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1. 发明专利

JP2006143901A METHOD FOR PRODUCING ETHYLENE/α-OLEFIN COPOLYMER 审中-公开
标题翻译：生产乙烯/α-烯烃共聚物的方法
公开(公告)号：JP2006143901A
公开(公告)日：2006-06-08
申请号：JP2004336523
申请日：2004-11-19
申请人： Tosoh Corp , 東ソー株式会社
发明人： SONE MAKOTO , HASEGAWA AYAKI , YANO AKIHIRO , SATO MORIHIKO
IPC分类号： C08F210/16
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an ethylene-α-olefin copolymer having various molecular weights, densities, molecular weight distributions and component distributions, optionally and with a good productivity. SOLUTION: This method for producing the ethylene-α-olefin copolymer is provided by using each at least of ≥1 kind of (A) a metallocene catalyst satisfying general formula (a): r=C poly /C rea ≥0.08 [wherein, C poly is a monomer ratio of the α-olefin/ethylene contained in the obtained copolymer; C rea is the monomer ratio of the α-olefin/ethylene contained in a hydrocarbon solvent; and (r) is a division of them], and (B) a metallocene catalyst satisfying general formula (b): r=C poly /C rea COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决的问题：提供一种制备具有各种分子量，密度，分子量分布和组分分布的乙烯-α-烯烃共聚物的方法，任选地并且具有良好的生产率。解决方案：通过使用至少≥1种（A）满足通式（a）的金属茂催化剂：这些乙烯-α-烯烃共聚物的制造方法：r = C < SB> / C ≥0.08[其中，C 聚是所得共聚物中所含的α-烯烃/乙烯的单体比例; C rea 是烃溶剂中所含的α-烯烃/乙烯的单体比例; 和（r）是它们的除数），和（B）满足通式（b）的茂金属催化剂：r = C poly / C rea 0.08，在聚合条件下，在共聚物的熔点或高于共聚物的熔点的温度和在共聚反应无活性的烃溶剂中<40MPa的压力下，使乙烯与3-20℃的α-烯烃共聚。版权所有（C）2006，JPO＆NCIPI

2. 发明专利

JP2005239689A Method for synthesizing organic compound useful as ligand of transition metal compound 有权
标题翻译：合成有机化合物作为过渡金属化合物配体的方法
公开(公告)号：JP2005239689A
公开(公告)日：2005-09-08
申请号：JP2004055361
申请日：2004-02-27
申请人： Tosoh Corp , 東ソー株式会社
发明人： HAMURA SATOSHI , HASEGAWA AYAKI , TANABIKI MASAO , YANO AKIHIRO
IPC分类号： C07C2/34 , C07C13/15 , C07C13/465 , C07C13/567 , C07C13/66 , C07C17/266 , C07C23/34 , C07F1/02
摘要： PROBLEM TO BE SOLVED: To synthesize easily an organic compound becoming a ligand of a cross-linked type transition metal compound useful as an olefin polymerization catalyst.
SOLUTION: This method for synthesizing the organic compound expressed as (C), as shown by reaction formula (1) [wherein, Cp
1 is cyclopentadienyl, indenyl, fluorenyl or such groups having a substituting group; R
1 s are independently the same or different and are each H, or a 1-30C hydrocarbon or a hydrocarbon including a hetero atom; Z is H or a leaving group; M is a metal component derived from the organometallic compound; Cp
1' is the same as the Cp
1 or a group in which the part of Cp
1 is metallized by the organometallic compound; and X is a halogen atom or a leaving group] is provided by performing the reaction of (A) a compound with an organometallic compound to convert them into (B) a reaction intermediate, then reacting it with a compound expressed by Cp
2 -X [Cp
2 is cyclopentadienyl, indenyl, fluorenyl or such groups having a substituent].
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：容易地合成成为可用作烯烃聚合催化剂的交联型过渡金属化合物的配体的有机化合物。解决方案：如反应式（1）所示，合成表示为（C）的有机化合物的方法[其中，Cp 1 是环戊二烯基，茚基，芴基或具有取代基组; R 1彼此独立地相同或不同，各自为H或1-30C烃或包含杂原子的烃; Z是H或离去基团; M是衍生自有机金属化合物的金属成分; Cp 1'与Cp 1 相同或其中部分Cp 1 由有机金属化合物金属化的基团; 并且X是卤素原子或离去基团]是通过（A）化合物与有机金属化合物的反应将其转化成（B）反应中间体，然后使其与由Cp 2 [SP SP 2]是环戊二烯基，茚基，芴基或具有取代基的这些基团。版权所有（C）2005，JPO＆NCIPI

