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    • 2. 发明专利
    • Aqueous piperazine-n, n '-biscarbodithioate solution, and method of producing the same
    • 水性哌嗪-N,N' - 双硬脂酸溶液及其制造方法
    • JP2012214429A
    • 2012-11-08
    • JP2011180509
    • 2011-08-22
    • Tosoh Corp東ソー株式会社
    • AYAMA YOSHINORINAGAI YASUYUKI
    • C07D295/20
    • C07D295/20
    • PROBLEM TO BE SOLVED: To solve a problem wherein distill-away treatment or the like by an inert gas is required to enhance the ratio of a piperazine-N, N '-biscarbodithioate of high heavy metal treatment ability, when producing the piperazine carbodithioate useful as a heavy metal treating agent, and wherein an industrial production method therefor is required.SOLUTION: The piperazine-N, N '-biscarbodithioate is produced with addition of a hydrophobic solvent in a method of reacting piperazine, carbon disulfide of reaction equivalent or more with respect to the piperazine, and an alkali metal hydroxide, in an aqueous solution. The method can produce the piperazine-N, N '-biscarbodithioate not containing piperazine-N-biscarbodithioate, without requiring the distill-away treatment or the like by the inert gas.
    • 解决的问题为了解决需要通过惰性气体进行蒸馏处理等以提高高重金属处理能力的哌嗪-N,N'-二硫代二硫酸酯的比例的问题,当生产 可用作重金属处理剂的哌嗪碳二硫酸酯,并且其中需要其工业生产方法。 解决方案:哌嗪-N,N'-二硫代二硫酸盐是通过在哌嗪,相对于哌嗪等于或更多的反应的二硫化碳和碱金属氢氧化物的反应中加入疏水性溶剂来制备的, 水溶液。 该方法可以生产不含哌嗪-N-二碳化二硫酸酯的哌嗪-N,N'-二硫代二硫酸酯,而不需要通过惰性气体进行蒸馏处理等。 版权所有(C)2013,JPO&INPIT
    • 3. 发明专利
    • Method for detoxifying object contaminated with organic halogen compound
    • 用有机卤素化合物污染物体的方法
    • JP2006022166A
    • 2006-01-26
    • JP2004199807
    • 2004-07-06
    • Tosoh Corp東ソー株式会社
    • SHIMIZU TOSHIKINAGAI YASUYUKI
    • C09K3/00A62D3/37A62D101/22B09C1/02B09C1/08C02F1/70C02F11/00C22C37/00C22C38/00C22C38/10
    • PROBLEM TO BE SOLVED: To provide a detoxifying agent and a detoxifying method using the same, decomposing organic halide contained in the soil which contains sulfides, oxides, hydroxides and phosphorus compounds, and industrial waste, polluted sludge and sludge, in a short time to a level lower than the environmental standards without producing harmful byproducts.
      SOLUTION: The invention relates to the detoxifying process using a detoxifying agent comprising Fe alloy and Fe salt and/or Al salt. The preferable Fe alloy comprises Ni, C and Co, and especially an alloy or partial alloy obtained by mechanical alloying is preferable. The detoxifying agent can be applied to a continuous digging treatment, in-site treatment for making the object to harmless to an underground deep part, and especially the agent is preferably applied to the liquefied object to be treated.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了提供一种使用其的解毒剂和解毒方法,将含有硫化物,氧化物,氢氧化物和磷化合物的土壤中的有机卤化物和工业废物,污染的污泥和污泥分解成 短时间达到低于环境标准的水平,而不产生有害副产品。 解决方案:本发明涉及使用包含Fe合金和Fe盐和/或Al盐的解毒剂的解毒方法。 优选的Fe合金包含Ni,C和Co,特别优选通过机械合金化获得的合金或部分合金。 解毒剂可以应用于连续的挖掘处理,使得物体对地下深部无害化的现场处理,特别是该试剂适用于待处理的液化物。 版权所有(C)2006,JPO&NCIPI
    • 4. 发明专利
    • Treatment method for making object to be treated contaminated by organic halogen compound harmless
    • 用于制造被有机卤化物化合物污染的物体的处理方法
    • JP2005034696A
    • 2005-02-10
    • JP2003197764
    • 2003-07-16
    • Tosoh Corp東ソー株式会社
    • SHIMIZU TOSHIKINAGAI YASUYUKI
    • A62D3/37A62D3/38A62D101/22B09C1/02B09C1/08B22F1/00C02F11/06A62D3/00
