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1. 发明专利

JP2007332164A Polylactic acid-based resin composition, molded product and method for producing the same 有权
标题翻译：基于聚氨酯的树脂组合物，模制产品及其生产方法
公开(公告)号：JP2007332164A
公开(公告)日：2007-12-27
申请号：JP2004256508
申请日：2004-09-03
申请人： Adeka Corp , Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社Adeka , 株式会社豊田中央研究所
发明人： HIDA ETSUO , KAWAMOTO HISAFUMI , URUSHIBARA TAKESHI , SAITO HITOSHI , OKUYAMA HISATSUGU , KANAMORI KENJI , NAKANO MITSURU , OKAMOTO HIROTAKA
IPC分类号： C08L67/04 , B29C45/73 , B29C45/76 , B29K67/00 , C08K3/34 , C08K5/25 , C08L101/16
CPC分类号： C08K5/25 , C08K3/34 , C08L67/04
摘要： PROBLEM TO BE SOLVED: To provide a polylactic acid-based resin composition affording a molded product having excellent heat resistance and impact strength with good moldability, to provide a heat-resistant polylactic acid-based resin molded product composed of the polylactic acid-based resin composition and to provide a method for producing the polylactic acid-based resin molded product.
SOLUTION: The polylactic acid-based resin composition is obtained by compounding a polylactic acid with a dibasic acid bis(benzoic acid hydrazide) compound represented by general formula (I) (wherein, R represents a 1-12C alkylene group, an alkenylene group, a cycloalkylene group or an alkylene group having an ether bond; R
1 , R
2 , R
3 and R
4 represent each a hydrogen atom, a halogen atom, a 1-12C alkyl group, a cycloalkyl group, an aryl group, an arylalkyl group or an alkylaryl group or R
1 and R
2 and/or R
3 and R
4 are bound to form a 5- to an 8-membered ring). The method for producing the heat-resistant polylactic acid-based resin molded product comprises melting the polylactic acid-based resin composition, filling a metal mold of a molding machine set within the range of not higher than the crystallization starting temperature to not lower than the glass transition temperature with the molten polylactic acid-based resin composition and molding the composition while crystallizing the composition.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决问题的方案为了提供具有优异耐热性和冲击强度以及良好成型性的成型体的聚乳酸系树脂组合物，提供由聚乳酸组成的耐热性聚乳酸类树脂成型体并提供聚乳酸类树脂成型体的制造方法。聚乳酸类树脂组合物通过将聚乳酸与通式（I）表示的二元酸双（苯甲酸酰肼）化合物（其中，R表示1-12个亚烷基，亚烯基，亚环烷基或具有醚键的亚烷基; R 1，R 2，R SP 3，R SP 3，代表氢原子，卤素原子，1-12C烷基，环烷基，芳基，芳基烷基或烷基芳基，或者R > 2 和/或R 3 和R 4 结合形成5-至8-元环）。制造耐热性聚乳酸类树脂成型体的方法包括使聚乳酸类树脂组合物熔融，将成型机的金属模填充在不高于结晶起始温度的范围内，成为不低于玻璃化转变温度与熔融的聚乳酸类树脂组合物接触并在组合物结晶的同时模塑该组合物。版权所有（C）2008，JPO＆INPIT

2. 发明专利

JP2006265457A Polylactic acid composition 有权
标题翻译：聚乳酸组合物
公开(公告)号：JP2006265457A
公开(公告)日：2006-10-05
申请号：JP2005088531
申请日：2005-03-25
申请人： Toyota Central Res & Dev Lab Inc , 株式会社豊田中央研究所
发明人： OKAMOTO HIROTAKA , KATAGIRI YOSHIHIDE , NAKANO MITSURU , USUKI ARIMITSU
IPC分类号： C08L67/04 , C08K5/10 , C08L101/16
CPC分类号： C08K5/10 , C08L67/04
摘要： PROBLEM TO BE SOLVED: To provide a polylactic acid composition which can provide great extensibility and flexibility so that a high degree of deformation, which is even greater than the state where the deformation is deviated from a linear behavior, can be conducted when stress is applied, and still has excellent delayed elasticity recovery characteristics that enables the recovery to almost the original shape after the elapse of a long time without rapid restoration of the shape when the stress is released after the deformation which is even greater than the state where the deformation is deviated from the linear behavior.
SOLUTION: The polylactic acid composition comprises polylactic acid and an ester-based plasticizer wherein the content of the ester-based plasticizer is 16-33 wt.% and a residual deforming quantity measured at the time 0.2 minute after stress release is ≥66.7% and the residual deforming quantity measured at the time 240 hours after the stress release is ≤33.3%, provided that the stress is released after the stress is applied to produce the great deformation which is even greater than the state where the deformation is deviated from the linear behavior.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：提供一种聚乳酸组合物，其能够提供大的延展性和柔软性，使得可以进行比变形偏离线性行为的状态高的变形的高度变形，并且仍然具有优异的延迟弹性恢复特性，其能够在经过长时间后恢复到几乎原始形状，而在变形之后释放应力时不会快速恢复形状，这甚至大于变形偏离线性行为。聚乳酸组合物包含聚乳酸和酯系增塑剂，其中酯类增塑剂的含量为16-33重量％，并且在应力释放后0.2分钟测量的残余变形量≥ 66.7％，应力释放后240小时测得的残余变形量≤33.3％，条件是施加应力后应力释放，产生大的变形，甚至大于变形偏差的状态从线性行为。版权所有（C）2007，JPO＆INPIT

