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1. 发明专利

JP2008086951A Manufacturing method of alkenyl acetate making catalyst 有权
标题翻译：乙酸乙烯酯制备催化剂的制备方法
公开(公告)号：JP2008086951A
公开(公告)日：2008-04-17
申请号：JP2006272772
申请日：2006-10-04
申请人： Showa Denko Kk , 昭和電工株式会社
发明人： YAMAMOTO YOSHIMI , SAIHATA AKIKO , SUGISHITA NORIYUKI
IPC分类号： B01J23/66 , B01J37/02 , C07B61/00 , C07C67/05 , C07C69/15
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide an alkenyl acetate making catalyst with improved activity and selectivity. SOLUTION: In the manufacturing method of the alkenyl acetate making catalyst, a carrier is made to support a chemical compound containing palladium, a chemical compound containing a Group 11 element and a chemical compound containing an alkali earth metal element. Then, the carrier is impregnated with an alkaline solution. Alternatively, this carrier is made to support the chemical compound containing palladium and the chemical compound containing the Group 11 element, and then, is impregnated with the alkaline solution of a chemical compound containing an alkali earth metal element. Further, the carrier is made to support an acetate following a reduction treatment of the above chemical compounds and a contact with an acid. Thus, the alkenyl acetate making catalyst composed of at least (a) the palladium, (b) the Group 11 element, (c) the alkali earth metal element, (d) the acetate and (e) the carrier can be obtained. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供具有改进的活性和选择性的乙烯基链烯酯制备催化剂。解决方案：在制备乙烯基链烯酯的催化剂的制造方法中，使载体包含钯，含有11族元素的化合物和含有碱土金属元素的化合物。然后，用碱性溶液浸渍载体。或者，使该载体支持含有钯的化合物和含有第11族元素的化合物，然后用含有碱土金属元素的化合物的碱溶液浸渍。此外，在上述化合物的还原处理和与酸的接触之后，使载体支持乙酸酯。因此，可以得到至少（a）钯，（b）11族元素，（c）碱土金属元素，（d）乙酸酯和（e）载体）的乙烯基链烯酸酯制造催化剂。版权所有（C）2008，JPO＆INPIT

2. 发明专利

JP2008080326A Method for manufacturing alkenyl acetate manufacturing catalyst 有权
标题翻译：制备乙酸亚丁基酯制备催化剂的方法
公开(公告)号：JP2008080326A
公开(公告)日：2008-04-10
申请号：JP2007193730
申请日：2007-07-25
申请人： Showa Denko Kk , 昭和電工株式会社
发明人： SAIHATA AKIKO
IPC分类号： B01J31/28 , B01J37/16 , C07B61/00 , C07C67/055 , C07C69/15
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for manufacturing an alkenyl acetate manufacturing catalyst where activity and selectivity are improved. SOLUTION: The catalyst is manufactured by using a method which includes the step of impregnating a carrier with an alkali solution with at least more than 0.9 mass fold and 1.0 mass fold or less of the absorbed amount of the career, the step of catalytically impregnating the carrier with the solution A of a compound containing at least palladium or platinum and a compound containing group II elements, and the step of supporting an acetate in the step or the carrier that performs reduction processing, and impregnates the carrier with the alkali solution and subsequently allows the carrier to contact a solution A to form a catalyst precursor and allow the sum of the alkali solution and the solution A to be 1.1 times by mass or more and 10.0 times by mass or less of the absorbed amount of the carrier. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决的问题：提供一种改善活性和选择性的制备乙酸烯基酯制造催化剂的方法。解决方案：通过使用包括以下方式制造催化剂的方法：使用碱性溶液浸渍载体的步骤，所述碱性溶液的吸附量至少大于0.9质量倍和1.0质量倍以下，步骤用至少包含钯或铂的化合物的溶液A和含有II族元素的化合物催化浸渍载体，以及在该步骤中负载乙酸酯或进行还原处理的载体的步骤，并用碱浸渍载体溶液，随后允许载体接触溶液A以形成催化剂前体，并使碱溶液和溶液A的总和为载体的吸收量的1.1质量倍数和10.0质量倍以上。版权所有（C）2008，JPO＆INPIT

