 방법을 제공하여 폴리염화비페닐 함유 기름을 포스겐, 다이옥신 등의 독성이 강한 물질이 발생되는 염려가 없고, 안전하게 무해화 처리할 수 있는 효과가 있다.
폴리염화비페닐, Poly Chlorinated Biphenyls, PCBs, 무해화

7. 发明授权

KR100440465B1 옥타클로로디벤조퓨란의 정량 방법 失效
标题翻译： 옥타클로로디벤조퓨란의정량방법
公开(公告)号：KR100440465B1
公开(公告)日：2004-07-15
申请号：KR1020000049299
申请日：2000-08-24
申请人： 재단법인 포항산업과학연구원
发明人： 김병억 , 김민균 , 사영삼 , 탁진권
IPC分类号： C07D307/91
摘要： PURPOSE: Provided is a method for quantifying octachlorodibenzofuran by non-polar gas chromatography column coated with stationary phase of which the functional group having a high polarity is substituted with alkylsilyl group. CONSTITUTION: Octachlorodibenzofuran is quantified by using non-polar gas chromatography column which is pre-treated by the steps of: inserting a solution of alkylsilyl group dissolved in polar solvent into polar gas chromatography column, in an oven of 220-275 deg.C; then inserting a solution of lower(primary)alcohol dissolved in non-polar solvent. Where, the non-polar solvent is selected from the group consisting of C5-C6 saturated hydrocarbon and the lower(primary)alcohol is selected from the group consisting of C1-C3 primary alcohol.
摘要翻译：目的：提供一种用非极性气相色谱柱定量八氯二苯并呋喃的方法，所述非极性气相色谱柱用固定相涂覆，其中具有高极性的官能团被烷基甲硅烷基取代。构成：使用非极性气相色谱柱对八氯二苯并呋喃进行定量，所述非极性气相色谱柱通过以下步骤进行预处理：将溶解在极性溶剂中的烷基甲硅烷基溶液置于极性气相色谱柱中，在220-275℃的烘箱中; 然后插入溶解在非极性溶剂中的低级（伯）醇的溶液。其中，非极性溶剂选自C5-C6饱和烃，较低（伯）醇选自C1-C3伯醇。

8. 发明公开

KR1020040056538A 다이옥신 저감능이 개선된 소각로용 여과포 및 그의 제조방법 无效
标题翻译：二氧化碳还原效率改进的用于焚烧炉的过滤织物及其制造方法
公开(公告)号：KR1020040056538A
公开(公告)日：2004-07-01
申请号：KR1020020083039
申请日：2002-12-24
申请人： 재단법인 포항산업과학연구원
发明人： 김민균 , 김병억
IPC分类号： B01D39/08
CPC分类号： B01D39/08 , B01D2239/0492 , B01D2239/06 , B01D2239/10 , D06M11/45 , F23G7/06
摘要： PURPOSE: A manufacturing method of dioxin reduction efficiency improved filter fabric for incinerator is provided to manufacture filter fabric capable of removing dioxin effectively and economically, and a dioxin reduction efficiency improved filter fabric for incinerator manufactured by the manufacturing method is provided. CONSTITUTION: The method comprises a process of spraying alumina (Al2O3) having an average diameter of 15 to 20 μm onto filter fabric for incinerator in a discharge flux of 100 to 200 mg/Nm¬3, wherein the spraying process is performed in the state that the filter fabric is installed at the incinerator. The dioxin reduction efficiency improved filter fabric for incinerator comprises alumina (Al2O3) having an average diameter of 15 to 20 μm.
摘要翻译：目的：提供二恶英还原效率的制造方法，改善焚烧炉用滤布，以制造能够有效且经济地除去二恶英的滤布，并且提供通过该制造方法制造的焚化炉的二恶英还原效率提高。构成：该方法包括将平均粒径为15〜20μm的氧化铝（Al 2 O 3）喷涂在100〜200mg / Nm 3的放电焊剂中的焚烧炉用滤布上，其中，喷雾处理以该状态进行过滤织物安装在焚烧炉上。二恶英还原效率提高，焚烧炉用滤布包含平均粒径为15〜20μm的氧化铝（Al2O3）。

