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    • 1. 发明专利
    • Additive agent for nonaqueous electrolytic solution, nonaqueous electrolytic solution, and electric power storage device
    • 非水溶性电解液,非电解电解质和电力存储装置的添加剂
    • JP2014194872A
    • 2014-10-09
    • JP2013070408
    • 2013-03-28
    • Sumitomo Seika Chem Co Ltd住友精化株式会社
    • FUJIMOTO SHOHEIONOZUKA TOMOHIROFUJITA KOJI
    • H01M10/0567H01G11/54H01M10/052H01M10/0568H01M10/0569
    • Y02E60/122
    • PROBLEM TO BE SOLVED: To provide an additive agent for nonaqueous electrolytic solution which enables the improvement of battery characteristics including battery life and capacity by forming, on an electrode surface, a stable solid electrolyte interface when being used for an electric power storage device, and to provide a nonaqueous electrolytic solution arranged by use of such an additive agent for nonaqueous electrolytic solution, and an electric power storage device arranged by use of such a nonaqueous electrolytic solution.SOLUTION: An additive agent for nonaqueous electrolytic solution comprises a succinimide disulfonate compound expressed by the following formula (1). In the formula (1), R, R, R, and Reach represent a hydrogen atom, a halogen atom, an alkyl group having 1-6 carbon atoms which may be substituted, or an o-phenylene group which is produced by coupling one of Rand Rwith one of Rand R, and which may be substituted.
    • 要解决的问题:提供一种用于非水电解液的添加剂,其能够通过在用于蓄电装置时在电极表面上形成稳定的固体电解质界面来改善包括电池寿命和容量的电池特性,以及 提供使用这种非水电解液用添加剂配置的非水电解液,以及使用这种非水电解液配置的蓄电装置。溶液:非水电解液用添加剂包含表示的琥珀酰亚胺二磺酸酯化合物 由下式(1)表示。 在式(1)中,R,R,R和Reach表示氢原子,卤素原子,可被取代的具有1-6个碳原子的烷基,或通过将一个 的兰德R与兰德R之一,并可以被替代。
    • 2. 发明专利
    • Additive for nonaqueous electrolyte, nonaqueous electrolyte and electricity storage device
    • 非水电解质,非电解电解质和电力储存装置的添加剂
    • JP2014013728A
    • 2014-01-23
    • JP2012151428
    • 2012-07-05
    • Sumitomo Seika Chem Co Ltd住友精化株式会社
    • ONOZUKA TOMOHIROFUJIMOTO SHOHEIFUJITA KOJI
    • H01M10/0567H01G11/54H01M10/052H01M10/0568H01M10/0569
    • Y02E60/122
    • PROBLEM TO BE SOLVED: To provide: an additive for a nonaqueous electrolyte excellent in storage stability, and, when used in an electricity storage device, such as a nonaqueous electrolyte secondary battery and an electric double layer capacitor, forming a stable SEI on an electrode surface, thereby capable of improving battery characteristics, such as cycle characteristics, charge/discharge capacity and internal resistance; a nonaqueous electrolyte including the additive for a nonaqueous electrolyte; and an electricity storage device including the nonaqueous electrolyte.SOLUTION: An additive for a nonaqueous electrolyte comprises a disulfonic acid amide compound represented by the following formula (1). In the formula (1), Xand Xeach independently represent a 1-6C alkylene group, or a 1-6C alkylene group having an oxygen atom, a nitrogen atom that may have a substituent, or a sulfur atom, in a carbon chain or at a chain end. A represents CHZ, m represents an integer of 1-6, n represents an integer of 0-12, and Z represents a 1-4C alkyl group, a silyl group, a phosphonate ester group, an acyl group, a cyano group or a nitro group, which may be substituted.
