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    • 2. 发明专利
    • SILVER HALIDE PHOTOGRAPHIC SENSITIVE MATERIAL
    • JPH10133345A
    • 1998-05-22
    • JP30236596
    • 1996-10-29
    • FUJI PHOTO FILM CO LTD
    • UCHIDA OSAMUONO MICHIO
    • G03C8/08G03C8/12G03C8/40
    • PROBLEM TO BE SOLVED: To provide a photosensitive material capable of releasing a large quantity of a photographic useful material under the condition of a small quantity of a reducing agent with an amplification reaction at the time of using a positively active parent nucleus and excellent in discrimination by incorporating a specific image forming compound. SOLUTION: The image forming material expressed by the formula is used. In the formula, Y represents a group to be reduced, which has a property of generating RED-L1 -(PUG)k reversely corresponding to the reaction of a photosensitive silver salt having an image like latent image, T represents a simple bond or a connecting group cleaved reversely corresponding to the development, RED represents a group having no reducing property until T-RED bond is cleaved and the group capable of reducing Y, L1 represents a simple bond or a connecting group, PUG represents a photographic useful compound and (k) represents integers of 1-3. As a result, the photosensitive material capable of causing the amplification reaction and excellent in discrimination is obtained.
    • 8. 发明专利
    • SILVER HALIDE PHOTOGRAPHIC SENSITIVE MATERIAL
    • JPS6259945A
    • 1987-03-16
    • JP20075185
    • 1985-09-11
    • FUJI PHOTO FILM CO LTD
    • ITO ISAMUONO MITSUNORI
    • G03C7/26G03C1/06G03C7/00G03C7/305G03C8/12
    • PURPOSE:To obtain the titled material having a stabilization of the photosensitive material during a storage and capable of releasing a photographic reagent with a necessary timing in the developing treatment by incorporating a precursor of a specific photographic reagent to the titled material. CONSTITUTION:One or more kinds of the precursor of the photographic reagent shown by formula wherein Z is 5.7 membered ring forming non-metallic atoms, R1-R3 are each a hydrogen atom or a substituent, (m) is 0-3, (n) is 0 or 1, (m+n) is 1-3, X is an electrophilic binding, L is a timing group, (l) is 0 or 1, PUG is a photographically usable group is incorporated to the silver halide (AgX) photographic sensitive material. Said AgX photographic sensitive material is stable under a storage condition and may release the photographic reagent rapidly and with a good efficiency of releasing the blocking group and with a timing necessary to the reagent during the treatment. Especially, the titled photosensitive material may release the photographic reagent with a good timing, even if the treatment is effected under a relatively low pH condition of 9-12. The titled material capable of preventing the reduction of the sensitivity and capable of displaying the function of the released photographic reagent sufficiently is obtd. by adding the precursor of said reagent shown by the formula to the titled material.
    • 9. 发明专利
    • Silver halide photosensitive material
    • 银红色光敏材料
    • JPS6195346A
    • 1986-05-14
    • JP21692684
    • 1984-10-16
    • Fuji Photo Film Co Ltd
    • YAGIHARA MORIOIKEGAWA AKIHIKO
    • C07D403/12C07D231/56C07D233/84C07D239/54C07D257/04G03C1/06G03C1/43G03C7/00G03C7/26G03C7/305G03C8/12
    • G03C7/30511G03C1/06Y10S430/156Y10S430/158Y10S430/159Y10S430/16
    • PURPOSE: To add a photographic reagent stable in storage but releasable at a necessary timing at the time of processing and capable of functioning at a wide range of pH by incorporating the specified blocked photographic reagent.