9. 发明授权

KR100435421B1 비산재에 포함된 다이옥신 정량방법 失效
标题翻译：通过电子邮件发送给朋友
公开(公告)号：KR100435421B1
公开(公告)日：2004-06-10
申请号：KR1019990059500
申请日：1999-12-20
申请人： 재단법인 포항산업과학연구원
发明人： 김병억 , 김민균 , 사영삼 , 탁진권
IPC分类号： G01N31/00
摘要： PURPOSE: A quantifying method of dioxin contained in fly ash is provided to obtain a correlation formula between a concentration of Chlorine ions and a concentration of dioxin for simply and reliably obtaining a content of dioxin without carrying out any complicated pre-processing for quantifying dioxin or using any high precision quantifying machines. CONSTITUTION: A quantifying method of dioxin contained in fly ash includes the steps of removing inorganic chlorine ions by cleaning the fly ash, dissolving the cleaned fly ash with acid to dissolve the chlorine ions and quantifying the concentration of the Chlorine ions, and obtaining a whole dioxin concentration by a formula(whole dioxin concentration(ng/g)=2.80x10-2(Chlorine ion concentration in the sample(microgram/g))1.45(R=0.829)) on the basis of the concentration of the Chlorine ions.
摘要翻译：目的：提供一种飞灰中所含二恶英的定量方法，以获得氯离子浓度与二恶英浓度之间的相关公式，以简单且可靠地获得二恶英含量，而无需进行任何复杂的用于定量二恶英的预处理或使用任何高精度量化机器。本发明提供了一种飞灰中二恶英的定量方法，包括通过清除飞灰去除无机氯离子，用酸溶解清洗后的飞灰溶解氯离子并定量氯离子浓度，得到一个完整的基于氯离子的浓度，通过公式（全二氧己二
烯浓度（ng / g）= 2.80×10-2（样品中的氯离子浓度（微克/克））1.45（R = 0.829）

10. 发明公开

KR1020000042038A 활성화된 구리 파우더를 이용한 다이옥신 분석시료의 전처리방법 无效
标题翻译：使用激活铜粉预处理二氧化硅样品的方法
公开(公告)号：KR1020000042038A
公开(公告)日：2000-07-15
申请号：KR1019980058106
申请日：1998-12-24
申请人： 재단법인 포항산업과학연구원 , 주식회사 포스코
发明人： 김병억 , 탁진권 , 김경태 , 김민균
IPC分类号： G01N1/28
摘要： PURPOSE: A method for pretreating dioxine sample is provided, before the quantitative analysis of dioxine, especially 2,3,7,8-tetrachlorinated dibenzo-p-dioxine. CONSTITUTION: A method comprises the steps of activating copper powder at 450-600°C for 4-24 hours, cooling the copper powder slowly, and storing it at 130°C; dissolving dioxine-containing sample in n-hexane or toluene, adding the activated copper powder into the dioxine sample solution, stirring the solution until the color of copper precipitates does not change, and sinking the copper precipitates; extracting dioxine with n-hexane at least twice, and concentrating the solution to about 1 ml; injecting the concentrated sample into the activated carbon column, carrying out the chromatography, and re-concentrating the eluted dioxine to 50-100 microliters; and analyzing the re-concentrated dioxine sample by HPGC/MS.
摘要翻译：目的：在二恶英定量分析前，特别是2,3,7,8-四氯化二苯并对二恶英进行预处理二恶英样品的方法。构成：一种方法包括在450-600℃下活化铜粉4-24小时，缓慢冷却铜粉并将其储存在130℃的步骤; 将含二恶英的样品溶解在正己烷或甲苯中，将活化的铜粉加入到二恶烷样品溶液中，搅拌溶液直到铜沉淀物的颜色不变，沉淀铜沉淀; 用正己烷萃取二恶英至少两次，并将溶液浓缩至约1ml; 将浓缩样品注入活性炭柱，进行色谱，并将洗脱的二恶烷浓缩至50-100微升; 并通过HPGC / MS分析重浓缩的二恶英样品。

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