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1. 发明专利

JP2014000552A Catalyst carrier for exhaust gas purification, catalyst for exhaust gas purification using the same, production method of catalyst carrier for exhaust gas purification 有权
标题翻译：用于排气净化的催化载体，用于排气净化的催化剂，用于排气净化的催化剂载体的生产方法
公开(公告)号：JP2014000552A
公开(公告)日：2014-01-09
申请号：JP2012138958
申请日：2012-06-20
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Toyota Motor Corp , トヨタ自動車株式会社
发明人： MORIKAWA AKIRA , SATO KIMITOSHI , YAMAMURA YOSHIE , KUMAGAI NAOKI , SUDA AKIHIKO , HAYASHI TAKAHIRO , NOBUKAWA KEN
IPC分类号： B01J23/76 , B01D53/94
摘要： PROBLEM TO BE SOLVED: To provide a catalyst carrier for exhaust gas purification that can obtain a transition metal carrier catalyst that shows excellent catalytic activity even when being exposed to high temperature, especially high catalytic activity from comparatively cold temperature.SOLUTION: A catalyst carrier for exhaust gas purification comprises a complex metal oxide porous body including alumina, ceria, and zirconia, an inclusion ratio of the alumina being 30-80 mass%, wherein in the complex metal oxide porous body after burning for 5 hours in air at 1100°C, in 100 fine small regions (one fine small region is length 300 nm×width 330 nm) obtained from an energy dispersion type X-ray analysis performed by a scan transmission electron microscope with a spherical surface aberration correction device, a condition in which standard deviations of an inclusion ratio (unit: at%) of an aluminum element, a cerium element and a zirconium element are all at most 19 is satisfied.
摘要翻译：要解决的问题：提供一种用于排气净化的催化剂载体，其可以获得即使在相对较低的温度下暴露于高温下特别高的催化活性时也显示出优异的催化活性的过渡金属载体催化剂。溶解：用于排气净化包括含有氧化铝，二氧化铈和氧化锆的复合金属氧化物多孔体，氧化铝的包含率为30〜80质量％，其中在空气中在1100℃下烧成5小时后的复合金属氧化物多孔体中在由具有球面像差校正装置的扫描透射电子显微镜进行的能量分散型X射线分析得到的100个细小区域（一个细小区域，长度300nm×宽度330nm）中，标准铝元素，铈元素和锆元素的包含率（单位：原子％）的偏差全部为19以上。

2. 发明专利

JP2014012267A Catalyst for reforming hydrocarbon, exhaust gas cleaning apparatus using the same and manufacturing method of catalyst for reforming hydrocarbon 有权
标题翻译：用于改造烃类的催化剂，使用其的排气净化装置和用于改造烃类的催化剂的制造方法
公开(公告)号：JP2014012267A
公开(公告)日：2014-01-23
申请号：JP2013087438
申请日：2013-04-18
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Toyota Motor Corp , トヨタ自動車株式会社
发明人： HIROSE TAKUTO , MORIKAWA AKIRA , HAYASHI TAKAHIRO , NAGAO SATOSHI
IPC分类号： B01J23/745 , B01D53/94 , B01J37/02 , B01J37/08 , C01B3/40 , F01N3/10
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for reforming hydrocarbon capable of achieving a high carbohydrate conversion ratio without containing precious metals and having nitrogen oxide reduction effects.SOLUTION: A catalyst for reforming hydrocarbon contains a metal oxide carrier having the content of alumina of 70 mass% or more and iron oxide and copper oxide carried on the metal oxide carrier and no precious metals. The supported amount of the iron oxide calculated as a metal is 1.0 to 15.0 pts.mass based on 100 pts.mass of the total metal oxide carrier and that of the copper oxide calculated as a metal is 0.5 to 5.0 pts.mass base on 100 pts.mass of total metal oxide carrier.
摘要翻译：要解决的问题：提供一种能够实现高碳水化合物转化率而不含贵金属并具有氮氧化物还原效果的重整烃催化剂。解决方案：用于重整烃的催化剂含有氧化铝含量为70的金属氧化物载体质量％以上，氧化铁和氧化铜载于金属氧化物载体上，无贵金属。作为金属计算的氧化铁的负载量为1.0〜15.0份，相对于总金属氧化物载体的100质量份计，作为金属计算的氧化铜为0.5〜5.0质量％总金属氧化物载体的pts.mass。

