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    • 3. 发明专利
    • Urethane-modified alkyd resin, resin composition for water-based urethane-modified alkyd coating and method for producing them
    • URETHANE改性的ALKYD树脂,用于水基改性的烷基涂料的树脂组合物及其生产方法
    • JP2008007717A
    • 2008-01-17
    • JP2006182167
    • 2006-06-30
    • Toyobo Co Ltd東洋紡績株式会社
    • TOGAWA KEIICHIROABE SHUNZONAKAJIMA TAKAHIROETO YOSHITAKA
    • C08G18/66C08G63/91C09D5/02C09D161/20C09D163/00C09D175/06
    • PROBLEM TO BE SOLVED: To obtain a resin composition for a water-based alkyd coating, which is friendly to the environment, has improved adhesivity, excellent color tone, weather resistance, slight thermal discoloration and stable qualities and to provide a method for producing the same. SOLUTION: The resin composition for a water-based urethane modified alkyd coating comprises an urethane modified alkyd resin (A) which is obtained by using a natural fatty acid ester and a polycarboxylic acid anhydride as acid components and a 2-50C polyhydric alcohol as an alcohol component in the presence of a polymerization catalyst containing at least an aluminum compound to produce a polyester polyol, reacting the polyester polyol with an organic diisocyanate compound and if necessary, a chain extender having a molecular weight of 6 g, reduced viscosity of 0.2-1.0 dl/g and an acid value of ≥50 equivalents/10 6 g and a curing agent (B) and is adjusted so as to satisfy a neutralization ratio of 1-2,000% by using a neutralizer (C) to the acid value of the resin (A). COPYRIGHT: (C)2008,JPO&INPIT
    • 待解决的问题:为了获得对环境友好的水性醇酸树脂涂料用树脂组合物,具有改善的粘合性,优异的色调,耐候性,轻微的热变色和稳定的特性,并提供了一种方法 为了生产相同。 解决方案:用于水基氨基甲酸酯改性醇酸树脂涂料的树脂组合物包括通过使用天然脂肪酸酯和多元羧酸酐作为酸组分得到的氨基甲酸酯改性醇酸树脂(A)和2-50C多元醇 在含有至少一种铝化合物的聚合催化剂存在下,作为醇组分的醇,以制备聚酯多元醇,使聚酯多元醇与有机二异氰酸酯化合物反应,如果需要,分子量小于500的扩链剂 氨基甲酸酯基浓度为300-5,000当量/ 10 SP 6,比浓粘度为0.2-1.0dl / g,酸值为≥50当量/ 10 SP 6, 通过使用中和剂(C)与树脂(A)的酸值相比,调节为使中和率达到1-2000%。 版权所有(C)2008,JPO&INPIT
    • 4. 发明专利
    • Polyester-polyether copolymer and method for producing the same
    • 聚酯聚合物共聚物及其制备方法
    • JP2008007581A
    • 2008-01-17
    • JP2006177492
    • 2006-06-28
    • Toyobo Co Ltd東洋紡績株式会社
    • MARUYAMA TAKESHISUZUKI KENTANAKAJIMA TAKAHIROABE SHUNZO
    • C08G63/84
    • PROBLEM TO BE SOLVED: To provide a polyester-polyether copolymer and a method for producing the same, wherein the copolymer does not contain a tin compound; discoloration of a resin resulting from poor thermal stability which is one of the weak points of titanium compounds is suppressed; and problems in production such as filter clogging by foreign matter are solved, corresponding to the market which desires resource saving and environmental protection.
