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    • 2. 发明专利
    • Method for producing titanium tetrachloride
    • 生产钛酸四钠的方法
    • JP2014181153A
    • 2014-09-29
    • JP2013056602
    • 2013-03-19
    • Toho Titanium Co Ltd東邦チタニウム株式会社
    • HORIKAWA MATSUHIDETANI SEIICHIROHORIGUCHI RYOTAFUKAZAWA HIDEKAZU
    • C01G23/02C01B9/02
    • PROBLEM TO BE SOLVED: To provide a technology for separating and recovering valuable substances from impurity metal chlorides by-produced in a production process of titanium tetrachloride using a titanium ore as a raw material, and reducing the absolute amount of waste materials.SOLUTION: A method for producing titanium tetrachloride includes: a titanium tetrachloride production step for producing titanium tetrachloride by reacting a titanium ore containing a titanium component and impurity metal components with coke by using chlorine; a titanium tetrachloride recovery step for recovering titanium chloride formed from the titanium component in the titanium tetrachloride production step; and a recovery step for recovering a chlorine component in impurity metal chlorides by-produced from the impurity metal components in the titanium tetrachloride production step in the form of hydrochloric acid and recovering unreacted titanium ore and coke.
    • 要解决的问题:提供一种在以钛矿为原料的四氯化钛生产工艺中副产的杂质金属氯化物中分离和回收有价值物质的技术,并减少废料的绝对量。解决方案:A 制造四氯化钛的方法包括:通过使用氯使含有钛成分的钛矿和杂质金属成分与焦炭反应来生产四氯化钛的四氯化钛的制造工序; 在四氯化钛制造工序中回收由钛成分形成的氯化钛的四氯化钛回收工序; 以及回收步骤,用于从盐酸形式的四氯化钛生产步骤中的杂质金属组分中回收氯化杂质中的氯成分并回收未反应的钛矿石和焦炭。
    • 3. 发明专利
    • Method for producing olefin polymerization solid catalyst component, olefin polymerization catalyst, and method for producing olefin polymer
    • 生产烯烃聚合固体催化剂组分,烯烃聚合催化剂的方法和生产烯烃聚合物的方法
    • JP2014162906A
    • 2014-09-08
    • JP2013037832
    • 2013-02-27
    • Toho Titanium Co Ltd東邦チタニウム株式会社
    • HOSAKA MOTOKINAKAMURA NORIAKIYAMADA SHINGOSUGANO TOSHIHIKO
    • C08F4/654C08F10/00
    • PROBLEM TO BE SOLVED: To provide a method for producing a novel olefin polymerization solid catalyst component that is excellent in polymerization activation of olefin and in to-hydrogen activation during polymerization, as well as that is capable of producing an olefin polymer having a high MFR and stereoregularity and having an excellent rigidity.SOLUTION: A method for producing an olefin polymerization solid catalyst component includes: applying a first step of contacting and reacting magnesium compound, titanium halide compound of tetravalence, and one or more kinds of a first inner electron donative compound in which aromatic dicarboxylic acid diesters are excluded, and followed by washing; applying a second step of contacting and reacting the product obtained, with one or more kinds of a second inner electron donative compound, and followed by washing; and applying a third step of contacting and reacting titanium halide compound of tetravalence and one or more kinds of a third inner electron donative compound.
    • 要解决的问题:提供一种在聚合过程中烯烃的聚合活化和氢氢活化优异的烯烃聚合固体催化剂组分的制备方法,以及能够生产具有高MFR的烯烃聚合物 和立构规整性并且具有优异的刚性。溶解性:一种烯烃聚合固体催化剂组分的制备方法,包括:施加使镁化合物,四价钛卤化物与一种或多种第一内电子给体接触和反应的第一步骤 除去芳族二羧酸二酯的化合物,然后洗涤; 将所得产物与一种或多种第二内给电子化合物接触和反应,然后进行洗涤; 并施加与四价钛卤化物化合物和一种或多种第三内给电子化合物接触和反应的第三步骤。
    • 4. 发明专利
    • Method for purifying polycrystalline silicon obtained by the zinc reduction method
    • 通过ZINC还原法获得多晶硅的方法
    • JP2014162687A
    • 2014-09-08
    • JP2013035750
    • 2013-02-26
    • Jnc CorpJnc株式会社Jx Nippon Mining & Metals CorpJx日鉱日石金属株式会社Toho Titanium Co Ltd東邦チタニウム株式会社
    • TANAKA TORUSATO KENJIKAWAI TAKAHIRO
    • C01B33/037
    • PROBLEM TO BE SOLVED: To provide a method for purifying polycrystalline silicon capable of effectively abating or removing, from a polycrystalline silicon obtained by the zinc reduction method, various impurities such as granular quartz glass, boron-based impurities, metal impurities such as zinc, etc.SOLUTION: The method of the present invention for purifying polycrystalline silicon comprises: (A) a step of washing, with hydrochloric acid, an acicular or dendritic polycrystalline silicon manufactured by the zinc reduction method; (B) a step of washing, with water, the polycrystalline silicon washed at the step (A); (C) a step of drying the polycrystalline silicon washed at the step (B); (D) a step of washing, with hydrofluoric acid, the polycrystalline silicon dried at the step (C); (E) a step of washing, with water, the polycrystalline silicon washed at the step (D); and (F) a step of drying the polycrystalline silicon washed at the step (E).
