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    • 3. 发明专利
    • Polyvinylidene fluoride-based multiple membrane and method for producing the same
    • 聚氟乙烯基氟化物多孔膜及其制造方法
    • JP2010094670A
    • 2010-04-30
    • JP2009216681
    • 2009-09-18
    • Toray Ind Inc東レ株式会社
    • ISHIZAKI TOSHIYUKIMINAKI TAKASHIIWAI KENTAMINEGISHI SHINICHI
    • B01D71/34B01D69/12B01D71/12B32B27/30C08J9/00C08J9/28C08J9/42C08L1/10C08L27/16
    • PROBLEM TO BE SOLVED: To provide a polyvinylidene fluoride-based multiple membrane having good capability of removing viruses, pure water permeation performance, and physical strength in a simple process in order to stabilize the water quality of permeation water through improvement of separation functions to a greater extent than conventional water treatment membranes.
      SOLUTION: The polyvinylidene fluoride-based multiple membrane contains 50 wt.% or more and 88 wt.% or less of a polyvinylidene fluoride-based resin with viscosity of 2,500 Pa s or more and 12 wt.% or more and 50 wt.% or less of cellulose ester and having a three-dimensional network structure with an average bore size of 0.01 μm or more and 1 μm or less and a thickness of 5 μm or more and 100 μm or less, wherein the multiple membrane is formed via lamination of a separation function layer having no macrovoid of substantially 5 μm or more on a polyvinylidene fluoride-based supporting membrane having a spherical structure with an average diameter of 0.1 μm or more and 5 μm or less.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了通过改善分离来稳定渗透水的水质,提供了在简单的方法中具有良好的去除病毒能力,纯水渗透性能和物理强度的聚偏二氟乙烯基多元膜 比传统的水处理膜功能更大。 解决方案:聚偏二氟乙烯系多层膜的粘度为2500Pa·s以上且12重量%以上且50重量%以下的50重量%以上且88重量%以下的聚偏二氟乙烯系树脂 重量%以下的纤维素酯,具有平均孔径为0.01μm以上且1μm以下,厚度为5μm以上且100μm以下的三维网状结构,其中,多膜为 通过在具有平均直径为0.1μm以上且5μm以下的球形结构的聚偏二氟乙烯系支撑膜上层压没有大致5μm以上的大孔的分离功能层而形成。 版权所有(C)2010,JPO&INPIT
    • 5. 发明专利
    • Porous film and its manufacturing method
    • 多孔膜及其制造方法
    • JP2008105019A
    • 2008-05-08
    • JP2007248758
    • 2007-09-26
    • Toray Ind Inc東レ株式会社
    • IWAI KENTAHANAKAWA MASAYUKIMINEGISHI SHINICHI
    • B01D71/26B01D71/38
    • PROBLEM TO BE SOLVED: To provide an ethylene-vinyl acetate copolymer porous film having both a high permeability and a high breaking strength/elongation.
      SOLUTION: The porous film is made of a copolymer of ethylene and vinyl acetate or a saponification product of the copolymer and has a spherical structure with a diameter of 0.3-5 μm. A stock solution containing 10-55 wt.% of the copolymer of ethylene and vinyl acetate, a poor solvent of the copolymer and a pore forming agent and having a temperature of 60-120°C is discharged into a cooling bath and solidified to make the porous film.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 待解决的问题:提供具有高渗透性和高断裂强度/伸长率的乙烯 - 乙酸乙烯酯共聚物多孔膜。 解决方案:多孔膜由乙烯和乙酸乙烯酯的共聚物或共聚物的皂化物制成,并具有直径为0.3-5μm的球形结构。 含有10-55重量%的乙烯和乙酸乙烯酯的共聚物,共聚物的不良溶剂和成孔剂,温度为60-120℃的储备溶液被排放到冷却浴中并固化 多孔膜。 版权所有(C)2008,JPO&INPIT
    • 8. 发明专利
    • Composite separation membrane and method for manufacturing the same
    • 复合分离膜及其制造方法
    • JP2007289927A
    • 2007-11-08
    • JP2007046695
    • 2007-02-27
    • Toray Ind Inc東レ株式会社
    • IWAI KENTAMINEGISHI SHINICHIHANAKAWA MASAYUKI
    • B01D69/12B01D71/10B01D71/12B01D71/26B01D71/34B01D71/38B01D71/42B01D71/44B01D71/56B01D71/68
    • PROBLEM TO BE SOLVED: To provide a composite separation membrane having both high permeability and high rupture strength.
