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    • 1. 发明专利
    • Curable resin composition
    • 可固化树脂组合物
    • JP2014109021A
    • 2014-06-12
    • JP2012265524
    • 2012-12-04
    • Yokohama Rubber Co Ltd:The横浜ゴム株式会社
    • AKABANE EIICHIROTATEWAKI TAKANOBU
    • C08G18/28C08G18/10C08G18/66
    • PROBLEM TO BE SOLVED: To provide a curable resin composition which has improved adhesion to a difficult-to-adhere painted surface and prevents bubbles from swelling.SOLUTION: The curable resin composition includes: a urethane prepolymer (B) which is produced from a reaction of a mixture of a disulfide-containing polyol compound (A) and polyoxyalkylene polyol with a polyisocyanate compound and has an isocyanate group at an end; and an oxazolidine compound (C). The disulfide-containing polyol compound (A) is a secondary alcohol. The curable resin composition has improved adhesion to a difficult-to-adhere painted surface and prevents bubbles from swelling.
    • 要解决的问题:提供一种固化性树脂组合物,该固化性树脂组合物具有改善的粘附性,难以粘附的涂覆表面,并防止气泡膨胀。溶解性:固化性树脂组合物包括:由反应生成的氨基甲酸酯预聚物(B) 的含二硫化物的多元醇化合物(A)和聚氧化烯多元醇与多异氰酸酯化合物的混合物,末端具有异氰酸酯基; 和恶唑烷化合物(C)。 含二硫化物的多元醇化合物(A)是仲醇。 可固化树脂组合物具有改善的粘附性,难以粘附的涂覆表面,并防止气泡膨胀。
    • 2. 发明专利
    • Curable resin composition
    • 可固化树脂组合物
    • JP2011127059A
    • 2011-06-30
    • JP2009288960
    • 2009-12-21
    • Yokohama Rubber Co Ltd:The横浜ゴム株式会社
    • TATEWAKI TAKANOBU
    • C08L81/04C08G75/14C08K5/29C08L71/00
    • PROBLEM TO BE SOLVED: To provide a curable resin composition excellent in compatibility.
      SOLUTION: The curable resin composition contains a hydroxy group-containing polysulfide polymer (A) which has a hydroxy group and a polysulfide skeleton and can be obtained by reaction of a polysulfide polymer having a thiol group with polyalkylene glycol mono (meth)acrylate having a hydroxy group terminal and/or hydroxyalkyl (meth)acrylate, a polyoxyalkylene polyol (B) which has a polyethylene ether skeleton and a polyalkylene ether skeleton except the polyethylene ether skeleton and a polyisocyanate compound (C). Content 1 (mass%) of the polyethylene ether skeleton in the polyoxyalkylene polyol (B) is 30% or more of content 2 (mass%) of the polysulfide skeleton in the hydroxy group-containing polysulfide polymer (A).
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供相容性优异的固化性树脂组合物。 解决方案:可固化树脂组合物含有具有羟基和多硫化物骨架的含羟基的多硫化物聚合物(A),可通过具有硫醇基的多硫化物聚合物与聚亚烷基二醇单(甲基) 具有羟基末端的丙烯酸酯和/或(甲基)丙烯酸羟烷基酯,具有聚乙烯醚骨架的聚氧化烯多元醇(B)和聚乙烯醚骨架除外的聚亚烷基醚骨架和多异氰酸酯化合物(C)。 聚氧化烯多元醇(B)中的聚乙烯醚骨架的含量1(质量%)为含羟基多硫化物聚合物(A)中的多硫醚骨架的含量2(质量%)的30质量%以上。 版权所有(C)2011,JPO&INPIT
    • 7. 发明专利
    • Isocyanate group-containing polysulfide polymer, oxazolidine-containing polysulfide polymer, and curable composition
    • 含异氰酸酯基的含聚合物聚合物,含有氧杂环丁烷的多聚物聚合物和可固化组合物
    • JP2010280881A
    • 2010-12-16
    • JP2009286273
    • 2009-12-17
    • Yokohama Rubber Co Ltd:The横浜ゴム株式会社
    • TATEWAKI TAKANOBUSAI MOTOFUMI
    • C08G18/64C08G18/10C08G18/70C08G75/14
    • PROBLEM TO BE SOLVED: To provide a curable composition excellent in adhesion and curability.