3. 发明专利

JP2007211014A Method for producing organic transition metal compound 有权
标题翻译：生产有机过渡金属化合物的方法
公开(公告)号：JP2007211014A
公开(公告)日：2007-08-23
申请号：JP2007038442
申请日：2007-02-19
申请人： Tosoh Corp , 東ソー株式会社
发明人： KANEKO TOSHIYUKI , IKEDA TAKAHARU , YANO AKIHIRO , SATO MORIHIKO
IPC分类号： C07F17/00 , C07F7/00 , C08F4/6592
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a transition metal compound to be used as a catalyst for producing a high-molecular weight polyolefin. SOLUTION: The method for producing the transition metal compound comprises the following operations (A) and (B): The operation (A) comprises the following: One equivalent of an organometallic compound of the general formula (3): R 9 x M 2 X 3 (y-x) or a metal hydride is reacted to a substrate followed by, without isolating the resultant compound's monoanion metal salt, reaction with a compound of the general formula (4): R 1 X 4 , or instead of the compound (4), with either one of compounds of the respective general formulas: R 2 X 4 , R 3 X 4 and R 4 X 4 , and the above operation (A) is repeated to introduce one or more substituents into the cyclopentadienyl ring moiety. The subsequent operation (B) comprises the following: Two equivalents of a compound (3) is reacted to the compound obtained by the repeated operation (A) followed by reaction with one equivalent of a transition metal halide. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：提供一种用作生产高分子量聚烯烃的催化剂的过渡金属化合物的制备方法。解决方案：制备过渡金属化合物的方法包括以下操作（A）和（B）：操作（A）包括以下：1当量的通式（3）的有机金属化合物： SP> 9 X 2 X 3 （yx）或金属氢化物与底物，然后不分离所得化合物的单阴离子金属盐，与通式（4）的化合物反应：或者代替化合物（4）所示的化合物，其中任一个具有以下通式的化合物：其中R 1，R 2，R 3，R 3， SP>和R 4 4 ，并重复上述操作（A）以将一个或多个取代基引入环戊二烯基环部分。后续操作（B）包括：将2当量的化合物（3）与通过重复操作（A）获得的化合物反应，随后与1当量的过渡金属卤化物反应。版权所有（C）2007，JPO＆INPIT

4. 发明专利

JP2007182588A Catalyst for producing olefin polymer and method for producing olefin polymer 有权
标题翻译：用于生产烯烃聚合物的催化剂和生产烯烃聚合物的方法
公开(公告)号：JP2007182588A
公开(公告)日：2007-07-19
申请号：JP2007096136
申请日：2007-04-02
申请人： Tosoh Corp , 東ソー株式会社
发明人： KANEKO TOSHIYUKI , YANO AKIHIRO
IPC分类号： C08F4/6592 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for producing an olefin polymer, which can save complicated synthesis processes for catalyst components and is used for efficiently producing the olefin polymer, and to provide a method for producing an olefin polymer in the presence of the same, by which the olefin polymer can efficiently be produced. SOLUTION: This method for producing the olefin polymer comprises polymerizing an olefin in the presence of a catalyst for producing the olefin polymer, comprising (a) a metallocene compound containing a transition metal in the group 4 in the periodic table and (b) an iminometallane compound represented by the general formula (29): R 2 NM 6 R 18 l-2 , wherein, R 18 groups are each independently H or a 1 to 20C hydrocarbon group or a halogenated hydrocarbon group; R 2 is a 1 to 20C halogenated hydrocarbon group; M 6 is a metal in the group 2, 12 or 13 in the periodic table; (l) is the valency of the metal M 6 . COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：提供一种用于制备烯烃聚合物的催化剂，其可以节省催化剂组分的复杂合成方法并用于有效生产烯烃聚合物，并提供在存在下制备烯烃聚合物的方法可以有效地制造烯烃聚合物。解决方案：用于制备烯烃聚合物的方法包括在用于制备烯烃聚合物的催化剂存在下聚合烯烃，包括（a）在周期表第4族中含有过渡金属的茂金属化合物和（b ）由通式（29）表示的亚氨基金属化合物：R 2 SP 2 R 12 / ，其中R 16是各自独立地为H或1〜20C烃基或卤代烃基; R 2 是1至20C卤代烃基; M 6 是周期表第2,12或13组中的金属; （1）是金属M 6的化合价。版权所有（C）2007，JPO＆INPIT