3. 发明专利

JP2011005484A Catalyst for producing alkene, method for producing the catalyst and method for producing the alkene 有权
标题翻译：用于生产烷烃的催化剂，用于生产催化剂的方法和用于生产烯烃的方法
公开(公告)号：JP2011005484A
公开(公告)日：2011-01-13
申请号：JP2010119946
申请日：2010-05-26
申请人： Showa Denko Kk , 昭和電工株式会社
发明人： INOUE GEN , SAIHATA AKIKO
IPC分类号： B01J27/057 , B01J23/28 , B01J37/08 , B01J37/16 , C07B61/00 , C07C5/333 , C07C11/04
CPC分类号： B01J23/28 , B01J23/002 , B01J27/0576 , B01J35/002 , B01J37/0009 , B01J37/031 , B01J37/06 , B01J37/10 , B01J37/16 , B01J37/18 , B01J2523/00 , C07C5/3332 , C07C2523/652 , Y02P20/52 , C07C11/04 , B01J2523/55 , B01J2523/64 , B01J2523/68
摘要： PROBLEM TO BE SOLVED: To provide a crystalline MoVTeOcatalyst which is used for producing alkene from alkane by oxidative dehydrogenation and has improved activity.SOLUTION: The catalyst for producing alkene is represented by formula (1): MoVTeO(wherein a is 1.0; b is 0.01-1.0; c is 0-1.0; d is the number of oxygen atoms required to electrically neutralize the whole compound according to the oxidation number of Mo, V and Te) and is obtained by reducing an Mo-V-Te compound oxide having a crystal structure.
摘要翻译：要解决的问题：提供一种用于通过氧化脱氢从烷烃生产烯烃的结晶MoVTeO催化剂，并且具有改善的活性。溶解性：制备烯烃的催化剂由式（1）表示：MoVTeO（其中a为1.0; b为 0.01-1.0; c是0-1.0; d是根据Mo，V和Te的氧化数将整个化合物电中和所需的氧原子数），并且是通过还原Mo-V-Te复合氧化物得到的，晶体结构。

4. 发明专利

JP2008279432A Method of manufacturing catalyst for producing alkenyl acetate 有权
标题翻译：制备乙酸烯丙酯催化剂的方法
公开(公告)号：JP2008279432A
公开(公告)日：2008-11-20
申请号：JP2008043176
申请日：2008-02-25
申请人： Showa Denko Kk , 昭和電工株式会社
发明人： SUGISHITA NORIYUKI , SAIHATA AKIKO
IPC分类号： B01J31/28 , B01J37/02 , B01J37/16 , C07B61/00 , C07C67/055 , C07C69/15
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for producing an alkenyl acetate having an enhanced activity or selectivity. SOLUTION: A method of manufacturing a catalyst for producing an alkenyl acetate includes a process 1 of contacting to impregnate a carrier with a solution A of a compound containing palladium or platinum, a process 2 of contacting to impregnate the carrier with a solution B of a compound containing at least a group II element and an alkaline compound, a process 3 of carrying out a reduction treatment, and a process 4 of supporting an acetic acid salt on the carrier wherein the process 1 and the process 2 are successively performed to obtain the catalyst for producing the alkenyl acetate including at least the carrier (a), palladium or platinum (b), the group II element (c), and the acetic acid salt (d). COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供具有增强的活性或选择性的用于生产乙烯基链烯酯的催化剂。解决方案：制备用于制备烯基乙烯酯的催化剂的方法包括使含有钯或铂的化合物的溶液A浸渍载体的方法1，使其与溶液浸渍载体的方法2 B，含有至少II族元素和碱性化合物的化合物，进行还原处理的方法3和在载体上负载乙酸盐的方法4，其中连续进行方法1和方法2 得到至少包含载体（a），钯或铂（b），II族元素（c）和乙酸盐（d）的链烯基乙酸酯的催化剂。版权所有（C）2009，JPO＆INPIT