3. 发明专利

JP2013122178A Exhaust emission control device for internal combustion engine 有权
标题翻译：用于内燃机的排气排放控制装置
公开(公告)号：JP2013122178A
公开(公告)日：2013-06-20
申请号：JP2011270313
申请日：2011-12-09
申请人： Toyota Motor Corp , トヨタ自動車株式会社 , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： HAYASHI TAKAHIRO , MORIKAWA AKIRA
IPC分类号： F01N3/24 , B01D53/94 , F01N3/08 , F01N3/10 , F01N3/22 , F01N3/28 , F02D41/14
CPC分类号： Y02T10/24
摘要： PROBLEM TO BE SOLVED: To improve deterioration in fuel consumption for NOreduction, in an exhaust emission control device for an internal combustion engine provided with a NOreduction catalyst device carrying a base metal catalyst and having low NOreduction performance.SOLUTION: In an exhaust emission control device for an internal combustion engine, in which, when an air-fuel ratio of exhaust gas flowing into a first NOreduction catalyst device 50 carrying a base metal catalyst is richer than a theoretical air-fuel ratio, NOis reduced by the first NOreduction catalyst device to generate ammonia and store the generated ammonia in a second NOreduction catalyst device 60, and in which, when the air-fuel ratio of the exhaust gas is lean, the NOis reduced by the stored ammonia by the second NOreduction catalyst device, it is controlled which of a bypass passage 32 of a hydrocarbon storage device and the hydrocarbon storage device the exhaust gas is caused to pass through so that hydrocarbon stored in the hydrocarbon storage device 40 at the upstream side of the first NOreduction catalyst device is discharged immediately before making a combustion air-fuel ratio of the internal combustion engine from lean to rich.
摘要翻译：要解决的问题：为了提高NO X 的燃料消耗的劣化，在具有NO X 还原性能的“POST”> X 还原催化剂装置。解决方案：在用于内燃机的废气排放控制装置中，当排气流入第一NO X 还原催化剂装置的空燃比时 50载有贱金属催化剂比理论空燃比更丰富，NO X 通过第一次NO X 减少催化剂装置，以产生氨并将生成的氨储存在第二NO X SB还原催化剂装置60中，并且其中当排气的空燃比较稀时， NO X 由储存的氨通过第二NO X“还原催化剂装置减少，控制旁路通道32 碳氢化合物储存装置和碳氢化合物储存装置使废气通过，使得在第一NO X 还原的上游侧储存在烃储存装置40中的烃催化剂装置是放电在将内燃机的燃烧空燃比从稀燃到浓之前立即进行。版权所有（C）2013，JPO＆INPIT