5. 发明专利

JP2006143900A METHOD FOR PRODUCING ETHYLENE/α-OLEFIN COPOLYMER 审中-公开
标题翻译：生产乙烯/α-烯烃共聚物的方法
公开(公告)号：JP2006143900A
公开(公告)日：2006-06-08
申请号：JP2004336522
申请日：2004-11-19
申请人： Tosoh Corp , 東ソー株式会社
发明人： SONE MAKOTO , HASEGAWA AYAKI , YANO AKIHIRO , SATO MORIHIKO
IPC分类号： C08F210/16
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an ethylene-α-olefin copolymer having various molecular weights, densities, molecular weight distributions and component distributions, optionally and with a good productivity.
SOLUTION: This method for producing the ethylene-α-olefin copolymer is provided by using at least ≥1 kind each of (A) a metallocene catalyst satisfying general formula (a): r=C
poly /C
rea ≥0.08 and (B) a metallocene catalyst satisfying general formula (b): r=C
poly /C
rea
摘要翻译：解决的问题：提供一种制备具有各种分子量，密度，分子量分布和组分分布的乙烯-α-烯烃共聚物的方法，任选地并且具有良好的生产率。解决方案：通过使用满足通式（a）的（A）茂金属催化剂中的至少≥1种，提供该乙烯-α-烯烃共聚物的制造方法：r = C 聚多 / C ≥0.08 并在聚合条件下在共聚物的熔点或高于40-400MPa压力的温度下将乙烯与2-20℃的α-烯烃共聚。版权所有（C）2006，JPO＆NCIPI

6. 发明专利

JP2006028326A Method for producing catalyst for producing macromonomer, and method for producing macromonomer 审中-公开
标题翻译：用于生产用于生产大肠杆菌的催化剂的方法，以及用于生产大肠杆菌的方法
公开(公告)号：JP2006028326A
公开(公告)日：2006-02-02
申请号：JP2004208469
申请日：2004-07-15
申请人： Tosoh Corp , 東ソー株式会社
发明人： INATOMI TAKASHI , YAMADA SATORU , YANO AKIHIRO
IPC分类号： C08F4/645 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To obtain a particulate macromonomer having high polymerization activities, excellent processability and a long chain branch, and providing good morphology. SOLUTION: The method for producing the macromonomer comprises polymerizing ethylene and optionally a ≥3C olefin in the presence of a catalyst comprising a component obtained by reacting (a) a specific transition metal compound with (b) a clay mineral treated with an organic compound at ≥50°C, and optionally (c) an organometal compound represented by the formula: M 3 R 6 m (wherein, M 3 is an element selected from magnesium, zinc and aluminum; and R 6 is each independently a hydrogen atom, a halogen atom, a 1-20C hydrocarbon group or a 1-20C alkoxy group). COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：获得具有高聚合活性，优异的加工性和长链分支的颗粒状大分子单体，并提供良好的形态。解决方案：生产大分子单体的方法包括在催化剂存在下聚合乙烯和任选的≥3C烯烃，催化剂包含通过使（a）特定的过渡金属化合物与（b）用 ≥50℃的有机化合物，以及（c）由下式表示的有机金属化合物：其中， M 3 是选自镁，锌和铝的元素; R 6 SP 6各自独立地为氢原子，卤素原子，1-20C烃基或1 -20℃的烷氧基）。版权所有（C）2006，JPO＆NCIPI

7. 发明专利

JP2005281676A Catalyst for producing particulate macromonomer and method for producing particulate macromonomer 有权
标题翻译：用于生产颗粒大分子的催化剂和生产颗粒大分子的方法
公开(公告)号：JP2005281676A
公开(公告)日：2005-10-13
申请号：JP2005029010
申请日：2005-02-04
申请人： Tosoh Corp , 東ソー株式会社
发明人： INATOMI TAKASHI , HAMURA SATOSHI , TANABIKI MASAO , YAMADA SATORU , YANO AKIHIRO
IPC分类号： C08F4/643 , C08F4/6592
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for producing a particulate macromonomer having excellent processability, long chain branches, and good morphology in a high polymerization activity, and to provide a method for producing the same. SOLUTION: This catalyst comprises (a) a specific transition metal compound, (b) a clay mineral treated with an organic compound, and, if necessary, (c) an organic metal compound represented by the formula: M 3 R 6 m (M 3 is an element selected from magnesium, zinc and aluminum; R 6 groups are each independently H, a halogen atom, a 1 to 20C hydrocarbon group or a 1 to 20C alkoxy). The method for producing a particulate macromonomer comprises polymerizing ethylene and, arbitrarily, a ≥3C olefin in the presence of the catalyst. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：提供一种具有优异的加工性，长支链和高聚合活性的良好形态的颗粒状大分子单体的制造用催化剂，提供其制造方法。解决方案：该催化剂包含（a）特定的过渡金属化合物，（b）用有机化合物处理的粘土矿物，如果需要，（c）由下式表示的有机金属化合物：M （M 3 是选自镁，锌和铝的元素; R 6 SP>基各自独立地为H，卤素原子，1〜20C烃基或1〜20C烷氧基）。制备颗粒状大分子单体的方法包括在催化剂存在下聚合乙烯和任意地使用≥3C烯烃。版权所有（C）2006，JPO＆NCIPI

