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1. 发明专利

JP2014162906A Method for producing olefin polymerization solid catalyst component, olefin polymerization catalyst, and method for producing olefin polymer 有权
标题翻译：生产烯烃聚合固体催化剂组分，烯烃聚合催化剂的方法和生产烯烃聚合物的方法
公开(公告)号：JP2014162906A
公开(公告)日：2014-09-08
申请号：JP2013037832
申请日：2013-02-27
申请人： Toho Titanium Co Ltd , 東邦チタニウム株式会社
发明人： HOSAKA MOTOKI , NAKAMURA NORIAKI , YAMADA SHINGO , SUGANO TOSHIHIKO
IPC分类号： C08F4/654 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a novel olefin polymerization solid catalyst component that is excellent in polymerization activation of olefin and in to-hydrogen activation during polymerization, as well as that is capable of producing an olefin polymer having a high MFR and stereoregularity and having an excellent rigidity.SOLUTION: A method for producing an olefin polymerization solid catalyst component includes: applying a first step of contacting and reacting magnesium compound, titanium halide compound of tetravalence, and one or more kinds of a first inner electron donative compound in which aromatic dicarboxylic acid diesters are excluded, and followed by washing; applying a second step of contacting and reacting the product obtained, with one or more kinds of a second inner electron donative compound, and followed by washing; and applying a third step of contacting and reacting titanium halide compound of tetravalence and one or more kinds of a third inner electron donative compound.
摘要翻译：要解决的问题：提供一种在聚合过程中烯烃的聚合活化和氢氢活化优异的烯烃聚合固体催化剂组分的制备方法，以及能够生产具有高MFR的烯烃聚合物和立构规整性并且具有优异的刚性。溶解性：一种烯烃聚合固体催化剂组分的制备方法，包括：施加使镁化合物，四价钛卤化物与一种或多种第一内电子给体接触和反应的第一步骤除去芳族二羧酸二酯的化合物，然后洗涤; 将所得产物与一种或多种第二内给电子化合物接触和反应，然后进行洗涤; 并施加与四价钛卤化物化合物和一种或多种第三内给电子化合物接触和反应的第三步骤。

2. 发明专利

JP2014070209A Solid catalyst component for olefin polymerization, catalyst for olefin polymerization and method for producing olefin polymer 审中-公开
标题翻译：用于烯烃聚合的固体催化剂组分，用于烯烃聚合的催化剂和用于生产烯烃聚合物的方法
公开(公告)号：JP2014070209A
公开(公告)日：2014-04-21
申请号：JP2012219315
申请日：2012-10-01
申请人： Toho Titanium Co Ltd , 東邦チタニウム株式会社
发明人： NAKAMURA NORIAKI , HOSAKA MOTOKI , UOZUMI TOSHIYA
IPC分类号： C08F4/654 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a solid catalyst component for olefin polymerization which exhibits high hydrogen response and polymerization activity compared with an olefin polymer obtained by using a solid catalyst component using the conventional diol diester as an electron donor, a catalyst for olefin polymerization, and a method for polymerizing olefin.SOLUTION: The solid catalyst component for olefin polymerization comprises titanium, magnesium, halogen and an ester compound represented by the formula (1). Also provided is a catalyst for olefin polymerization formed from the solid catalyst component, an organic aluminum compound and an external electron donative compound.
摘要翻译：要解决的问题：提供一种与通过使用常规二醇二酯作为电子给体的固体催化剂组分获得的烯烃聚合物相比，具有高氢响应性和聚合活性的烯烃聚合用固体催化剂组分，烯烃聚合用催化剂，和烯烃聚合方法。溶液：烯烃聚合用固体催化剂组分包括钛，镁，卤素和由式（1）表示的酯化合物。还提供了由固体催化剂组分，有机铝化合物和外给电子化合物形成的用于烯烃聚合的催化剂。

