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    • 1. 发明专利
    • Method for producing carbon nanotube and method for producing electrode for fuel cell
    • 制备碳纳米管的方法和用于生产燃料电池的电极的方法
    • JP2011148673A
    • 2011-08-04
    • JP2010044276
    • 2010-03-01
    • Chiba UnivToyota Motor Corpトヨタ自動車株式会社国立大学法人 千葉大学
    • MURATA NARUAKIIMANISHI MASAHIROIMAIZUMI YOSHIAKIKUSHIDA MASATO
    • C01B31/02H01M4/96
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To provide a method for producing carbon nanotubes, which method uses an LB (Langmuir-Blodgett) method and controls the number of the carbon nanotubes per unit area to a desired value. SOLUTION: In the method for producing carbon nanotubes, metallic microparticles 24 having surfaces modified with stearic acid are prepared as an LB film substance 22. As the metallic particles 24, an iron (Fe) nanocolloid having a particle diameter of about 5 nm is used. The LB film substance 22 is dropped onto the water surface of a trough 12, and as shown with a drawing 2, the LB film substance 22 is transcribed onto the retaining surface of a substrate 30. After a process of film formation by using the LB method is performed, the substrate 30 is arranged in a CVD apparatus 50. Calcination is performed with an electric furnace 52 in order to eliminate the stearic acid. A raw material gas of the carbon nanotubes is continuously flowed into a CVD apparatus 50 in order to cause the carbon nanotubes to grow. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供一种生产碳纳米管的方法,该方法使用LB(Langmuir-Blodgett)方法并将每单位面积的碳纳米管数控制到所需值。 解决方案:在制备碳纳米管的方法中,制备具有用硬脂酸改性的表面的金属微粒24作为LB膜物质22.作为金属颗粒24,将粒径为约5的铁(Fe)纳米胶体 nm。 将LB膜物质22滴落到槽12的水面上,如图2所示,LB膜物质22被转印到基板30的保持面上。在使用LB的成膜工序 执行方法,将基板30布置在CVD装置50中。为了消除硬脂酸,用电炉52进行煅烧。 将碳纳米管的原料气体连续流入CVD装置50,以使碳纳米管生长。 版权所有(C)2011,JPO&INPIT
    • 2. 发明专利
    • Control device of fuel cell system
    • 燃料电池系统的控制装置
    • JP2009009891A
    • 2009-01-15
    • JP2007172027
    • 2007-06-29
    • Toyota Motor Corpトヨタ自動車株式会社
    • TAKEUCHI HIROAKIMURATA NARUAKI
    • H01M8/04H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a control device of a fuel cell system which can detect the drying state of an electrolyte membrane surely and in an early stage.
      SOLUTION: The control device (25) of the fuel cell system is provided with a measuring means for measuring a pressure loss of a fuel gas in the fuel cell, a calculating means which, based on the pressure loss of the fuel gas measured by the measuring means, calculates a lowered amount of the pressure loss of the fuel gas in a predetermined time duration, and a diagnosing means which, based on the lowered amount of the pressure loss of the fuel gas calculated by the calculating means, diagnoses the drying state in the fuel cell by determining that there exist such cells in which a portion of an electrolyte membrane becomes dry and partial deviation occurs in a reaction region of an electrolyte membrane.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种可以确定地和早期地检测电解质膜的干燥状态的燃料电池系统的控制装置。 解决方案:燃料电池系统的控制装置(25)设置有用于测量燃料电池中的燃料气体的压力损失的测量装置,计算装置,其基于燃料气体的压力损失 通过测量装置测量,计算预定持续时间内燃料气体的压力损失的降低量,以及诊断装置,其基于由计算装置计算的燃料气体的压力损失量的降低量诊断 通过确定存在电解质膜的一部分变得干燥并且在电解质膜的反应区域中发生部分偏移的这种单元,来确定燃料电池中的干燥状态。 版权所有(C)2009,JPO&INPIT
    • 3. 发明专利
    • Fuel cell, and its manufacturing method
