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1. 发明专利

JP2015030800A 水性インキ用コアシェル型樹脂微粒子分散体及び水性インキ組成物有权
标题翻译：核心壳树脂细颗粒墨水和水性墨水组合物的分散
公开(公告)号：JP2015030800A
公开(公告)日：2015-02-16
申请号：JP2013161584
申请日：2013-08-02
申请人：東洋インキScホールディングス株式会社 , Toyo Ink Sc Holdings Co Ltd
发明人： KOIKE TAKAAKI , NISHINA AKIKO , OTAKE TAKAAKI , SATO YUKI , SUZUKI YOSHIKO , ISHIHARA CHIKASHI , SHIOZAWA TATSUYA , NIITSUMA MASAMI
IPC分类号： C09D11/00
摘要：【課題】非極性フィルム基材に対しても、低温乾燥下、優れた塗膜物性(基材密着性、耐水摩擦性)を発現し、一方でインキの保存安定性、再溶解性、版洗浄性にも優れる水性インキコアシェル型樹脂微粒子分散体及び水性インキ組成物の提供。【解決手段】水溶性樹脂(A)の存在下、水性媒体中でエチレン性不飽和単量体(b)を乳化重合してなるコアシェル型の樹脂微粒子分散体(B)を、水性樹脂(A)の組成、エチレン性不飽和単量体(b)の組成、及び水性インキ用コアシェル型樹脂微粒子分散体(B)の性状を制御することにより、本願発明の課題が解決することができる。【選択図】なし
摘要翻译：要解决的问题：为了提供一种用于水性油墨和水性油墨组合物的核 - 壳树脂微粒分散体，其在低温条件下显影出涂膜的优异物理性质（与基材的粘合性和湿摩擦阻力）即使对非极性膜基材进行高温干燥，也显示优异的储存稳定性，油墨的再溶解性和板清洗性。溶液：通过乳液制备用于水性油墨的核 - 壳树脂微粒分散体（B）在水溶性树脂（A）的存在下，在水性介质中聚合烯属不饱和单体（b）。通过控制水性树脂（A）的组成，烯键式不饱和单体（b）的组成和水性油墨的核 - 壳树脂微粒分散体（B）的方面，可以获得期望的性能。

2. 发明专利

JP2013168323A Binder resin composition for electrode for nonaqueous secondary battery 审中-公开
标题翻译：用于非水性二次电池的电极的粘合剂树脂组合物
公开(公告)号：JP2013168323A
公开(公告)日：2013-08-29
申请号：JP2012032041
申请日：2012-02-16
申请人： Toyo Ink Sc Holdings Co Ltd , 東洋インキScホールディングス株式会社
发明人： HARUTA KAZUNARI , INAGAKI MASARU , OTAKE TAKAAKI
IPC分类号： H01M4/62 , C08F220/10 , C08F230/08 , C08F246/00
CPC分类号： Y02E60/12
摘要： PROBLEM TO BE SOLVED: To provide a binder resin composition for an electrode for a nonaqueous secondary battery, the binder resin composition being excellent in adhesion to a collector and enabling the manufacture of a nonaqueous secondary battery that offers a high discharge capacity even under high-temperature environments.SOLUTION: The binder composition for an electrode for a nonaqueous secondary battery contains cross-linked resin particles. The cross-linked resin particles are obtained by emulsion polymerization of (A) at least one monomer selected from the group consisting of monomers having one ethylenic unsaturated group and a monofunctional or multifunctional alkoxysilyl group in one molecule, and monomers having two or more ethylenic unsaturated groups in one molecule, (B) an acidic group-containing ethylenic unsaturated monomer other than (A), and (C) another monomer having an ethylenic unsaturated group, including a monomer (c) having an ethylenic unsaturated group, in water in the presence of a surfactant with the aid of a radical polymerization initiator. The resin particles are neutralized with an alkali metal hydroxide and/or an alkali metal carbonate.
摘要翻译：要解决的问题：为了提供一种用于非水二次电池的电极用粘合剂树脂组合物，该粘合剂树脂组合物对集电体的粘附性优异，并且能够制造即使在高分子量聚合物下也具有高放电容量的非水二次电池，非水系二次电池用电极用粘合剂组合物含有交联树脂粒子。交联树脂颗粒通过（A）在一分子中选自具有一个烯属不饱和基团和单官能或多官能烷氧基甲硅烷基的单体中的至少一种单体和具有两个或更多个烯属不饱和单体的单体进行乳液聚合而获得（B）除（A）以外的含酸性基团的烯属不饱和单体，和（C）具有烯键式不饱和基团的单体（包含具有烯属不饱和基团的单体（c））在水中的借助自由基聚合引发剂存在表面活性剂。用碱金属氢氧化物和/或碱金属碳酸盐中和树脂颗粒。