3. 发明专利

JP2005290257A Crystal nucleating agent for polylactic acid molding, method for producing polylactic acid molding using the same and polylactic acid molding 有权
标题翻译：用于聚酯酸成型的晶体核化剂，使用其制备聚乳酸模塑的方法和聚酯酸模塑
公开(公告)号：JP2005290257A
公开(公告)日：2005-10-20
申请号：JP2004109300
申请日：2004-04-01
申请人： Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： URAYAMA YUJI , KICHISE YOSHIFUMI , OKUYAMA HISATSUGU , NAKANO MITSURU
IPC分类号： C08J5/00 , B29C45/78 , B29K67/00 , C08L67/04 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide a polylactic acid-based molding with excellent transparency and excellent heat resistance in producing the polylactic acid-based molding.
SOLUTION: The crystal nucleating agent comprises a polylactic acid stereocomplex as a main component. The polylactic acid stereocomplex is, for example, produced by dripping a solution of a poly-L-lactic acid and a poly-D-lactic acid to a solvent not to dissolve the poly-L-lactic acid and the poly-D-lactic acid. The average particle diameter of the crystal nucleating agent is preferably ≤500 μm.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供在制备聚乳酸类模塑品时具有优异的透明性和优异的耐热性的聚乳酸类模塑品。解决方案：晶体成核剂包括聚乳酸立体络合物作为主要成分。聚乳酸立体络合物例如通过将聚-L-乳酸和聚-D-乳酸的溶液滴加到不溶解聚-L-乳酸和聚-D-乳酸的溶剂中而制备酸。结晶成核剂的平均粒径优选为≤500μm。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2005281331A Polylactic acid resin composition, molding obtained from the composition, and method for producing the molding 有权
标题翻译：聚酰亚胺树脂组合物，由组合物获得的成型品及其制造方法
公开(公告)号：JP2005281331A
公开(公告)日：2005-10-13
申请号：JP2004092852
申请日：2004-03-26
申请人： Toyota Central Res & Dev Lab Inc , 株式会社豊田中央研究所
发明人： OUCHI MAKOTO , OKAMOTO HIROTAKA , NAKANO MITSURU , USUKI ARIMITSU
IPC分类号： C08L67/04 , C08K3/34 , C08K5/20 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide a polylactic acid resin composition which can give a molding having reduced deformation and excellent heat resistance even when the molding time is short, to provide a polylactic acid resin molding, and to provide a method for molding the same.
SOLUTION: The polylactic acid resin composition is a polylactic acid resin composition containing poly-L-lactic acid and poly-D-lactic acid, wherein the poly-D-lactic acid content is 0.01 to 20 wt.% based on the total amount of the poly-L-lactic acid and the poly-D-lactic acid, and a crystallization accelerator is further contained.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：为了提供即使在成型时间短的情况下也能够得到变形变小和耐热性优异的成型体的聚乳酸树脂组合物，提供聚乳酸树脂成型体，提供成型方法一样。解决方案：聚乳酸树脂组合物是含有聚-L-乳酸和聚-D-乳酸的聚乳酸树脂组合物，其中聚-D-乳酸含量为0.01-20重量％，基于进一步含有聚L-乳酸和聚-D-乳酸的总量和结晶促进剂。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2005255806A Polylactic acid resin composition and molded product of the same 有权
标题翻译：聚酰胺树脂组合物及其成型产品
公开(公告)号：JP2005255806A
公开(公告)日：2005-09-22
申请号：JP2004068165
申请日：2004-03-10
申请人： Toyota Central Res & Dev Lab Inc , 株式会社豊田中央研究所
发明人： OUCHI MAKOTO , OKAMOTO HIROTAKA , NAKANO MITSURU , USUKI ARIMITSU
IPC分类号： C08L67/04 , C08K5/20 , C08K5/3477 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide a polylactic acid resin composition capable of selectively and quickly crystallizing the stereo complex crystals of a poly L-lactic acid with a poly D-lactic acid without using any metal salt as a nucleating agent, and obtaining a polylactic acid having a high stereo complex crystal ratio, and a molded product obtained by melting and molding the same. SOLUTION: This polylactic acid composition contains the polylactic acid capable of forming the stereo complex crystal and an oxamide derivative or isocyanulic acid derivative expressed by general formula (1) or (2) [wherein, R 1 to R 5 are each a 1-20C alkyl which may have substituting group]. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：提供一种聚乳酸树脂组合物，其能够使用聚D-乳酸选择性且快速地结晶聚L-乳酸的立体络合物结晶，而不使用任何金属盐作为成核剂，以及获得具有高立体络合物结晶比的聚乳酸，以及通过熔融和成型获得的模塑产品。解决方案：该聚乳酸组合物含有能够形成立体络合物结晶的聚乳酸和由通式（1）或（2）表示的氧杂酰胺衍生物或异氰尿酸衍生物[其中，R 1 R 5 各自为可以具有取代基的1-20C烷基。版权所有（C）2005，JPO＆NCIPI