    • 燃料电池及其制造方法
    • JP2007134182A
    • 2007-05-31
    • JP2005326704
    • 2005-11-10
    • Toyota Motor Corpトヨタ自動車株式会社
    • MURATA NARUAKINAKANISHI HARUMICHIIMANISHI MASAHIROTAMURA YOSHIHISA
    • H01M8/24H01M8/02H01M8/10
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a fuel cell in which fixing work of a plurality of hollow type cells can be simplified to have high productivity in the fuel cell having a structure in which the plurality of the hollow type cells are integrally fixed. SOLUTION: This is the fuel cell which has a hollow electrolyte membrane, a pair of electrodes installed on the inner and outer surfaces of the hollow electrolyte membrane, and current collecting materials respectively connected to the pair of the electrodes, which is provided with the two or more hollow type cells in which at least one end part is opened, and which has a cell assembly in which a twisted structure for twisting bundles of slender members including the two or more hollow type cells is retained by a bundling member. COPYRIGHT: (C)2007,JPO&INPIT
    • 解决的问题:提供一种燃料电池,其中可以简化多个中空型电池的固定工作,从而在具有多个中空型电池整体固定的结构的燃料电池中具有高生产率 。 解决方案:这是具有中空电解质膜,安装在中空电解质膜的内表面和外表面上的一对电极以及分别连接到一对电极的集电材料的燃料电池,其设置 与其中至少一个端部打开的两个或更多个中空型电池,并且其具有电池组件,其中用于扭绞包括两个或更多个中空型电池的细长构件的束的扭曲结构被捆扎构件保持。 版权所有(C)2007,JPO&INPIT
    • 4. 发明专利
    • Fuel cell
    • 燃料电池
    • JP2007134181A
    • 2007-05-31
    • JP2005326700
    • 2005-11-10
    • Toyota Motor Corpトヨタ自動車株式会社
    • NAKANISHI HARUMICHIMURATA NARUAKIIMANISHI MASAHIROTAMURA YOSHIHISA
    • H01M8/04H01M8/02H01M8/10H01M8/24
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To improve power generation efficiency of a fuel cell by reducing the amount of energy consumed by operation of auxiliary equipment such as a pump for circulating a coolant.
      SOLUTION: This is the fuel cell which is provided with hollow type cells 6 and a cooling device 7. The cooling device is provided with a cooling part 8 for directly cooling the hollow type cells, a coolant returning part 10 for forming a circulation passage together with the cooling part, and a heat exchanger 9 for cooling the coolant discharged from the cooling part. The cooling part has a flow passage including an up-flowing passage 8a where the direction has been decided from the gravity direction lower part side to the gravity direction upper part side, and the coolant returning part has the flow passage including a down-flowing passage 10a where the direction from the gravity direction upper part side to the gravity direction lower part side has been decided. The heat exchanger enables so that the coolant is circulated by utilizing natural convection in order that the coolant can be circulated through the flow passage in the coolant returning part naturally in the circulation direction using a downward force generated by the contraction caused by the heat deprived of by the heat exchanger.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:通过减少诸如用于循环冷却剂的泵的辅助设备的操作所消耗的能量的量来提高燃料电池的发电效率。 解决方案:这是设置有中空型电池6和冷却装置7的燃料电池。冷却装置设置有用于直接冷却中空型电池的冷却部8,用于形成 循环通道和冷却部分,以及用于冷却从冷却部排出的冷却剂的热交换器9。 冷却部具有流路,该流路包括从重力方向下部侧到重力方向上部侧的方向的上游通道8a,并且冷却剂返回部具有包括下流通道 10a,其中已经确定了从重力方向上部侧到重力方向下部侧的方向。 热交换器使得冷却剂能够通过利用自然对流而循环,以便冷却剂可以通过冷却剂返回部件中的流动通道循环而循环,该向下的流动由产生的由热量 通过热交换器。 版权所有(C)2007,JPO&INPIT
    • 6. 发明专利
