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1. 发明专利

JP2008243661A Cylindrical lithium secondary battery 有权
标题翻译：圆柱形锂二次电池
公开(公告)号：JP2008243661A
公开(公告)日：2008-10-09
申请号：JP2007083761
申请日：2007-03-28
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： FUKUI ATSUSHI , YAMAMOTO HIDEKAZU , TAKANO YASUO , SAWA KATSUICHIRO , SUNANO TAIZO , JINNO MARUO
IPC分类号： H01M2/16 , H01M4/02 , H01M4/04 , H01M4/131 , H01M4/134 , H01M4/1391 , H01M4/1395 , H01M4/36 , H01M4/38 , H01M4/505 , H01M4/525 , H01M4/587 , H01M4/62 , H01M10/052 , H01M10/0567 , H01M10/0569 , H01M10/0587
CPC分类号： H01M10/052 , H01M2/1653 , H01M4/364 , H01M4/386 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/622 , H01M4/625 , H01M2004/021 , H01M2010/4292 , Y10T29/49115
摘要： PROBLEM TO BE SOLVED: To provide a lithium secondary battery superior in charge and discharge cycle characteristics even in the case of a cylindrical lithium secondary battery in which a material containing silicon or the like to cause volume expansion in storing lithium is used for a negative electrode active material, and its manufacturing method. SOLUTION: In the lithium secondary battery equipped with a positive electrode 1 in which a positive electrode mixture layer containing a positive electrode active material is arranged on a surface of a positive electrode current collector consisting of a conductive metal foil, and a negative electrode 2 in which a negative electrode mixture layer having a negative electrode active material containing silicon particles and/or silicon alloy particles is arranged on a surface of a negative electrode current collector consisting of the conductive metal foil, the positive electrode active material amount is 50 mg or less per 1 cm 2 of the positive electrode, the average diameter of the silicon particles and/or the silicon alloy particles is 5 μm or more and 15 μm or less, and a theoretical electric capacity factor of the negative electrode against the positive electrode is 1.2 or more. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：即使在其中使用含有硅等材料以引起储存锂的体积膨胀的圆柱形锂二次电池的情况下，也提供具有优异的充放电循环特性的锂二次电池，负极活性物质及其制造方法。解决方案：在具有正电极1的锂二次电池中，其中在由导电金属箔构成的正极集电体的表面上配置有包含正极活性物质的正极合剂层，负极在由导电性金属箔构成的负极集电体的表面配置具有含有硅粒子和/或硅合金粒子的负极活性物质的负极合剂层的电极2，正极活性物质量为50 mg / mm 2以下，硅粒子和/或硅合金粒子的平均直径为5μm以上且15μm以下，理论电容率因子的负极相对于正极为1.2以上。版权所有（C）2009，JPO＆INPIT

2. 发明专利

JP2008235083A Negative electrode for lithium secondary battery, and lithium secondary cell 审中-公开
标题翻译：用于锂二次电池和锂二次电池的负极
公开(公告)号：JP2008235083A
公开(公告)日：2008-10-02
申请号：JP2007075039
申请日：2007-03-22
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： TAKANO YASUO , SUNANO TAIZO , SAWA KATSUICHIRO , JINNO MARUO
IPC分类号： H01M4/134 , H01M4/38 , H01M4/62
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To obtain a lithium secondary battery negative electrode that is the lithium secondary battery negative electrode which has a superior cycle characteristic and in which active material particles containing silicon alloy are used, and a lithium secondary battery using it. SOLUTION: The lithium secondary battery negative electrode is obtained, in which an active material layer containing a binder and the active material particles containing silicon alloy composed of silicon and at least one kind of metal element are arranged on a surface of a current collector consisting of a conductive metal foil, then this is sintered under a non-oxidizing atmosphere, and in which the active material particles have a first phase 2 composed of the alloy of silicon and the metal element and a second phase 1 composed mainly of silicon, while the first phase 2 has a three-dimensional mesh structure in the active material particles, and the second phase 1 is enveloped in the first phase 2. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：为了获得使用具有优越的循环特性的锂二次电池负极并且其中使用含有硅合金的活性材料颗粒的锂二次电池负极和使用它的锂二次电池。解决方案：获得锂二次电池负极，其中包含粘合剂的活性材料层和由硅和至少一种金属元素组成的硅合金的活性材料颗粒被布置在电流的表面上收集器由导电金属箔构成，然后在非氧化性气氛下烧结，其中活性物质颗粒具有由硅和金属元素的合金组成的第一相2和主要由硅构成的第二相1 而第一相2在活性物质颗粒中具有三维网格结构，第二相1在第一阶段2中被包围。版权所有：（C）2009，JPO＆INPIT

