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1. 发明授权

KR100911136B1 반응성 티에노티오펜 失效
标题翻译：反应性三硝基苯
公开(公告)号：KR100911136B1
公开(公告)日：2009-08-06
申请号：KR1020020039135
申请日：2002-07-06
申请人： 메르크 파텐트 게엠베하
发明人： 파란드루이스 , 톰슨마르쿠스 , 길스마크 , 골딩마크 , 히니마틴 , 티어니스티븐 , 쉬쿠노브맥심 , 스파로웨데이비드 , 맥쿨로치이아인
IPC分类号： C07D495/22
CPC分类号： C07D495/14 , C09K19/3491 , H01L51/0036
摘要： 본 발명은 반응성 티에노티오펜, 예를 들면 박막 트랜지스터 액정 디스플레이를 위한 유기 전계효과 트랜지스터 (FET 또는 OFET) 및 RFID 태그 같은 집적 회로 장치 등의 전자, 전자광학, 또는 광학 장치에서, 평판 디스플레이에서의 전계발광 장치, 및 광전지 및 센서 장치에서의 반도체 또는 전하 전달 물질로서의 그 용도, 및 반응성 티에노티오펜을 함유하는 ID 태그, 발광 장치 또는 전계효과 트랜지스터에 관한 것이다.

2. 发明公开

KR1020060135783A 반응성 메소젠 전하 수송 화합물 无效
标题翻译：反应性电荷运输化合物
公开(公告)号：KR1020060135783A
公开(公告)日：2006-12-29
申请号：KR1020067017273
申请日：2005-01-31
申请人： 메르크 파텐트 게엠베하
发明人： 히니마틴 , 장웨이민 , 티어니스티븐 , 스패로우데이빗 , 쉬쿠노브맥심 , 맥쿨로흐아이언
IPC分类号： C07D333/24 , C07D333/16 , C07D409/04 , C07D409/10
CPC分类号： C07D333/18 , C07D333/16 , C07D333/24 , C08G61/126 , C09K19/3491 , C09K19/3833 , C09K19/582 , Y10T428/10
摘要： The invention relates to new reactive mesogenic compounds with charge transport properties comprising at least two thiophene groups, their use as semiconductors or charge transport materials, in optical, electro- optical or electronic devices like for example liquid crystal displays, optical films, organic field effect transistors (FET or OFET) for thin film transistor liquid crystal displays and integrated circuit devices such as RFID tags, electroluminescent devices in flat panel displays, and in photovoltaic and sensor devices, and to a field effect transistor, light emitting device or ID tag comprising the reactive mesogenic charge transport compounds.
摘要翻译：本发明涉及具有电荷传输性质的新的反应性介晶化合物，其包括至少两个噻吩基团，它们作为半导体或电荷传输材料的用途，在光学，电光或电子器件中，例如液晶显示器，光学膜，有机场效应用于薄膜晶体管液晶显示器的晶体管（FET或OFET）以及诸如RFID标签，平板显示器中的电致发光器件以及光伏和传感器设备中的集成电路器件以及场效应晶体管，发光器件或ID标签，包括反应性介晶电荷转移化合物。