8. 发明专利

JP2005239688A Method for producing substituted indenyl compound 有权
标题翻译：生产取代的茚基化合物的方法
公开(公告)号：JP2005239688A
公开(公告)日：2005-09-08
申请号：JP2004055360
申请日：2004-02-27
申请人： Tosoh Corp , 東ソー株式会社
发明人： HAMURA SATOSHI , HASEGAWA AYAKI , TANABIKI MASAO , YANO AKIHIRO
IPC分类号： C07C17/275 , C07B61/00 , C07C25/22
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a substituted indenyl compound by progressing the reaction of a diphenylbenzofulvene with a nucleophilic reagent which can not progress under a usual condition, under an industrially utilizable condition.
SOLUTION: This method for producing the substituted indenyl compound is provided by performing the reaction of (A) the diphenylbenzofulvene or its derivative with (B) an activating agent [a reaction mixture of (b-1) a Lewis acid compound with (b-2) an organometallic compound], and then performing a reaction with (C) a nucleophilic reagent.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：提供一种通过在工业上可利用的条件下进行二苯基苯并富烯与不能在通常条件下进行的亲核试剂的反应来制备取代的茚基化合物的方法。解决方案：制备取代茚基化合物的方法是通过（A）二苯基苯并富烯或其衍生物与（B）活化剂[（b-1）路易斯酸化合物的反应混合物与（b-2）有机金属化合物]，然后与（C）亲核试剂进行反应。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2005206777A Ethylenic polymer and production method therefor 有权
标题翻译：乙烯聚合物及其生产方法
公开(公告)号：JP2005206777A
公开(公告)日：2005-08-04
申请号：JP2004089036
申请日：2004-03-25
申请人： Tosoh Corp , 東ソー株式会社
发明人： SONE MAKOTO , YANO AKIHIRO , SATO MORIHIKO
IPC分类号： C08F10/02 , C08F4/642 , C08F4/659 , C08F4/6592
摘要： PROBLEM TO BE SOLVED: To obtain an ethylenic polymer having high moldability and also exhibiting excellent characteristics such as transparency, low hexane-extractables, low-temperature heat-sealability and strength balance. SOLUTION: When homopolymerizing ethylene or copolymerizing ethylene with a 3-20C α-olefin using an olefin polymerization catalyst composed of (a) a modified clay compound, (b) at least two transition metal compounds and (c) an organoaluminum compound, the reaction is preferably carried out in a single reaction vessel. COPYRIGHT: (C)2005,JPO&NCIPI

10. 发明专利

JP2005139101A Method for producing substituted methylene-crosslinked substituted indenyl-substituted cyclopentadienyl compound 审中-公开
标题翻译：用于生产取代的亚甲基交联的取代的取代的环戊二烯基化合物的方法
公开(公告)号：JP2005139101A
公开(公告)日：2005-06-02
申请号：JP2003375509
申请日：2003-11-05
申请人： Tosoh Corp , 東ソー株式会社
发明人： TANABIKI MASAO , HAMURA SATOSHI , HASEGAWA AYAKI , YANO AKIHIRO
IPC分类号： C07C1/00 , C07C13/567 , C08F4/60
摘要： PROBLEM TO BE SOLVED: To provide a method for efficiently producing a substituted methylene-crosslinked substituted indenyl-substituted cyclopentadienyl compound. SOLUTION: This method for efficiently producing the substituted methylene-crosslinked substituted indenyl-substituted cyclopentadienyl compound is characterized by continuing the reaction of a periodic table group 6 transition metal carbonyl compound represented by the formula (1): M(CO) 3 L 3 (1) with a compound represented by formula (2), while continuously or intermittently removing a by-produced coordination-bonding compound (L) on the outside of the reaction system, and then reacting the prepared transition metal allene compound represented by formula (3) with a substituted cyclopentadienyl anion represented by formula (4). COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种有效制备取代的亚甲基交联的取代茚基取代的环戊二烯基化合物的方法。解决方案：用于有效制备取代的亚甲基交联的取代茚基取代的环戊二烯基化合物的方法的特征在于继续与式（1）表示的周期表6族过渡金属羰基化合物的反应：M（CO）（2）表示的化合物，同时连续地或间歇地除去副产物的配位键合化合物（L），其中，然后使制备的由式（3）表示的过渡金属联苯化合物与由式（4）表示的取代的环戊二烯阴离子反应。版权所有（C）2005，JPO＆NCIPI

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