      SOLUTION: The composite separation membrane comprising a separating functional layer, which is a layer (a polymer B layer) substantially containing a polymer B with a thickness of not less than 1% and not more than 50% of the thickness of the entire membrane, and a membrane inner layer other than the polymer B layer, which is a layer (a polymer AB layer) substantially containing a polymer A and the polymer B with a thickness of not less than 50% and not more than 99% of the thickness of the entire membrane, is produced by protecting fine pores in the separating functional layer of the separation membrane substantially containing the polymer B by applying a protection agent, packing monomers of the polymer A in the reverse outermost surface to the separating functional layer coated with the protection agent, polymerizing the monomers, and thereafter removing the protection agent.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供具有高渗透性和高断裂强度的复合分离膜。 解决方案:复合分离膜包括分离功能层,其是基本上含有聚合物B的层(聚合物B层),其厚度不小于厚度的1%且不大于50% 整个膜和除了聚合物B层以外的膜内层,其是基本上含有聚合物A的层(聚合物AB层)和厚度不小于50%且不大于99%的聚合物B 整个膜的厚度是通过施加保护剂来保护基本上含有聚合物B的分离膜的分离功能层中的细孔而制成的,聚合物A的最外表面中的单体包裹在分离功能层上 与保护剂反应,聚合单体,然后除去保护剂。 版权所有(C)2008,JPO&INPIT
    • 10. 发明专利
    • Composite membrane and method for manufacturing the same
    • 复合膜及其制造方法
    • JP2012187575A
    • 2012-10-04
    • JP2012038366
    • 2012-02-24
    • Toray Ind Inc東レ株式会社
    • ISHIZAKI TOSHIYUKIKOMORI KENJIKOBAYASHI ATSUSHIIWAI KENTA
    • B01D71/34B01D69/10B01D69/12B01D71/14B32B3/24B32B23/08B32B27/30
    • PROBLEM TO BE SOLVED: To provide a composite membrane using polyvinylidene fluoride resin having virus removal performance and antifouling performance which is excellent in a separation function layer in order to stabilize the water quality of permeated water by improving a separation function in comparison with a conventional water treatment membrane and a method of manufacturing the composite membrane.SOLUTION: There is provided a coat layer formed of polyvinylidene fluoride resin containing 9 wt.% or more and 46 wt.% or less of cellulose ester and a melt viscosity of 3,300 Pa s or more on a supported membrane, wherein the outermost surface pore diameter of the coat layer is 0.01 μm or more and 0.1 μm or less on average, and the wall of the coat layer is formed with a three-dimensional network structure whose average pore diameter is 0.01 μm or more and 0.5 μm or less, and whose thickness is 10 μm or more and 120 μm or less.
    • 解决问题的方法为了提供具有病毒去除性能和防污性能的聚偏二氟乙烯树脂的复合膜,其具有优异的分离功能层,以便通过提高分离功能来稳定渗透水的水质,与 常规水处理膜和复合膜的制造方法。 解决方案:提供一种由负载膜上含有9重量%以上且46重量%以下的纤维素酯和3,300Pa·s以上的熔融粘度的聚偏二氟乙烯树脂形成的涂层,其中, 涂层的最外表面孔径平均为0.01μm以上且0.1μm以下,涂层的壁由平均孔径为0.01μm以上至0.5μm的三维网状结构形成,或 较小,厚度为10μm以上且120μm以下。 版权所有(C)2013,JPO&INPIT