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    • 42. 发明公开
    • 이트리움-니켈/활성탄 촉매 제조방법 및이트리움-니켈/활성탄 촉매를 이용한 유기물질의 초임계수기화에 의한 수소 제조시스템 및 방법
    • Y-NI /活性碳催化剂的生产方法和氢生产系统以及使用Y-NI /活性炭催化剂的有机化合物的超临界水气化方法
    • KR1020090082766A
    • 2009-07-31
    • KR1020080008705
    • 2008-01-28
    • 한국에너지기술연구원
    • 이인구
    • B01J21/18B01J23/755B01J23/10C01B3/38
    • Y02P20/52Y02P20/544B01J37/024B01J23/755B01J37/08B01J37/18C01B3/326
    • A preparation method of Y-Ni/activated carbon catalysts capable of stably performing a supercritical water vaporization reaction of organic materials, and a system and a method for producing hydrogen by supercritical water vaporization of the organic materials using the Y-Ni/activated carbon catalysts are provided. A system for producing hydrogen by supercritical water vaporization of organic materials using a Y-Ni/activated carbon catalyst comprises: a reactor(20) including a reaction pipe(21) which is divided into a preheating part(21a) and a vaporization part(21b), a vaporization part thermocouple, a preheating part thermocouple(211), a plurality of thermocouples(23), a cylindrical heating furnace(22), a front heater(25a), a rear heater(25b), and a support(28); a first storage vessel(30a) and a second storage vessel(30b) which have digital balances(31a,31b) mounted on bottom sides thereof, and which are connected to a cross(34) communicating with a front end of the reactor by supply pipes(11), wherein high pressure pumps(32a,32b) and valves(33a,33b) are mounted on the supply pipes; a solid remover(40) installed on a discharge pipe(12) formed on a rear end of the reactor; a high pressure manometer(50) measuring pressure in the discharge pipe; a post-pressure controller(60) controlling the pressure in the discharge pipe; a gas-liquid separator(70) separating a product decompressed to the atmospheric pressure through the post-pressure controller into gas phase and liquid phase; a gas collecting part(80) collecting a gas sample from the product in the gas phase; and a gas flow meter(90) measuring flow rate of the produced gas in real-time.
    • 能够稳定地进行有机材料的超临界水蒸发反应的Y-Ni /活性炭催化剂的制备方法,使用Y-Ni /活性炭催化剂的有机材料的超临界水蒸发生成氢的体系和方法 被提供。 使用Y-Ni /活性炭催化剂通过有机材料的超临界水汽化生产氢的体系包括:反应器(20),其包括反应管(21),其分为预热部分(21a)和蒸发部分 21b),蒸发部分热电偶,预热部分热电偶(211),多个热电偶(23),圆柱形加热炉(22),前部加热器(25a),后部加热器(25b)和支撑件 28); 第一储存容器(30a)和第二储存容器(30b),其具有安装在其底侧上的数字平衡(31a,31b),并且连接到通过供应与反应器的前端连通的十字 管道(11),其中高压泵(32a,32b)和阀(33a,33b)安装在供应管上; 安装在形成在反应器后端的排出管(12)上的固体去除器(40) 测量排出管中的压力的​​高压压力计(50); 控制排出管中的压力的​​后压控制器(60); 将通过后压控制器减压至大气压的产物分离成气相和液相的气液分离器(70) 在气相中从所述产品收集气体样品的气体收集部分(80) 以及气体流量计(90),其实时测量所产生的气体的流量。
    • 43. 发明授权
    • 탄소나노튜브 합성장치 및 방법
    • 碳纳米管合成装置和方法
    • KR100851391B1
    • 2008-08-08
    • KR1020070041068
    • 2007-04-27
    • 세메스 주식회사
    • 김형준황호수조중근
    • B82B3/00B82Y40/00
    • B82Y30/00B01J23/745B01J23/755B01J37/18B82Y40/00C01B32/16
    • An apparatus for synthesizing carbon nanotubes is provided to facilitate the collection of synthesized carbon nanotubes, to enable an efficient management of a reactor, and to increase productivity. An apparatus for synthesizing carbon nanotubes includes: a reactor(110) in which carbon nanotubes are synthesized, and of which a long axis is erected; a cassette(210) on which many substrates(220) are loaded; a transfer unit(170) which moves along the erected long axis of the reactor to load/unload the cassette into/from the reactor; a heater(120) which supplies heat to the reactor; a gas supply part(130) which supplies gas for carbon nanotube synthesis to the reactor; and a gas discharge part(140) for discharging the used gas from the reactor into the outside. Further, the gas supply part supplies gas to an upper part of the reactor and the gas discharge part discharges the gas to a lower part of the reactor.
    • 提供了一种用于合成碳纳米管的装置,以便于收集合成的碳纳米管,从而能够有效地管理反应器并提高生产率。 合成碳纳米管的装置包括:其中合成有碳纳米管并且其长轴竖立的反应器(110); 其上装载有许多衬底(220)的盒(210) 转移单元(170),其沿着反应器的竖立的长轴移动以将盒装载/卸载到反应器中; 加热器(120),其向所述反应器供应热量; 将碳纳米管合成气体供给反应器的气体供给部(130) 以及用于将废气从反应器排出到外部的气体排出部分(140)。 此外,气体供给部将气体供给到反应器的上部,气体排出部将气体排出到反应器的下部。
    • 50. 发明公开
    • 아세틸렌의 선택적 수소화를 위한 팔라듐계 촉매
    • 用于乙炔选择性氢化的基于钯的催化剂
    • KR1020050109602A
    • 2005-11-21
    • KR1020057017963
    • 2004-03-26
    • 바스프 에스이
    • 문상흡김우재강정화안인영
    • B01J23/63C07C5/09
    • C07C5/09B01J23/58B01J23/63B01J23/6484B01J37/0201B01J37/0205B01J37/0238B01J37/18C07C7/167C07C2523/58C07C2523/63C07C2523/68Y02P20/52C07C11/04
    • The present invention describes a Pd-catalyst, further consisting of La, Ti, Nb, K or Si, which have high ethylene selectivity even after a low temperature reduction in the se-lective hydrogenation of acetylene to ethylene and the production method of the same. A catalyst of the invention consists essentially of 0.05 to 2.0% by weight, based on the supported catalyst, of palladium and one or two metals chosen form the group consist-ing of lanthanum, niobium, titanium, potassium and silicon. The said catalyst is pre-pared by the following procedure: 1) Impregnating a support in aqueous solution of tetra amine palladium hydroxide, followed by drying and calcination; 2) The second and, if necessary, a third metal is impregnated by impregnating the Pd-catalyst in the solution of the metal precursor followed by drying and calcina- tion; 3) The catalyst according to step (2) is then reduced in hydrogen at 200°C to 600°C for 1 to 5 hours.
    • 本发明描述了一种Pd催化剂,其进一步由La,Ti,Nb,K或Si组成,即使在乙炔对乙烯的选择性氢化中的低温还原后也具有高的乙烯选择性及其制备方法 。 本发明的催化剂基本上由基于负载型催化剂的0.05至2.0重量%的钯和选自镧,铌,钛,钾和硅组成的组中的一种或两种金属组成。 所述催化剂通过以下步骤预处理:1)将载体浸渍在四胺氢氧化钯水溶液中,然后干燥和煅烧; 2)通过将Pd催化剂浸渍在金属前体溶液中,然后干燥和煅烧来浸渍第二种金属和必要时的第三种金属; 3)然后根据步骤(2)的催化剂在氢气中在200℃至600℃下还原1至5小时。