3. 发明授权

KR100908829B1 티에노티오펜 유도체 失效
标题翻译： 티에노티오펜유도체
公开(公告)号：KR100908829B1
公开(公告)日：2009-07-21
申请号：KR1020020039323
申请日：2002-07-08
申请人： 메르크 파텐트 게엠베하
发明人： 파란드루이스 , 톰슨마르쿠스 , 길스마크 , 히니마틴 , 티어니스티븐 , 쉬쿠노브맥심 , 스파로웨데이비드 , 맥쿨로치이아인
IPC分类号： C07D495/22
CPC分类号： H01B1/127 , C07D495/14 , C09K19/3491 , H01L51/0036 , Y02E10/549 , Y10T428/10
摘要： The invention relates to new thienothiophene derivatives, their use as semiconductors or charge transport materials, in optical, electrooptical or electronic devices like for example organic field effect transistors (FET or OFET) for thin film transistor liquid crystal displays and integrated circuit devices such as RFID tags, electroluminescent devices in flat panel displays, and in photovoltaic and sensor devices, and to a field effect transistor, light emitting device or ID tag comprising the thienothiophene derivatives.
摘要翻译：本发明涉及新型噻吩并噻吩衍生物，其作为半导体或电荷传输材料用于光学，电光学或电子器件，例如用于薄膜晶体管液晶显示器的有机场效应晶体管（FET或OFET）以及诸如RFID的集成电路器件标签，平板显示器中的电致发光装置以及光伏和传感器装置中，并且涉及包含噻吩并噻吩衍生物的场效应晶体管，发光装置或ID标签。

4. 发明公开

KR1020030007053A 티에노티오펜 유도체 失效
标题翻译：噻吩衍生物
公开(公告)号：KR1020030007053A
公开(公告)日：2003-01-23
申请号：KR1020020039323
申请日：2002-07-08
申请人： 메르크 파텐트 게엠베하
发明人： 파란드루이스 , 톰슨마르쿠스 , 길스마크 , 히니마틴 , 티어니스티븐 , 쉬쿠노브맥심 , 스파로웨데이비드 , 맥쿨로치이아인
IPC分类号： C07D495/22
CPC分类号： H01B1/127 , C07D495/14 , C09K19/3491 , H01L51/0036 , Y02E10/549 , Y10T428/10
摘要： PURPOSE: Provided are new thienothiophene derivatives, and their use as semiconductors or charge transport materials, in optical, electrooptical or electronic devices like for example organic field effect transistors (FET or OFET) for thin film transistor liquid crystal displays and integrated circuit devices such as radio frequency identification (RFID) tags, electroluminescent devices in flat panel displays, and in photovoltaic and sensor devices. CONSTITUTION: A thienothiophene is represented by the formula(1) of R¬1-Z¬1-(A¬1-Z¬2)m-(T-Z¬3)n-(A¬2-Z¬4)o-R¬2, wherein R¬1 and R¬2 are each independently, H, halogen, CN, NO2, or straight chain, branched or cyclic alkyl with 1 to 20 C-atoms, which is unsubstituted, or mono- or poly-substituted by F, Cl, Br, I or CN, wherein optionally one or more non-adjacent CH2 groups are replaced, in each case independently, by -O-, -S-, -NH-, -NR-, -SiRR-, -CO-, -COO-, -OCO-, -OCO-O-, -S-CO-, -CO-S-, -CH=CH- or -C=C- in such a manner that O and/or S atoms are not linked directly to one another, R¬0 and R¬00 are independently of each other H or alkyl with 1 to 12 C-atoms, A¬1 and A¬2 are independently of each other an alicyclic or aromatic group which optionally contains one or more hetero atoms and optionally exhibits one or more fused rings, and A¬1 may also be T, Z¬1 to Z¬4 are independently of each other -O-, -S-, -CO-, -COO-, -OCO-, -O-COO-, -CO-NR-, -NR-CO-, -OCH2-, -CH2O-, -SCH2-, -CH2S-, -CF2O-, -OCF2-, -CF2S-, -SCF2-, -CH2CH2-, -CF2CH2-, -CH2CF2-, -CF2CF2-, -CH=N-, -N=CH-, -N=N-, -CH=CR-, -CX=CX-, -C=C-, -CH=CH-COO-, -OCO-CH=CH- or a single bond, X¬1 and X¬2 are independently of each other H, F, Cl or CN, T is a group consisting of 3, 4, 5 or 6 fused thiophene rings wherein at least 3 of the thiophene rings are fused together, and which in each case are optionally mono- or polysubstituted by R¬1, m and o are independently of each other 0, 1, 2 or 3, and n is 1,2 or 3.
摘要翻译：目的：提供新的噻吩并噻吩衍生物及其作为半导体或电荷传输材料在光学，电光学或电子器件中的用途，例如用于薄膜晶体管液晶显示器的有机场效应晶体管（FET或OFET）和集成电路器件如射频识别（RFID）标签，平板显示器中的电致发光装置，以及光伏和传感器装置。构成：噻吩并噻吩由式（1）表示：R 1 -Z 1 - （A 1 -Z-2）m - （T Z 3）n - （A 2 - Z - 4） 2，其中R 1和R 2各自独立地为H，卤素，CN，NO 2或具有1至20个C原子的直链，支链或环状烷基，其为未取代的，或被单取代或多取代 F，Cl，Br，I或CN，其中任选地一个或多个不相邻的CH 2基团在每种情况下独立地被-O - ， - S - ， - NH - ， - NR - ， - SiRR - ， - CO-，-COO-，-OCO-，-OCO-O-，-S-CO-，-CO-S-，-CH = CH-或-C = C- 原子不彼此直接连接，R 10和R 100彼此独立地为H或具有1至12个C原子的烷基，A 1和A 2彼此独立地为脂环族或芳族基团，任选地含有一个或多个杂原子并且任选地表现出一个或多个稠合环，并且A 1也可以是T，Z 1至Z 4彼此独立地为-O - ， - S - ， - CO-， - COO-，-OCO-，-O-COO-，-CO-NR-，-NR-CO-，-OCH 2 - ， - CH 2 O-， - SCH 2 - ， - CH 2 - ， - CF 2 - ， - CF 2 - ， - CH 2 CH 2 - ， - C 2 CH 2 - ， - CH 2 CF 2 - ，-N = N-，-CH = CR-，-CX = CX-，-C = C-，-CH = CH-COO-，-OCO-CH = CH-或单键，X1和X ¬2彼此独立地为H，F，Cl或CN，T为3,4,5或6个稠合噻吩环，其中至少3个噻吩环稠合在一起，并且其在每种情况下是任选的被R 1，m和o单取代或多取代，彼此独立地为0,1,2或3，n为1,2或3。

