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    • 1. 发明公开
    • 이온 액체를 이용한 전도성 고분자의 나노입자의 제조방법및 이를 이용한 전도성 고분자 컴퍼지트 물질의 제조방법
    • 使用离子液体的导电性聚合物纳米粒子的制备方法和使用该复合材料的复合材料的制造
    • KR1020070102963A
    • 2007-10-22
    • KR1020070037519
    • 2007-04-17
    • 김진열
    • 김진열김재택민영근하마구찌히로오권시중
    • C08J3/12C08G83/00C08G65/329B82B3/00
    • Y02P20/542
    • A method for preparing nanoparticles of a conductive polymer by using an ionic liquid is provided to obtain conductive polymer nanoparticles easily blendable with other host polymers at a high yield by a simple cost-efficient polymerization/doping process, and to produce a conductive composite material. A method for preparing nanoparticles of a conductive polymer comprises a step of forming 10-500 nm-sized nanoparticles of a conductive polymer represented by the following formula 2 by using an ionic liquid containing a compound represented by the following formula 1 as a solvent. In the formulae, each of R' and R" represents a C1-C15 hydrocarbon or a hydrocarbon containing at most 5 atoms other than carbon; Y^- is an anion selected from the group consisting of NO3-, BF4-, PF6-, AlCl4-, Al2Cl7-, FeCl3- and FeCl4-;each of R1 and R2 is selected from the group consisting of H, a C1-C15 alkyl, C1-C15 ether, halogen atom and benzene; hetero atom X is selected from S, O, Se and NH; and n is 1-1000.
    • 提供通过使用离子液体制备导电聚合物的纳米颗粒的方法,以通过简单的成本有效的聚合/掺杂方法获得与其它主体聚合物容易地以高收率共混的导电聚合物纳米颗粒,并制备导电复合材料。 制备导电聚合物纳米颗粒的方法包括通过使用含有由下式1表示的化合物作为溶剂的离子液体形成由下式2表示的导电聚合物的10-500nm尺寸的纳米颗粒的步骤。 在该式中,R'和R“各自表示C1-C15烃或含碳以外的至多5个原子的烃; Y 1 - 是选自NO 3 - ,BF 4 - ,PF 6 - AlCl4-,Al2Cl7-,FeCl3-和FeCl4-; R1和R2各自选自H,C1-C15烷基,C1-C15醚,卤素原子和苯;杂原子X选自S, O,Se和NH; n为1-1000。