      SOLUTION: An isocyanate group-containing polysulfide polymer having an isocyanate group is obtained by reacting a hydroxyl group-containing polysulfide polymer having a hydroxyl group, which is obtained from a reaction of a polysulfide polymer having a thiol group with a (meth)acrylic acid ester of polyoxyalkylene glycol and/or hydroxyalkyl(meth)acrylate, with a polyisocyanate compound. An oxazolidine-containing polysulfide polymer having oxazolidine is obtained by reacting the isocyanate group-containing polysulfide polymer with an active hydrogen group-containing oxazolidine compound having an active hydrogen group. The curable composition contains the isocyanate group-containing polysulfide polymer and/or the oxazolidine-containing polysulfide polymer and a urethane prepolymer.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 待解决的问题:提供粘附性和固化性优异的固化性组合物。 解决方案:具有异氰酸酯基的含异氰酸酯基的多硫化物聚合物是通过使具有羟基的含羟基的多硫化物聚合物(其由具有硫醇基的多硫化物聚合物的反应得到的)与(甲基) )聚氧亚烷基二醇和/或(甲基)丙烯酸羟烷基酯的丙烯酸酯与多异氰酸酯化合物。 通过使含异氰酸酯基的多硫化物聚合物与具有活性氢基团的含活性氢基的恶唑烷化合物反应,得到具有恶唑烷的含恶唑烷的多硫化物聚合物。 可固化组合物含有含异氰酸酯基的多硫化物聚合物和/或含恶唑烷的多硫化物聚合物和氨基甲酸酯预聚物。 版权所有(C)2011,JPO&INPIT
    • 8. 发明专利
    • Method for producing one-pack moisture-curable polyurethane composition
    • 生产单层水分可固化聚氨酯组合物的方法
    • JP2010174177A
    • 2010-08-12
    • JP2009020152
    • 2009-01-30
    • Yokohama Rubber Co Ltd:The横浜ゴム株式会社
    • TACHIBANA KUMIKOTATEWAKI TAKANOBUHOSOKAWA NAOYUKI
    • C08G18/10C08K3/00C08K3/04C08L75/04
    • PROBLEM TO BE SOLVED: To provide a method for producing a one-pack moisture-curable polyurethane composition excellent in thixotropy with good appearance, and to provide a method for producing the composition, significantly improving the production yield by accurately measuring the NCO% and utilizing the measurement result as a feedback to a stage prior to the production process.
      SOLUTION: The method for producing a one-pack moisture-curable polyurethane composition includes: a step (X) of obtaining a mixture (α) by mixing a component (A) containing an active hydrogen compound and a powder component (B) containing no calcium carbonate; a step of at least partially eliminating the residual water content in the mixture (α); a step of obtaining a mixture (β) containing a urethane prepolymer by mixing a polyisocyanate compound (C) with the above paste mixture (α); a step of measuring the NCO% in the mixture (β); and a step (Y) of mixing the mixture (β) with calcium carbonate.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供一种具有良好外观的触变性优异的单组分湿气固化性聚氨酯组合物的制造方法,提供一种制造该组合物的方法,通过精确测定NCO,显着提高生产率 %,并将测量结果用作在生产过程之前的阶段的反馈。 制造单组分湿气固化型聚氨酯组合物的方法包括:通过混合含有活性氢化合物的组分(A)和粉末组分(B)得到混合物(α)的步骤(X) )不含碳酸钙; 至少部分消除混合物(α)中的残留水分含量的步骤; 通过将多异氰酸酯化合物(C)与上述糊料混合物(α)混合,得到含有氨基甲酸酯预聚物的混合物(β)的步骤; 测量混合物(N)中NCO%的步骤; 和混合物(β)与碳酸钙的步骤(Y)。 版权所有(C)2010,JPO&INPIT
    • 10. 发明专利
    • Latent curing agent and curable resin composition using the same
    • 使用相同的固化剂和可固化树脂组合物
    • JP2010024286A
    • 2010-02-04
    • JP2008184890
    • 2008-07-16
    • Yokohama Rubber Co Ltd:The横浜ゴム株式会社
    • SAI MOTOFUMITATEWAKI TAKANOBU
    • C08G18/38C07D263/04
    • PROBLEM TO BE SOLVED: To provide a curable resin composition which has an excellent balance between storage stability (workability) of a base material component and curing property after mixing the base material component and a curing agent component, has good anti-foaming property and can reduce a volatile component to the outside of the system, and to provide a latent curing agent used for the composition. SOLUTION: The latent curing agent is expressed by formula (1) or (2), wherein n represents an integer of 0 to 2; R 1 represents a hydroxy group or an alkyl group or alkoxy group having 1 to 12 carbon atoms which may be branched, and when n is 2, R 1 may be identical or different from each other; R 2 represents an alkyl group or alkoxy group having 1 to 6 carbon atoms, which may be branched or have a hydroxy group; each of R 3 and R 4 independently represents a hydrogen atom or an alkyl group or phenyl group having 1 to 6 carbon atoms which may be branched. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供在基材成分的保存稳定性(加工性)和混合基材成分与固化剂成分后的固化性能之间具有优异平衡性的固化性树脂组合物,具有良好的消泡性 性能并且可以将挥发性组分减少到系统外部,并提供用于组合物的潜在性固化剂。 解决方案:潜在性固化剂由式(1)或(2)表示,其中n表示0至2的整数; R 1表示可以是支链的羟基或具有1至12个碳原子的烷基或烷氧基,当n是2时,R“1”可以相同或 彼此不同; R SP 2表示可以是支链或具有羟基的碳原子数为1〜6的烷基或烷氧基; R SP 3和R SP 4中的每一个独立地表示氢原子或可以是支链的具有1至6个碳原子的烷基或苯基。 版权所有(C)2010,JPO&INPIT