4. 发明专利

JP2013122179A Exhaust emission control device for internal combustion engine 审中-公开
标题翻译：用于内燃机的排气排放控制装置
公开(公告)号：JP2013122179A
公开(公告)日：2013-06-20
申请号：JP2011270325
申请日：2011-12-09
申请人： Toyota Motor Corp , トヨタ自動車株式会社 , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： HAYASHI TAKAHIRO , MORIKAWA AKIRA
IPC分类号： F01N3/08 , B01D53/94 , F01N3/24 , F01N3/28 , F02D41/14
CPC分类号： Y02T10/24
摘要： PROBLEM TO BE SOLVED: To improve deterioration in fuel consumption for NOreduction in exhaust gas, in an exhaust emission control device for an internal combustion engine provided with a NOreduction catalyst device carrying a base metal catalyst and having low NOreduction performance.SOLUTION: An exhaust emission control device for an internal combustion engine includes: a first NOreduction catalyst device 40 carrying a base metal catalyst disposed at an exhaust passage 30; a second NOreduction catalyst device 50 disposed at the exhaust passage at a downstream side of the first NOreduction catalyst device and having ammonia storage capability; and a first NOsensor 80 disposed at the exhaust passage at a downstream side of the second NOreduction catalyst device. After a combustion air-fuel ratio of the internal combustion engine is made richer than a theoretical air-fuel ratio, the combustion air-fuel ratio of the internal combustion engine is made leaner than the theoretical air-fuel ratio. When the combustion air-fuel ratio of the internal combustion engine is made leaner than the theoretical air-fuel ratio, if NOis detected by the first NOsensor, the combustion air-fuel ratio of the internal combustion engine is made richer than the theoretical air-fuel ratio.
摘要翻译：要解决的问题：为了提高排气中的NO X 的燃料消耗的劣化，在内燃机的排气排放控制装置中， SB POS =“POST”> X 还原催化剂装置，其具有贱金属催化剂并且具有低NO X 还原性能。解决方案：一种用于内燃机的废气排放控制装置，包括：承载设置在排气通道30处的贱金属催化剂的第一NOS SB POS =“X”SB“还原催化剂装置40; 设置在第一NO SB SB“还原催化剂装置的下游侧的排气通道处的第二NOS SB POS =”X“SB”还原催化剂装置“，以及具有氨储存能力; 以及设置在第二NO ”> X“还原催化剂装置的下游侧的排气通道处的第一NO X 传感器80。在内燃机的燃烧空燃比变得比理论空燃比更浓之后，使内燃机的燃烧空燃比比理论空燃比更稀。当内燃机的燃烧空燃比比理论空燃比更精细时，如果通过第一NO X “> X 传感器，使内燃机的燃烧空燃比变得比理论空燃比更浓。版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2013122177A Exhaust emission control device for internal combustion engine 有权
标题翻译：用于内燃机的排气排放控制装置
公开(公告)号：JP2013122177A
公开(公告)日：2013-06-20
申请号：JP2011270311
申请日：2011-12-09
申请人： Toyota Motor Corp , トヨタ自動車株式会社 , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： HAYASHI TAKAHIRO , MORIKAWA AKIRA
IPC分类号： F01N3/08 , B01D53/94 , F01N3/10 , F01N3/20 , F01N3/24
CPC分类号： Y02T10/24
摘要： PROBLEM TO BE SOLVED: To improve deterioration in fuel consumption for NOreduction, in an exhaust emission control device for an internal combustion engine with a NOreduction catalyst device carrying a base metal catalyst and having low NOreduction performance.SOLUTION: A NOreduction catalyst device 40 carrying a base metal catalyst is disposed at a third exhaust passage 30 positioned at a downstream side of a confluence part 100 between a first exhaust passage 10 of a first cylinder group and a second exhaust passage 20 of a second cylinder group. A NOstorage device 50 is disposed at the second exhaust passage. A communication passage 60 communicating the second exhaust passage at a downstream side of the NOstorage device with the third exhaust passage at a downstream side of the NOstorage device is provided. When a combustion air-fuel ratio of the first cylinder group is made rich and when a combustion air-fuel ratio of the second cylinder group is made lean, exhaust gas flowing out from the NOstorage device passes through the communication passage. When the combustion air-fuel ratio of the second cylinder group is made rich, the exhaust gas flowing out from the NOstorage device passes through the NOreduction catalyst device.
摘要翻译：要解决的问题为了改善NO X 的燃料消耗的劣化，在具有NO X 还原性能的“X”SB“还原催化剂装置”。
解决方案：承载贱金属催化剂的NOS SB POS =“POST”> X“还原催化剂装置40设置在位于汇合部100的下游侧的第三排气通道30之间，位于第一第一气缸组的排气通道10和第二气缸组的第二排气通道20。存储装置50设置在第二排气通道中。否则，将 X 存储装置50。在NO X 存储装置的下游侧将第二排气通道与NO X 存储设备。当第一气缸组的燃烧空燃比变浓时，当第二气缸组的燃烧空燃比变稀时，从NO X < SB>存储装置通过通信通道。当第二气缸组的燃烧空燃比变浓时，从NO X 储存装置流出的废气通过NO X 还原催化剂装置。版权所有（C）2013，JPO＆INPIT

6. 发明专利

JP2011043416A Ultrasonic inspection system 有权
标题翻译：超声波检查系统
公开(公告)号：JP2011043416A
公开(公告)日：2011-03-03
申请号：JP2009191989
申请日：2009-08-21
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所
发明人： HAYASHI TAKAHIRO , KITAYAMA TSUNAJI
IPC分类号： G01N29/00
摘要： PROBLEM TO BE SOLVED: To enhance the SN ratio of a detection signal from damage or the like present in an object, in an ultrasonic inspection system. SOLUTION: The ultrasonic inspection system 10 is constituted of a laser drive device 12 for irradiating the object 50 with a laser beam to excite ultrasonic vibration in the object 50, a galvano scanner 14 for causing the laser beam to scan the surface of the object 50, ultrasonic probes 16 and 18 being a plurality of the receiving means arranged to the object 50, a control unit 30 or the like. The control unit 30 includes an individual imaging processing part 32 for imaging the ultrasonic vibration distribution in the object on a two-dimensional surface at every receiving means on the basis of the detection signal received by each of the receiving means corresponding to the scanning timing of the laser beam, and an image-enhancing processing part 34 for performing enhancement processing subjecting a plurality of image data at the same position to sum operation or integral operation with respect to a plurality of individual imaging data to obtain enhancement processing data at the position. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：解决的问题：在超声波检查系统中，提高检测信号与物体中存在的损伤等的SN比。解决方案：超声波检查系统10由激光驱动装置12构成，激光驱动装置12用激光束照射物体50，以激发物体50中的超声波振动;电动扫描器14，用于使激光束扫描物体50的表面对象50，超声波探头16和18是布置在物体50上的多个接收装置，控制单元30等。控制单元30包括单独的成像处理部分32，用于根据每个接收装置接收到的检测信号，对每个接收装置的二维表面上的物体中的超声波振动分布进行成像，激光束和图像增强处理部分34，用于对相同位置处的多个图像数据进行加和处理，以相对于多个单独的成像数据求和运算或积分操作，以获得该位置处的增强处理数据。版权所有（C）2011，JPO＆INPIT