3. 发明专利

JP2006252998A Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：JP2006252998A
公开(公告)日：2006-09-21
申请号：JP2005068856
申请日：2005-03-11
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： SUNAKAWA TAKUYA , FUKUI ATSUSHI , SUNANO TAIZO , MINAMI HIROYUKI , SAWA KATSUICHIRO , JINNO MARUO , SAITO TOSHIHIKO
IPC分类号： H01M2/02 , H01M4/02 , H01M4/134 , H01M4/36 , H01M4/38 , H01M10/05 , H01M10/052 , H01M10/0567
CPC分类号： H01M10/052 , H01M2/0257 , H01M2/0275 , H01M4/02 , H01M4/131 , H01M4/134 , H01M4/1395 , H01M4/386 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/58 , H01M10/0567 , H01M10/0587 , H01M2004/021 , Y02T10/7011
摘要： PROBLEM TO BE SOLVED: To provide a lithium secondary battery capable of improving by leaps and bounds the charge and discharge cycle characteristics by suppressing generation of gas originated from decomposition of a non-aqueous electrolyte, while suppressing increase of manufacturing cost of the battery. SOLUTION: The lithium secondary battery has a power generation element comprising a negative electrode 2 containing a negative electrode active material particle consisting of silicone and/or silicone alloy, a positive electrode 1 containing a positive electrode active material consisting of a lithium transition metal compound oxide, and a non-aqueous electrolyte housed in an aluminum laminate outer package 6. The non-aqueous electrolyte contains an ion of at least one kind of element selected from a group of Co, Cu, Mg, Mn, Ni, Fe, and Zr. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决的问题：提供一种能够通过抑制源自非水电解质分解的气体的产生而跨越和跨越来提高充电和放电循环特性的锂二次电池，同时抑制生产成本的增加电池。解决方案：锂二次电池具有包含负极2的发电元件，负极2含有由硅氧烷和/或硅氧烷合金组成的负极活性物质颗粒，正极1含有由锂过渡层组成的正极活性物质金属复合氧化物，以及容纳在铝层压体外包装6中的非水电解质。非水电解质含有选自Co，Cu，Mg，Mn，Ni，Fe中的至少一种元素的离子，和Zr。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2013232323A Negative electrode for nonaqueous electrolyte secondary battery, method for producing the same, and nonaqueous electrolyte secondary battery 审中-公开
标题翻译：用于非水电解质二次电池的负极，其制造方法和非电解电解质二次电池
公开(公告)号：JP2013232323A
公开(公告)日：2013-11-14
申请号：JP2012103421
申请日：2012-04-27
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： SAWA KATSUICHIRO , SUNANO TAIZO
IPC分类号： H01M4/134 , H01M4/1395 , H01M4/62 , H01M4/66
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide a negative electrode for a nonaqueous electrolyte secondary battery, capable of improving charge/discharge cycle characteristics of a nonaqueous electrolyte secondary battery.SOLUTION: A negative electrode 11 for a nonaqueous electrolyte secondary battery 1 includes a negative electrode collector 11a, a polyimide layer 11b and a negative electrode active material layer 11c. The polyimide layer 11b is disposed on the negative electrode collector 11a. The polyimide layer 11b contains copper and a first polyimide resin. The negative electrode active material layer 11c is disposed on the polyimide layer 11b. The negative electrode active material layer 11c contains a negative electrode active material and a second polyimide resin. The negative electrode active material contains at least one of silicon and a silicon alloy.
摘要翻译：要解决的问题：提供一种能够改善非水电解质二次电池的充放电循环特性的非水电解质二次电池用负极。解决方案：非水电解质二次电池1的负极11包括负极集电体 11a，聚酰亚胺层11b和负极活性物质层11c。聚酰亚胺层11b设置在负极集电体11a上。聚酰亚胺层11b含有铜和第一聚酰亚胺树脂。负极活性物质层11c配置在聚酰亚胺层11b上。负极活性物质层11c含有负极活性物质和第二聚酰亚胺树脂。负极活性物质含有硅和硅合金中的至少一种。

