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    • 109. 发明公开
    • 희토류원소계 초전도 산화물을 이용하는 유기금속증착용 전구용액 제조방법 및 유기금속증착법에 의한 박막형 초전도체 제조방법
    • 通过使用超导氧化物生产有机金属沉积的前驱体溶液的方法和通过有机金属沉积方法生产薄膜型超导体的方法
    • KR1020050010193A
    • 2005-01-27
    • KR1020030049157
    • 2003-07-18
    • 학교법인 한국산업기술대학
    • 홍계원이희균김찬중유상임위성훈
    • C01G3/00
    • H01L39/2425C01G3/006C01P2002/72C01P2006/40C04B35/4508C04B35/6264C04B35/6325C04B2235/3215C04B2235/3224C04B2235/3225C04B2235/3227C04B2235/3229C23C18/1216C23C18/1254C23C18/1291C23C18/1295
    • PURPOSE: A process is provided to produce a precursor solution for organic metal deposition by using a superconductive oxide. And a process is also provided to produce a thin film type superconductor by an organic metal deposition method. CONSTITUTION: The process for producing the precursor solution for the organic metal deposition contains the steps of: dissolving a superconductive material powder in a TFA(trifluoro acetate) solution and melting in a hot plate; evaporating the solution by increasing the temperature of the hot plate when the powder is dissolved perfectly and heating continuously to make a jelly state; stopping the heating when the solution dose not flow and cooling the solution; dissolving the jelly state compound in an organic solvent. The superconductive material powder is REBa2Cu3O7-x, wherein RE is a rare earth element such as Y, La, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, or a composition thereof. And the process for producing the thin film type superconductor comprises the steps of: preparing the superconductive material powder-TFA precursor solution; spreading the precursor solution on a metal substrate having a texture or a single crystal metal substrate to form a thin film; drying and then calcining the thin film.
    • 目的:提供一种通过使用超导氧化物制备用于有机金属沉积的前体溶液的方法。 还提供了通过有机金属沉积方法制造薄膜型超导体的方法。 构成:用于生产有机金属沉积前体溶液的方法包括以下步骤:将超导材料粉末溶解在TFA(三氟乙酸盐)溶液中并在热板中熔化; 当粉末完全溶解时通过增加热板的温度来蒸发溶液,并持续加热以产生果冻状态; 当溶液不流动并冷却溶液时停止加热; 将果胶状化合物溶解在有机溶剂中。 超导材料粉末是REBa2Cu3O7-x,其中RE是诸如Y,La,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu的稀土元素或其组成。 并且制造薄膜型超导体的方法包括以下步骤:制备超导材料粉末-TFA前体溶液; 将前体溶液铺展在具有纹理的金属基底或单晶金属基底上以形成薄膜; 干燥然后煅烧薄膜。