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    • 4. 发明专利
    • Polymerization initiator, method for producing polymeric modified material using the same, and molded body containing polymeric modified material
    • 聚合引发剂,使用其聚合改性材料的方法和含聚合物改性材料的成型体
    • JP2010024263A
    • 2010-02-04
    • JP2008183595
    • 2008-07-15
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • HAYASHIDA KENICHINAKAMURA HIROSHIISHII MASAHIKO
    • C08F4/00C08F292/00
    • PROBLEM TO BE SOLVED: To provide a method for producing a polymeric modified material, by which polymer chains can be grafted at high density to a surface of a substrate such as silica and a carbon material, and a polymeric modified material having the characteristics of the substrate can be obtained.
      SOLUTION: The method for producing a polymeric modified material includes steps of: reacting a substrate having a nucleophilic functional group on the surface with a polymerization initiator containing a halogenated methyl aromatic compound derivative expressed by formula (1):X
      1 -CH
      2 -Ar-(Y
      1 )
      n to bond the polymerization initiator to the surface of the substrate; and reacting the substrate having the polymerization initiator bonded to the surface with radical polymerizable monomers to graft and polymerize the radical polymerizable monomers to the surface of the substrate. In formula (1), X
      1 represents a halogen atom; Ar represents an aromatic ring; Y
      1 represents a group containing a functional group having polymerization initiating ability; and n represents an integer of 1 to 3.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种生产聚合物改性材料的方法,其中聚合物链可以以高密度接枝到诸如二氧化硅和碳材料的基材的表面,以及具有 可以获得基板的特性。 解决方案:聚合物改性材料的制备方法包括以下步骤:使表面具有亲核官能团的基材与含有由式(1)表示的卤代甲基芳族化合物衍生物的聚合引发剂反应:X 将聚合引发剂键合到基材的表面上,以使聚合引发剂与基材的表面结合;将<! - SIPO 1 表示卤原子; Ar表示芳香环; Y 1 表示含有具有聚合引发能力的官能团的基团; 并且n表示1〜3的整数。(C)2010,JPO&INPIT