5. 发明专利

JP2005285581A Cathode for lithium secondary battery and lithium secondary battery 有权
标题翻译：锂二次电池和锂二次电池的阴极
公开(公告)号：JP2005285581A
公开(公告)日：2005-10-13
申请号：JP2004098481
申请日：2004-03-30
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： FUKUI ATSUSHI , MINAMI HIROYUKI , SAWA KATSUICHIRO , TORIMAE MARIKO , KUSUMOTO YASUYUKI , JINNO MARUO
IPC分类号： H01M10/05 , H01M4/134 , H01M4/38 , H01M4/62 , H01M4/02 , H01M10/40
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a cathode for a lithium secondary battery with excellent initial charge/discharge efficiency, and a lithium secondary battery using the cathode.
SOLUTION: The cathode for the lithium secondary battery is obtained by arranging a mixture layer including cathode active material particles containing silicon and/or silicon alloy and a binder on the surface of a collector, of which an active layer void ratio as defined in formulae 1 and 2 is 60% or less after charging and discharging of a first cycle or later.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供具有优异的初始充电/放电效率的锂二次电池的阴极和使用该阴极的锂二次电池。解决方案：锂二次电池的阴极通过在集电体的表面上布置包含含有硅和/或硅合金的阴极活性材料颗粒和粘合剂的混合层，其中定义了有源层空隙率式1和2中的第一循环或更迟的充放电后为60％以下。版权所有（C）2006，JPO＆NCIPI

6. 发明专利

JP2005268120A Lithium secondary battery and its manufacturing method 审中-公开
标题翻译：锂二次电池及其制造方法
公开(公告)号：JP2005268120A
公开(公告)日：2005-09-29
申请号：JP2004080750
申请日：2004-03-19
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： ITAYA SHOJI , FUKUI ATSUSHI , KUSUMOTO YASUYUKI , MINAMI HIROYUKI , TORIMAE MARIKO , SAWA KATSUICHIRO , FUJIMOTO MASAHISA
IPC分类号： H01M4/66 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/62 , H01M10/05 , H01M4/02 , H01M4/04 , H01M10/40
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide a lithium secondary battery with excellent charging/discharging cycle property using a negative electrode wherein initial charge/discharge efficiency of a negative electrode provided with a negative electrode active material containing silicon is improved.
SOLUTION: The lithium secondary battery 10 of this invention has the negative electrode 12 wherein a negative electrode mix layer having a negative electrode active material containing silicon and a binder is formed on a conductive metal foil as a negative electrode current collector, a positive electrode 11 and a nonaqueous electrolyte. A binder solution wherein the contact angle of a solution containing a binder and a silicon wafer at in 20 °C is less than 10.6 degrees is used. Silicon used as the negative electrode active material is equivalent to the crushed silicon wafer. Since the wettability of the binder and the negative electrode active material particles is good when the binder solution is used, high adhesion between negative electrode active material particles and the binder can be obtained, a good conduction network can be formed in the negative electrode mix layer, and the negative electrode 12 with excellent charge-discharge characteristics can be obtained.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种具有优异的充电/放电循环特性的锂二次电池，其使用负极，其中提供含有含硅的负极活性物质的负极的初始充电/放电效率提高。解决方案本发明的锂二次电池10具有负极12，其中在作为负极集电体的导电金属箔上形成具有含有硅和粘合剂的负极活性物质的负极混合层，正极11和非水电解质。使用其中在20℃下含有粘合剂和硅晶片的溶液的接触角小于10.6度的粘合剂溶液。用作负极活性物质的硅相当于破碎的硅晶片。由于粘合剂和负极活性物质粒子的润湿性在使用粘合剂溶液时是良好的，因此可以获得负极活性物质粒子和粘合剂之间的高附着性，可以在负极混合层中形成良好的导电网络并且可以获得具有优异的充放电特性的负电极12。版权所有（C）2005，JPO＆NCIPI

