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    • 6. 发明专利
    • JPH05286717A
    • 1993-11-02
    • JP11304492
    • 1992-04-06
    • SUMITOMO ELECTRIC INDUSTRIES
    • NAGAISHI RYUKINAKANISHI SHUSUKEITOZAKI HIDEO
    • C01G1/00C01G3/00H01B12/06H01B13/00H01L39/24
    • PURPOSE:To form the thin film excellent in surface properties and superconductivity with good reproducibility by irradiating a target with a laser beam via a through-hole slightly smaller than the beam in the laser vapor deposition process. CONSTITUTION:A vacuum vessel 1 consists of a substrate holder 2, a target holder 3 and a transparent window 4. A laser device 5 is provided with a laser beam focusing optical line 8 and a slit 9 furnished with a through-hole slightly smaller than the beam line. Consequently, only the center of the laser beam reaches a target 7, and the target is irradiated with a high and uniform beam. For example, a (100) substrate of an MgO single crystal is used as a substrate 6, and a multiple oxide sintered compact of YBa2Cu3O7 is used as the target 7. A 70X70mm brass sheet with 2mm thickness is used for the slit 9 and a 6X24mm through-hole is used. The temp. of the substrate is controlled to 700 deg.C, the gas pressure to 400m Torr and the energy density of the laser beam to 1.5-2.0J/cm , and a thin film having 2000Angstrom thickness is formed.
    • 8. 发明专利
    • SUPERCONDUCTING ELEMENT AND MANUFACTURE THEREOF
    • JPH04179282A
    • 1992-06-25
    • JP30827090
    • 1990-11-14
    • SUMITOMO ELECTRIC INDUSTRIES
    • NAGAISHI RYUKITANAKA SABUROITOZAKI HIDEO
    • H01L39/22H01L39/24
    • PURPOSE:To integrally form the entire part for not only easy manufacture but also stable characteristics by forming a region, wherein ions of a substance which easily diffuse into an oxide superconductor and deteriorate superconductive characteristics of the oxide superconductor are implanted, into a part of an oxide superconducting thin film formed on a substrate. CONSTITUTION:An oxide superconducting thin film 10 having a junction layer 3, which is formed like a line along the entire width of a superconducting element by arsenic ion implantation, is formed as a Josephson element. A MgO single crystal substrate is used as a substrate and a Y1Ba2Cu3O7-X is used as an oxide superconductor. First, an oxide superconducting thin film 10 is formed on the MgO substrate 4. The oxide superconducting thin film 10 of C-axis orientation is grown and formed on the substrate 4 by the sputtering method with a sintered material including Y, Ba and Cu in terms of the atomic ratio of 1:2:4.5 used as a target. Next, photoresists 5, 6 are formed on the oxide superconducting thin film 10 with an interval of 0.5mum and the arsenic ions implanted into the oxide superconducting thin film 10. The arsenic ions are diffused into the region where the ions are implanted to form a junction layer 3 of 500 to 100nm in thickness and a superconducting junction is formed of a junction layer 3 between the superconducting layers 1 and 2.
    • 9. 发明专利
    • SUPERCONDUCTING ELEMENT
    • JPH04152685A
    • 1992-05-26
    • JP27849890
    • 1990-10-17
    • SUMITOMO ELECTRIC INDUSTRIES
    • NAGAISHI RYUKITANAKA SABUROITOZAKI HIDEO
    • H01L39/22
    • PURPOSE:To form the whole element integrally so as to enable it to be easily formed and stabilized in characteristic by a method wherein a layer of material which diffuses into an oxide superconductor to turn it into a non-superconductor is formed, and a non-superconducting layer is formed of an oxide superconductor which is turned non-superconductive by the diffusion of the material concerned. CONSTITUTION:A superconducting element is formed of an oxide superconducting thin film 10 provided onto a board 4 provided with an Si layer 40 on its surface. The oxide superconducting thin film 10 provided onto a part other than the Si layer 40 is formed into superconducting layers 1 and 2 made of crystal orientated in a C axis. Si atoms are diffused into the oxide superconducting thin film 10 adjacent to the Si layer 40 to partially turn the film 10 into a non-superconducting layer 3. The oxide superconducting thin film 10 is extremely small in thickness at a part 20 located on the side face of the Si layer 40, and the superconducting layers 1 and 2 are made to constitute a superconductive junction at the part 20 concerned. This superconducting element can be formed without laminating a non-superconducting thin film or the like on an oxide superconducting thin film. The superconducting element is formed of an oxide superconducting thin film originally formed in one piece, so that an interface between a superconducting layer and a non-superconducting layer can be formed very sharp.