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1. 发明专利

JPH0376709A CATALYST COMPONENT FOR ALPHA-OLEFIN POLYMERIZATION 失效
公开(公告)号：JPH0376709A
公开(公告)日：1991-04-02
申请号：JP21144289
申请日：1989-08-18
申请人： TONEN CORP
发明人： FURUHASHI HIROYUKI , USUI MIYUKI , KOYAMA NAOMI , OKANO TOMOKO , NAKANO AKIRA , UEKI SATOSHI
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00
摘要： PURPOSE:To increase the strengths of catalyst particles by bringing a solid component mainly comprising a metal oxide, Mg, Ti, a halogen, and an electron- donating compd. into contact with an olefin in the presence of a trialkylaluminum and a specific dimethoxysilane compd. CONSTITUTION:An oxide of a metal of the group II-IV of the periodic table, an Mg compd. (e.g. MgCl2), a di- to tetravalent Ti compd. (e.g. TiCl4), and an electron-donating compd. (e.g. acetyl chloride) are brought into contact with each other to give a solid component mainly comprising a metal oxide, Mg, Ti, a halogen, and an electron-donating compd., which is then brought into contact with an olefin at 100 deg.C or lower in the presence of a trialkylaluminum (e.g. trimethylalminum) and a dimethoxysilane compd. of the formula (wherein R and R are each a 1-10C aliph. hydrocarbon group) having a quantum- chemically calculated volume of 170-500Angstrom and an electron density of an oxygen atom in the methoxy group of 0.690-0.800A.U. or having the volume of 200-500Angstrom and the electron density of 0.685-0.800A.U.

2. 发明专利

JPH03174411A PRODUCTION OF POLY-ALPHA-OLEFIN 失效
公开(公告)号：JPH03174411A
公开(公告)日：1991-07-29
申请号：JP7182890
申请日：1990-03-23
申请人： TONEN CORP
发明人： OKANO TOMOKO , SENDA KANAKO , AIBA KAZUKIYO , FURUHASHI HIROYUKI , MURATA MASAHIDE , UEKI SATOSHI
IPC分类号： C08F10/00 , C08F4/60 , C08F4/654
摘要： PURPOSE:To obtain the title compound of high melt flow in high yields by polymerizing an alpha-olefin in the presence of a specified catalyst. CONSTITUTION:An alpha-olefin (e.g. propylene) is polymerized in the presence of a catalyst comprising a solid catalyst component essentially consisting of Mg, Ti, halogen and an electron-donating compound (e.g. di-n-butyl phthalate), an organo-metallic compound (e.g. triethylaluminum) and an ethoxylated siline compound represented by the formula: RnSi(OC2H5)4-n (wherein R is a 4-10C aliphatic hydrocarbon group; and n is 1 or 2) and having a volume of 240-500Angstrom as determined by a calculation based on quantum chemistry and an electron density of the O atoms of the ethoxy groups of 0.680-0.800 atomic unit as determined by the same calculation (e.g. t-amyltriethoxysilane).

3. 发明专利

JPH0333106A CATALYST FOR POLYMERIZATION OF ALPHA-OLEFIN 失效
公开(公告)号：JPH0333106A
公开(公告)日：1991-02-13
申请号：JP16712289
申请日：1989-06-30
申请人： TONEN CORP
发明人： OKANO TOMOKO , SENDA KANAKO , FURUHASHI HIROYUKI , UEKI SATOSHI
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00
摘要： PURPOSE:To obtain the title catalyst which can show both excellent polymerization activity and stereoregular polymerization activity without forming any noxious substance by mixing a specified solid catalyst component with an organometallic compound and a plurality of specified aromatic group-free organosilicon compounds. CONSTITUTION:A catalyst for the polymerization of an alpha-olefin comprising (A) a solid catalyst component essentially consisting of a metal oxide, Mg, TI, a halogen and an electron-donating compound [e.g. one obtained by bringing a reaction product of a metal oxide (e.g. SiO2) with a magnesium dialkoxide into contact with an electron- donating compound (e.g. carboxylic acid) and TiCl4], an organometallic compound (B) (e.g. organoaluminum compound), a dimethoxylated silane compound (C) represented by the formula (wherein R and R may be the same or different from each other and are each a 1-10C aliphatic hydrocarbon group) and having a volume of 150-500Angstrom as determined based on quantum chemical calculation and trimethoxyhydrocarbylsilane and/or tetramethoxysilane (D). According to the above, the title catalyst which can show both polymerization activity at least as high as that of a catalyst containing a silane compound having an aromatic group and stereoregular polymerization activity without forming any noxious substance which is problematic when a silane compound having an aromatic group is used can be obtained.