3. 发明专利

JP2012204246A Binder resin composition for nonaqueous secondary battery electrode 有权
标题翻译：非水性二次电池电极的粘结剂树脂组合物
公开(公告)号：JP2012204246A
公开(公告)日：2012-10-22
申请号：JP2011069466
申请日：2011-03-28
申请人： Toyo Ink Sc Holdings Co Ltd , 東洋インキScホールディングス株式会社
发明人： KOIKE TAKAAKI , HARUTA KAZUNARI , KINOSHITA SACHIKO , NISHINA AKIKO , OTAKE TAKAAKI , INAGAKI MASARU , MIYAJIMA KOICHIRO , IKEDA SHINGO , MOROISHI YORIYUKI
IPC分类号： H01M4/62
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a binder resin composition for a nonaqueous secondary battery electrode, excellent in binding properties and electrolyte resistance, and capable of providing a nonaqueous secondary battery which maintains high discharge capacity even after repetition of charge and discharge and under a high temperature environment due to heat generation.SOLUTION: A binder resin composition for a nonaqueous secondary battery electrode includes a resin fine particle dispersion which is obtained by performing emulsion polymerization of an ethylenically unsaturated monomer (C) in an aqueous medium under a condition of the presence of a maleic-modified polybutadiene (B) formed by ring-opening of an anhydride ring of a maleic anhydride-modified polybutadiene (BP) by a compound (A) having a hydroxy group.
摘要翻译：解决的问题：提供一种非水系二次电池用电极用粘结剂树脂组合物，其结合性和耐电解质性优异，能够提供即使在重复进行充放电后也能保持高放电容量的非水二次电池，在高温环境下由于发热。解决方案：非水系二次电池用电极用粘合剂树脂组合物包括通过在水性介质中在马来酸酐存在下进行烯键式不饱和单体（C）的乳液聚合而得到的树脂微粒分散体，通过由具有羟基的化合物（A）开环马来酸酐改性的聚丁二烯（BP）的酸酐环而形成的改性聚丁二烯（B）。版权所有（C）2013，JPO＆INPIT