6. 发明专利

JP2003073538A Biodegradable resin composite material 有权
标题翻译：生物可降解树脂复合材料
公开(公告)号：JP2003073538A
公开(公告)日：2003-03-12
申请号：JP2001269146
申请日：2001-09-05
申请人： Toyota Central Res & Dev Lab Inc , 株式会社豊田中央研究所
发明人： NAKANO MITSURU , OKAMOTO HIROTAKA , TSUKIGASE AZUSA , USUKI ARIMITSU
IPC分类号： C08L67/04 , C08G63/78 , C08K9/04 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide a biodegradable resin composite material in which a laminar clay mineral is sufficiently homogeneously dispersed in polylactic acid and which has excellent rigidity and sufficiently high crystallization rate, and to provide a method for producing the same.
SOLUTION: This biodegradable resin composite material is characterized by comprising the polylactic acid and a laminar clay mineral organized with a hydroxyl group-having organic onium salt and bound to the polylactic acid through the hydroxyl group of the organic onium salt.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：提供一种生物降解性树脂复合材料，其中层状粘土矿物充分均匀地分散在聚乳酸中，并且具有优异的刚性和足够高的结晶速率，并提供其制备方法。解决方案：该生物降解性树脂复合材料的特征在于包含聚乳酸和由具有羟基的有机鎓盐组成的层状粘土矿物，并通过有机鎓盐的羟基与聚乳酸结合。

7. 发明专利

JP2005139270A Polylactic acid resin composition, its manufacturing process and molding 有权
标题翻译：聚酰胺树脂组合物及其制造工艺和成型
公开(公告)号：JP2005139270A
公开(公告)日：2005-06-02
申请号：JP2003376039
申请日：2003-11-05
申请人： Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： OUCHI MAKOTO , OKAMOTO HIROTAKA , NAKANO MITSURU , USUKI ARIMITSU , KANAMORI KENJI , OKUYAMA HISATSUGU , YAMASHITA SEIJI , KAGEYAMA YASUSHI
IPC分类号： C08L67/04 , C08G63/08 , C08J5/00 , C08K3/34 , C08K9/04 , C08K9/08 , C08L101/16
CPC分类号： C08G63/08 , C08K9/08 , C08L67/04 , C08L2666/18
摘要： PROBLEM TO BE SOLVED: To provide a polylactic acid resin composition by which a stereo crystal of a poly-L-lactic acid and a poly-D-lactic acid is selectively crystallized and a polylactic acid having a sufficiently high stereo crystal ratio, its manufacturing process and a polylactic acid molding having a sufficiently high stereo crystal ratio.
SOLUTION: The polylactic acid resin composition contains a layered clay mineral, a polylactic acid-layered clay mineral complex consisting of either of a poly-L-lactic acid or a poly-D-lactic acid bound to the layered clay mineral and either of the poly-L-lactic acid or the poly-D-lactic acid not bound to the layered clay mineral.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：提供一种聚乳酸树脂组合物，其中聚-L-乳酸和聚-D-乳酸的立体结晶被选择性结晶，并且具有足够高的立体结晶比的聚乳酸，其制造方法和具有足够高的立体结晶比的聚乳酸模塑。聚乳酸树脂组合物含有层状粘土矿物，与层状粘土矿物结合的聚-L-乳酸或聚-D-乳酸中的任一种的聚乳酸层状粘土矿物复合体，以及聚-L-乳酸或不与层状粘土矿物结合的聚-D-乳酸中的任一种。版权所有（C）2005，JPO＆NCIPI