7. 发明专利

JP2003019421A Method for cleaning exhaust gas 有权
标题翻译：清洁排气的方法
公开(公告)号：JP2003019421A
公开(公告)日：2003-01-21
申请号：JP2002131412
申请日：2002-05-07
申请人： Cataler Corp , Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社キャタラー , 株式会社豊田中央研究所
发明人： KANAZAWA TAKAAKI , MIYOSHI NAOTO , MATSUMOTO SHINICHI , HAYASHI TAKAHIRO , TANIZAWA TSUNEYUKI , IGUCHI SATORU , TANAKA TOSHIAKI , TAKESHIMA SHINICHI , YAMAZAKI KIYOSHI , SAIKI MOTOHISA , SUZUKI TADASHI , KASAHARA KOICHI , TATEISHI SHUJI
IPC分类号： F01N3/10 , B01D53/86 , B01D53/94 , B01J23/656 , B01J23/89
摘要： PROBLEM TO BE SOLVED: To restrain a high cleaning ratio of NOx which is practically allowable even after endurance at a high temperature in purifying exhaust gas containing sulfur oxide in an oxygen surplus atmosphere. SOLUTION: The above exhaust gas is brought into contact with a catalyst for cleaning exhaust gas with at least one kind of metal selected from rare earth metals, and at least one kind of metal selected from transition metals such as Fe, Ni, Co and Mn carried together with noble metals. The two or more carried metals take SO2 contained in the exhaust gas into the catalyst as multiple sulfate. The multiple sulfate produced in this way is easy to be decomposed at a low temperature in a stoichiometrically enriched atmosphere compared with the case of sulfate produced by a single metal, so that the effect of occluding NOx in rare earth metals can be given once more.
摘要翻译：要解决的问题：为了抑制即使在高温下耐久性中在氧气余量中净化含有氧化硫的废气中也可以实际容许的高清洁率。解决方案：使用选自稀土金属中的至少一种金属和选自Fe，Ni，Co和Mn等过渡金属中的至少一种金属，使上述废气与用于清除废气的催化剂接触携带贵金属。两种或多种携带的金属将废气中所含的SO 2作为多重硫酸盐进入催化剂。与以单一金属生产的硫酸盐的情况相比，在化学计量浓度大的气氛中，以这种方式生产的多重硫酸盐易于在低温下分解，从而可以再次给予NOx在稀土金属中的吸附效果。

8. 发明专利

JP2009056456A Method for manufacturing catalytic carrier 有权
标题翻译：制备催化载体的方法
公开(公告)号：JP2009056456A
公开(公告)日：2009-03-19
申请号：JP2008190055
申请日：2008-07-23
申请人： Toyota Motor Corp , Univ Of Tokyo , トヨタ自動車株式会社 , 国立大学法人東京大学
发明人： HIRATA HIROTO , HAYASHI TAKAHIRO , OGURA MASARU
IPC分类号： B01J29/035 , B01D53/86 , B01J32/00 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing a catalytic carrier by uniformly forming a coating film of a metal oxide different from a porous material on the surface of each pore of the porous material, particularly, the porous material having a controlled nanoporous structure. SOLUTION: The method for manufacturing the catalytic carrier comprises a step of coating the surface of each pore of the porous material with the metal oxide different from the porous material, in the concrete, comprises a step (a) of immersing the porous material in a solution containing at least one kind of metal salt and drying the resulting porous material, a step (b) of heating the dried porous material in the presence of ammonia and water at the temperature enough to evaporate at least a part of each of ammonia and water and a step (c) of firing the obtained produced material. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：提供一种通过在多孔材料的每个孔的表面上均匀地形成不同于多孔材料的金属氧化物的涂膜来制造催化剂载体的方法，特别是具有受控纳米多孔结构。解决方案：用于制造催化剂载体的方法包括在混凝土中用不同于多孔材料的金属氧化物涂覆多孔材料的每个孔表面的步骤，包括将多孔材料在包含至少一种金属盐并干燥所得多孔材料的溶液中的材料，步骤（b）在氨和水的存在下加热干燥的多孔材料，其温度足以蒸发至少一部分氨和水的步骤（c）和烧制所得生产材料的步骤（c）。版权所有（C）2009，JPO＆INPIT