4. 发明专利

JP2013028658A Binder resin composition for aqueous inkjet, and inkjet ink using the same 有权
标题翻译：用于水性喷嘴的粘合剂树脂组合物和使用其的喷墨
公开(公告)号：JP2013028658A
公开(公告)日：2013-02-07
申请号：JP2011163583
申请日：2011-07-26
申请人： Toyo Ink Sc Holdings Co Ltd , 東洋インキScホールディングス株式会社
发明人： KOIKE TAKAAKI , HARUTA KAZUNARI , NISHINA AKIKO , OTAKE TAKAAKI , KITAMOTO TAKESHI , OSHIMA YOSHITERU , KIMURA KAZUYA
IPC分类号： B41J2/01 , B41M5/00 , C08F246/00 , C09D11/00 , C09D11/322
摘要： PROBLEM TO BE SOLVED: To provide a binder resin composition for aqueous inkjet, excellent in storage stability and discharge stability of an ink, and developing good coated film resistances (wear resistance, water resistance, solvent resistance) by low-temperature drying.SOLUTION: The binder resin composition for aqueous inkjet contains a resin microparticle (F) obtained by emulsion polymerizing 0 to 20 wt.% of an aromatic ethylenically unsaturated monomer (A) having no ionic functional group, 0.5 to 3.0 wt.% of a sulfonic acid group-containing ethylenically unsaturated monomer (B) or a phosphoric acid group-containing ethylenically unsaturated monomer (C), 0.1 to 3.0 wt.% of a non-ionic aqueous ethylenically unsaturated monomer (D), and 0.1 to 10 wt.% of a crosslinkable ethylenically unsaturated monomer (E).
摘要翻译：要解决的问题：提供一种水性喷墨用粘合剂树脂组合物，油墨的保存稳定性和喷出稳定性优异，并且通过低温干燥显影出良好的涂膜电阻（耐磨性，耐水性，耐溶剂性）。解决方案：水性喷墨用粘合剂树脂组合物含有通过使0〜20重量％的不具有离子性官能团的芳香族烯属不饱和单体（A）乳化聚合而获得的树脂微粒（F）为0.5〜3.0重量％含有磺酸基的烯属不饱和单体（B）或含磷酸基的烯键式不饱和单体（C），0.1〜3.0重量％的非离子含水烯键式不饱和单体（D）和0.1〜10 可交联烯属不饱和单体（E）的重量％。版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2012201691A Ink composition for aqueous inkjet 有权
标题翻译：水性喷墨墨水组合物
公开(公告)号：JP2012201691A
公开(公告)日：2012-10-22
申请号：JP2011064366
申请日：2011-03-23
申请人： Toyo Ink Sc Holdings Co Ltd , 東洋インキScホールディングス株式会社
发明人： KINOSHITA SACHIKO , HARUTA KAZUNARI , KOIKE TAKAAKI , NISHINA AKIKO , OTAKE TAKAAKI , TAKAHASHI MASATOSHI , YODA JUN , SUGIHARA MASAHIRO
IPC分类号： B41J2/01 , B41M5/00 , C09D11/00 , C09D11/322 , C09D11/324 , C09D11/326 , C09D11/38
摘要： PROBLEM TO BE SOLVED: To provide an ink composition for an aqueous inkjet, which has storage stability and dischargeability and excellent printability, abrasion resistance, water resistance, solvent resistance, gloss and brightness of a printed material, stands up to rubbing between printed materials in continuous printing, and contact with water and an alcohol-based solvent, and has improved dischargeability.SOLUTION: The ink composition for aqueous inkjet includes at least resin fine particles (D) and a moisturizing solvent. The average particle diameter of the resin fine particles (D) is 150-350 nm, the amount of coarse particles of 1.5-5 μm at 30 ppm solid concentration is ≤25,000 particles/cmand the amount of coarse particles of 5-10 μm is ≤4,000 particles/cm.
摘要翻译：要解决的问题：为了提供具有储存稳定性和放电性以及优异的印刷性，耐磨性，耐水性，耐溶剂性，印刷材料的光泽和亮度的水性喷墨的油墨组合物，可以直接摩擦印刷材料连续印刷，并与水和醇基溶剂接触，并具有改善的排出性能。解决方案：用于水性喷墨的油墨组合物至少包括树脂细颗粒（D）和保湿溶剂。树脂微粒（D）的平均粒径为150〜350nm，固体成分浓度为30ppm时为1.5-5μm的粗粒子的粒子数为≤25,000个/ cm 3， SP>，5-10μm的粗颗粒量≤4,000粒/ cm 3 。版权所有（C）2013，JPO＆INPIT

6. 发明专利

JP2015030799A 水性インキ用バインダー樹脂組成物及び水性インキ組成物有权
标题翻译：水性油墨和水性油墨组合物的粘结剂树脂组合物
公开(公告)号：JP2015030799A
公开(公告)日：2015-02-16
申请号：JP2013161583
申请日：2013-08-02
申请人：東洋インキScホールディングス株式会社 , Toyo Ink Sc Holdings Co Ltd
发明人： KOIKE TAKAAKI , NISHINA AKIKO , OTAKE TAKAAKI , SUZUKI YOSHIKO , ISHIHARA CHIKASHI , SHIOZAWA TATSUYA , NIITSUMA MASAMI
IPC分类号： C09D11/02
摘要：【課題】非極性フィルム基材に対して、低温乾燥条件下、良好な塗膜物性(密着性、耐水摩擦性、耐水ブロッキング性、低臭気)を発現し、一方でインキの保存安定性、再溶解性、版洗浄性にも優れる水性インキ用バインダー組成物ならびにそれを含有する水性インキ組成物【解決手段】すなわち、本発明は、水溶性樹脂(A)の存在下、水性媒体中でエチレン性不飽和単量体(b)を重合してなる酸価50〜90mgKOH/gのコアシェル型樹脂微粒子分散体(B)と、水性媒体中でエチレン性不飽和単量体(c)を重合してなる酸価0〜30mgKOH/gの樹脂微粒子分散体(C)を含有する事を特徴とする水性インキ用バインダー樹脂組成物を用いることにより上記課題を解決するに至った。【選択図】なし
摘要翻译：要解决的问题：为了提供在低温干燥条件下形成涂膜的良好物理性能（粘合性，湿摩擦阻力，耐湿粘连性和低气味）的水性油墨用粘合剂组合物，以及显示优异的储存稳定性，油墨的再溶解性和板清洁性，并提供含有粘合剂组合物的水性油墨组合物。溶液：用于水性油墨的粘合剂树脂组合物包括：核 - 壳树脂细颗粒分散体（B）在水溶性树脂（A）的存在下在水性介质中聚合烯键式不饱和单体（b）制备的酸值为50〜90mgKOH / g的（B）和通过在水性介质中聚合烯键式不饱和单体（c）而制备的酸值为0〜30mgKOH / g的树脂微粒分散液（C）。

