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    • 1. 发明专利
    • Display device
    • 显示设备
    • JP2014071173A
    • 2014-04-21
    • JP2012215561
    • 2012-09-28
    • Toyoda Gosei Co Ltd豊田合成株式会社Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • ANDO HIROAKIBABA KAZUMASAIDO NAOYASUISHII MASAHIKOKATO MAKOTO
    • G02F1/167G02F1/19
    • PROBLEM TO BE SOLVED: To provide a display device capable of changing a structural color into multiple colors.SOLUTION: A display device 10 includes: a display electrode 13 through which at least the rays of light of a visible light region are transmitted; a back electrode 14 arranged so as to be opposite to a display substrate with an interval; colloidal crystal solution 15 interposed between the respective electrodes; and a voltage application device 20 for applying a voltage via the respective electrodes 13 and 14 to the colloidal crystal solution. The colloidal crystal solution 15 has a colloidal crystal structure formed by periodically arraying many colloidal particles 15b that are dispersoids with predetermined intervals in a liquid dispersive medium 15a. Fine particles 15c whose primary particle diameters are smaller than those of the colloidal particles 15b are added and dispersed in the dispersive medium 15a.
    • 要解决的问题:提供能够将结构颜色改变为多种颜色的显示装置。显示装置10包括:显示电极13,至少透射可见光区域的光线; 以与间隔相对地布置成与显示基板相对的背面电极14; 夹在各个电极之间的胶体晶体溶液15; 以及用于经由各个电极13和14将电压施加到胶体晶体溶液的电压施加装置20。 胶态晶体溶液15具有通过在液体分散介质15a中周期性地排列以预定间隔分散的许多胶体粒子15b而形成的胶体晶体结构。 一次粒径小于胶体粒子15b的微粒15c被分散在分散介质15a中。
    • 2. 发明专利
    • Display device
    • 显示设备
    • JP2013137384A
    • 2013-07-11
    • JP2011287787
    • 2011-12-28
    • Toyoda Gosei Co Ltd豊田合成株式会社Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • ANDO HIROAKIBABA KAZUMASAISHII MASAHIKO
    • G02F1/167
    • PROBLEM TO BE SOLVED: To provide a display device capable of stably maintaining a structural color.SOLUTION: A display device 10 includes: a display electrode 13 transmitting light in at least a visible light region; a backplate electrode 14 disposed to face a display substrate with a space; a colloidal crystal solution 15 held between each of the electrodes 13 and 14; and a voltage application device 20 applying voltage to the colloidal crystal solution 15 via each of the electrodes 13 and 14. The colloidal crystal solution 15 has a colloidal crystal structure formed by periodically arranging many colloidal particles 15b to be dispersoids in a dispersion medium 15a of liquid at prescribed intervals. The voltage application device 20 applies DC voltage of a pulsating flow to the colloidal crystal solution 15.
    • 要解决的问题:提供能够稳定地保持结构颜色的显示装置。显示装置10包括:显示电极13,其至少透射可见光区域的光; 背面板电极14,设置成与空间相对的显示基板; 保持在每个电极13和14之间的胶体晶体溶液15; 电压施加装置20经由电极13和14中的每一个向胶体晶体溶液15施加电压。胶体晶体溶液15具有胶体晶体结构,其通过在分散介质15a中周期性地排列许多胶体粒子15b以形成分散体 液体以规定的间隔。 电压施加装置20将脉动流的直流电压施加到胶体晶体溶液15。
    • 4. 发明专利
    • Image display device
    • 图像显示设备
    • JP2009020435A
    • 2009-01-29
    • JP2007184591
    • 2007-07-13
    • Toyoda Gosei Co LtdToyota Central R&D Labs Inc株式会社豊田中央研究所豊田合成株式会社
    • ANDO HIROAKIMIYAZAKI TAKESHINAKAMURA HIROSHIISHII MASAHIKO
    • G09F9/30
    • PROBLEM TO BE SOLVED: To provide an image display device capable of maintaining image display even when external force is removed and of achieving energy saving.
