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    • 2. 发明专利
    • Catalyst for controlling exhaust gas and its regenerating method
    • 用于控制排气的催化剂及其再生方法
    • JP2007260568A
    • 2007-10-11
    • JP2006089190
    • 2006-03-28
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • TANABE TOSHITAKANAGAI YASUTAKAHATANAKA YOSHIODOMAE KAZUHIKOYAMAMOTO TOSHIOTAKAGI NOBUYUKIIKEDA YASUO
    • B01J23/63B01D53/94B01D53/96B01J23/96B01J38/12F01N3/10F01N3/28
    • PROBLEM TO BE SOLVED: To provide a catalyst for controlling exhaust gas, the activity of which can be recovered by redistributing a platinum particle, which is exposed to high-temperature exhaust gas for a long time and the grain of which is grown, into minute platinum particles in a short time even in a comparatively low temperature range and to provide a method for regenerating the catalyst for controlling exhaust gas. SOLUTION: The catalyst for controlling exhaust gas is provided with: a first catalyst layer comprising a first carrier containing a first multiple oxide of zirconia and/or alumina and at least one element, which is selected from the group consisting of alkaline-earth metal elements, rare earth elements and group 3A elements and contains cerium, and platinum deposited on the first carrier; and a second catalyst layer which comprises a second carrier containing a second multiple oxide of zirconia and/or alumina and at least one element selected from the group consisting of alkaline-earth metal elements, rare earth elements other than cerium and group 3A elements, and platinum deposited on the second carrier and which is arranged on the surface layer side of the first catalyst layer. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种用于控制废气的催化剂,其活性可以通过重新分配长时间暴露于高温废气并且其晶粒生长的铂颗粒来回收 即使在相当低的温度范围内也能在短时间内变成微小的铂颗粒,并且提供一种用于再生用于控制废气的催化剂的方法。 解决方案:用于控制废气的催化剂具有:第一催化剂层,其包含含有氧化锆和/或氧化铝的第一多重氧化物和/或氧化铝的第一载体和至少一种元素,所述第一载体选自碱 - 土金属元素,稀土元素和3A族元素,并含有铈,铂沉积在第一载体上; 以及第二催化剂层,其包含含有氧化锆和/或氧化铝的第二多重氧化物的第二载体和选自碱土金属元素,除铈和3A族元素之外的稀土元素中的至少一种元素,以及 铂沉积在第二载体上并且布置在第一催化剂层的表面层侧。 版权所有(C)2008,JPO&INPIT
    • 3. 发明专利
    • Catalyst for purifying exhaust gas and its regenerating method
    • 用于净化排气的催化剂及其再生方法
    • JP2007260567A
    • 2007-10-11
    • JP2006089177
    • 2006-03-28
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • YAMAMOTO TOSHIONAGAI YASUTAKATANABE TOSHITAKAHATANAKA YOSHIODOMAE KAZUHIKOTAKAGI NOBUYUKIMIURA MASAHIDEIKEDA YASUO
    • B01J23/56B01D53/94B01D53/96B01J23/89B01J23/96B01J38/12F01N3/10F01N3/20
    • Y02T10/47
    • PROBLEM TO BE SOLVED: To provide a catalyst for purifying exhaust gas, in which a noble metal particle is restrained from being agglomerated even when the catalyst is exposed to high-temperature exhaust gas for a long time, in the grain-grown one of which a noble metal is dispersed again in a short time in a low temperature range to regenerate the grain-grown catalyst and which can be regenerated in such a state that the catalyst is mounted in an exhaust gas system of an internal-combustion engine and to provide a method for regenerating the catalyst. SOLUTION: The catalyst for purifying exhaust gas is provided with: a carrier containing a multiple oxide of zirconia and/or alumina and at least one element selected from the group consisting of alkaline-earth metal elements, rare earth elements and group 3A elements; a noble metal deposited on the carrier; and an additional component which is deposited on the carrier and contains at least one element selected from the group consisting of alkaline-earth metal elements, rare earth elements and group 3A elements. The catalyst for controlling exhaust gas is characterized in that the amount of the noble metal to be deposited is within 0.05-2 mass% of the catalyst and the molar ratio of (the amount of the additional component to be deposited)/(the amount of the noble metal to be deposited) in terms of metals is within 0.5-20. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供即使当催化剂长时间暴露于高温废气时也抑制贵金属颗粒聚集的废气净化催化剂,在谷物生长中 其中一种贵金属在短时间内再次分散在低温范围内以再生晶粒生长的催化剂,并且可以在催化剂安装在内燃机的排气系统中的状态下再生 并提供催化剂再生的方法。 解决方案:用于净化废气的催化剂具有:含有氧化锆和/或氧化铝的多重氧化物的载体和选自碱土金属元素,稀土元素和3A族中的至少一种元素 要素; 沉积在载体上的贵金属; 以及另外的成分,其沉积在载体上并含有选自碱土金属元素,稀土元素和3A族元素中的至少一种元素。 用于控制废气的催化剂的特征在于,待沉积的贵金属的量在催化剂的0.05-2质量%内,(待附加成分的添加量)/(催化剂的添加量 要沉积的贵金属)在0.5-20以内。 版权所有(C)2008,JPO&INPIT
    • 4. 发明专利
    • Exhaust-gas cleaning catalyst and its regeneration method
    • 排气净化催化剂及其再生方法
    • JP2007289921A
    • 2007-11-08
    • JP2006351446
    • 2006-12-27
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • HATANAKA YOSHIOTANABE TOSHITAKANAGAI YASUTAKAYAMAMOTO TOSHIODOMAE KAZUHIKOTAKAGI NOBUYUKIMIURA MASAHIDEIKEDA YASUO
    • B01J23/63B01D53/86B01D53/94B01J23/58B01J23/96B01J35/10F01N3/18
    • Y02T10/47
    • PROBLEM TO BE SOLVED: To provide an exhaust-gas cleaning catalyst and a generation method of the exhaust-gas cleaning catalyst, which can fully control growth of particles of a noble metal to fully control a deterioration in the catalyst activity even if exposed to an exhaust gas of high temperature for a long time and also re-distribute the noble metal to easily regenerate the catalyst activity so that the catalyst activity per unit amount of the supported noble metal is fully high and the excellent catalyst activity is displayed even if a growth of the particles of the noble metal in its use. SOLUTION: The exhaust-gas cleaning catalyst has a carrier of fluorite type structure containing a composite oxide of Zr and at least one metallic element which is chosen from a group consisting of a rare earth element and an alkaline earth metal element, and also contains Ce, and the noble metal supported by the carrier, wherein the amount of metallic element contained in the carrier is in the range of 51-75 mol% by metal conversion for the carrier and the amount of Ce contained in metallic element is 90 mol% or more by metal conversion for metallic element. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供排气净化催化剂和废气净化催化剂的生成方法,其可以完全控制贵金属的颗粒的生长,以完全控制催化剂活性的劣化,即使 长时间暴露于高温废气,并且还重新分配贵金属以容易地再生催化剂活性,使得每单位量的负载型贵金属的催化剂活性高,并且甚至显示出优异的催化剂活性 如果贵金属的颗粒在其使用中生长。 废气净化催化剂具有含有Zr的复合氧化物和选自由稀土元素和碱土金属元素组成的组中的至少一种金属元素的萤石型结构的载体,以及 还含有Ce和由载体担载的贵金属,其中载体中所含的金属元素的量通过金属转化为载体的51-75mol%,金属元素中所含的Ce的量为90 mol%以上金属元素的金属转化率。 版权所有(C)2008,JPO&INPIT
    • 5. 发明专利
    • Catalyst for purifying exhaust gas, its manufacturing method and its regenerating method
    • 用于净化排气的催化剂及其制备方法及其再生方法
    • JP2008023483A
    • 2008-02-07
    • JP2006200843
    • 2006-07-24
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • YAMAMOTO TOSHIONAGAI YASUTAKATANABE TOSHITAKAHATANAKA YOSHIODOMAE KAZUHIKOTAKAGI NOBUYUKIMIURA MASAHIDEIKEDA YASUO
    • B01J23/58B01J23/96B01J38/18