3. 发明专利

JP2014037521A Production method of solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and production method of olefin polymerization body 有权
标题翻译：用于烯烃聚合的固体催化剂组分的生产方法，烯烃聚合的催化剂和烯烃聚合体的生产方法
公开(公告)号：JP2014037521A
公开(公告)日：2014-02-27
申请号：JP2013037830
申请日：2013-02-27
申请人： Toho Titanium Co Ltd , 東邦チタニウム株式会社
发明人： HOSAKA MOTOKI , NAKAMURA NORIAKI , YAMADA SHINGO , SUGANO TOSHIHIKO
IPC分类号： C08F4/658 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a production method of a novel solid catalyst component for olefin polymerization that can produce an olefin polymerization body in which polymerization activity of olefin and activity to hydrogen at polymerization are excellent, and an MFR and stereoregularity are high, and excellent rigidity is possessed.SOLUTION: A production method of a solid catalyst component for olefin polymerization performs: a first process in which a magnesium compound, a tetravalent titanium halide compound, and at least one of a first inner electron donative compound are contacted and reacted to perform by cleaning; a second process in which to the obtained product material, a tetravalent titanium halide compound and at least one of a second inner electron donative compound are contacted and reacted to perform cleaning; and a third process in which after that, at least one of a third inner electron donative compound is contacted and reacted.
摘要翻译：要解决的问题：提供一种用于烯烃聚合的新型固体催化剂组分的制备方法，其可以生产烯烃聚合体，其中烯烃的聚合活性和聚合时的氢活性优异，并且MFR和立构规整性高，以及具有优异的刚性。解决方案：用于烯烃聚合的固体催化剂组分的制备方法：其中镁化合物，四价卤化钛化合物和至少一种第一内给电子化合物接触并反应的第一种方法通过清洁执行; 第二种方法是将获得的产物材料中的四价卤化钛化合物和第二内给电子化合物中的至少一种接触并反应进行清洗; 以及第三种方法，其中第三种内给电子化合物中的至少一种接触并反应。

4. 发明专利

JP2013028705A Solid catalyst component for olefin polymerization, method for producing the same, olefin polymerization catalyst, and method for producing olefin polymer 有权
标题翻译：用于烯烃聚合的固体催化剂组分，其制备方法，烯烃聚合催化剂和用于生产烯烃聚合物的方法
公开(公告)号：JP2013028705A
公开(公告)日：2013-02-07
申请号：JP2011165347
申请日：2011-07-28
申请人： Toho Titanium Co Ltd , 東邦チタニウム株式会社
发明人： HOSAKA MOTOKI
IPC分类号： C08F4/654 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a solid catalyst component for olefin polymerization which gives a polyolefin having high flowability upon melting and a wide molecular weight distribution.SOLUTION: The solid catalyst component for olefin polymerization contains Ti, Mg, a halogen atom and an ester compound represented by general formula (1), wherein n and m represent the number of carbon atoms in the cyclic skeleton of the cycloalkyl group, are an integer of 3-14, and may be the same or different, R represents a hydrogen atom, a halogen atom, a 1-8C alkyl group, a vinyl group or an allyl group and may be the same or different, and Rand Rrepresent a 1-12C alkyl group and may be the same or different.
摘要翻译：要解决的问题：提供用于烯烃聚合的固体催化剂组分，其产生在熔融时具有高流动性和宽分子量分布的聚烯烃。解决方案：用于烯烃聚合的固体催化剂组分含有Ti，Mg，卤素原子和由通式（1）表示的酯化合物，其中n和m表示环烷基的环状骨架中的碳原子数为3〜14的整数，可以相同或不同，R表示氢原子，卤素原子，1-8C烷基，乙烯基或烯丙基，可以相同或不同，并且 R 1 ，R 2 表示1-12C烷基，可以相同或不同。版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2013028704A Solid catalyst component for olefin polymerization, method for producing the same, olefin polymerization catalyst, and method for producing olefin polymer 有权
标题翻译：用于烯烃聚合的固体催化剂组分，其制备方法，烯烃聚合催化剂和用于生产烯烃聚合物的方法
公开(公告)号：JP2013028704A
公开(公告)日：2013-02-07
申请号：JP2011165346
申请日：2011-07-28
申请人： Toho Titanium Co Ltd , 東邦チタニウム株式会社
发明人： HOSAKA MOTOKI
IPC分类号： C08F4/654 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a solid catalyst component for olefin polymerization which enables a polyolefin having high flowability upon melting and a wide molecular weight distribution to be obtained in a good yield without using a large amount of hydrogen during polymerization, and to provide a method for producing the solid catalyst component for olefin polymerization, a catalyst and a method for producing a polymer.SOLUTION: The solid catalyst component for olefin polymerization contains titanium, magnesium, a halogen atom and an ester compound represented by general formula (1), wherein R represents a hydrogen atom, a halogen atom, a methyl group or an ethyl group, a plurality of Rs may be the same or different, and Rand Reach represent a 1-12C alkyl group and may be the same or different.
摘要翻译：要解决的问题：提供一种用于烯烃聚合的固体催化剂组分，其能够在聚合过程中不使用大量氢气的情况下以良好的产率获得熔融时具有高流动性和宽分子量分布的聚烯烃，以及提供一种烯烃聚合用固体催化剂成分的制造方法，催化剂及聚合物的制造方法。解决方案：用于烯烃聚合的固体催化剂组分含有钛，镁，卤素原子和由通式（1）表示的酯化合物，其中R表示氢原子，卤素原子，甲基或乙基，多个Rs可以相同或不同，并且R 1 和R 2 各自表示1-12C烷基并且可以相同或不同。版权所有（C）2013，JPO＆INPIT

