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1. 发明专利

JP2012217938A An exhaust gas purifying catalyst 审中-公开
标题翻译：排气净化催化剂
公开(公告)号：JP2012217938A
公开(公告)日：2012-11-12
申请号：JP2011086720
申请日：2011-04-08
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： TAKAGI NOBUYUKI , SOFUE YUICHI , IKEDA HIDEYOSHI , INDE RYOICHI
IPC分类号： B01J23/44 , B01D53/86 , B01D53/94 , F01N3/10 , F01N3/24
摘要： PROBLEM TO BE SOLVED: To provide an exhaust gas purifying catalyst capable of preventing the S poisoning of a metal catalyst (noble metal) to keep suitable catalytic activity.SOLUTION: The exhaust gas purifying catalyst 50 includes a base material 54, a lower layer 66 arranged on the base material 54 and an upper layer 62 arranged on the lower layer 66. The upper layer 62 is equipped with a carrier 63 and Pt 64 being a noble metal supported on the carrier 63 and not substantially equipped with Pd. Further, the upper layer is equipped with a hydrocarbon adsorbent 65 while the lower layer 66 is equipped with a carrier 67, and Pt 68 and Pd 69 being the noble meals supported on the carrier 67.
摘要翻译：要解决的问题：提供能够防止金属催化剂（贵金属）的S中毒以保持合适的催化活性的废气净化催化剂。解决方案：废气净化催化剂50包括基材54，布置在基材54上的下层66和布置在下层66上的上层62.上层62装有载体63和 Pt 64是负载在载体63上并且基本上不配备Pd的贵金属。此外，上层配备有碳氢化合物吸附剂65，而下层66配备有载体67，Pt 68和Pd 69是载体67上的贵重餐。权利要求：（C）2013， JPO＆INPIT

2. 发明专利

JP2012217933A An exhaust gas purifying catalyst 审中-公开
标题翻译：排气净化催化剂
公开(公告)号：JP2012217933A
公开(公告)日：2012-11-12
申请号：JP2011086457
申请日：2011-04-08
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： TAKAGI NOBUYUKI , SOFUE YUICHI , IKEDA HIDEYOSHI , INDE RYOICHI
IPC分类号： B01J23/44 , B01D53/86 , B01D53/94 , F01N3/08 , F01N3/10 , F01N3/24 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To provide an exhaust gas purifying catalyst excellent in the purification capacity for carbon monoxide even under a low temperature condition.SOLUTION: The exhaust gas purifying catalyst includes a base material 54, a lower layer 60 arranged on the base material 54 and an upper layer 62 arranged on the lower layer 60. The lower layer 60 has a carrier 64 and Pd particles 66 and Pt particles 68 supported on the carrier 64 as noble metals. Further, the upper layer 62 has the carrier 64, the Pd particles 66 supported on the carrier 64 as the noble metals and a hydrocarbon adsorbing material 70. In this exhaust gas purifying catalyst, the HC poisoning of the catalyst is suppressed and the purification capacity for carbon monoxide under the low temperature condition is enhanced.
摘要翻译：要解决的问题：即使在低温条件下也提供一氧化碳的净化能力优异的排气净化催化剂。解决方案：废气净化催化剂包括基材54，布置在基材54上的下层60和布置在下层60上的上层62.下层60具有载体64和Pd颗粒66 和作为贵金属负载在载体64上的Pt颗粒68。此外，上层62具有载体64，作为贵金属担载在载体64上的Pd颗粒66和烃吸附材料70.在该废气净化催化剂中，催化剂的HC中毒被抑制，并且净化能力对于一氧化碳在低温条件下的增强。版权所有（C）2013，JPO＆INPIT

