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    • 1. 发明专利
    • SURFACE-TREATING DEVICE FOR PHOTORESIST
    • JPH10149982A
    • 1998-06-02
    • JP35338796
    • 1996-11-20
    • USHIO ELECTRIC INC
    • ISO SHINICHIMATSUNO HIROMITSUIGARASHI RYUSHIKAMEDA SHINJI
    • G03F7/20H01L21/027
    • PROBLEM TO BE SOLVED: To provide a surface-treating device which can only reform the surface of a photoresist applied to a silicon substrate, etc. SOLUTION: A surface-treating device only reforms the surface of a photoresist by irradiating the surface with vacuum ultraviolet rays having a wavelength of 172nm from excimer lamps 1 (1a, 1b, 1c,...) utilizing dielectric barrier discharge of in a tube wall load without substantially causing any reaction between ultraviolet rays having wavelengths which do not fall within the range of 170-200nm and the photoresist. The device also irradiates the photoresist with vacuum ultraviolet rays having a wavelength of 185nm and ultraviolet ryas having a wavelength of 185nm emitted from low-pressure mercury lamps through an optical filter which transmits more ultraviolet rays having the wavelength of 185nm than those having a wavelength of 254nm so that the intensity of the vacuum ultraviolet rays having the wavelength of 185nm can become 10 times or more stronger than that of the ultraviolet rays having the wavelength of 254nm on the surface of the photoresist. A high AC voltage is applied across the device so that the device can repeat discharge generating periods for emitting the ultraviolet rays and no-discharge generating periods (Tb).
    • 3. 发明专利
    • OPTICAL CLEANING METHOD
    • JPH08236492A
    • 1996-09-13
    • JP6011895
    • 1995-02-24
    • USHIO ELECTRIC INC
    • ISO SHINICHIMATSUNO HIROMITSUIGARASHI RYUSHISUGAWARA HIROSHIHIRAMOTO TATSUMI
    • B08B7/00H01L21/302H01L21/304H01L21/3065
    • PURPOSE: To improve th cleaning efficiency of an optical cleaning method and, at the same time, to reduce the damage to an object to be cleaned by ultraviolet rays or heat by turning on and turning off ultraviolet lamps while the object is cleaned by repeatedly turning on and turning off the power source of the ultraviolet lamps. CONSTITUTION: About five dielectric barrier discharge lamps 4 which are composed of ultraviolet lamps are arranged closely to an object 8 to be cleaned in a cleaning duct 3 while the lamps 4 are connected in parallel with one power source 10 and the object 8 is supported by a supporting jig 5. The object 8 is cleaned by using such an irradiating device by turning on and turning off the lamps 4 while the object 8 is cleaned by repeatedly turning on and turning off the power source 10. When the lamps 4 are turned on, the object 8 is cleaned by the same action as that of the prior art optical cleaning. In addition, even when the lamps 4 are turned off, the object 8 is cleaned, because contaminants are decomposed as a result of a reaction between the contaminants and the active oxygen species remaining in the duct 3. Therefore, the object 8 can be cleaned with a cleaning efficiency which is higher than that obtained when the lamps 4 are continuously turned on. In addition, the object 8 is not damage by heat, because the temperatures of the lamps 4 do not rise.
    • 5. 发明专利
    • METHOD FOR MODIFYING PLASTIC SURFACE
    • JPH07179629A
    • 1995-07-18
    • JP34465893
    • 1993-12-21
    • USHIO ELECTRIC INC
    • HIRAMOTO TATSUMIIGARASHI RYUSHIMATSUNO HIROMITSUMATSUSHIMA TAKEOISO SHINICHI
    • C08J7/00
    • PURPOSE:To improve the rate of surface modification by allowing a dielectric barrier discharge lamp which uses a part or the whole of the enclosure of a radiating space as a radiation outlet to radiate while keeping the smallest thickness of a water layer, the shortest radiation passage distance, below a specified value. CONSTITUTION:A sheet 109 of a plastic having C-F bonds (e.g. a polyfluoroethylene) or C-H bonds (e.g. PP) is caused to pass through near the liq. level 23 while the temp. of a radiation outlet in a water tank 21 contg. water 22 is kept at 250 deg.C or lower with a cooling medium 25. The surface of the sheet thus passing through is modified by exposing it ti vacuum ultraviolet rays with wavelengths of 160-200mum emitted from a dielectric barrier discharge lamp 105 sealed with Xe or a gas mainly comprising Xe at a tube wall load of 0.2W/cm or higher while the smallest thickness of the water layer, the shortest radiation passage distance, on the top 13 of the radiation outlet of the lamp 105 is kept at 5mum or lower. When the sealed gas is Ar/Cl2 or a Cl compd., the distance is kept at 20mum or lower; when the gas is Ar/F or an F compd., to 2,000mum or lower.
    • 6. 发明专利
    • METHOD FOR MODIFYING PLASTIC SURFACE
    • JPH07179628A
    • 1995-07-18
    • JP34465793
    • 1993-12-21
    • USHIO ELECTRIC INC
    • HIRAMOTO TATSUMIIGARASHI RYUSHIMATSUNO HIROMITSUMATSUSHIMA TAKEOISO SHINICHI
    • C08J7/00
    • PURPOSE:To improve the rate of surface modification by allowing a dielectric barrier discharge lamp which uses a part or the whole of the enclosure of a radiating space as a radiation outlet to radiate while keeping the thickness of an aq. soln, layer, the shortest radiation passage distance, below a specified value. CONSTITUTION:A sheet 109 of a plastic having C-F bonds (e.g. a polyfluoroethylene) is passed through near the liq. level 23 while the temp. of a radiation outlet in a water tank 21 contg. an aq. soln. 22 of an Al compd. [e.g. Al(OH)3] or a B compd. (e.g. H3BO3) is kept at 250 deg.C or lower with a cooling medium 25. The surface of the sheet thus passing through is modified by exposing it to rays of radiation with wavelengths of 160-200mu emitted from an dielectric barrier discharge lamp 105 sealed with Xe or a gas mainly comprising Xe at as tube wall load of 0.2W/cm while the smallest thickness of the liq. layer, the shortest radiation passage distance, on the top 13 of the radiation outlet of the lamp 105 is kept at 5mum or lower. When the sealed gas is Ar/Cl2 or a Cl compd., the distance is kept at 20mum or lower; when the sealed gas is Ar/F or an F compd., at 2,000mum or lower.