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    • 21. 发明公开
    • 석탄재를 이용한 폐수 내 유기물질 흡착제 및 이의 제조방법
    • 通过使用煤飞灰在废水中吸收有机化合物及其制备方法
    • KR1020140081952A
    • 2014-07-02
    • KR1020120150157
    • 2012-12-21
    • 재단법인 포항산업과학연구원
    • 김병억
    • B01J20/04B01J20/20B01D53/04
    • B01J20/30B01D53/02B01J20/20B01J20/28061
    • The present invention relates to an adsorbent for organic substances from waste water using coal fly ash and a preparation method thereof. More specifically, the present invention provides a preparation method including the steps of preparing fine coal particles, adding acid, and adding alkali and an adsorbent of organic substances by the preparation method. According to the present invention, an adsorbent of organic substances from waste water is prepared using coal fly ash which is a waste generated after coal combustion, thereby allowing a waste to be recycled as a resource. Also, the organic substances in waste water can be adsorbed and removed by a treatment using the adsorbent, and thus the adsorbent can also be used for purification of waste water.
    • 本发明涉及一种使用煤飞灰的废水有机物吸附剂及其制备方法。 更具体地说,本发明提供一种制备方法,其包括通过制备方法制备细煤颗粒,加入酸,加入碱和有机物质的吸附剂的步骤。 根据本发明,使用作为煤燃烧后产生的废物的煤飞灰来制备来自废水的有机物质的吸附剂,从而使废弃物作为资源再循环。 此外,废水中的有机物质可以通过使用吸附剂的处理来吸附除去,因此吸附剂也可以用于废水的净化。
    • 23. 发明公开
    • 석탄재를 활용한 산성가스 흡착제 및 그 제조방법
    • 使用煤飞灰的酸性气体吸附剂及其制备方法
    • KR1020140039359A
    • 2014-04-02
    • KR1020120104238
    • 2012-09-19
    • 재단법인 포항산업과학연구원
    • 김병억
    • B01J20/04C07F3/04
    • B01J20/20B01D53/04B01D2253/102B01D2253/1124B01D2253/304B01D2253/306B01D2257/302B01J20/041B01J20/28004B01J20/28059
    • The present invention provides a method for preparing an acidic gas adsorbent, which comprises: a slurry formation step of forming a slurry by mixing coal fly ash and acid; a calcium oxide addition step of adding a calcium oxide containing material to the slurry; a filtration and drying step of filtering and drying precipitates; and a crushing step of crushing the dried precipitates; and the acidic gas adsorbent containing the coal fly ash and the calcium oxide containing material in a weight ratio of 1:1-3. By using the method for preparing the acidic gas adsorbent of the present invention, a user can produce the acidic gas adsorbent with excellent absorption ability, and economic feasibility and environmentally friendly properties of the acidic gas adsorbent can be improved by utilizing the coal fly ash discharged from a thermoelectric power plant. [Reference numerals] (AA) Acid gas adsorbent; (S100) Forming a slurry; (S110) Adding calcium oxide; (S120) Filtering and drying; (S130) Pulverizing
    • 本发明提供一种酸性气体吸附剂的制备方法,包括:通过混合煤飞灰和酸形成浆料的浆料形成步骤; 添加含氧化钙的材料的氧化钙添加工序; 过滤和干燥沉淀物的过滤和干燥步骤; 和粉碎干燥的沉淀物的破碎步骤; 和含有煤飞灰和含氧化钙的材料的酸性气体吸附剂的重量比为1:1-3。 通过使用本发明的酸性气体吸附剂的制备方法,使用者可以生产具有优良吸收能力的酸性气体吸附剂,通过利用煤飞灰排出,可以提高酸性气体吸附剂的经济可行性和环境友好性 来自热电厂。 (附图标记)(AA)酸性气体吸附剂; (S100)形成浆料; (S110)添加氧化钙; (S120)过滤干燥; (S130)粉碎
    • 27. 发明公开
    • 고농도 염소계 유기화합물의 처리장치
    • 用于处理高浓度氯化物有机化合物的装置
    • KR1020090067656A
    • 2009-06-25
    • KR1020070135393
    • 2007-12-21
    • 재단법인 포항산업과학연구원
    • 김민균김병억
    • B01D53/26
    • An apparatus for treating high concentration chlorine-based organic compounds is provided to prevent the environmental exposure of the high concentration chlorine-based organic compounds by treating toxic high concentration chlorine-based organic compounds promptly and simply. An apparatus for treating high concentration chlorine-based organic compounds comprises a reaction vessel(1), an oxygen supply pipe(6), an incineration vessel(4), a high voltage supply unit(8), and a tungsten wire(7). The oxygen supply pipe supplies oxygen into the reaction vessel. The incineration vessel is installed within the reaction vessel. A waste sample of the high concentration chlorine-based organic compounds is put into the incineration vessel. The high voltage supply unit supplies high voltage to the reaction vessel. The tungsten wire delivers the high voltage supplied from the high voltage supply unit to the incineration vessel.
