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    • 4. 发明专利
    • PRODUCTION OF SINTERED QUARTZ GLASS MOLDED ARTICLE
    • JP2000103630A
    • 2000-04-11
    • JP28869298
    • 1998-09-28
    • USHIO ELECTRIC INC
    • TAGAWA KOJITORIKAI TETSUYA
    • C03B8/00C03B19/06C03B20/00C03B32/00C04B35/14C04B35/64
    • PROBLEM TO BE SOLVED: To provide a method for producing a sintered quartz glass molded article, capable of giving the article having enhanced light transmittance by sintering a false quartz powder molded article consisting mainly of quartz glass in an atmosphere having a specific hydrogen pressure or larger and a specified temperature or higher. SOLUTION: A false quartz glass molded product is sintered in an atmosphere having a hydrogen pressure of >=10-2 Pa and a temperature of >=1,773K. When hydrogen gas is contained in the sintering atmosphere, SiO2 is reacted with hydrogen to produce SiO and SiH4, which are scattered from the quartz glass because of having high volatility. Since crystalline quartz such as cristobalite or β-quartz which is by-produced on the sintering treatment do not leave on the surface of the quartz glass, the transparent molded article having a high light transmission is obtained. When the atmosphere comprises pure hydrogen gas having a high hydrogen gas pressure, the reaction often excessively proceeds to largely consume SiO2. Thereby, when the atmosphere comprising a gas mixture of hydrogen gas with an inert gas is used as the sintering atmosphere and further when the sintering temperature is controlled, the consumption of the quartz glass due to the scattering of the SiO2, SiH4, etc., can be inhibited.
    • 7. 发明专利
    • METHOD FOR SINTERING SINTERED QUARTZ GLASS MOLDING
    • JP2000086251A
    • 2000-03-28
    • JP28045498
    • 1998-09-17
    • USHIO ELECTRIC INC
    • TAGAWA KOJIMORINAGA KENJITORIKAI TETSUYA
    • C03B8/00C03B19/06C03B20/00C03B32/00
    • PROBLEM TO BE SOLVED: To obtain a crystal-free dense transparent sintered quartz glass which does not get cloudy or crack even after long-time use at a high temperature by selecting a partial pressure of oxygen in a sintering atmosphere and a sintering temperature at which Moganite is formed in a sintering process and carrying out sintering. SOLUTION: A sintered quartz glass molding is sintered in an atmosphere at =1,530 deg.K sintering temperature. Microcrystals of cristobalite, β-quartz, etc., formed on the surface of the molding are not further formed and Moganite as one of polymorphisms of silica is formed. Since the formed Moganite is released from the surface at >=1,530 deg.K, the objective dense sintered quartz glass is obtd. A slurry is prepd. from silica powder of 1.5 μm average particle diameter, poured into a gypsum mold and dried to form a primary molding. This molding is heated in hydrogen at 1,273 deg.K for about 1 hr and the resultant temporarily sintered molding is sintered at a partial pressure of oxygen and a sintering temperature at which is formed. The sintered molding does not get cloudy or crack even after long-time use at >=973 deg.K.
    • 9. 发明专利
    • FUNCTIONALLY GRADIENT MATERIAL AND LAMP
    • JP2000037806A
    • 2000-02-08
    • JP20780798
    • 1998-07-23
    • USHIO ELECTRIC INC
    • TORIKAI TETSUYAMORINAGA KENJITAGAWA KOJI
    • B32B5/14B32B7/02B32B15/00C09K3/10H01J61/36
    • PROBLEM TO BE SOLVED: To provide a functionally gradient material comprising an insulating inorg. substance component and a conductive inorg. substance component and reduced in the microscopic gap of thermal expansion characteristics in a structure and large in thermal durability and a lamp comprising the functionally gradient material. SOLUTION: A functionally gradient material is constituted by laminating first - third layers and the first layer L1 contains a first insulating inorg. substance component and a second insulating inorg. substance component having the coefficient of linear expansion between that of the first insulating inorg. substance component and that of a conductive inorg. substance component and the second layer L2 contains a second insulating inorg. substance component and the third layer L3 contains the second insulating inorg. substance component and the conductive inorg. substance component. The ratio of the first insulating inorg. substance component is reduced in the order of the first, second and third layers L1, L2, L3 and the ratio of the second insulating inorg. substance component is larger than the first and third layers L1, L3 in the second layer L2 and the ratio of the conductive inorg. substance component is increased in the order of the first, second and third layers L1, L2, L3. In a lamp, the seal member comprising the functionally gradient material is used in the constitution of a seal part.