3. 发明专利

JP2012245429A Noble metal supported catalyst 审中-公开
标题翻译： NOBLE金属支持的催化剂
公开(公告)号：JP2012245429A
公开(公告)日：2012-12-13
申请号：JP2011116742
申请日：2011-05-25
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： IKEDA HIDEYOSHI , MIURA MASAHIDE , SAITO YOSHINORI
IPC分类号： B01J23/63 , B01D53/94 , B01J37/03 , F01N3/10 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To provide a noble metal supported catalyst that can exert high catalytic activity from a point of time immediately after manufactured, and can maintain the high catalytic activity even after a long-term operation.SOLUTION: The noble metal supported catalyst contains a support formed of a plurality of particles agglomerating that contain a metal oxide, and a plurality of particles of a catalytic noble metal supported on surfaces of the particles located in the support.
摘要翻译：要解决的问题：提供一种能够在制造后立即施加高催化活性的贵金属担载催化剂，并且即使在长期运行后也能保持高的催化活性。解决方案：贵金属负载型催化剂含有由多个颗粒聚集形成的载体，所述颗粒含有金属氧化物，并且多个颗粒的催化贵金属负载在位于载体中的颗粒的表面上。版权所有（C）2013，JPO＆INPIT

4. 发明专利

JP2011147901A Exhaust gas purifying catalyst 审中-公开
标题翻译：排气净化催化剂
公开(公告)号：JP2011147901A
公开(公告)日：2011-08-04
申请号：JP2010012247
申请日：2010-01-22
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： IKEDA HIDEYOSHI , KANAZAWA TAKAAKI
IPC分类号： B01J23/63 , B01D53/94 , B01J37/04 , F01N3/10
CPC分类号： B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/407 , B01D2255/908 , B01D2255/9207 , B01D2258/014 , B01J21/066 , B01J23/63 , B01J37/0244 , B01J37/0248 , Y02T10/22
摘要： PROBLEM TO BE SOLVED: To have a high specific surface area even after a high-temperature enduring at 1,000°C or higher, and to prevent a sintering of a noble metal to improve a durability. SOLUTION: An exhaust gas purifying catalyst includes a catalyst powder supporting Pt on a ceria-zirconia composite oxide and a Ce/alumina powder containing Ce in the structure. The Ce/alumina has a little deterioration degree of the specific surface area even in a high-temperature lean atmosphere. Further, it is thought that in Pt supported by the ceria-zirconia composite oxide, a Pt-O-Ce bond is formed between Ce present finely on a Ce/alumina surface. Therefore, migration of Pt is controlled and the sintering is prevented. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：即使在1000℃以上的高温耐久性之后也具有高的比表面积，并且防止贵金属的烧结以提高耐久性。解决方案：废气净化催化剂包括在二氧化铈 - 氧化锆复合氧化物上负载Pt的催化剂粉末和在该结构中含有Ce的Ce /氧化铝粉末。 Ce /氧化铝即使在高温稀薄气氛中也具有比表面积的劣化程度。此外，认为在由氧化铈 - 氧化锆复合氧化物负载的Pt中，在Ce /氧化铝表面上精细地存在的Ce之间形成Pt-O-Ce键。因此，可以控制Pt的迁移，防止烧结。版权所有（C）2011，JPO＆INPIT

5. 发明专利

JP2014202596A 微量物質の分析方法审中-公开
标题翻译：追踪物质分析方法
公开(公告)号：JP2014202596A
公开(公告)日：2014-10-27
申请号：JP2013078692
申请日：2013-04-04
申请人：トヨタ自動車株式会社 , Toyota Motor Corp
发明人： KIMOTO HIROYUKI , IKEDA HIDEYOSHI
IPC分类号： G01N21/65
摘要：【課題】微量物質を高感度検出することが可能な、微量物質の分析方法を提供する。【解決手段】微量物質に黄色発色団を形成する工程と、黄色発色団を形成された微量物質へ、波長が380nm以上490nm未満である光を照射する工程と、光の照射後に得られるラマンスペクトルを分析する工程とを有する、微量物質の分析方法とする。【選択図】図1
摘要翻译：要解决的问题：提供一种配置成以高精度检测痕量物质的痕量物质分析方法。微量物质分析方法包括以下步骤：在痕量物质中形成黄色发色团; 用形成在其中的黄色发色团用波长380-490nm的光照射微量物质; 并分析在光照射后获得的拉曼光谱。