    • 要解决的问题:为了提供一种能够有效地从通过锌还原法获得的多晶硅中去除或除去多晶硅的多晶硅的方法,可以使用诸如颗粒状石英玻璃,硼基杂质,金属杂质如锌的各种杂质, 本发明的多晶硅纯化方法包括:(A)用盐酸洗涤通过锌还原法制造的针状或树状多晶硅的步骤; (B)用水洗涤步骤(A)洗涤多晶硅的步骤; (C)在步骤(B)中干燥洗涤的多晶硅的步骤; (D)用氢氟酸洗涤在步骤(C)干燥的多晶硅的步骤; (E)用水洗涤在步骤(D)洗涤的多晶硅的步骤; 和(F)在步骤(E)中干燥洗涤的多晶硅的步骤。
    • 5. 发明专利
    • All-solid-state lithium battery
    • 全固态锂电池
    • JP2014120264A
    • 2014-06-30
    • JP2012273331
    • 2012-12-14
    • Toho Titanium Co Ltd東邦チタニウム株式会社
    • NAKAJIMA MAMORUSAKAI HIDEKI
    • H01M10/0562H01M4/48H01M4/62H01M10/052
    • Y02E60/122
    • PROBLEM TO BE SOLVED: To provide an all-solid-state lithium battery which is stable in the water and remarkably improved in discharge capacity ratio.SOLUTION: An all-solid-state lithium battery includes: a positive electrode active material layer; a negative electrode active material layer comprising a negative electrode active material having a potential of 1.6-3.0 V vs.Li/Li; and a solid electrolyte layer which is provided between the positive electrode active material layer and the negative electrode active material layer and comprises a lithium lanthanum titanium oxide represented by one of the following general formulae. General formula: (1-a)LaLiTiO-aSrTiO, general formula: (1-a)LaLiTiO-aLaKTiO, general formula: LaLiTiMO, and general formula: SrLaLiTiTaO(where, 0.55≤x≤0.59 and 0≤a≤0.2 are satisfied, and M represents at least one selected from among Al, Fe and Ga)
    • 要解决的问题:提供在水中稳定的全固态锂电池,并且显着提高放电容量比。解决方案:全固态锂电池包括:正极活性材料层; 负极活性物质层,其包含电位为1.6〜3.0V的LiBiLiLLL的负极活性物质; 以及固体电解质层,其设置在所述正极活性物质层和所述负极活性物质层之间,并且包含由以下通式之一表示的氧化钛镧钛氧化物。 通式:(1-a)LaLiTiO-aSrTiO,通式:(1-a)LaLiTiO-aLaKTiO,通式为LaLiTiMO,通式为SrLaLiTiTaO(其中,满足0.55≤x≤0.59且0≤a≤0.2) ,M表示选自Al,Fe和Ga中的至少一种)
    • 8. 发明专利
    • Production method of solid catalyst component for olefin polymerization, catalyst for olefin polymerization, and production method of olefin polymerization body
    • 用于烯烃聚合的固体催化剂组分的生产方法,烯烃聚合的催化剂和烯烃聚合体的生产方法
    • JP2014037521A
    • 2014-02-27
    • JP2013037830
    • 2013-02-27
    • Toho Titanium Co Ltd東邦チタニウム株式会社
    • HOSAKA MOTOKINAKAMURA NORIAKIYAMADA SHINGOSUGANO TOSHIHIKO
    • C08F4/658C08F10/00
    • PROBLEM TO BE SOLVED: To provide a production method of a novel solid catalyst component for olefin polymerization that can produce an olefin polymerization body in which polymerization activity of olefin and activity to hydrogen at polymerization are excellent, and an MFR and stereoregularity are high, and excellent rigidity is possessed.SOLUTION: A production method of a solid catalyst component for olefin polymerization performs: a first process in which a magnesium compound, a tetravalent titanium halide compound, and at least one of a first inner electron donative compound are contacted and reacted to perform by cleaning; a second process in which to the obtained product material, a tetravalent titanium halide compound and at least one of a second inner electron donative compound are contacted and reacted to perform cleaning; and a third process in which after that, at least one of a third inner electron donative compound is contacted and reacted.
    • 要解决的问题:提供一种用于烯烃聚合的新型固体催化剂组分的制备方法,其可以生产烯烃聚合体,其中烯烃的聚合活性和聚合时的氢活性优异,并且MFR和立构规整性高,以及 具有优异的刚性。解决方案:用于烯烃聚合的固体催化剂组分的制备方法:其中镁化合物,四价卤化钛化合物和至少一种第一内给电子化合物接触并反应的第一种方法 通过清洁执行; 第二种方法是将获得的产物材料中的四价卤化钛化合物和第二内给电子化合物中的至少一种接触并反应进行清洗; 以及第三种方法,其中第三种内给电子化合物中的至少一种接触并反应。