7. 发明专利

JP2012216517A Binder resin composition for nonaqueous secondary battery electrode 有权
标题翻译：非水性二次电池电极的粘结剂树脂组合物
公开(公告)号：JP2012216517A
公开(公告)日：2012-11-08
申请号：JP2012066839
申请日：2012-03-23
申请人： Toyo Ink Sc Holdings Co Ltd , 東洋インキScホールディングス株式会社
发明人： HARUTA KAZUNARI , KINOSHITA SACHIKO , KOIKE TAKAAKI , NISHINA AKIKO , OTAKE TAKAAKI , INAGAKI MASARU , MIYAJIMA KOICHIRO , IKEDA SHINGO , MOROISHI YORIYUKI
IPC分类号： H01M4/62
CPC分类号： Y02E60/12
摘要： PROBLEM TO BE SOLVED: To provide a binder resin composition for a nonaqueous secondary battery electrode, having little adverse effects on human bodies and the environment, excellent in adhesion with a collector, and capable of manufacturing a nonaqueous secondary battery retaining high discharge capacity even after repetition of charge and discharge and under a high-temperature environment due to heat generation.SOLUTION: A binder resin composition for a nonaqueous secondary battery electrode is a resin composition obtained by polymerizing a mixture including an ethylenically unsaturated monomer (A) which can be radically polymerized and a polyamide resin (B) in an aqueous medium including a surfactant, a polymerization initiator and water as essential components. The mixture of the (A) and the (B) are forcibly emulsified in the presence of a surfactant and water, and polymerized after the emulsified product has an average particle size of 2 μm or less.
摘要翻译：解决问题的方法：提供一种非水系二次电池用电极用粘合剂树脂组合物，对人体和环境的不良影响小，集电体附着性优异，能够制造保持高放电性的非水二次电池即使在重复充放电之后并且由于发热而在高温环境下。解决方案：非水系二次电池用电极用粘合剂树脂组合物是将包含可自由基聚合的烯属不饱和单体（A）和聚酰胺树脂（B）的混合物在含有表面活性剂，聚合引发剂和水作为必要组分。（A）和（B）的混合物在表面活性剂和水的存在下强制乳化，在乳化产物的平均粒径为2μm以下后进行聚合。版权所有（C）2013，JPO＆INPIT

8. 发明专利

JP2012204245A Binder resin composition for nonaqueous secondary battery electrode 审中-公开
标题翻译：非水性二次电池电极的粘结剂树脂组合物
公开(公告)号：JP2012204245A
公开(公告)日：2012-10-22
申请号：JP2011069464
申请日：2011-03-28
申请人： Toyo Ink Sc Holdings Co Ltd , 東洋インキScホールディングス株式会社
发明人： HARUTA KAZUNARI , KINOSHITA SACHIKO , KOIKE TAKAAKI , NISHINA AKIKO , OTAKE TAKAAKI , INAGAKI MASARU , MIYAJIMA KOICHIRO , IKEDA SHINGO , MOROISHI YORIYUKI
IPC分类号： H01M4/62
CPC分类号： Y02E60/12
摘要： PROBLEM TO BE SOLVED: To provide a binder resin composition for nonaqueous secondary battery electrodes which has less adverse effects on human body and environment, has good adhesiveness to current collectors, and makes it possible to manufacture a nonaqueous secondary battery which maintains a high discharge capacity even in a high temperature environment due to repetitive charging and discharging or heat generation.SOLUTION: The binder resin composition for nonaqueous secondary battery electrodes is a resin composition derived by polymerizing an admixture containing ethylenically unsaturated monomer (A) capable of radical polymerization and polyester resin (B) in an aqueous medium consisting of, as essential components, a surface active agent, a polymerization initiator and water. The admixture of (A) and (B) is forcibly emulsified in the presence of surface active agent and water until the average particle size of the resultant emulsion becomes 2 μm or less before being polymerized.
摘要翻译：解决的问题：为了提供对人体和环境的不利影响较小的非水二次电池用电极用粘合剂树脂组合物，对集电体的粘附性良好，可以制造维持即使在高温环境中由于重复的充放电或发热而具有高放电容量。非水二次电池用电极用粘合剂树脂组合物是将含有能够自由基聚合的烯键式不饱和单体（A）和聚酯树脂（B）的混合物在含水介质中混合而得的树脂组合物，，表面活性剂，聚合引发剂和水。（A）和（B）的混合物在表面活性剂和水的存在下强制乳化，直到聚合前所得乳液的平均粒径为2μm以下。版权所有（C）2013，JPO＆INPIT

