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    • 1. 发明专利
    • Sealing material composition containing polymer with epoxy group
    • 含聚合物与环氧聚合物的密封材料组合物
    • JP2005105041A
    • 2005-04-21
    • JP2003337324
    • 2003-09-29
    • Toagosei Co Ltd東亞合成株式会社
    • INUKAI HIROSHIMOCHIZUKI KATSUNOBUYONEDA KOTAROIIDA AKIHITOKAWAI MICHIHIRO
    • C09K3/10
    • PROBLEM TO BE SOLVED: To provide a sealing material composition which has the high weatherability and the excellent adhesion to a base material.
      SOLUTION: The sealing material composition contains 1-100 parts by mass of an epoxy group-containing (meth)acrylate copolymer having a glass transition temperature of 10 °C or lower and a number-average molecular weight of 500-3,000 and 100 parts by mass of a base polymer. Preferably, the (meth)acrylate copolymer contains as the constitutional monomer unit a (meth)acrylate unit having the numbers of such carbons of 1-20 as is contained in the residue derived from an alcohol forming an ester and a radical-polymerizable monomer unit with an epoxy group.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种具有高耐候性和对基材的优异粘附性的密封材料组合物。 解决方案:密封材料组合物含有玻璃化转变温度为10℃以下,数均分子量为500〜300的含有环氧基的(甲基)丙烯酸酯共聚物1-100质量份, 100质量份基础聚合物。 优选地,(甲基)丙烯酸酯共聚物作为构成单体单元,含有由形成酯的醇的残基和自由基聚合性单体单元中含有的碳原子数为1-20的(甲基)丙烯酸酯单元 与环氧基团。 版权所有(C)2005,JPO&NCIPI
    • 2. 发明专利
    • Prediction method of deterioration of paint film
    • 预测涂膜的预测方法
    • JP2005017132A
    • 2005-01-20
    • JP2003183126
    • 2003-06-26
    • Nagoya CityToagosei Co Ltd名古屋市東亞合成株式会社
    • KIMATA YOSHINORIIIDA AKIHITOIIDA HIROSHI
    • G01N17/00G01Q30/04G01Q60/24G01Q60/32G01Q90/00G01N13/16
    • PROBLEM TO BE SOLVED: To provide a method for predicting the time of deterioration of a paint film occurring after a long-term weathering test from the result of a short-time weathering test.
      SOLUTION: This prediction method of deterioration of the paint film is characterized as follows: the surface shape of each paint film is measured by a scanning probe microscope by using a plurality of paint films having different deterioration times in the weathering test, to thereby acquire the average surface roughness on the surface; a mathematical expression for showing the relation between the average surface roughness and the deterioration time is acquired from numerical value information of the average surface roughness acquired on each paint film and the deterioration time of the paint film; and the average surface roughness is substituted for the expression to thereby determine the time corresponding thereto. The prediction method of deterioration of the paint film is also characterized by using following expression (1) or the expression (2) as the mathematical expression. The expression (1): R=αt+β, the expression (2): R=βe
      αt , wherein R is the average surface roughness, t is the deterioration time; and α and β are regression coefficients in each expression.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种用于预测长期风化试验后出现的漆膜的劣化时间的方法,其从短时耐候试验结果来看。 < P>解决方案:这种漆膜劣化的预测方法的特征如下:通过扫描探针显微镜,通过使用在耐候性试验中具有不同劣化时间的多个漆膜测量各涂膜的表面形状, 从而获得表面上的平均表面粗糙度; 从各涂膜获得的平均表面粗糙度的数值信息和涂膜的劣化时间的数值信息求出表示平均表面粗糙度与劣化时间的关系的数学表达式。 并用平均表面粗糙度代替表达式,从而确定与之对应的时间。 涂膜的劣化的预测方法的特征还在于使用下面的表达式(1)或表达式(2)作为数学表达式。 表达式(1):R =αt+β,表达式(2):R =βeαt其中R是平均表面粗糙度,t是劣化时间; α和β是每个表达式的回归系数。 版权所有(C)2005,JPO&NCIPI
    • 3. 发明专利
    • Sealing material composition
    • 密封材料组成
    • JP2005179560A
    • 2005-07-07
    • JP2003424444
    • 2003-12-22
    • Toagosei Co Ltd東亞合成株式会社
    • YONEDA KOTAROINUKAI HIROSHIIIDA AKIHITOMOCHIZUKI KATSUNOBU
    • C09K3/10C08F2/44C08F220/12C08F283/06
    • PROBLEM TO BE SOLVED: To provide a silyl-functional sealing material composition which gives a cured product extremely excellent in weather resistance, alkali resistance and stain resistance.
      SOLUTION: The sealing material composition comprises a vinyl polymer (A) having a glass transition temperature of -80 to 10°C, a number-average molecular weight of 500-3,000, 1-50 mass% of alkyl methacrylate units as constituent monomer units and 0.05-2 hydrolyzable silyl groups on the average per molecule, and an oxyalkylene polymer (B) bearing a hydrolyzable silyl group, where the ratio of the vinyl polymer (A) is 1-150 pts.mass based on 100 pts.mass of the oxyalkylene polymer (B).