5. 发明公开

KR1020030010508A 모노-, 올리고- 및 폴리-4-플루오로티오펜 및 전하 이동물질로서의 이들의 용도 无效
标题翻译：单 - ，二 - 和多 - 四氟硼酸及其作为电荷运输材料的用途
公开(公告)号：KR1020030010508A
公开(公告)日：2003-02-05
申请号：KR1020020043488
申请日：2002-07-24
申请人： 메르크 파텐트 게엠베하
发明人： 히니마틴 , 파란드루이스 , 길스마크 , 톰슨마르쿠스 , 티어니스티븐 , 쉬쿠노브맥심 , 스파로웨데이비드 , 맥쿨로치이아인
IPC分类号： C08F228/06
CPC分类号： H01L51/0036 , C07D333/28 , C08G61/02 , C08G61/126 , Y02E10/549
摘要： PURPOSE: A monomer, oligomer and polymer containing 4-fluorothiophene repeating unit and its use as a charge transport material are provided, to improve the charge transporting property, the processability and the oxidation stability. CONSTITUTION: The monomer, oligomer and polymer comprises at least one identical or different repeating unit represented by -£(Y)a-(D)b-(Z)c|-, wherein D is 3-substituted-4-fluorothiophene group represented by the formula 2. In the formula 2, R1 is a linear, branched or cyclic alkyl group of C1-C20 (wherein the group is unsubstituted or substituted with at least one F, Cl, Br, I, CN or OH, and at least one non-adjacent CH2 groups can be independently replaced one another by -O-, -S-, -NH-, -NR0-, -SiR0R00-, -CO-, -COO-, -OCO-, -OCO-O-, -S-CO-, -CO-S-, -CH=CH- or C-C triple bond in such a way that O and/or S atoms are not linked directly to one another), or optionally substituted aryl or heteroaryl group, R0 and R00 are independently H or an alkyl group of C1-C12; Y and Z are independently -CX1=CX2-, C-C triple bond, or optionally substituted arylene or heteroarylene; X1 and X2 are independently H, F, Cl or CN; and a, b and c are independently 0 or 1, a+b+c>0, and b is 1 in at least one repeating unit.
摘要翻译：目的：提供含有4-氟噻吩重复单元的单体，低聚物和聚合物及其作为电荷传输材料的用途，以提高电荷传输性能，加工性能和氧化稳定性。构成：单体，低聚物和聚合物包含至少一个相同或不同的重复单元，由 - （（A）） - （D）b-（Z）c | - 表示，其中D是3-取代-4-氟噻吩基团在式2中，R1是C1-C20的直链，支链或环状烷基（其中该基团是未取代的或被至少一个F，Cl，Br，I，CN或OH取代，并且在至少一个不相邻的CH 2基团可以彼此独立地被-O - ， - S - ， - NH - ， - NRO - ， - SiRORO - ， - CO - ， - COO - ， - OCO-，-OCO-O - ，-S-CO-，-CO-S-，-CH = CH-或CC三键，使得O和/或S原子彼此不直接连接）或任选取代的芳基或杂芳基 R 0和R 00独立地为H或C 1 -C 12烷基; Y和Z独立地为-CX1 = CX2-，C-C三键或任选取代的亚芳基或亚杂芳基; X1和X2独立地为H，F，Cl或CN; a，b和c独立地为0或1，a + b + c> 0，b为至少一个重复单元。