    • 要解决的问题:提供一种储存稳定性优异的非水电解质添加剂,并且在用于诸如非水电解质二次电池和双电层电容器的蓄电装置中时,在电极上形成稳定的SEI 从而能够改善电池特性,例如循环特性,充放电容量和内阻; 包含非水电解质添加剂的非水电解质; 以及包含非水电解质的蓄电装置。溶液:非水电解质添加剂包含由下式(1)表示的二磺酸酰胺化合物。 在式(1)中,Xand Xeach独立地表示碳链或1-6个碳原子的1-6C亚烷基或具有氧原子的1-6C亚烷基,可以具有取代基的氮原子或硫原子 一个链结。 A表示CHZ,m表示1-6的整数,n表示0〜12的整数,Z表示1-4C的烷基,甲硅烷基,膦酸酯基,酰基,氰基或 硝基,其可以被取代。
    • 3. 发明专利
    • Method for producing n-[4-(6,7-difluoro-2,4-dioxo-1,4-dihydro-2h-quinazoline-3-yl)-phenyl]-acetamide
    • 生产N- [4-(6,7-二氟-2,4-二氧代-1,4-二氢-2H-喹唑啉-3-基) - 苯基] - 乙酰胺的方法
    • JP2012162464A
    • 2012-08-30
    • JP2011021873
    • 2011-02-03
    • Sumitomo Seika Chem Co Ltd住友精化株式会社
    • TANAKA MUNEAKIKUAD PAULKOBAYASHI TETSUYAONOZUKA TOMOHIRO
    • C07D239/96
    • PROBLEM TO BE SOLVED: To provide a method for efficiently producing high-purity N-[4-(6,7-difluoro-2,4-dioxo-1,4-dihydro-2H-quinazoline-3-yl)-phenyl]-acetamide used as an important precursor for production of pharmaceutical intermediates.SOLUTION: In the method for producing N-[4-(6,7-difluoro-2,4-dioxo-1,4-dihydro-2H-quinazoline-3-yl)-phenyl]-acetamide, N-[4-(6,7-difluoro-2,4-dioxo-1,4-dihydro-2H-quinazoline-3-yl)-phenyl]-acetamide is obtained by reacting 2-amino-4,5-difluorobenzoic acid methyl ester with a phenyl chloroformate compound at a predetermined molar ratio, and then, reacting the resultant phenoxy carbonyl amine compound with N-acetyl 1,4-phenylene diamine in a solvent in the presence of a base without performing an isolating process.
    • 待解决的问题:提供一种有效生产高纯度N- [4-(6,7-二氟-2,4-二氧代-1,4-二氢-2H-喹唑啉-3-基) - 苯基] - 乙酰胺用作药物中间体的重要前体。 解决方案:在N- [4-(6,7-二氟-2,4-二氧代-1,4-二氢-2H-喹唑啉-3-基) - 苯基] - 乙酰胺的制备方法中, 得到[4-(6,7-二氟-2,4-二氧代-1,4-二氢-2H-喹唑啉-3-基) - 苯基] - 乙酰胺,通过2-氨基-4,5-二氟苯甲酸甲酯 酯与预定摩尔比的氯甲酸苯酯化合物反应,然后使所得苯氧基羰基胺化合物与N-乙酰基1,4-苯二胺在溶剂中在碱的存在下反应而不进行分离过程。 版权所有(C)2012,JPO&INPIT
    • 5. 发明专利
    • Boron-containing sulfonic ester compound, additive agent for nonaqueous electrolytic solution, nonaqueous electrolytic solution, and electric power storage device
    • 含硼含硫酸酯化合物,非水溶性电解质添加剂,非水溶性电解液和电力存储装置
    • JP2014194870A
    • 2014-10-09
    • JP2013070406
    • 2013-03-28
    • Sumitomo Seika Chem Co Ltd住友精化株式会社
    • ONOZUKA TOMOHIROFUJITA KOJI
    • H01M10/0567C07F5/02H01G11/54H01M10/052H01M10/0568H01M10/0569
    • Y02E60/122
    • PROBLEM TO BE SOLVED: To provide a novel additive agent for electrolytic solution which is superior in safety, and which enables the improvement of battery characteristics of a nonaqueous electrolytic secondary battery by forming, on an electrode surface, a solid electrolyte interface (SEI) serving to enhance the cycle characteristics, charge and discharge efficiencies, internal resistance and the like, thereby overcoming the problem of a lithium ion battery that an additive agent used for the formation of SEI on an electrode surface is imperfect in its performance.SOLUTION: A boron-containing sulfonic ester compound is expressed by the formula (1). In the formula (1), Rand Rrepresent a hydrogen atom, a halogen atom, an alkyl group having 1-6 carbon atoms which may be substituted, or a group which may be coupled with Rand R. Using the boron-containing sulfonic ester compound for an electric power storage device, a stable solid electrolyte interface can be formed on an electrode surface to improve the battery characteristics including battery life and capacity.