9. 发明专利

JP2008290052A MANUFACTURING METHOD OF NOx OCCLUSION REDUCTION TYPE CATALYST 审中-公开
标题翻译： NOx氧化还原型催化剂的制备方法
公开(公告)号：JP2008290052A
公开(公告)日：2008-12-04
申请号：JP2007140794
申请日：2007-05-28
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： HAYASHI TAKAHIRO , INATOMI YUSAKU
IPC分类号： B01J37/02 , B01D53/94 , B01J23/58 , F01N3/08 , F01N3/10 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of a NOx occlusion reduction type catalyst uniformly carrying a catalyst noble metal and a NOx holding substance in the whole thickness of a catalyst carrying layer, having diffusion pores for a cleaning object gas and capable of retaining a NOx holding function after being heated. SOLUTION: The manufacturing method of the NOx occlusion reduction type catalyst having the catalyst carrying layer carrying the catalyst noble metal and the NOx holding substance includes the step of making the catalyst carrying layer on a substrate, and the process comprises the step of coating the substrate with a catalyst carrier slurry made by dispersing, in water, a catalyst carrying material, the catalyst noble metal, a water-insoluble organic acid salt of a metal as the NOx holding substance and a binder, and drying and burning the above coated substrate. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：解决问题的方法：提供一种在具有用于清洁对象气体的扩散孔的催化剂载体层的整个厚度上均匀地承载催化剂贵金属和NOx保持物质的NOx吸留还原型催化剂的制造方法，能够在加热后保持NOx保持功能。解决方案：具有载持催化剂贵金属和NOx保持物质的催化剂载体层的NOx吸留还原型催化剂的制造方法包括在催化剂载体层上制备催化剂载体层的步骤，该方法包括以下步骤：用催化剂载体材料，催化剂贵金属，作为NOx保持物质的金属的水不溶性有机酸盐和粘合剂分散在水中，并将上述干燥和燃烧制成的催化剂载体浆料涂布在基材上涂层基材。版权所有（C）2009，JPO＆INPIT

10. 发明专利

JP2005306687A Hydrogen gas separation apparatus, hydrogen gas production apparatus, and fuel cell system 审中-公开
标题翻译：氢气分离装置，氢气生产装置和燃料电池系统
公开(公告)号：JP2005306687A
公开(公告)日：2005-11-04
申请号：JP2004128355
申请日：2004-04-23
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： HAYASHI TAKAHIRO
IPC分类号： C01B3/52 , C01B3/26 , H01M8/06 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen gas separation apparatus by which high-purity hydrogen gas can be produced from a gaseous mixture containing at least hydrogen gas and organic materials, and to provide a hydrogen gas production apparatus and a fuel cell system using the hydrogen gas separation apparatus. SOLUTION: The hydrogen gas generation apparatus includes a gas supply pipe 31 which supplies a gaseous mixture containing at least the hydrogen gas, toluene, and unreacted methylcyclohexane and the hydrogen gas separation equipment 20 to which the gaseous mixture is supplied from the gas supply pipe 31, houses an aqueous alkylalkanolamide solution dissolving the toluene and unreacted methylcyclohexane included in the gaseous mixture and has a gas discharge port 27 for discharging the hydrogen gas passing through the aqueous alkylalkanolamide solution. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决的问题：提供一种氢气分离装置，其可以由至少含有氢气和有机材料的气体混合物制造高纯度氢气，并提供氢气制备装置和燃料电池系统使用氢气分离装置。解决方案：氢气产生装置包括：气体供给管31，其供给至少含有氢气，甲苯和未反应的甲基环己烷的气体混合物和从气体供给气体混合物的氢气分离设备20 供给管31包含溶解在气态混合物中的甲苯和未反应的甲基环己烷的烷基链烷醇酰胺溶液水溶液，并具有用于排出通过烷基链烷醇酰胺溶液的氢气的排气口27。版权所有（C）2006，JPO＆NCIPI

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