6. 发明专利

JP2003064120A Catalyst for olefin polymerization 审中-公开
标题翻译：烯烃聚合催化剂
公开(公告)号：JP2003064120A
公开(公告)日：2003-03-05
申请号：JP2001258055
申请日：2001-08-28
申请人： Toho Titanium Co Ltd , 東邦チタニウム株式会社
发明人： TASHINO KUNIHIKO , HOSAKA MOTOKI , SATO MAKI
IPC分类号： C08F4/654 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for olefin polymerization that can give olefin polymer in high yield, particularly can give propylene polymer in high yield, as the high stereoregularity is retained, with an extremely high response to hydrogen. SOLUTION: The olefin polymerization catalyst comprises the following components (A) through (c): (A) the solid catalyst component formed from (a) a magnesium compound, (b) titanium tetrachloride and (c) a phthalic diester derivative represented by general formula (1); (B) an organoaluminum compound; and (C) a halogen-containing organosilicon compound.
摘要翻译：要解决的问题：为了提供可以以高收率产生烯烃聚合物的烯烃聚合催化剂，特别是可以以高收率产生丙烯聚合物，因为高立体规整性被保留，对氢的响应非常高。解决方案：烯烃聚合催化剂包含以下组分（A）至（c）：（A）由（a）镁化合物，（b）四氯化钛和（c）由一般化合物表示的邻苯二甲酸二酯衍生物形成的固体催化剂组分公式1）; （B）有机铝化合物; 和（C）含卤素的有机硅化合物。

7. 发明专利

JP2011256120A Process for producing organoaminosilane compound 审中-公开
标题翻译：生产有机氨基硅烷化合物的方法
公开(公告)号：JP2011256120A
公开(公告)日：2011-12-22
申请号：JP2010130160
申请日：2010-06-07
申请人： Toho Titanium Co Ltd , 東邦チタニウム株式会社
发明人： HOSAKA MOTOKI , SATO MAKI
IPC分类号： C07F7/10
摘要： PROBLEM TO BE SOLVED: To provide a novel process for producing an organoaminosilane compound which can inexpensively and safely obtain an organoaminosilane compound having no Si-OR bond at all in a high yield.SOLUTION: The process for producing an organoaminosilane compound comprises reacting an organodialkoxysilane compound represented by formula (1): RRSiORORand an organoamine compound represented by formula (2): RRNH with an alkylmagnesium compound represented by formula (3): RMgX to obtain an organoaminosilane compound represented by formula (4): RRSi(NRR).
摘要翻译：要解决的问题：提供一种有机氨基硅烷化合物的新方法，其可以廉价且安全地获得高收率的完全没有Si-OR键的有机基氨基硅烷化合物。解决方案：用于制备有机基氨基硅烷化合物的方法包括使由式（1）表示的有机基二烷氧基硅烷化合物：R 1，R 2， SP＆lt; SP POS =“POST”> 3 或 4 和由式（2）表示的有机胺化合物：R 5与由式（3）表示的烷基镁化合物的反应，得到有机基氨基硅烷，得到有机基氨基硅烷（式中，R 1，R 2，由式（4）表示的化合物：R 1 Si（NR 5 < SP> R 6 ） 2 。版权所有（C）2012，JPO＆INPIT