    • 要解决的问题:提供一种安全性优异的新型电解液添加剂,通过在电极表面上形成固体电解质界面(SEI),能够提高非水电解质二次电池的电池特性 以提高循环特性,充放电效率,内阻等,从而克服了用于在电极表面上形成SEI的添加剂的锂离子电池的性能不完善的问题。解决方案:硼 (1)表示的磺酸酯化合物。 在式(1)中,兰德R表示氢原子,卤素原子,可被取代的具有1-6个碳原子的烷基,或可与兰德R连接的基团。使用含硼磺酸酯化合物 对于蓄电装置,可以在电极表面上形成稳定的固体电解质界面,以改善包括电池寿命和容量的电池特性。
    • 8. 发明专利
    • Additive for nonaqueous electrolyte, nonaqueous electrolyte, and electricity storage device
    • 非水电解质,非电解电解质和电力储存装置的添加剂
    • JP2014067585A
    • 2014-04-17
    • JP2012212103
    • 2012-09-26
    • Sumitomo Seika Chem Co Ltd住友精化株式会社
    • ONOZUKA TOMOHIROFUJIMOTO SHOHEIFUJITA KOJI
    • H01M10/0567H01G11/54H01M10/052H01M10/0568H01M10/0569
    • Y02E60/122
    • PROBLEM TO BE SOLVED: To provide an additive for a nonaqueous electrolyte, excellent in storage stability, and, when used in an electricity storage device such as a nonaqueous electrolyte secondary battery, forming a stable SEI on a surface of an electrode, thereby improving battery characteristics such as cycle characteristics, charge/discharge capacity and internal resistance, and to provide a nonaqueous electrolyte containing the additive for a nonaqueous electrolyte and an electricity storage device using the nonaqueous electrolyte.SOLUTION: An additive for a nonaqueous electrolyte comprises an N-aryl carboxylic acid amide compound having a structure represented by the following formula (1) and having an energy of the lowest vacant orbital of less than 0. In the formula (1), Ar represents an aryl group that may be substituted, R represents a hydrogen atom, a 1-6C alkyl group that may be substituted, or an aryl group that may be substituted, and n represents an integer of 0-6.
    • 要解决的问题:提供一种非水电解质添加剂,其储存稳定性优异,并且在用于非水电解质二次电池等蓄电装置时,在电极表面形成稳定的SEI,从而改善电池 特性如循环特性,充放电容量和内阻,以及提供含有非水电解质添加剂的非水电解质和使用非水电解质的蓄电装置。溶液:非水电解质添加剂包括N-芳基 具有由下式(1)表示的结构并且具有小于0的最低空位轨道的能量的羧酸酰胺化合物。在式(1)中,Ar表示可被取代的芳基,R表示氢 原子,可以被取代的1-6C烷基或可被取代的芳基,n表示0-6的整数。
    • 10. 发明专利
    • Phosphorus-containing sulfonic acid ester compound, additive for nonaqueous electrolyte, nonaqueous electrolyte, and power storage device
    • 含磷酸的硫酸酯化合物,非水电解质,非电解电解质和电力储存装置的添加剂
    • JP2013203698A
    • 2013-10-07
    • JP2012074515
    • 2012-03-28
    • Sumitomo Seika Chem Co Ltd住友精化株式会社
    • ONOZUKA TOMOHIROFUJIMOTO SHOHEIFUJITA KOJI
    • C07F9/40C07F9/6553H01G11/54H01M10/0567H01M10/0568H01M10/0569
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a novel phosphorus-containing sulfonic acid ester compound; to provide an additive for a nonaqueous electrolyte capable of forming a stable SEI on an electrode surface and improving cell properties such as cycle characteristics, charge and discharge capacity, internal resistance when used for a power storage device such as a nonaqueous electrolyte secondary cell; and to provide a nonaqueous electrolyte using the additive for a nonaqueous electrolyte, and a power storage device using the nonaqueous electrolyte.SOLUTION: A phosphorus-containing sulfonic acid ester compound is represented by formula (1). In formula (1): Rand Rare each a 1-6C alkyl group or the like; Rand Rare each a 1-6C alkyl group or the like, or Rand Rform an optionally substituted 1-6C alkylene group or the like wherein Rand Rbecome common groups to form a cyclic structure; and Y is a hydrogen atom, a 1-6C alkyl group or the like.
    • 要解决的问题:提供一种新型含磷磺酸酯化合物; 提供一种能够在电极表面上形成稳定的SEI的非水电解质的添加剂,并且在用于非水电解质二次电池等蓄电装置时,提高电池特性,例如循环特性,充放电容量,内阻等。 并提供使用非水电解质添加剂的非水电解质和使用非水电解质的蓄电装置。溶液:含磷磺酸酯化合物由式(1)表示。 在式(1)中:R 1 R 1各自为1〜6个C烷基等; 兰德Rare各自为1-6C烷基等,或兰德Rform为任选取代的1-6C亚烷基等,其中兰德Rbecome为共同基团以形成环状结构; Y为氢原子,1-6C烷基等。