      SOLUTION: The method for producing a polyester-polyether copolymer comprises subjecting a dicarboxylic acid mainly composed of an aromatic dicarboxylic acid or a dicarboxylic acid diester mainly composed of an aromatic dicarboxylic acid diester and a diol having a molecular weight of less than 250 mainly composed of 1,4-butanediol and a polyalkylene glycol having a number-average molecular weight of 400-4,000 to esterification or ester exchange reaction, followed by polycondensation reaction, wherein an environmentally friendly polyester-polyether copolymer with suppressed discoloration resulting from poor heat resistance can be obtained by at least using one selected from the group consisting of aluminum compounds as a catalyst.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供聚酯 - 聚醚共聚物及其制备方法,其中共聚物不含锡化合物; 抑制作为钛化合物的弱点之一的热稳定性差的树脂的变色; 解决了过滤器外来物质堵塞等生产过程中遇到的资源节约型和环保型市场。 解决方案:聚酯 - 聚醚共聚物的制备方法包括使主要由芳族二羧酸或主要由芳族二羧酸二酯组成的二羧酸二酯和分子量小于250的二醇的二羧酸 主要由1,4-丁二醇和数均分子量为400-4,000的聚亚烷基二醇组成,用于酯化或酯交换反应,随后进行缩聚反应,其中环境友好的聚酯 - 聚醚共聚物由于热量差导致抑制变色 可以通过至少使用选自铝化合物作为催化剂的一种来获得耐受性。 版权所有(C)2008,JPO&INPIT
    • 5. 发明专利
    • Biodegradable polyester resin composition for light scattering sheet and method for producing the same
    • 用于光散射片的生物可降解聚酯树脂组合物及其生产方法
    • JP2007262118A
    • 2007-10-11
    • JP2006085053
    • 2006-03-27
    • Toyobo Co Ltd東洋紡績株式会社
    • TOGAWA KEIICHIROABE SHUNZOETO YOSHITAKA
    • C08L67/00C08G63/60C08K7/16C08L101/16
    • PROBLEM TO BE SOLVED: To obtain a biodegradable resin composition for a light scattering layer of a light scattering sheet using an organic solvent-soluble biodegradable polyester resin, in more detail, a biodegradable polyester resin composition for a light scattering sheet, which is a resin composition comprising light-focusing beads dispersed by using a polyester resin (A), keeps transparency, has excellent adhesivity and heat resistance and is useful for improvement in contrast of especially a liquid crystal display, etc.
      SOLUTION: In the polyester resin (A) that is produced by copolymerizing lactic acid and a 2-30C dicarboxylic acid as acid components with a 2-30C glycol as a glycol component, the biodegradable polyester resin composition for a light scattering sheet comprises light-focusing beads dispersed in the copolyester (A) having the ratio of lactic acid of 40-98 mol%, a glass transition temperature of ≤70°C, a reduced viscosity of ≥0.20 dl/g and an acid value of ≤300 equivalents/10
      6 g.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题为了获得使用有机溶剂可生物降解聚酯树脂的光散射片的光散射层的生物降解性树脂组合物,更详细地,涉及一种用于光散射片的可生物降解的聚酯树脂组合物,其中 是包含通过使用聚酯树脂(A)分散的聚光珠的树脂组合物,保持透明性,具有优异的粘合性和耐热性,并且可用于改善特别是液晶显示器等的对比度。解决方案:在 通过将乳酸与作为酸成分的2-30C二羧酸与作为二醇成分的2-30C二醇的2-30C二羧酸共聚制成的聚酯树脂(A),用于光散射片的生物降解性聚酯树脂组合物包含分散的聚光珠 在乳酸的比例为40-98摩尔%,玻璃化转变温度≤70℃,比浓粘度≥0.20dl/ g的共聚酯(A)和酸值 ≤300当量/ 10 6。 版权所有(C)2008,JPO&INPIT
    • 6. 发明专利
    • Resin composition for light scattering sheet and method for producing the same
    • 用于光散射片的树脂组合物及其制造方法
    • JP2007262116A
    • 2007-10-11
    • JP2006085051
    • 2006-03-27
    • Toyobo Co Ltd東洋紡績株式会社
    • TOGAWA KEIICHIRONAKAJIMA TAKAHIROABE SHUNZOETO YOSHITAKA
    • C08L67/02C08G63/84C08K3/40G02B5/02
    • PROBLEM TO BE SOLVED: To obtain a resin composition for a light scattering sheet, which keeps luminous intensity necessary for improvement in contrast of liquid crystal display, has excellent adhesivity to a substrate sheet and heat resistance, namely controls discoloration being a defect of a copolyester obtained by using a titanium compound as a polymerization catalyst and has excellent transparency.