    • 提供了一种处理高浓度氯基有机化合物的装置,以便迅速且简单地处理有毒的高浓度氯基有机化合物来防止高浓度氯基有机化合物的环境暴露。 用于处理高浓度氯基有机化合物的设备包括反应容器(1),供氧管(6),焚烧容器(4),高压供应单元(8)和钨丝(7) 。 供氧管将氧气供应到反应容器中。 焚烧容器安装在反应容器内。 将高浓度氯基有机化合物的废样放入焚烧容器中。 高压电源单元向反应容器提供高电压。 钨丝将从高压供应单元提供的高压输送到焚烧容器。
    • 28. 发明公开
    • PAHs로 오염된 토양의 정화방법
    • PAHS污染土壤的脱氧方法
    • KR1020080056982A
    • 2008-06-24
    • KR1020060130251
    • 2006-12-19
    • 재단법인 포항산업과학연구원
    • 김병억김민균사영삼
    • B09C1/08
    • B09C1/08A62D3/38
    • A remediating method of soils contaminated with PAHs(Poly Aromatic Hydrocarbons) is provided to remediate the contaminated soils or sediments within a short time while less affecting the environment by adding an oxidizer to contaminated soils or sediments containing the PAHs and projecting ultrasonic waves onto the contaminated soils or sediments. A remediating method of soils contaminated with poly aromatic hydrocarbons comprises: a first step of adding 100 mM to 1 M of an oxidizer to 50 to 500 g of soils contaminated with poly aromatic hydrocarbons; a second step of adding 150 mg to 1 g of a metal oxide as a catalyst to the oxidizer added contaminated soils; a third step of agitating the oxidizer and the metal oxide added contaminated soils; and a fourth step of irradiating ultrasonic waves onto the agitation-completed soils for at least one hour. The oxidizer is hydrogen peroxide. The metal oxide includes CuO, Al2O3, and ZnO. The contaminated soils are particularly marine sediments.
    • 提供了多环芳烃污染土壤的补救方法(聚芳香烃),可在短时间内对污染土壤或沉积物进行修复,同时对受污染的土壤或含有PAHs的沉积物添加氧化剂,并将超声波投射到污染物 土壤或沉积物。 用聚芳烃污染的土壤的补救方法包括:向50-500克被多芳香烃污染的土壤中加入100mM至1M的氧化剂的第一步骤; 向作为催化剂的1g金属氧化物中加入150mg添加污染土壤的第二步骤; 搅拌氧化剂和添加污染土壤的金属氧化物的第三步骤; 以及将超声波照射到搅拌完成的土壤上至少1小时的第四步骤。 氧化剂是过氧化氢。 金属氧化物包括CuO,Al 2 O 3和ZnO。 受污染的土壤特别是海洋沉积物。
    • 29. 发明公开
    • 고로 슬래그를 이용한 중금속 흡착제의 제조방법
    • 通过使用炉渣制造重金属吸附剂的方法
    • KR1020080056980A
    • 2008-06-24
    • KR1020060130249
    • 2006-12-19
    • 재단법인 포항산업과학연구원
    • 김민균김병억
    • B01J20/02B01J20/00
    • B01J20/10B01J20/28059B01J20/3078B01J20/32C02F1/281C04B5/00
    • A method of manufacturing an adsorbent is provided, wherein the adsorbent eliminates a large amount of the heavy metals at a low operating cost by passing wastewater containing heavy metals through a filter filled with an adsorbent made of surface area-improved blast furnace slag, thereby eliminating the heavy metals. A method of manufacturing a heavy metal adsorbent by using blast furnace slag comprises: a first step of ball milling blast furnace slag into a fine powder type blast furnace slag; a second step of dipping the fine powder type blast furnace slag into an 1% aqueous NaOH solution for at least 6 hours; a third step of passing a fine powder type blast furnace slag treated with a base through a filter paper to filter the NaOH solution, and drying the blast furnace slag in air for 24 hours; and a fourth step of injecting the blast furnace slag into an oven and heating the blast furnace slag to 300 deg.C in a nitrogen atmosphere for 12 hours. The blast furnace slag passing through the four steps has a surface area of 34 m^2/g. The fine powder type blast furnace slag used as the adsorbent has a particle diameter of 1 mm or less.
    • 提供一种制造吸附剂的方法,其中吸附剂通过使含有重金属的废水通过填充有由表面积改善的高炉矿渣制成的吸附剂的过滤器而以低操作成本消除大量的重金属,由此消除 重金属。 使用高炉渣制造重金属吸附剂的方法包括:将高炉矿渣球磨成细粉型高炉矿渣的第一步骤; 将细粉末型高炉渣浸入1%NaOH水溶液中至少6小时的第二步骤; 将通过滤纸处理的细粉末型高炉渣通过滤纸过滤第三步骤,将NaOH溶液过滤,并将高炉炉渣在空气中干燥24小时; 以及第四步骤,将高炉渣注入烘箱中,并在氮气气氛中将高炉渣加热至300℃12小时。 通过四步的高炉渣的表面积为34m 2 / g。 用作吸附剂的细粉型高炉矿渣的粒径为1mm以下。