7. 发明专利

JP2007227239A Anode for a lithium secondary battery and lithium secondary cell 审中-公开
标题翻译：锂二次电池和锂二次电池的阳极
公开(公告)号：JP2007227239A
公开(公告)日：2007-09-06
申请号：JP2006048738
申请日：2006-02-24
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： SATO KAZUYUKI , SAWA KATSUICHIRO , SUNANO TAIZO , JINNO MARUO , TARUI HISAKI
IPC分类号： H01M4/02 , H01M4/133 , H01M4/134 , H01M4/36 , H01M4/38 , H01M4/587 , H01M10/05
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide an anode for a lithium secondary battery capable of restraining deterioration of a current-collecting property inside an electrode due to exfoliation of a mixture layer from a collector, with a large charging and discharging capacity, and with excellent charge/discharge cycle characteristics, as well as a lithium secondary battery. SOLUTION: A mixture obtained by mixing a metal material with its volume expanding/contracting by absorbing/releasing lithium, and scaly graphite with shearing stress applied in a dry state is used as an active material. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决的问题：提供一种锂二次电池的阳极，其能够抑制由于集电体的混合层的剥离而导致的电极内的集电性的劣化，具有大的充电和放电能力，以及具有优异的充放电循环特性，以及锂二次电池。解决方案：使用通过将金属材料与其吸收/释放锂的体积膨胀/收缩混合获得的混合物和在干燥状态下施加的剪切应力的鳞片状石墨作为活性材料。版权所有（C）2007，JPO＆INPIT

8. 发明专利

JP2006278185A Lithium secondary battery and its producing method 有权
标题翻译：锂二次电池及其制造方法
公开(公告)号：JP2006278185A
公开(公告)日：2006-10-12
申请号：JP2005096848
申请日：2005-03-30
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： SUNAKAWA TAKUYA , FUKUI ATSUSHI , SAWA KATSUICHIRO , SUNANO TAIZO , JINNO MARUO , MINAMI HIROYUKI , SAITO TOSHIHIKO
IPC分类号： H01M2/02 , H01M4/02 , H01M4/36 , H01M4/38 , H01M10/05 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/058
CPC分类号： Y02E60/122 , Y02P70/54 , Y02T10/7011
摘要： PROBLEM TO BE SOLVED: To provide a lithium secondary battery which is dramatically improved in charge-discharge cycle characteristic by restraining rise of production cost of the battery and controlling decomposition of nonaqueous electrolyte and degradation of a negative pole active material particle surface accompanied with it as well as its producing method. SOLUTION: The lithium secondary battery comprises power generation elements of a negative pole 2 containing negative pole active material particles made of silicon or silicon alloy, a positive pole 1 containing a positive pole active material made of lithium transition metal compound oxide, and nonaqueous electrolyte held in aluminium laminate package 6. In the nonaqueous electrolyte, perchlorate of at least one element selected among the group of Ba, Mg, Zn, Co, Mn, Ni, Ce, and Sr is dissolved. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决的问题：提供一种锂二次电池，其通过抑制电池的制造成本的上升并且控制非水电解质的分解和负极活性物质颗粒表面的降解而伴随着充放电循环特性显着提高，伴随着以及它的生产方法。解决方案：锂二次电池包括含有由硅或硅合金制成的负极活性物质颗粒的负极2的发电元件，含有由锂过渡金属复合氧化物制成的正极活性材料的正极1和保持在铝层压体包装体6中的非水电解液。在非水电解质中，溶解了选自Ba，Mg，Zn，Co，Mn，Ni，Ce和Sr中的至少一种元素的高氯酸盐。版权所有（C）2007，JPO＆INPIT