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供赋予固化产物耐候性,耐碱性和耐污性极好的甲硅烷基官能的密封材料组合物。 解决方案:密封材料组合物包括玻璃化转变温度为-80至10℃,数均分子量为500-3,000的乙烯基聚合物(A),1-50质量%的甲基丙烯酸烷基酯单元为 构成单体单元和每个分子平均为0.05-2个水解甲硅烷基,以及含有水解性甲硅烷基的氧化烯聚合物(B),其中乙烯基聚合物(A)的比例为1-150pts.mass,基于100个 氧化烯聚合物(B)的质量。 版权所有(C)2005,JPO&NCIPI
    • 4. 发明专利
    • Sealant composition
    • 密封组合物
    • JP2005097455A
    • 2005-04-14
    • JP2003334635
    • 2003-09-26
    • Toagosei Co Ltd東亞合成株式会社
    • INUKAI HIROSHIYONEDA KOTAROMOCHIZUKI KATSUNOBUIIDA AKIHITO
    • C09K3/10C08L33/06C08L71/00
    • PROBLEM TO BE SOLVED: To provide a sealant composition having high weatherability and extensibility, expressing good contamination resistance and having optimum workability. SOLUTION: The sealant composition comprises (A) a (meth)acrylic ester copolymer obtained by continuous polymerization of a radical-polymerizable monomer at 150-350°C, having a weight-average molecular weight of 8,000-30,000 and a glass transition temperature of -70 to -10°C and having no hydrolyzable silyl group, (B) a polyoxyalkylene-based compound having a weight-average molecular weight of 1,000-100,000 and hydrolyzable silyl groups and (C) a plasticizer. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供具有高耐候性和延展性的密封剂组合物,表现出良好的耐污染性并具有最佳的可加工性。 解决方案:密封剂组合物包含(A)通过可自由基聚合的单体在150-350℃下连续聚合得到的(甲基)丙烯酸酯共聚物,其重均分子量为8,000-30,000,玻璃 转化温度为-70〜-10℃,不具有水解甲硅烷基,(B)重均分子量为1,000〜10000000的聚氧化烯系化合物和可水解甲硅烷基,(C)增塑剂。 版权所有(C)2005,JPO&NCIPI
    • 8. 发明专利
    • Curable composition
    • 可固化组合物
    • JP2006022169A
    • 2006-01-26
    • JP2004199981
    • 2004-07-07
    • Toagosei Co Ltd東亞合成株式会社
    • INUKAI HIROSHIYONEDA KOTAROIIDA AKIHITOMOCHIZUKI KATSUNOBU
    • C08L101/10C08F20/18C08L33/08
    • PROBLEM TO BE SOLVED: To provide a moisture-curable composition excellent in deep part curability and weather resistance.
      SOLUTION: The curable composition comprises 1-200 pts. mass vinyl polymer (A) and 100 pts. mass polymer (B) other than the vinyl polymer (A), wherein the polymer (A) has acrylic methyl unit or acrylic ethyl unit as the constituent monomer unit, ≤10°C glass transition temperature, 500-20,000 weight-average molecular weight and the polymer (B) has hydrolyzable silyl. The particularly suitable vinyl polymer (A) has 5-90 mass % acrylic methyl unit or acrylic ethyl unit based on the total structural monomer unit.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供深部固化性和耐候性优异的湿气固化性组合物。

      解决方案:可固化组合物包含1-200个点。 质量乙烯基聚合物(A)和100份。 除了乙烯基聚合物(A)以外的聚合物(B),其中聚合物(A)具有丙烯酸甲基单元或丙烯酸乙基单元作为构成单体单元,≤10℃玻璃化转变温度,500-20,000重均分子量 并且聚合物(B)具有可水解的甲硅烷基。 特别合适的乙烯基聚合物(A)基于总结构单体单元具有5-90质量%的丙烯酸甲基单元或丙烯酸乙基单元。 版权所有(C)2006,JPO&NCIPI

    • 10. 发明专利
    • Sealing material composition
    • 密封材料组成
    • JP2005179559A
    • 2005-07-07
    • JP2003424442
    • 2003-12-22
    • Toagosei Co Ltd東亞合成株式会社
    • YONEDA KOTAROINUKAI HIROSHIIIDA AKIHITOMOCHIZUKI KATSUNOBU
    • C09K3/10
    • PROBLEM TO BE SOLVED: To provide a silyl-functional sealing material composition which gives a cured product excellent in the balance among weather resistance, alkali resistance and stain resistance.
      SOLUTION: The sealing material composition comprises a vinyl polymer (A) having a glass transition temperature of -80 to 10°C and a number-average molecular weight of 500-3,000 and bearing 0.05-2 hydrolyzable silyl groups on the average per molecule, and an oxyalkylene polymer (B) bearing a hydrolyzable silyl group, where the ratio of the vinyl polymer (A) is more than 100 pts.mass but not more than 150 pts.mass based on 100 pts.mass of the oxyalkylene polymer (B).
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种赋予耐候性,耐碱性和耐污性之间的平衡优异的固化产物的甲硅烷基官能的密封材料组合物。 解决方案:密封材料组合物包含玻璃化转变温度为-80至10℃,数均分子量为500-3,000的乙烯基聚合物(A),平均含有0.05-2个可水解的甲硅烷基 和分子中含有水解性甲硅烷基的氧化烯聚合物(B),其中乙烯基聚合物(A)的比例大于100pts.mass但不大于150pts.mass,基于100个聚亚烷基 聚合物(B)。 版权所有(C)2005,JPO&NCIPI