      SOLUTION: The image display device 10 is equipped with display devices 22 which reflect visible light of specific wavelength in such a state where a plurality of display devices are arranged to be planar, and a shape deforming part 30 which elastically deforms the display device 22. Each display device 22 has colloidal particles 23a arranged at regular spacings and filler 23b lying between the colloidal particles 23a and elastically deformed. The shape deforming part 30 is disposed to apply pressing force to the display device 22 and equipped with a shape holding member 31 formed of material reversibly plastically deformed by the external force. The shape holding member 31 is plastically deformed when it is driven by a deforming driving part 32, elastically deform the display element 22 to change reflection wavelength, whereby display content is varied.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供即使当外力被去除并且实现节能时也能够保持图像显示的图像显示装置。 解决方案:图像显示装置10配备有在多个显示装置被布置为平面的状态下反射特定波长的可见光的显示装置22和使显示器弹性变形的形状变形部30 每个显示装置22具有以规则间隔布置的胶体颗粒23a和位于胶体颗粒23a之间的弹性变形的填料23b。 形状变形部30被设置成对显示装置22施加按压力,并且配备有由外力可逆地塑性变形的材料形成的形状保持构件31。 当由变形驱动部32驱动时,形状保持构件31塑性变形,使显示元件22弹性变形以改变反射波长,从而显示内容变化。 版权所有(C)2009,JPO&INPIT
    • 5. 发明专利
    • Display device
    • 显示设备
    • JP2013073002A
    • 2013-04-22
    • JP2011211683
    • 2011-09-27
    • Toyoda Gosei Co Ltd豊田合成株式会社Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • ANDO HIROAKIBABA KAZUMASAISHII MASAHIKOKATO MAKOTO
    • G02F1/167
    • PROBLEM TO BE SOLVED: To provide a display device at low cost that can prevent colloidal particles from being aggregated and fastened even when a high DC voltage is applied.SOLUTION: A display device 10 includes: a display electrode 13 that transmits light at least in a visible light region; a back electrode 14 that is oppositely arranged to a display substrate with a gap; a colloidal crystal solution 15 held between respective electrodes 13 and 14; and a dielectric liquid film 16 mediated in the boundary surface between the respective electrodes 13 and 14 and colloidal crystal solution 15. The colloidal crystal solution 15 includes a colloidal crystal structure formed by a number of colloidal particles 15b, which are dispersoid, in the disperse medium 15a of a liquid at a predetermined interval periodically. The dielectric liquid film 16 is a thin film composed of a dielectric liquid having a property such that the liquid neither mixes with the colloidal crystal solution 15 nor flows therein.
    • 要解决的问题:提供一种低成本的显示装置,即使在施加高的直流电压时也能够防止胶体颗粒聚集和紧固。 解决方案:显示装置10包括:至少在可见光区域透射光的显示电极13; 背面电极14,其与具有间隙的显示基板相对布置; 保持在各个电极13和14之间的胶体晶体溶液15; 以及在各电极13,14与边界面之间介电的介电液膜16和胶体晶体溶液15.胶体晶体溶液15包括由分散体中分散有多个胶体颗粒15b形成的胶体晶体结构 周期性地以预定间隔的液体的介质15a。 介电液膜16是由具有使胶液与胶体晶体15不混合也不流过的特性的电介质液构成的薄膜。 版权所有(C)2013,JPO&INPIT
    • 6. 发明专利
    • Colloidal crystal composition
    • 胶体晶体组成
    • JP2009235259A
    • 2009-10-15
    • JP2008083873
    • 2008-03-27
    • Toyoda Gosei Co LtdToyota Central R&D Labs Inc株式会社豊田中央研究所豊田合成株式会社
    • ANDO HIROAKIMIYAZAKI TAKESHINAKAMURA HIROSHIISHII MASAHIKO
    • C09K19/54C09K19/12G02B1/02G02B5/08G02B5/26G02F1/13G02F1/1334