    • PROBLEM TO BE SOLVED: To provide a catalyst for purifying exhaust gas, the deterioration of whose activity can be restrained by restraining the grain growth of a noble metal even if the catalyst for purifying exhaust gas is exposed in high-temperature exhaust gas for a long time and which can be regenerated by breaking up the grain-grown noble metal again into satisfactorily minute particles. SOLUTION: The catalyst for purifying exhaust gas comprises: a compound oxide particle A which consists of a metal oxide containing alumina at least and a first basic oxide, that is deposited on the surface of the metal oxide and contains at least one element selected from the group consisting of alkaline-earth metallic elements, rare earth elements and 3A group elements, and in which the amount of the first basic oxide to be deposited on the metal oxide is 0.1-30 mass%; another compound oxide particle B consisting of zirconia and a second basic oxide containing at least one element selected from the group consisting of alkaline-earth metallic elements, rare earth elements and 3A group elements; an additional component which is deposited on the compound oxide particle B and contains at least one element selected from the group consisting of alkaline-earth metallic elements, rare earth elements and 3A group elements; and the noble metal deposited on the compound oxide particle B at least. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供一种用于净化废气的催化剂,即使在废气净化用催化剂暴露于高温废气中的情况下,也可以通过抑制贵金属的晶粒生长来抑制其活性的劣化 长时间并且可以通过将晶粒生长的贵金属再次分解成令人满意的微小颗粒而再生。 解决方案:用于净化废气的催化剂包括:复合氧化物颗粒A,其由至少含有氧化铝的金属氧化物和第一碱性氧化物组成,其沉积在金属氧化物的表面上并且含有至少一种元素 选自碱土金属元素,稀土元素和3A族元素,其中沉积在金属氧化物上的第一碱性氧化物的量为0.1-30质量%; 由氧化锆和含有选自碱土金属元素,稀土元素和3A族元素中的至少一种元素的第二碱性氧化物构成的复合氧化物粒子B; 沉积在复合氧化物颗粒B上并含有选自碱土金属元素,稀土元素和3A族元素中的至少一种元素的附加成分; 以及至少沉积在复合氧化物粒子B上的贵金属。 版权所有(C)2008,JPO&INPIT
    • 9. 发明专利
    • Catalyst for purifying exhaust gas, its manufacturing method and its regenerating method
    • 用于净化排气的催化剂及其制备方法及其再生方法
    • JP2008023482A
    • 2008-02-07
    • JP2006200837
    • 2006-07-24
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • YAMAMOTO TOSHIONAGAI YASUTAKATANABE TOSHITAKAHATANAKA YOSHIODOMAE KAZUHIKOTAKAGI NOBUYUKIMIURA MASAHIDEIKEDA YASUO
    • B01J23/58B01J23/96B01J38/18
    • PROBLEM TO BE SOLVED: To provide a catalyst for purifying exhaust gas, the deterioration of whose activity can be restrained by restraining the grain growth of a noble metal even if the catalyst for purifying exhaust gas is exposed in high-temperature exhaust gas for a long time and which can be regenerated by breaking up the noble metal, which is exposed in high-temperature exhaust gas for the long time and grain-grown, again into satisfactorily minute noble metal particles. SOLUTION: The catalyst for purifying exhaust gas comprises: a compound oxide particle A which consists of alumina and a first basic oxide containing at least one element selected from the group consisting of alkaline-earth elements, rare earth elements and 3A group elements and the content of which is 5-50 mass%; another compound oxide particle B consisting of zirconia and a second basic oxide containing at least one element selected from the group consisting of alkaline-earth elements, rare earth elements and 3A group elements; an additional component which is deposited on the compound oxide particle B and contains at least one element selected from the group consisting of alkaline-earth elements, rare earth elements and 3A group elements; and the noble metal deposited on the compound oxide particle B at least. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供一种用于净化废气的催化剂,即使在废气净化用催化剂暴露于高温废气中的情况下,也可以通过抑制贵金属的晶粒生长来抑制其活性的劣化 长时间并且可以通过将在高温废气中长时间暴露并晶粒生长的贵金属再次分解成令人满意的微小贵金属颗粒而再生。 解决方案:用于净化废气的催化剂包括:复合氧化物颗粒A,其由氧化铝和含有至少一种选自碱土元素,稀土元素和3A族元素的元素的第一碱性氧化物组成 其含量为5-50质量%; 由氧化锆和含有选自碱土元素,稀土元素和3A族元素中的至少一种元素的第二碱性氧化物构成的复合氧化物粒子B; 沉积在复合氧化物粒子B上并含有选自碱土元素,稀土元素和3A族元素中的至少一种元素的附加成分; 以及至少沉积在复合氧化物粒子B上的贵金属。 版权所有(C)2008,JPO&INPIT