6. 发明专利

JP2012217937A Exhaust gas purifying catalyst, and exhaust gas purifying apparatus equipped therewith 审中-公开
标题翻译：排气净化催化剂，排气净化装置
公开(公告)号：JP2012217937A
公开(公告)日：2012-11-12
申请号：JP2011086628
申请日：2011-04-08
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： TAKAGI NOBUYUKI , SOFUE YUICHI , IKEDA HIDEYOSHI , INDE RYOICHI
IPC分类号： B01J37/02 , B01D46/42 , B01D53/86 , B01D53/94 , B01J20/18 , B01J23/44 , B01J29/74 , B01J38/02 , F01N3/023 , F01N3/025 , F01N3/029 , F01N3/10 , F01N3/24 , F01N3/36
摘要： PROBLEM TO BE SOLVED: To provide an exhaust gas purifying catalyst excellent in oxidation capacity after S poisoning regeneration treatment is applied to noble metals in the catalyst.SOLUTION: The exhaust gas purifying catalyst includes a base material 60 and a catalyst coating layer 62 formed on the surface of the base material. The catalyst coating layer is formed into a laminated structure having upper and lower layers composed of the lower layer 64 near to the surface of the base material and the upper layer 66 relatively remote from the surface of the base material. The upper layer contains a carrier, noble metals 70 supported on the carrier and a hydrocarbon adsorbent 68 and the lower layer contains a carrier and the noble metals supported on the carrier. Here, the lower layer contains platinum 72 and palladium 74 as noble metals and the content of platinum when the sum total amount of platinum and palladium contained in the lower layer is set to 100 mass% is ≥70 and ≤95 mass%.
摘要翻译：待解决的问题：为了提供在催化剂中对贵金属施加S中毒再生处理后的氧化能力优异的废气净化催化剂。解决方案：废气净化催化剂包括基材60和形成在基材表面上的催化剂涂层62。催化剂涂层形成为具有由下层64靠近基材的表面的上层和下层以及相对远离基材表面的上层66的层叠结构。上层包含载体，负载在载体上的贵金属70和烃吸附剂68，下层含有载体，负载在载体上的贵金属。这里，下层含有作为贵金属的铂72和钯74，将下层中所含的铂和钯的总和量设定为100质量％时的铂含量为≥70且≤95质量％。版权所有（C）2013，JPO＆INPIT

7. 发明专利

JP2012187519A Catalyst for exhaust gas purification 审中-公开
标题翻译：催化剂用于排气净化
公开(公告)号：JP2012187519A
公开(公告)日：2012-10-04
申请号：JP2011053405
申请日：2011-03-10
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： IKEDA HIDEYOSHI , MIURA MASAHIDE
IPC分类号： B01J23/63 , B01D53/94 , F01N3/10
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for exhaust gas purification that can still maintain the purification performance thereof even if subjected to high temperature exhaust gas (e.g., 600-1,100°C).SOLUTION: The catalyst 1 for exhaust gas purification includes a porous carrier 20, and palladium 30 carried by the porous carrier 20. The porous carrier 20 contains a CZ carrier 10 composed of ceria-zirconia composite oxide, and a silica-alumina carrier 12 composed of alumina to which silica is added. The palladium 30 is selectively carried by the CZ carrier. In this type of the catalyst for exhaust gas purification, the interaction of a silica component and the palladium 30 in the silica-alumina carrier 12 improves the catalytic activity in a high temperature (e.g., 600-1,100°C).
摘要翻译：要解决的问题：提供即使经受高温废气（例如600-1100℃）仍能保持其净化性能的废气净化用催化剂。废气净化用催化剂1包括多孔载体20和由多孔载体20承载的钯30.多孔载体20含有由二氧化铈 - 氧化锆复合氧化物构成的CZ载体10和二氧化硅 - 氧化铝载体12由添加了二氧化硅的氧化铝组成。钯30由CZ载体选择性携带。在这种类型的废气净化用催化剂中，二氧化硅 - 氧化铝载体12中的二氧化硅组分和钯30的相互作用改善了在高温（例如600-1100℃）下的催化活性。版权所有（C）2013，JPO＆INPIT