4. 发明专利

JPH0333104A CATALYST FOR POLYMERIZATION OF ALPHA-OLEFIN 失效
公开(公告)号：JPH0333104A
公开(公告)日：1991-02-13
申请号：JP16712089
申请日：1989-06-30
申请人： TONEN CORP
发明人： OKANO TOMOKO , SENDA KANAKO , FURUHASHI HIROYUKI , UEKI SATOSHI , IMAI MASABUMI , USUI MIYUKI
IPC分类号： C08F4/658 , C08F4/60 , C08F4/655 , C08F10/00
摘要： PURPOSE:To produce a highly stereoregular poly-alpha-olefin with an activity at least as high as that when an organosilicon compound having an aromatic group is used by using a catalyst consisting of activated titanium trichloride, an organometallic compound and a specified dimethoxylated silane compound. CONSTITUTION:A catalyst for the polymerization of an alpha-olefin comprising (A) activated titanium trichloride, (B) an organometallic compound, and (C) a dimethoxylated silane compound represented by the general formula: R R (OCH3)2 [wherein R and R2 may be the same or different from each other and are each a 1-10C aliphatic hydrocarbon group] and having a volume of 170-500Angstrom as determined based on quantum chemical calculation and an electron density of the oxygen atom of the methoxy group of 0.685-0.800 A.U. (atomic unit) as determined in the same way or having the above volume of 200-500Angstrom and the above electron density of 0.680-0.800 A.U. When the above silane compound C is used, any noxious substance which is problematic when a silane compound having an aromatic group is used does not form.

5. 发明专利

JPH0333103A CATALYST FOR POLYMERIZATION OF ALPHA-OLEFIN 失效
公开(公告)号：JPH0333103A
公开(公告)日：1991-02-13
申请号：JP16711989
申请日：1989-06-30
申请人： TONEN CORP
发明人： OKANO TOMOKO , SENDA KANAKO , FURUHASHI HIROYUKI , UEKI SATOSHI , NAKANO AKIRA
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00
摘要： PURPOSE:To produce a highly stereoregular poly-alpha-olefin with an activity at least as high as that attained when an organosilane compound having an aromatic group is used by using a catalyst consisting of a titanium-containing solid catalyst component, an organometallic compound and a specified dimethoxylated silane compound. CONSTITUTION:A catalyst for the polymerization of an alpha-olefin comprising (A) a solid catalyst component essentially consisting of a metal oxide, magnesium, titanium, a halogen and an electron-donating compound, (B) an organometallic compound, and (C) a dimethoxylated silane compound represented by the general formula: R R Si(OCH3)2 [wherein R and R may be the same or different from each other and are each a 1-10C aliphatic hydrocarbon group] and having a volume of 170-500Angstrom as determined based on quantum chemical calculation and an electron density of the oxygen atom of the methoxy group of 0.690-0.800 A.U. (atomic unit) as determined in the same way or having the above volume of 200-500Angstrom and the above electron density of 0.685-0.800 A.U. This silane compound does not form any noxious substance which is problematic when a silane compound having an aromatic group is used.

6. 发明专利

JPH03174412A PRODUCTION OF POLY-ALPHA-OLEFIN 失效
公开(公告)号：JPH03174412A
公开(公告)日：1991-07-29
申请号：JP7182990
申请日：1990-03-23
申请人： TONEN CORP
发明人： OKANO TOMOKO , SENDA KANAKO , FURUHASHI HIROYUKI , NAKANO AKIRA , UEKI SATOSHI
IPC分类号： C08F10/00 , C08F4/60 , C08F4/654 , C08F4/658
摘要： PURPOSE:To obtain the title compound of high melt flow in high yields by polymerizing an alpha-olefin in the presence of a specified catalyst. CONSTITUTION:An alpha-olefin (e.g. propylene) is polymerized in the presence of a catalyst comprising a solid catalyst component essentially consisting of a metal oxide (e.g. SiO2), Mg, Ti, halogen and an electron-donating compound (e.g. di-n-butyl phthalate), an organometallic compound (e.g. triethylaluminum) and an ethoxylated silane compound represented by the formula: RnSi(OC2H5)4-n (wherein R is a 3-10C aliphatic hydrocarbon group; and n is 1 or 2) and having a volume of 200-500Angstrom as determined by a calculation based on quantum chemistry and an electron density of the O atoms of the ethoxy groups of 0.680-0.800 as determined by the same calculation (e.g. n-butyltriethoxysilane).