      CONSTITUTION: The incorporated blocked photographic reagent is represented by the formula in which A is the photographic reagent or its precursor combined through a hetero atom; each of R
      1 WR
      3 is H or a substituent; Z is an atomic group necessary for forming a carbon ring or hetero ring except one having -NH- at the adjacent position of the C atom substd. by R
      1 . Such a photographic reagent precursor may be added to any layer so long as it is arranged so as to effectively function on the development of a silver halide emulsion. The use of the blocked reagent permits the reagent to be stable during storage and to be released at the necessary timing. When the reagent moiety of the reagent precursor is, e.g., a fog or development inhibitor, the gradation of a dotted image can be lengthened. The blocked reagent or its precursor can be widely used for each of color and black-and-white photosensitive material.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:加入保存时稳定的照相试剂,在加工时必要的时间可释放,并能通过掺入特定的封闭的照相试剂在宽的pH范围内起作用。 构成:结合的封闭照相试剂由下式表示,其中A是通过杂原子组合的照相试剂或其前体; R 1 -R 3中的每一个为H或取代基; Z是形成碳环或杂环所需的原子团,除了在C原子的相邻位置具有-NH-的原子。 通过R 1。 这样的照相试剂前体可以添加到任何层中,只要它被布置成有效地发挥卤化银乳剂的功能。 使用封闭的试剂允许试剂在储存期间稳定并在必要的时间被释放。 当试剂前体的试剂部分是例如雾或显影抑制剂时,可以延长点状图像的灰度。 封闭的试剂或其前体可广泛用于各种颜色和黑白感光材料。
    • 10. 发明专利
    • Photosensitive material
    • 感光材料
    • JPS6188257A
    • 1986-05-06
    • JP21114684
    • 1984-10-08
    • Fuji Photo Film Co Ltd
    • FURUYA KEIZOKOYAMA KOICHITORIUCHI MASAHARU
    • C07D417/12C07D231/22C07D231/46C07D257/04C07D275/06C07D417/14G03C7/00G03C7/305G03C8/12
    • G03C7/305
    • PURPOSE:To obtain the titled material having a good preservative stability and capable of releasing a photographic useful copd. with a high efficiency and to obtain a transcribing image having a good quality for a short period by incorporating to a photosensitive layer a specific LDA compd. capable of releasing a photographically useful compd. by a redox reaction. CONSTITUTION:The titled material comprises the photosensitive layer contg. the unmobile LDA compd. capable of releasing the photographically useful compd. or its precursor by the redox reaction and shown by the formula (wherein D is a group contg. an electron donator or its precusor, Acp is a group capable of rleasing a -Z-Q- residue by a Quinonemethide type releasing reaction due to a reduction, R and R are each a hydrogen atom, and an alkyl group etc. Z is a bivalence atom group, Q is a group capable of releasing the photographically useful compd. and its precusor, Ball is a ballast group, A is a combining group, (x), (y) and (z) are 1 or 2, (n) and (m) are >=1. The LDA compd. may be use to a negative and an autopositive emulsions, thereby preventing to generate a fog and eliminating toe without affecting D max and a trascription rate and remarkably preventing to generate the fog using a small amount of the LDA compd.
    • 目的:获得具有良好防腐稳定性且能够释放摄影有用copd的标题材料。 并且通过将特定的LDA组合物结合到光敏层中并获得具有短时间质量的转录图像。 能够释放摄影有用的compd。 通过氧化还原反应。 构成:标题材料包括光敏层。 非移动LDA compd 能够释放摄影有用的compd。 或其前体通过氧化还原反应并由式表示(其中D是电子给体或其前体的基团,Acp是能够通过由于还原而被喹诺酮类型释放反应挥发-ZQ-残基的基团, R 1和R 2分别是氢原子和烷基等。Z是二价原子基团,Q是能够释放摄影有用的化合物及其前体的基团,Ball是镇流剂组, A是组合组,(x),(y)和(z)分别为1或2,(n)和(m)= 1,LDA化合物可用于阴性和自动正乳剂, 防止产生雾而消除脚趾,而不影响D max和行驶速度,并且显着防止使用少量的LDA组合物产生雾。