    • PROBLEM TO BE SOLVED: To provide a temperature-selective infrared-transmitting film having a new constitution. SOLUTION: In a film-like colloidal crystal 10, silica particles 11 are dispersed with regularity in a cross-linked polymer matrix 12. A liquid crystalline substance 15 is added to the colloidal crystal 10 (2.A). In the temperature-selective infrared-transmitting film 100, the liquid crystalline substance 15 infiltrates in each gap between the cross-linked polymer matrix 12 and a silica particle 11, and allows to swell as a whole. T NI is a transition point between a liquid crystal phase (nematic phase) and an isotropic liquid phase. The refractive index of the liquid crystalline substance 15 is largely changed by the phase transition between the isotropic liquid phase 15i (2.B) where rod-like molecules in a droplet assemble randomly at a temperature T higher than the transition point T NI and the liquid crystal phase (nematic phase) 15n (2.C) where the rod-like molecules in a droplet align regularly at a temperature T lower than the transition point T NI . Thereby, the infrared reflectance of the temperature-selective infrared-transmitting film 100 is changed by temperature. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供具有新结构的温度选择性红外线透射膜。 解决方案:在膜状胶体晶体10中,将二氧化硅颗粒11规则地分散在交联聚合物基质12中。将液晶物质15加入到胶体晶体10(2.A)中。 在温度选择性红外线透过膜100中,液晶物质15渗透在交联聚合物基质12和二氧化硅粒子11之间的每个间隙中,并且允许整体膨胀。 T NI 是液晶相(向列相)和各向同性液相之间的转变点。 液晶物质15的折射率通过各向同性液相15i(2.B)之间的相变大大地改变,其中液滴中的棒状分子在高于转变点T 的温度T随机组装, NI 和液滴(向列相)15n(2.C),其中液滴中的棒状分子在低于转变点T 的温度T上有规律地排列。 由此,温度选择性红外线透过膜100的红外线反射率由温度变化。 版权所有(C)2010,JPO&INPIT
    • 7. 发明专利
    • Polymerization initiator, method for producing polymeric modified material using the same, and molded body containing polymeric modified material
    • 聚合引发剂,使用其聚合改性材料的方法和含聚合物改性材料的成型体
    • JP2010024263A
    • 2010-02-04
    • JP2008183595
    • 2008-07-15
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • HAYASHIDA KENICHINAKAMURA HIROSHIISHII MASAHIKO
    • C08F4/00C08F292/00
    • PROBLEM TO BE SOLVED: To provide a method for producing a polymeric modified material, by which polymer chains can be grafted at high density to a surface of a substrate such as silica and a carbon material, and a polymeric modified material having the characteristics of the substrate can be obtained.
      SOLUTION: The method for producing a polymeric modified material includes steps of: reacting a substrate having a nucleophilic functional group on the surface with a polymerization initiator containing a halogenated methyl aromatic compound derivative expressed by formula (1):X
      1 -CH
      2 -Ar-(Y
      1 )
      n to bond the polymerization initiator to the surface of the substrate; and reacting the substrate having the polymerization initiator bonded to the surface with radical polymerizable monomers to graft and polymerize the radical polymerizable monomers to the surface of the substrate. In formula (1), X
      1 represents a halogen atom; Ar represents an aromatic ring; Y
      1 represents a group containing a functional group having polymerization initiating ability; and n represents an integer of 1 to 3.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种生产聚合物改性材料的方法,其中聚合物链可以以高密度接枝到诸如二氧化硅和碳材料的基材的表面,以及具有 可以获得基板的特性。 解决方案:聚合物改性材料的制备方法包括以下步骤:使表面具有亲核官能团的基材与含有由式(1)表示的卤代甲基芳族化合物衍生物的聚合引发剂反应:X 将聚合引发剂键合到基材的表面上,以使聚合引发剂与基材的表面结合;将<! - SIPO 1 表示卤原子; Ar表示芳香环; Y 1 表示含有具有聚合引发能力的官能团的基团; 并且n表示1〜3的整数。(C)2010,JPO&INPIT
    • 9. 发明专利
    • Coating method and coated body obtained by the same
    • 涂层方法和涂层方法
    • JP2010142712A
    • 2010-07-01
    • JP2008321238
    • 2008-12-17
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • YOMO SHUJITATE KAZUYUKIISHII MASAHIKOKUWANO KAZUYUKI
    • B05D1/36