8. 发明专利

JP2005060474A Aliphatic polyester composition and its molded article 审中-公开
标题翻译：涤纶聚酯组合物及其成型品
公开(公告)号：JP2005060474A
公开(公告)日：2005-03-10
申请号：JP2003290275
申请日：2003-08-08
申请人： Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： OKAMOTO HIROTAKA , NAKANO MITSURU , OUCHI MAKOTO , USUKI ARIMITSU , KANAMORI KENJI , URAYAMA YUJI , OKUYAMA HISATSUGU , ISOBE YASUMITSU , INAO TAKASHI
IPC分类号： C08L67/00 , C08K3/34 , C08K5/20 , C08K5/29 , C08K5/353 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To obtain an aliphatic polyester composition which has excellent moldability and impact resistance, sufficiently inhibits deterioration under a moist heat condition and on a thermal treatment, and has excellent moist heat ageing resistance and heat resistance, and to provide a molded article melt-molded from the composition. SOLUTION: The aliphatic polyester composition is characterized by comprising an aliphatic polyester having a weight-average mol. wt. of ≥100,000 and a residual monomer content of ≤5,000 ppm, and at least one hydrolysis inhibitor selected from the group consisting of amide group-having low molecular compounds, talc, carbodiimide compounds, isocyanate compounds, and oxazoline compounds. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题为了获得具有优异的成型性和耐冲击性的脂肪族聚酯组合物，在湿热条件和热处理下充分抑制劣化，并且具有优异的耐湿热老化性和耐热性，并且提供由该组合物熔融成型的成型品。解决方案：脂族聚酯组合物的特征在于包含具有重均分子量的脂族聚酯。重量。 ≥100,000，残留单体含量≤5,000ppm的至少一种水解抑制剂和选自具有酰胺基的低分子化合物，滑石，碳化二亚胺化合物，异氰酸酯化合物和恶唑啉化合物的至少一种水解抑制剂。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2005029759A Aliphatic polyester composition and its molded item 有权
标题翻译：涤纶聚酯组合物及其成型品
公开(公告)号：JP2005029759A
公开(公告)日：2005-02-03
申请号：JP2003273582
申请日：2003-07-11
申请人： Toyota Central Res & Dev Lab Inc , 株式会社豊田中央研究所
发明人： OKAMOTO HIROTAKA , NAKANO MITSURU , OUCHI MAKOTO , USUKI ARIMITSU
IPC分类号： C08L67/00 , C08K3/34 , C08K9/04 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To obtain an aliphatic polyester composition having sufficiently high impact resistance and exhibiting sufficiently suppressed thermal deterioration at the time of a heat treatment enough to assure excellent durability, and a molded item obtained by melt molding the same.
SOLUTION: The aliphatic polyester composition comprises an aliphatic polyester, an unmodified natural rubber and an acrylic-modified natural rubber, where the total content of the unmodified natural rubber and the acrylic-modified natural rubber in the composition is 1-40 wt% and the content of the acrylic-modified natural rubber in the total amount of the unmodified natural rubber and the acrylic-modified natural rubber is 0.5-70 wt%.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题为了获得具有足够高的耐冲击性并且在热处理时充分抑制热劣化的脂肪族聚酯组合物，足以确保优异的耐久性，以及通过熔融模塑获得的模制品。解决方案：脂族聚酯组合物包含脂族聚酯，未改性天然橡胶和丙烯酸改性天然橡胶，其中组合物中未改性天然橡胶和丙烯酸改性天然橡胶的总含量为1-40重量％％，未改性天然橡胶和丙烯酸改性天然橡胶的总量中丙烯酸改性天然橡胶的含量为0.5〜70重量％。版权所有（C）2005，JPO＆NCIPI

10. 发明专利

JP2004277658A Crosslinking epoxidized oil composite material, method for producing the same and porous inorganic material 审中-公开
公开(公告)号：JP2004277658A
公开(公告)日：2004-10-07
申请号：JP2003074302
申请日：2003-03-18
申请人： Toyota Central Res & Dev Lab Inc , 株式会社豊田中央研究所
发明人： UYAMA HIROSHI , KOBAYASHI SHIRO , NAKANO MITSURU , USUKI ARIMITSU
IPC分类号： C04B38/06 , C08G59/20 , C08K9/04 , C08L63/00
摘要： PROBLEM TO BE SOLVED: To provide a crosslinking epoxidized oil composite material that has sufficiently increased strengths, hardness and elasticity, while it retains a high level intrinsic stretchability of the crosslinking epoxidized oil.
SOLUTION: The crosslinking epoxidized oil composite material comprises a crosslinked epoxidized oil and a layer of clay mineral that is organized with an organic onium compound dispersed in the epoxidized oil.
COPYRIGHT: (C)2005,JPO&NCIPI

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