9. 发明专利

JP2006196435A Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：JP2006196435A
公开(公告)日：2006-07-27
申请号：JP2005245895
申请日：2005-08-26
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： SAWA KATSUICHIRO , FUKUI ATSUSHI , SUNAKAWA TAKUYA , JINNO MARUO
IPC分类号： H01M4/02 , H01M4/131 , H01M4/134 , H01M4/1395 , H01M4/62 , H01M10/05 , H01M10/052 , H01M10/0567
CPC分类号： H01M4/131 , H01M4/134 , H01M4/1395 , H01M4/364 , H01M4/386 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0567 , H01M2004/028
摘要： PROBLEM TO BE SOLVED: To enhance charge and discharge cycle characteristics in a lithium secondary battery using a material containing silicon as a negative electrode active material. SOLUTION: This lithium secondary battery includes a negative electrode 2 containing silicon as a negative electrode active material, a positive electrode 1 containing lithium transition metal complex oxide as a positive electrode active material, and a nonaqueous electrolyte. Lithium carbonate is added in the positive electrode, and a carbon dioxide is dissolved in the nonaqueous electrolyte. COPYRIGHT: (C)2006,JPO&NCIPI

10. 发明专利

JP2005190977A Lithium secondary battery and its manufacturing method 有权
标题翻译：锂二次电池及其制造方法
公开(公告)号：JP2005190977A
公开(公告)日：2005-07-14
申请号：JP2004071483
申请日：2004-03-12
申请人： Sanyo Electric Co Ltd , 三洋電機株式会社
发明人： SAWA KATSUICHIRO , MINAMI HIROYUKI , TORIMAE MARIKO , FUKUI ATSUSHI , KUSUMOTO YASUYUKI , SAYAMA KATSUNOBU , JINNO MARUO
IPC分类号： H01M4/66 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/40 , H01M4/62 , H01M10/05 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/058 , H01M10/40 , H01M4/02
CPC分类号： H01M10/052 , H01M4/0471 , H01M4/134 , H01M4/386 , H01M4/405 , H01M10/0567 , H01M10/058 , H01M2004/027 , Y10T29/49108
摘要： PROBLEM TO BE SOLVED: To provide a lithium secondary battery using a negative electrode including active material containing silicon and/or silicon alloy, which has large charge and discharge capacity and superior cycle characteristics, and suppresses production of porous active material, caused by charging and discharging so that the increase in the thickness of electrode, after charging and discharging, is suppressed. SOLUTION: This lithium secondary battery includes a negative electrode, provided by sintering a mixture layer including active material particles, containing silicon and/or silicon alloy and a binder on a surface of a current collector, consisting of a conductive metal foil, a positive electrode and a non-aqueous electrolyte, wherein carbon dioxide is dissolved in the non-aqueous electrolyte. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种使用包含含有硅和/或硅合金的活性物质的负极的锂二次电池，其具有大的充放电能力和优异的循环特性，并且抑制了多孔活性材料的产生，导致通过充放电，能够抑制充放电后的电极厚度的增加。解决方案：该锂二次电池包括负极，其通过在包含导电金属箔的集电体的表面上烧结含有硅和/或硅合金的活性材料颗粒和粘合剂的混合层而提供，正电极和非水电解质，其中二氧化碳溶解在非水电解质中。版权所有（C）2005，JPO＆NCIPI

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