      SOLUTION: The resin composition for a light scattering sheet comprises light-focusing beads dispersed in a copolyester (A) which is produced in the presence of a polymerization catalyst containing at least an aluminum compound, comprises an acid component constituting the copolyester, being a dicarboxylic acid and a glycol component composed of 10-100 mol% of an alkylene glycol and 0-90 mol% of other glycols and has a reduced viscosity of ≥0.10 dl/g.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题为了获得保持对液晶显示器的对比度提高所需的发光强度的光散射片用树脂组合物,对基片的粘附性和耐热性均优异,即控制变色为缺陷 的通过使用钛化合物作为聚合催化剂获得并具有优异透明性的共聚酯。 解决方案:光散射片用树脂组合物包含分散在共聚酯(A)中的聚光珠,其在至少包含铝化合物的聚合催化剂存在下制备,包含构成共聚酯的酸组分, 是由10-100摩尔%亚烷基二醇和0-90摩尔%其它二醇组成的二羧酸和二元醇组分,并且具有≥0.10dl/ g的比浓粘度。 版权所有(C)2008,JPO&INPIT
    • 7. 发明专利
    • Resin composition for light scattering sheet and method for producing the same
    • 用于光散射片的树脂组合物及其制造方法
    • JP2007262115A
    • 2007-10-11
    • JP2006085050
    • 2006-03-27
    • Toyobo Co Ltd東洋紡績株式会社
    • TOGAWA KEIICHIRONAKAJIMA TAKAHIROABE SHUNZOETO YOSHITAKA
    • C08L67/02C08G63/84C08K3/40G02B5/02
    • PROBLEM TO BE SOLVED: To obtain a resin composition for a condensing agent of liquid crystal display, which keeps luminous intensity necessary for improvement in contrast of liquid crystal display, has excellent adhesivity to a substrate sheet and heat resistance, namely controls discoloration being a defect of a copolyester obtained by using a titanium compound as a polymerization catalyst and has excellent transparency. SOLUTION: The resin composition for a light scattering sheet comprises light-focusing beads dispersed in a copolyester (A) which is produced in the presence of a polymerization catalyst containing at least an aluminum compound and contains 0.01-3 wt.% calculated as a sulfur content of a metal sulfonate group in the molecule. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题为了获得液晶显示器的对比度保持发光强度所需的液晶显示器的缩合剂用树脂组合物,对基片的粘附性和耐热性优异,即控制变色 是通过使用钛化合物作为聚合催化剂获得的共聚酯的缺点,并且具有优异的透明性。 解决方案:光散射片用树脂组合物包含分散在共聚酯(A)中的聚光珠,其在至少包含铝化合物的聚合催化剂存在下制备,并含有0.01-3重量%的计算值 作为分子中的金属磺酸盐基团的硫含量。 版权所有(C)2008,JPO&INPIT
    • 8. 发明专利
    • Alkyd resin, resin composition for water-based alkyd coating and method for producing them
    • ALKYD树脂,用于水性碱性涂料的树脂组合物及其生产方法
    • JP2008007718A
    • 2008-01-17
    • JP2006182168
    • 2006-06-30
    • Toyobo Co Ltd東洋紡績株式会社
    • TOGAWA KEIICHIROABE SHUNZONAKAJIMA TAKAHIROETO YOSHITAKA
    • C08G63/49C08G63/84C08L33/04C08L67/08C09D5/02C09D7/12C09D133/06C09D161/00C09D163/00C09D167/08C09D175/04
    • PROBLEM TO BE SOLVED: To obtain a resin composition for a water-based alkyd coating, more in detail, a resin composition which contains no tin, no lead and no zinc compounds so as to deal with resource saving and markets desiring environmental conservation, controls resin discoloration caused by deficiency of thermal stability being the defect of a titanium-based catalyst and has excellent heat resistance, especially useful for coating. SOLUTION: The alkyd resin is obtained by blending an oily alkyd resin (A) which is produced by using a natural fatty acid ester and a polycarboxylic acid anhydride as acid components and a 2-50C polyhydric alcohol as an alcohol component in the presence of a polymerization catalyst containing at least an aluminum compound and has an acid value of ≥50eq/10 6 g with a copolymerized (meth)acrylate resin (B) having an acid value of ≥50eq/10 6 g. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题为了获得水性醇酸树脂涂料用树脂组合物,更详细地说,不含锡,无铅和不含锌化合物的树脂组合物,以应对资源节约和市场渴望环境 保护,控制由热稳定性不足引起的树脂变色是钛基催化剂的缺点,并具有优异的耐热性,特别适用于涂料。 解决方案:醇酸树脂通过将通过使用天然脂肪酸酯和多元羧酸酐作为酸组分制备的油性醇酸树脂(A)和作为醇组分的2-50℃多元醇混合,得到 使用酸值≥50eq/ 10的共聚的(甲基)丙烯酸酯树脂(B),存在至少含有铝化合物的聚合催化剂并具有≥50eq/ 10 6的酸值 6 克。 版权所有(C)2008,JPO&INPIT