6. 发明公开

KR1020030007034A 반응성 티에노티오펜 失效
标题翻译：反应性三硝基苯
公开(公告)号：KR1020030007034A
公开(公告)日：2003-01-23
申请号：KR1020020039135
申请日：2002-07-06
申请人： 메르크 파텐트 게엠베하
发明人： 파란드루이스 , 톰슨마르쿠스 , 길스마크 , 골딩마크 , 히니마틴 , 티어니스티븐 , 쉬쿠노브맥심 , 스파로웨데이비드 , 맥쿨로치이아인
IPC分类号： C07D495/22
CPC分类号： C07D495/14 , C09K19/3491 , H01L51/0036
摘要： PURPOSE: Provided are reactive thienothiophenes, and their use as semiconductors or charge transport materials, in optical, electrooptical or electronic devices like for example organic field effect transistors (FET or OFET) for thin film transistor liquid crystal displays and integrated circuit devices such as radio frequency identification (RFID) tags, electroluminescent devices in flat panel displays, and in photovoltaic and sensor devices. Also, provided is a field effect transistor, light emitting device or identification (ID) tag comprising the reactive thienothiophenes. CONSTITUTION: A compound is represented by the formula 1 of P-Sp-T-R I, wherein P is a polymerizable or reactive group, Sp is a spacer group or a single bond, R is H, halogen, CN, NO2, an aliphatic, alicyclic or aromatic group with up to 40 C atoms that optionally comprises at least one hetero atom and/or at least one fused ring, or is P-Sp-, and T is a group comprising at least two fused thiophene rings.
摘要翻译：目的：提供反应性噻吩并噻吩及其作为半导体或电荷传输材料的用途，例如用于薄膜晶体管液晶显示器的有机场效应晶体管（FET或OFET）和诸如无线电的集成电路器件的光学，电光或电子器件频率识别（RFID）标签，平板显示器中的电致发光装置，以及光伏和传感器装置。此外，提供了包含反应性噻吩并噻吩的场效应晶体管，发光器件或识别（ID）标签。构成：化合物由P-Sp-TR I的式1表示，其中P是可聚合或反应性基团，Sp是间隔基或单键，R是H，卤素，CN，NO 2，脂族，具有至多40个C原子的脂环族或芳族基团任选地包含至少一个杂原子和/或至少一个稠环，或者是P-Sp-，T是包含至少两个稠合噻吩环的基团。

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