    • PROBLEM TO BE SOLVED: To provide a coating method which can obtain a laminated coated film with little unevenness in the uppermost layer surface even if two kinds of paints are laminated by a wet-on-wet method and baked, and each layer is hardened to secure high durability, etc. SOLUTION: The coating method includes forming the laminated coated film provided with a lower layer formed on a substrate and the uppermost layer formed on the lower layer. The coating method also includes a process of preparing a thermoset paint containing a base substance resin of 5°C or less in the glass transition temperature as a paint for a lower layer to form the lower layer and of preparing a thermoset paint in which the weight reduction rate in the curing temperature is 0.5 mass% or less as a paint for the uppermost layer to form the uppermost layer, a process of forming an uncured laminated coated film by laminating the paint for the lower layer and the paint for the uppermost layer by a wet-on-wet method on the substrate, and a process of applying a heat treatment to the uncured laminated coated film to cure the paint for the lower layer and the paint for the uppermost layer. COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:为了提供一种可以获得最上层表面几乎不均匀的层压涂膜的涂布方法,即使通过湿法湿法层压两种涂料并烘烤,并且每层 硬化以确保高耐久性等。解决方案:涂布方法包括形成层叠涂膜,该层压涂膜设置有形成在基板上的下层,而形成在下层上的最上层。 该涂布方法还包括一种在玻璃化转变温度下制备含有5℃或更低的基础物质树脂的热固性涂料作为下层涂料以形成下层并制备热固性涂料的方法,其中重量 固化温度的还原率为最上层的涂料为0.5质量%以下,通过将下层的涂料和最上层的涂料层压而形成未固化的层叠涂膜的工序 基底上的湿法湿法,以及对未固化的层叠涂膜施加热处理以固化下层用涂料和最上层用涂料的工序。 版权所有(C)2010,JPO&INPIT
    • 10. 发明专利
    • Manufacturing method for colloidal crystal immobilized with polymer, and colloidal crystal immobilized with polymer
    • 用聚合物固定的胶体晶体的制造方法和用聚合物固定的胶体晶体
    • JP2008303261A
    • 2008-12-18
    • JP2007150016
    • 2007-06-06
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • NAKAMURA HIROSHIISHII MASAHIKO
    • C08F2/44C08F257/02C08F265/06C08F292/00
    • C08F2/44C08F222/10C08F2222/1013C08F2222/1026
    • PROBLEM TO BE SOLVED: To provide a manufacturing method for a colloidal crystal immobilized with a polymer, immobilizing colloidal particles formed in a liquid while sufficiently maintaining array structure thereof, and easily controlling crystal structure (lattice constant, crystal form and the like) of the colloidal crystal. SOLUTION: This manufacturing method for the colloidal crystal immobilized with the polymer includes a process for obtaining a monomer dispersion liquid formed with the three-dimensional regular array state of colloidal crystal, by making the colloidal particles within a range having 0.01-10 μm of average particle size, and bringing a monodisperse degree expressed by expression (1):ämonodisperse degree (unit:%)}=(ästandard deviation of particle sizes}/äaverage particle size})×100 into 20% or less contained in a monomer-containing liquid containing one kind or more of monomers, and by dispersing the colloidal particles to form the three-dimensional regular array state having a reflection peak in a reflection spectrum, and a process for polymerizing the monomers in the monomer dispersion liquid to obtain the colloidal crystal immobilized with the polymer. COPYRIGHT: (C)2009,JPO&INPIT
    • 解决问题:为了提供固定有聚合物的胶体晶体的制造方法,在充分保持其阵列结构的同时固定形成在液体中的胶体粒子,并且容易控制晶体结构(晶格常数,晶体形态等) )胶体晶体。 解决方案:固定有聚合物的胶体晶体的制造方法包括通过使胶体粒子在0.01-10的范围内获得形成有胶体晶体的三维正排列状态的单体分散液的方法 平均粒径的μm,将表达式(1)表示的单分散度:单分散度(单位:%)} =(粒径的标准偏差/平均粒径})×100变为包含在 含有一种或多种单体的含单体液体,并且通过分散胶体颗粒以形成在反射光谱中具有反射峰的三维规则阵列状态,以及使单体分散液中的单体聚合以获得 胶体晶体固定在聚合物上。 版权所有(C)2009,JPO&INPIT