7. 发明专利

JPH0376708A CATALYST COMPONENT FOR ALPHA-OLEFIN POLYMERIZATION 失效
公开(公告)号：JPH0376708A
公开(公告)日：1991-04-02
申请号：JP21144189
申请日：1989-08-18
申请人： TONEN CORP
发明人： KOYAMA NAOMI , USUI MIYUKI , FURUHASHI HIROYUKI , OKANO TOMOKO , MURATA MASAHIDE , UEKI SATOSHI
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00
摘要： PURPOSE:To increase the strengths of catalyst particles by bringing a solid component mainly comprising Mg, Ti, a halogen, and an electron-donating compd. into contact with an olefin in the presence of a trialkylaluminum and a specific dimethoxysilane compd. CONSTITUTION:An Mg compd. (e.g. MgCl2), a di- to tetravalent Ti compd. (e.g. TiCl4), and an electron-donating compd. (e.g. acetyl chloride) are brought into contact with each other to give a solid component mainly comprising Mg, Ti, a halogen, and an electron-donating compd. Which is then brought into contact with an olefin at 100 deg.C or lower in the presence of a trialkylaluminum (e.g. trimethylaluminum) and a dimethoxysilane compd. of the formula (wherein R and R are each a 1-10C aliph. hydrocarbon group) having a quantum- chemically calculated volume of 230-500Angstrom and an electron density of an oxygen atom in the methoxy group of 0.685-0.800A.U.

8. 发明专利

JPH0333105A CATALYST FOR POLYMERIZATION OF ALPHA-OLEFIN 失效
公开(公告)号：JPH0333105A
公开(公告)日：1991-02-13
申请号：JP16712189
申请日：1989-06-30
申请人： TONEN CORP
发明人： OKANO TOMOKO , SENDA KANAKO , MURATA MASAHIDE , FURUHASHI HIROYUKI , UEKI SATOSHI
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00
摘要： PURPOSE:To produce a highly stereoregular poly-alpha-olefin with an activity at least as high as that attained when an organosilicon compound having an aromatic group is used by using a catalyst consisting of a titanium-containing solid catalyst component, an organometallic compound and a specified silane compound. CONSTITUTION:A catalyst for the polymerization of an alpha-olefin comprising (A) a solid catalyst component essentially consisting of magnesium, titanium, a halogen and an electron-donating compound, (B) an organometallic compound, (C) a dimethoxylated silane compound represented by the general formula: R R Si(OCH3)2 [wherein R and R may be the same or different from each other and are each a 1-10C aliphatic hydrocarbon group] and having a volume of 150-500Angstrom as determined based on quantum chemical calculation, (D) trimethoxyhydrocarbylsilane and/or (E) tetramethoxysilane. The above silane compound does not form any noxious substance which is problematic when a silane compound having an aromatic group is used.

9. 发明专利

JPH0333102A CATALYST FOR POLYMERIZATION OF ALPHA-OLEFIN 失效
公开(公告)号：JPH0333102A
公开(公告)日：1991-02-13
申请号：JP16711889
申请日：1989-06-30
申请人： TONEN CORP
发明人： OKANO TOMOKO , SENDA KANAKO , MURATA MASAHIDE , FURUHASHI HIROYUKI , UEKI SATOSHI
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00
摘要： PURPOSE:To produce a highly stereoregular poly-alpha-olefin with an activity at least as high as that attained when an organosilicon compound having an aromatic group is used by using a catalyst prepared by combining a titanium- containing solid catalyst component with an organometallic compound and a specified dimethoxylated silane compound. CONSTITUTION:A catalyst for the polymerization of alpha-olefin comprising (A) a solid catalyst component essentially consisting of magnesium, titanium, a halogen and an electron-donating compound, (B) an organometallic compound, and (C) a dimethoxylated silane compound represented by the general formula: R R Si(OCH3)2 [wherein R and R may be the same or different from each other and are each a 1-10C aliphatic hydrocarbon group] and having a volume of 230-500Angstrom as determined based on quantum chemical calculation and an electron density of the oxygen atom of the methoxy group of 0.685-0.800 A.U. (atomic unit) as determined in the same way. This silane compound does not form any noxious substance which is problematic when a silane compound having an aromatic group is used.

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