5. 发明专利

JPH08230116A MULTILAYER LAMINATE 失效
公开(公告)号：JPH08230116A
公开(公告)日：1996-09-10
申请号：JP4059095
申请日：1995-02-28
申请人： SHOWA DENKO KK
发明人： SAIHATA AKIKO , WATANABE KAZUYUKI , NAKAGAMI SAKUYOSHI
IPC分类号： B32B21/08 , B32B27/12 , B32B27/22 , B32B27/24 , B32B27/32 , C08F8/00 , C08L53/00
摘要： PURPOSE: To provide a multilayer laminate which has excellent hot stampable moldability and releasing strength. CONSTITUTION: A multilayer laminate comprises at least two layers of a layer (I) made of propylene resin composition prepared at a melt flow rate (measured under the conditions of 230 deg.C and 2.16kg of a load based on JIS K 7210) to 50 to 300g/10min obtained by dynamically heat treating a blend of (A) 100 pts.wt.of propylene-α-olefin block copolymer in which the ratio η1 /η2 of the melting viscosity η1 at a shearing speed of 10 sec to the melting viscosity η2 at a shearing speed of 10 sec measured by a slit die method is 3.5 to 8 and (B) 0.005 to 2 pts.wt. of organic peroxide and a base material layer (II) made of woody and fiber material.

6. 发明专利

JPH08176367A POLYPROPYLENE-BASED RESIN COMPOSITION 失效
公开(公告)号：JPH08176367A
公开(公告)日：1996-07-09
申请号：JP32073194
申请日：1994-12-22
申请人： SHOWA DENKO KK
发明人： IWASHITA TOSHIYUKI , SAIHATA AKIKO , MURAYAMA KOUSHIN , TAKOSHI HIROTAKA
IPC分类号： C08L23/10 , C08L51/00
摘要： PURPOSE: To obtain a polypropylene-based resin composition having high melt tension and good rigidity, impact resistance and moldability and especially excellent in recycling property because of slight lowering of melt tension after re-melting due to recycle uses. CONSTITUTION: This composition comprises (A) 60-98wt.% polypropylene-based resin and (B) 40-2wt.% resin-treated material obtained by subjecting the polypropylene-based resin to ionizing radiation treatment, blending 100 pts.wt. of the treated resin with 0.02-5 pts.wt. polyfunctional monomer and dynamically heat treating the blend. The resin-treated material (B) may be obtained by previously treating the polypropylene-based resin with the polyfunctional monomer before subjecting the polypropylene-based resin to ionizing radiation treatment and then subjecting the pre-treated polypropylene-based resin to ionizing radiation treatment.

7. 发明专利

JP2002105020A METHOD FOR PRODUCING LOWER ALIPHATIC CARBOXYLATE 失效
公开(公告)号：JP2002105020A
公开(公告)日：2002-04-10
申请号：JP2000291350
申请日：2000-09-26
申请人： SHOWA DENKO KK
发明人： FUJITA AYUMI , KADOWAKI ETSUKO , SAIHATA AKIKO , UCHIDA HIROSHI
IPC分类号： B01D3/14 , C07B61/00 , C07C67/04 , C07C67/08 , C07C67/54 , C07C69/14
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a lower aliphatic carboxylate, comprising subjecting a lower aliphatic carboxylic acid and a lower olefin as starting raw materials to a gas phase esterification reaction, by which the conversion of the lower aliphatic carboxylic acid can highly be improved to enhance the production of the lower aliphatic carboxylate. SOLUTION: This method for producing the lower aliphatic carboxylate, characterized by adding a lower alcohol corresponding to the hydration product of the lower olefin to the gas phase reaction product, condensing the lower aliphatic carboxylic acid with the added lower alcohol to obtain the lower aliphatic carboxylate, and then separating the lower aliphatic carboxylate.