9. 发明专利

JP2014082149A Binder resin composition for nonaqueous secondary battery electrode 有权
标题翻译：非水性二次电池电极的粘结剂树脂组合物
公开(公告)号：JP2014082149A
公开(公告)日：2014-05-08
申请号：JP2012230562
申请日：2012-10-18
申请人： Toyo Ink Sc Holdings Co Ltd , 東洋インキScホールディングス株式会社
发明人： HARUTA KAZUNARI , KURAUCHI KEISUKE , OTAKE TAKAAKI
IPC分类号： H01M4/62
摘要： PROBLEM TO BE SOLVED: To provide a long life nonaqueous secondary battery excellent in electrolyte resistance, high in flexibility, high in adhesion with a collector, and capable of reducing deterioration in discharge capacity in charge/discharge cycles even after the repetition of charge/discharge and under a high-temperature environment due to heat generation.SOLUTION: The problem is solved by a binder resin composition for a nonaqueous secondary battery electrode, which is obtained by polymerizing a monomer mixture containing, as an essential component, a radically polymerizable ethylenic unsaturated monomer (A) having a 10-40C branched alkyl group.
摘要翻译：要解决的问题：为了提供耐电解质优异，柔性高，与集电体附着性高的长寿命非水二次电池，即使在充放电循环重复之后，也能够减少充放电循环中的放电容量的劣化并且在高温环境下由于发热而解决。解决方案：通过将含有作为必需成分的自由基聚合性烯属不饱和单体的单体混合物的非水二次电池用电极用粘合剂树脂组合物具有10-40℃支链烷基的单体（A）。

10. 发明专利

JP2013193986A Crosslinking agent and method for producing the same 有权
标题翻译：交联剂及其生产方法
公开(公告)号：JP2013193986A
公开(公告)日：2013-09-30
申请号：JP2012062284
申请日：2012-03-19
申请人： Toyo Ink Sc Holdings Co Ltd , 東洋インキScホールディングス株式会社
发明人： KOIKE TAKAAKI , NISHINA AKIKO , OTAKE TAKAAKI , MIYASHITA TOMO
IPC分类号： C07C309/15 , C08G73/00 , C08K5/29 , C08L101/08 , C09D11/00
摘要： PROBLEM TO BE SOLVED: To provide a crosslinking agent including a hydrophilic polycarbodiimide compound which forms a stable association in an aqueous medium, is excellent in dispersion stability and storage stability at room temperature and high temperature, and further is excellent in curability at low temperature and compatibility with a base agent, to provide a method for producing the crosslinking agent, and to provide an aqueous resin composition containing the crosslinking agent.SOLUTION: There is disclosed a crosslinking agent including a hydrophilic polycarbodiimide compound represented by general formula (1) (in the formula, an average polymerization degree n denotes an integer of 1 to 15; R, Rare hydrophilic groups comprising the residue of a hydrophilic organic compound having one active hydrogen in a molecule, which can react with an isocyanate group and at least one side of them is the hydrophilic group with which an N-alkyl amino sulfonic acid salt reacts; and X is a 4-20C aliphatic hydrocarbon group, a 6-15C alicyclic hydrocarbon group or a 7-15C aromatic hydrocarbon group).
摘要翻译：要解决的问题：为了提供包含在水性介质中形成稳定缔合的亲水性聚碳化二亚胺化合物的交联剂，在室温和高温下的分散稳定性和储存稳定性优异，并且在低温下的固化性也优异，与基剂的相容性，提供交联剂的制造方法，以及提供含有交联剂的水性树脂组合物。溶剂：公开了一种交联剂，其包括通式（1）表示的亲水性聚碳化二亚胺化合物（在平均聚合度n表示1〜15的整数，R表示分子内含有一个活性氢的亲水性有机化合物的残基的亲水性基团，其可以与异氰酸酯基反应，并且至少一面为它们是N-烷基氨基磺酸盐与其反应的亲水基团; X是4-2 0C脂族烃基，6-15C脂环族烃基或7-15C芳族烃基）。

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