    • Membrane electrode composite for fuel cell
    • 用于燃料电池的膜电极复合材料
    • JP2006216420A
    • 2006-08-17
    • JP2005028531
    • 2005-02-04
    • Toyota Motor Corpトヨタ自動車株式会社
    • IMANISHI MASAHIRONAKANISHI HARUMICHIMURATA NARUAKITAMURA YOSHIHISA
    • H01M8/02H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a membrane electrode composite of which the output density per a unit volume is high and of which the current collection efficiency is high. SOLUTION: The membrane electrode composite for a fuel cell comprises at least a tubular solid electrolyte membrane, an outside catalyst electrode layer formed at the outer peripheral face of the solid electrolyte membrane, an inside catalyst electrode layer arranged at the inside of the solid electrolyte membrane, and an inside current collector having a columnar shape arranged at the inside of the inside catalyst electrode layer. The membrane electrode composite for the fuel cell is provided in which a plurality of grooves are formed in the outer peripheral face of the inside current collector in the axial direction, an inside current collector side inside catalyst electrode layer is formed which is the inside catalyst electrode layer formed on a recessed face of the groove of the inside current collector, a solid electrolyte membrane side inside catalyst electrode layer is formed which is the inside catalyst electrode layer formed on the inner peripheral face of the solid electrolyte membrane, and the inside current collector side inside catalyst electrode layer and the solid electrolyte membrane side inside catalyst electrode layer are continuously formed so as to form an inside catalyst electrode layer inner space in its inner part. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种单位体积的输出密度高且电流收集效率高的膜电极复合体。 解决方案:用于燃料电池的膜电极复合材料至少包括管状固体电解质膜,形成在固体电解质膜的外周面的外部催化剂电极层,布置在固体电解质膜的内侧的内部催化剂电极层 固体电解质膜和内部集电体,其内部具有排列在内侧的催化剂电极层的内部的柱状。 提供了一种燃料电池用膜电极复合体,其在轴向上在内部集电体的外周面形成有多个槽,形成内侧的催化剂电极层的内部集电体侧,内侧的催化剂电极 形成在内部集电体的槽的凹面上的层,形成在固体电解质膜的内周面上形成的内侧催化剂电极层的内部的固体电解质膜侧的内部集电体 连续形成催化剂电极层内侧的固体电解质膜侧和固体电解质膜侧,以在其内部形成内部的催化剂电极层内部空间。 版权所有(C)2006,JPO&NCIPI
    • 7. 发明专利
    • Inside current collector used for membrane electrode composite for fuel cell, and membrane electrode composite for fuel cell
    • 用于燃料电池的膜电极组合物的内部集电器和用于燃料电池的膜电极复合材料
    • JP2006216418A
    • 2006-08-17
    • JP2005028529
    • 2005-02-04
    • Toyota Motor Corpトヨタ自動車株式会社
    • IMANISHI MASAHIRONAKANISHI HARUMICHIMURATA NARUAKITAMURA YOSHIHISA
    • H01M8/02H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide an inside current collector capable of homogenizing gas concentration in a membrane electrode composite for a fuel cell and furthermore capable of preventing flooding. SOLUTION: The inside current collector used for the membrane electrode composite for the fuel cell at least comprises a tubular solid electrolyte membrane, an outside catalyst electrode layer formed in the outer peripheral face of the solid electrolyte membrane, an inside catalyst electrode layer formed at the inner peripheral face of the solid electrolyte membrane, and the inside current collector arranged so as to be contacted with the inner peripheral face of the inner catalyst electrode layer, and has at least two axial direction flow passages formed in the tubular axial direction and a coupling flow passage to couple between the axial direction passages. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种能够均匀化用于燃料电池的膜电极复合材料中的气体浓度的内部集电体,并且还能够防止淹水。 解决方案:用于燃料电池的膜电极复合体的内部集电体至少包括管状固体电解质膜,形成在固体电解质膜的外周面的外部催化剂电极层,内部催化剂电极层 形成在所述固体电解质膜的内周面上,所述内部集电体被配置成与所述内部催化剂电极层的内周面接触,并且具有沿管状轴向形成的至少两个轴向流路 以及联接流动通道以在轴向通道之间联接。 版权所有(C)2006,JPO&NCIPI