    • PROBLEM TO BE SOLVED: To provide a treatment method by which an organic compound in soil, industrial waste and sludge is decomposed to environmental standards or lower in a short period of time, and the object to be treated can be made harmless without producing harmful by-products. SOLUTION: It has been found that, in the method for making the object to be treated contaminated by an organic halogen compound harmless, the object to be treated is subjected to liquefaction mixing, so that legal restriction value can be cleared in a short period of time without producing objects controlled by environmental standards as decomposition by-products. Further, by the treatment, in-site treatment of making the object to be treated harmless to an under ground deep part is possible without performing continuous treatment and an excavation step. On the mixing, it is desirable that the pH of the liquefaction mixture is COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种土壤,工业废物和污泥中的有机化合物在短时间内分解为环境标准或降低的处理方法,并且待处理对象可以在没有 生产有害副产品。 解决方案:已经发现,在使有待处理的物体被污染的方法无害化的方法中,要处理的物体进行液化混合,从而可以在 短时间内不产生受环境标准控制的物质作为分解副产物。 此外,通过处理,可以在不进行连续处理和挖掘步骤的情况下进行使待处理物体对地下深部无害化的现场处理。 在混合时,液化混合物的pH值优选为<7,或者将金属处理剂或金属处理剂和氧化剂加入待处理物体中,然后将被处理物 进行液化混合。 版权所有(C)2005,JPO&NCIPI
    • 6. 发明专利
    • PRODUCTION OF N-METHYLIMIDAZOLES
    • JPH09169737A
    • 1997-06-30
    • JP33313995
    • 1995-12-21
    • TOSOH CORP
    • KISO HIROYUKINAGAI YASUYUKIHARA YASUSHI
    • C07D233/58C07D233/68
    • PROBLEM TO BE SOLVED: To produce N-methylimidazoles in ultrahigh yield under mild conditions without using a catalyst and without forming quaternary imidazolium compounds as a by-product by reacting imidazoles with dimethyl carbonate under specific temperature conditions. SOLUTION: Imidazoles [preferably a compound of the formula (R to R are each H, a halogen, etc.) such as imidazole] are reacted with dimethyl carbonate at 120-200 deg.C. The reaction is preferably carried out in the liquid phase by using the dimethyl carbonate in a molar amount of 0.7-2 times expressed in terms of molar ratio based on the imidazoles and replacing a reactor with an inert gas such as nitrogen gas. The reactional pressure is preferably atmospheric one. Furthermore, the reaction is preferably conducted while dropping the dimethyl carbonate at a rate corresponding to the amount consumed by reaction so as not to provide an extremely large excessive amount thereof. A solvent having the boiling point of the compound of the imidazoles or higher than the reactional temperature is preferably used in the case of using the solvent.
    • 7. 发明专利
    • Method for producing solid amine carbodithioate salt and method for producing aqueous solution of amine carbodithioate salt
    • 生产固体胺碳酸盐的方法和生产胺水溶液的水溶液的方法
    • JP2012158575A
    • 2012-08-23
    • JP2011021308
    • 2011-02-03
    • Tosoh Corp東ソー株式会社
    • AYAMA YOSHINORINAGAI YASUYUKI
    • C07C333/16C07D295/10
    • PROBLEM TO BE SOLVED: To solve such a problem that the conventional method for obtaining a solid amine carbodithioate salt is not efficient, and in particular, when an amine carbodithioate salt has high solubility, it has been difficult to efficiently obtain the solid amine carbodithioate salt.SOLUTION: In a method for producing an amine carbodithioate salt by mixing an amine, carbon disulfide, and a metal hydroxide in an aqueous solution and making them react with one another, the solid amine carbodithioate salt is efficiently obtained by making 1.3 times equivalent or more of the metal hydroxide with respect to the amino group of the amine to react with carbon disulfide coexist therewith. Moreover, an aqueous solution of the amine carbodithioate salt with high concentration is simultaneously produced by further mixing the amine, carbon disulfide, and the metal hydroxide with the aqueous solution of the amine carbodithioate salt from which the solid amine carbodithioate salt has been separated and making them react with one another.
    • 要解决的问题为了解决用于获得固体胺碳二硫酸盐的常规方法不是有效的问题,特别是当胺二硫代酸盐具有高溶解度时,难以有效地获得固体 胺碳二硫酸盐。 解决方案:通过在水溶液中混合胺,二硫化碳和金属氢氧化物并使它们彼此反应来制备胺二硫酸盐的方法,通过制备1.3倍的固体胺碳二硫酸盐来有效地获得 与胺的氨基相当或多于一个与二硫化碳反应的金属氢氧化物与其共存。 此外,通过将胺,二硫化碳和金属氢氧化物与已经分离出固体胺二硫代酸盐的胺碳二亚硫酸盐的水溶液进一步混合,同时制备高浓度的胺碳二硫酸盐的水溶液, 他们相互反应。 版权所有(C)2012,JPO&INPIT