8. 发明专利

JPH09267042A ACID CATALYST CONSISTING OF ACID SALT OF HETEROPOLY-ACID 失效
公开(公告)号：JPH09267042A
公开(公告)日：1997-10-14
申请号：JP17245696
申请日：1996-07-02
申请人： SHOWA DENKO KK
发明人： SAIHATA AKIKO , UCHIDA HIROSHI , SUZUKI TOSHIRO , SANO KENICHI
IPC分类号： B01J23/28 , B01J23/30 , B01J27/188 , B01J27/19 , B01J35/10 , C07B61/00 , C07C67/08 , C07C69/54
摘要： PROBLEM TO BE SOLVED: To produce an acid catalyst hardly causing a deterioration of activity and having a long service life by using an acid salt of a heteropoly-acid having specified values of specific surface area, fine pore volume and pore diameter, respectively and exhibiting a specified acid content value. SOLUTION: In the acid catalyst consisting of the acid salt of the heteropoly- acid having mesopores useful for various kinds of org. reactions, the acid salt of the heteropoly-acid having >=10m /g specific surface area, >=0.01cc/g fine pore volume, in which >=30% of total fine pores have >=40Å pore size and having an acid content having =120 deg.C with a gaseous polar solvent after previously drying at >=160 deg.C. In this case, an org. carboxylic acid or an org. carboxylate are used as the polar solvent.

9. 发明专利

JPH08230117A MULTILAYER LAMINATE 失效
公开(公告)号：JPH08230117A
公开(公告)日：1996-09-10
申请号：JP4059195
申请日：1995-02-28
申请人： SHOWA DENKO KK
发明人： SAIHATA AKIKO , WATANABE KAZUYUKI , NAKAGAMI SAKUYOSHI
IPC分类号： B32B21/08 , B32B27/12 , B32B27/22 , B32B27/24 , B32B27/32 , C08L21/00 , C08L23/14 , C08L23/18
摘要： PURPOSE: To provide a multilayer laminate which has excellent surface flexibility, releasing strength and embossing characteristics. CONSTITUTION: A multilayer laminate comprises at least two layers of a layer (I) made of propylene resin composition prepared at a melt flow rate (measured under the conditions of 230 deg.C and 2.16kg of a load based on JIS K 7210) of 50 to 300g/10min obtained by dynamically heat treating a blend of (A) 100 pts.wt. of propylene-α-olefin block copolymer in which the ratio η1 /η2 of the melting viscosity η1 at a shearing speed of 10 sec to the melting viscosity η2 at a shearing speed of 10 sec measured by a slit die method is 3.5 to 8, (B) 5 to 150 pts.wt. of rubberlike polymer and (C) 0.005 to 2 pts.wt. of organic peroxide and a base material layer (II) made of woody and fiber material.

10. 发明专利

JPH08217925A HEAT-SENSITIVE ADHESIVE FILM AND MULTILAYER LAMINATE MADE THEREOF 失效
公开(公告)号：JPH08217925A
公开(公告)日：1996-08-27
申请号：JP2822395
申请日：1995-02-16
申请人： SHOWA DENKO KK
发明人： NAGAOKA KOJI , TAKOSHI HIROTAKA , SAIHATA AKIKO
IPC分类号： C08J5/18 , B32B5/18 , B32B7/10 , B32B27/08 , B32B27/12 , B32B27/32 , C08K5/05 , C08K5/053 , C08K5/10 , C08K5/103 , C08L23/08
摘要： PURPOSE: To obtain a heat-sensitive adhesive film excellent in low-temperature adhesiveness and having excellent adhesion to various substrates and high heat creep resistance by mixing a specified ethylene copolymer with a polyhydric alcohol compound and a reaction promoter. CONSTITUTION: This heat-resistant adhesive film has a thickness of 10-150μm and comprises an ethylene copolymer (A) being a multi-component copolymer comprising ethylene, a radical-polymerizable acid anhydride and a radical- polymerizable comonomer other than the former anhydride and having a content of units derived from one radical-polymerizable acid anhydride of 0.1-5wt.% and a content of units derived from the other radical-polymerizable comonomer of 10-50wt.%, a polyhydric alcohol compound (B) having at least two OH groups in the molecule and a reaction promoter (C), wherein the molar ratio of the units derived from the radical-polymerizable acid anhydride of component A to the units of the hydroxyl groups of component B is 0.01-10, and the amount of component C is 0.001-20 pts.wt. per 100 pts.wt. component A.

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