8. 发明专利

JP2012217934A Exhaust gas purification catalyst 有权
标题翻译：排气净化催化剂
公开(公告)号：JP2012217934A
公开(公告)日：2012-11-12
申请号：JP2011086552
申请日：2011-04-08
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： TAKAGI NOBUYUKI , SOFUE YUICHI , IKEDA HIDEYOSHI , INDE RYOICHI , KAMATA MASAYA
IPC分类号： B01J23/44 , B01D53/94 , F01N3/08 , F01N3/10 , F01N3/24 , F01N3/28
CPC分类号： B01J29/74 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/20707 , B01D2255/20715 , B01D2255/2092 , B01D2255/9022 , B01D2255/912 , B01J23/42 , B01J23/44 , B01J37/0244 , B01J2523/00 , F01N3/0814 , F01N3/0835 , F01N2510/0684 , Y02T10/22 , Y10S502/52712 , Y10S502/52713 , B01J2523/31 , B01J2523/47 , B01J2523/48
摘要： PROBLEM TO BE SOLVED: To provide an exhaust gas purification catalyst excellent in the purification capacity for carbon monoxide even under a low temperature condition.SOLUTION: The exhaust gas purifying catalyst includes a base material 54, a lower layer 57 arranged on the base material 54 and an upper layer 58 arranged on the lower layer 57. The upper layer 58 is equipped with a first catalyst and a second catalyst and the lower layer 57 is equipped with the first catalyst. The first catalyst has AlOas a carrier and has Pt and Pd as noble metals supported on AlOwhile the second catalyst typically has a AlO-ZrO-TiOcomposite oxide as a carrier and has Pd as the noble metal supported on the AlO-ZrO-TiOcomposite oxide. Further, the upper layer 58 has a hydrocarbon adsorbent 68. This exhaust gas purification catalyst is suppressed from the HC poisoning and sulfur poisoning of the catalyst and enhanced in the purification capacity of carbon monoxide.
摘要翻译：解决的问题：即使在低温条件下也能提供一氧化碳的净化能力优异的废气净化催化剂。解决方案：废气净化催化剂包括基材54，布置在基材54上的下层57和布置在下层57上的上层58.上层58装备有第一催化剂和第二催化剂和下层57配备有第一催化剂。第一催化剂具有作为载体的Al 2 O 3 ，并且将Pt和Pd作为负载在Al 2 O 3 ，而第二催化剂通常具有Al 2 POST“> 3 -ZrO 2 -TiO 2 复合氧化物作为载体，并具有Pd作为贵金属支持在 2 O 3 -ZrO 2 -TiO 2 复合氧化物。此外，上层58具有碳氢化合物吸附剂68.该排气净化催化剂可抑制催化剂的HC中毒和硫中毒，提高一氧化碳的净化能力。版权所有（C）2013，JPO＆INPIT

9. 发明专利

JP2012050961A Catalyst for purifying exhaust gas 审中-公开
标题翻译：用于净化排气的催化剂
公开(公告)号：JP2012050961A
公开(公告)日：2012-03-15
申请号：JP2010197850
申请日：2010-09-03
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： MATSUBARA HIROYUKI , IKEDA HIDEYOSHI
IPC分类号： B01J23/58 , B01D53/94 , B01J37/02 , F01N3/10
摘要： PROBLEM TO BE SOLVED: To improve a catalytic performance in a catalyst using Pd without increasing a hydrogen sulfide discharge.SOLUTION: The catalyst for purifying exhaust gas, provided with a catalyst layer having the bilayer consisting of an upper layer and a lower layer provided on a catalyst carrier perpendicular to an exhaust gas flow direction, is composed of: a front part on an exhaust gas upstream side in which the upper layer consists of a composite oxide of Zr and Ce and an alumina which support Rh, and the lower layer consists of a composite oxide of Zr and Ce and an alumina which support Pd; and a rear part on an exhaust gas downstream side that consists of the composite oxide of Zr and Ce and an alumina which support Rh. A basic substance is added only to the front part, and additionally, the length of the upper layer part in the exhaust gas flow direction is shorter than the length of the lower layer part in the exhaust gas direction.
摘要翻译：要解决的问题：为了提高催化剂中使用Pd而不增加硫化氢排放的催化性能。解决方案：提供具有由垂直于废气流动方向设置在催化剂载体上的由上层和下层组成的双层的催化剂层的排气净化用催化剂由以下部分组成：废气上游侧，其上部由Zr和Ce的复合氧化物和支撑Rh的氧化铝组成，下层由Zr和Ce的复合氧化物和支持Pd的氧化铝组成; 以及由Zr和Ce的复合氧化物和支撑Rh的氧化铝构成的废气下游侧的后部。基本物质仅添加到前部，另外，排气流动方向上的上层部的长度比排气气体方向的下层部的长度短。版权所有（C）2012，JPO＆INPIT

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