8. 发明专利

JP2008280472A Catalyst for use in polymerization of olefins, and method for manufacturing olefinic polymer by using the catalyst 有权
标题翻译：用于烯烃聚合的催化剂和使用催化剂制备烯烃聚合物的方法
公开(公告)号：JP2008280472A
公开(公告)日：2008-11-20
申请号：JP2007127636
申请日：2007-05-14
申请人： Toho Titanium Co Ltd , 東邦チタニウム株式会社
发明人： YANO TAKEFUMI , HOSAKA MOTOKI , SATO MAKI , KIMURA KOHEI
IPC分类号： C08F4/654 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide such a catalyst for use in the polymerization of olefins as has the high catalytic activity, the capability of giving the highly stereoregular polymer in a better yield, and the excellent hydrogen-response, and to provide a method for manufacturing an olefinic polymer by using the catalyst. SOLUTION: The catalyst for use in the polymerization of olefins is formed from (A) a solid catalyst component containing Mg, Ti, a halogen, and an electron-donating compound, (B) an organoaluminum compound expressed by general formula: R 8 p AlQ 3-p and (C) an aminosilane compound expressed by formula: (R 1 R 2 N)(R 3 HN)SiR 4 R 5 . The method for manufacturing olefinic polymers is carried out in the presence of the catalyst concerned. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：为了提供具有高催化活性的用于烯烃聚合的这种催化剂，能够以更好的产率赋予高度立构规整性聚合物和优异的氢响应的能力，并提供使用该催化剂制造烯烃聚合物的方法。解决方案：用于烯烃聚合的催化剂由（A）含有Mg，Ti，卤素和给电子化合物的固体催化剂组分形成，（B）由通式表示的有机铝化合物：（C）由下式表示的氨基硅烷化合物：（R 1 SP＆lt; SP＆gt;＆lt; SP＆gt; 2 N）（R 3 HN）SIR 4 - [R 5 。制备烯烃聚合物的方法是在有关催化剂存在下进行的。版权所有（C）2009，JPO＆INPIT

9. 发明专利

JP2013067701A Solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and method for producing olefin polymer 审中-公开
标题翻译：用于烯烃聚合的固体催化剂组分，用于烯烃聚合的催化剂和用于生产烯烃聚合物的方法
公开(公告)号：JP2013067701A
公开(公告)日：2013-04-18
申请号：JP2011206057
申请日：2011-09-21
申请人： Toho Titanium Co Ltd , 東邦チタニウム株式会社
发明人： UOZUMI TOSHIYA , HOSAKA MOTOKI , SUGANO TOSHIHIKO , UZAWA TSUTOMU , MARUI SHINTA
IPC分类号： C08F4/654 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a solid catalyst component for olefin polymerization, having high stereoregularity and high activity, and to provide a catalyst for the olefin polymerization.SOLUTION: The solid catalyst component for the olefin polymerization includes titanium, magnesium, a halogen and a compound (A) represented by the formula: RnX=C(COOR)(COOR). The catalyst for the olefin polymerization is formed out of the solid catalyst component, an organoaluminum compound and an external electron-donating compound.

10. 发明专利

JP2014070109A Solid catalyst component for polymerizing olefins, catalyst for polymerizing olefins, and method of producing polymers of olefins 有权
标题翻译：用于聚合烯烃的固体催化剂组分，用于聚合烯烃的催化剂和生产烯烃聚合物的方法
公开(公告)号：JP2014070109A
公开(公告)日：2014-04-21
申请号：JP2012215726
申请日：2012-09-28
申请人： Toho Titanium Co Ltd , 東邦チタニウム株式会社
发明人： HOSAKA MOTOKI , UMEBAYASHI HIDETOSHI , SUGANO TOSHIHIKO
IPC分类号： C08F4/654 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a solid catalyst component for polymerizing olefins capable of polymerizing olefins under high polymerizing activities when used as a catalyst for polymerizing olefins and providing, in high yield, polymers of olefins in which contents of fine powders, coarse powders and volatile organic components (VOC) are reduced.SOLUTION: A solid catalyst component for polymerizing olefins is produced by: suspending a dialkoxymagnesium wet body containing dialkoxymagnesium (a) and 0.7 to 1.5 mass% of alcohol (b) into an inert organic solvent; and contacting an inner electron donor (c) with a titanium halide compound (d).
摘要翻译：要解决的问题：提供一种固体催化剂组分，用于在用作聚合烯烃的催化剂的高聚合活性下聚合烯烃的烯烃，并以高产率提供烯烃的聚合物，其中细粉末，粗粉和挥发性有机成分（VOC）被还原。溶剂：用于聚合烯烃的固体催化剂组分通过以下方法制备：将含有二烷氧基镁（a）的二烷氧基镁湿体和0.7至1.5质量％的醇（b）悬浮于惰性有机溶剂中; 并使内电子给体（c）与卤化钛化合物（d）接触。

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