    • 8. 发明专利
    • Fuel cell and separator
    • 燃油电池和分离器
    • JP2005235666A
    • 2005-09-02
    • JP2004045601
    • 2004-02-23
    • Toyota Motor Corpトヨタ自動車株式会社
    • KOBAYASHI NORIYUKIMURATA NARUAKISANO SEIJIGOTO SHOGOKOBAYASHI MASAFUMI
    • H01M8/02H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a fuel cell having a separator of porous material in which generated water in a diffusion layer is efficiently discharged. SOLUTION: The fuel cell 10 has a cathode separator 22 comprising a compact portion and a porous portion in which the area ratio of the contact region 229P to the non-contact region (oxidation gas passage) of the porous portion 40 and the diffusion layer 212 is set to be larger than the are ratio of the contact region 229S to the non-contact region (oxidation gas passage) of the compact portion and the diffusion layer 212. Further, the porous portion 40 has a predetermined shape (71-78) as area increasing means on the contacting surface in the contact region 229P. As the result, the generated water condensed in diffusion layer 212 is effectively absorbed in the porous portion 40. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决的问题:提供一种燃料电池,其具有多孔材料的隔膜,其中扩散层中的生成水被有效地排出。 解决方案:燃料电池10具有阴极分离器22,其包括致密部分和多孔部分,其中接触区域229P与多孔部分40的非接触区域(氧化气体通道)的面积比和 扩散层212被设定为大于接合区域229S与致密部分和扩散层212的非接触区域(氧化气体通道)的比例。此外,多孔部分40具有预定的形状(71 -78)作为接触区域229P中的接触表面上的面积增加装置。 结果,在扩散层212中凝结的产生的水被有效地吸收在多孔部分40中。版权所有(C)2005,JPO&NCIPI
    • 9. 发明专利
    • Fuel cell system and method of operating the fuel cell system
    • 燃料电池系统和操作燃料电池系统的方法
    • JP2010251219A
    • 2010-11-04
    • JP2009101557
    • 2009-04-20
    • Toyota Motor Corpトヨタ自動車株式会社
    • NAKAZAWA SATORUMURATA NARUAKI
    • H01M8/04H01M8/02
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To improve power generation performance of a fuel cell using a nonaqueous electrolyte attaining generating operation in a moderate temperature range.
      SOLUTION: A fuel cell system 20 includes a fuel cell stack 30 on which a plurality of fuel cells 31 are laminated. The fuel cell 31 is a fuel cell using an ionic liquid in an electrolyte membrane. When a voltage V of the fuel cell 31 drops to a value lower than a predetermined value Th, the fuel cell system 20 flows a current larger than an output request 95, starts a heater 75 to supply an oxidation gas which is higher than 100°C to the fuel cell stack 30, switches the supply route of the oxidation gas from a route via bypass pining 77 to a route via a dehydrating device 74 to supply dry air to the fuel cell stack 30, and increases the flow velocity of the oxidation gas to be supplied.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提高使用非水电解质的燃料电池在中等温度范围内实现发电操作的发电性能。 解决方案:燃料电池系统20包括其上层叠有多个燃料电池31的燃料电池组30。 燃料电池31是在电解质膜中使用离子液体的燃料电池。 当燃料电池31的电压V下降到低于预定值Th的值时,燃料电池系统20流过大于输出请求95的电流,启动加热器75以提供高于100°的氧化气体 C向燃料电池堆30切换氧化气体的供给路径,经由旁通管路77从路径经由脱水装置74向路径供给,向燃料电池堆30供给干燥空气,并且提高氧化物的流速 供应气体 版权所有(C)2011,JPO&INPIT