    • 9. 发明专利
    • (meth) acrylic-modified oily alkyd resin, resin composition for water-based alkyd coating and method for producing them
    • (METH)丙烯酸改性油性树脂,用于水性碱性涂料的树脂组合物及其生产方法
    • JP2008007716A
    • 2008-01-17
    • JP2006182166
    • 2006-06-30
    • Toyobo Co Ltd東洋紡績株式会社
    • TOGAWA KEIICHIROABE SHUNZONAKAJIMA TAKAHIROETO YOSHITAKA
    • C08F283/02C08G63/84C09D5/00C09D7/12C09D151/08C09D161/00C09D163/00C09D175/04
    • PROBLEM TO BE SOLVED: To obtain a resin composition for a water-based alkyd coating, more in detail, a resin composition which contains no tin, no lead and no zinc compounds so as to deal with resource saving and markets desiring environmental conservation, controls resin discoloration caused by deficiency of thermal stability being a drawback of a titanium-based catalyst and has excellent heat resistance, especially useful for coating. SOLUTION: The (meth)acrylic modified oily alkyd resin is obtained by using a natural fatty acid ester and a polycarboxylic acid anhydride as acid components and a 2-50C polyhydric alcohol as an alcohol component in the presence of a polymerization catalyst containing at least an aluminum compound to give an oily alkyd resin and subjecting the oily alkyd resin to graft polymerization with a polymerizable monomer and has an acid value of ≥50eq/10 6 g. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题为了获得水性醇酸树脂涂料用树脂组合物,更详细地说,不含锡,无铅和不含锌化合物的树脂组合物,以应对资源节约和市场渴望环境 保护,控制由热稳定性不足引起的树脂变色是钛基催化剂的缺点,并具有优异的耐热性,特别适用于涂料。 解决方案:(甲基)丙烯酸改性油性醇酸树脂通过使用天然脂肪酸酯和多元羧酸酐作为酸组分和2-50℃多元醇作为醇组分,在含有 至少一种铝化合物,得到油性醇酸树脂,并使油性醇酸树脂用可聚合单体进行接枝聚合,并具有≥50eq/ 10 <6>的酸值。 版权所有(C)2008,JPO&INPIT
    • 10. 发明专利
    • Oil-free alkyd resin, resin composition for oil-free alkyd coating and method for producing them
    • 无油烷基树脂,无油烷基涂料用树脂组合物及其生产方法
    • JP2008007715A
    • 2008-01-17
    • JP2006182165
    • 2006-06-30
    • Toyobo Co Ltd東洋紡績株式会社
    • TOGAWA KEIICHIROABE SHUNZONAKAJIMA TAKAHIROETO YOSHITAKA
    • C08G81/00
    • PROBLEM TO BE SOLVED: To obtain an oil-free alkyd resin and a resin composition for an oil-free alkyd coating, more in detail, a resin composition which contains no tin, no lead and no zinc compounds so as to deal with resource saving and markets desiring environmental conservation, controls resin discoloration caused by deficiency of thermal stability stability being the defect of a titanium-based catalyst and has excellent heat resistance, especially useful for coating.
      SOLUTION: The oily alkyd resin comprises 100 parts wt. of a polyester resin (A) having an acid value of 100-1,500 equivalents/10
      6 g and a hydroxy value of 10-1,000 equivalents/10
      6 g obtained by producing a polyester by a condensation polymerization reaction of a dicarboxylic acid and a polyhydric alcohol in the presence of a polymerization catalyst containing at least an aluminum compound and introducing an unsaturated group to the polyester and 1-50 parts wt. of resol-type phenol resin (B).
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题为了获得无油醇酸树脂和无油醇酸树脂涂料的树脂组合物,更详细地说,不含锡,不含铅和不含锌化合物以处理的树脂组合物 节约资源和市场需要环保,控制由热稳定性不足导致的树脂变色是钛基催化剂的缺点,具有优异的耐热性,特别适用于涂料。 油性醇酸树脂包含100重量份。 的聚酯树脂(A),其酸值为100-1,500当量/ 10 SP 6,羟基值为10-1,000当量/ 10 SP 6,通过生产 通过二羧酸和多元醇的缩聚反应,在至少含有铝化合物的聚合催化剂存在下,将不饱和基团引入到聚酯中,并将其重量为1-50重量份, 的分解型酚醛树脂(B)。 版权所有(C)2008,JPO&INPIT