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    • 1. 发明公开
    • 이포름산나트륨의 제조
    • 生产SODIUM DIFORMATE
    • KR1020080007345A
    • 2008-01-18
    • KR1020077025541
    • 2006-05-02
    • 바스프 에스이
    • 하욱,알렉산더그로프,슈테판렌츠,로버트리크,다니엘라하일렉,요에르크라욱스,게르하르트
    • C07C51/41C07C53/06C07C53/02
    • C07C51/412C07C53/06
    • The invention relates to a method for producing a solid sodium diformate preparation having a minimum formic acid concentration of 35 percent by weight relative to the total weight of the sodium diformate preparation. According to said method, an aqueous solution having a molar ratio HCOOH: HCOONa of more than 1.5:1 and a molar ratio HCOOH: H2O of at least 1.1:1 is produced from sodium formate and at least 74 percent by weight of formic acid at an elevated temperature, the aqueous solution is crystallized, and the solid phase is separated from the mother liquor. (i) A partial amount (A) of the mother liquor is used during the production of the aqueous solution while (ii) a partial amount (B) of the mother liquor is mixed with a sodium-containing base and the obtained sodium formate-containing mixture is also used during the production of the aqueous solution, optionally after separating a portion of the same and optionally after concentrating the same, the partial amounts (A) and (B) of the mother liquor amounting to 100 percent by weight.
    • 本发明涉及相对于二甲酸钠制剂的总重量,具有35重量%的最小甲酸浓度的固体二甲酸钠制剂的制备方法。 根据所述方法,由HCOOH:HCOONa的摩尔比大于1.5:1,HCOOH:H2O的摩尔比至少为1.1:1的水溶液由甲酸钠和至少74重量%的甲酸生成, 升高的温度,水溶液结晶,并将固相与母液分离。 (i)在制造水溶液期间使用母液的部分量(A),同时(ii)将一部分(B)母液与含钠碱混合,得到的甲酸钠 - 在制备水溶液时也可以使用含水混合物,任选地在分离其一部分后,任选地在浓缩之后,母液的部分量(A)和(B)均为100重量%。