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1. 发明专利

JPS5340714A PREPARATION OF **UNSATURATEDDAAACYLLCARBOXYLIC ACID ESTERS 失效
公开(公告)号：JPS5340714A
公开(公告)日：1978-04-13
申请号：JP7919975
申请日：1975-06-24
申请人： SAGAMI CHEM RES , SUMITOMO CHEMICAL CO
发明人： KONDOU SEI , MATSUI KIYOHIDE , NEGISHI AKIRA , TAKAHATA YURIKO , SUGIMOTO KIKUO
IPC分类号： C07C69/738 , B01J21/02 , B01J25/00 , B01J27/00 , B01J27/14 , B01J31/00 , B01J31/04 , C07B61/00 , C07C69/95
摘要： PURPOSE:The title compounds are obtained advantageously on a commercial base by reacting beta-alkoxyacrylic acid esters or beta, beta-dialkoxycarboxylic acid esters with allyl alcohol derivatives in the presence of a catalyst.

2. 发明专利

JPS5253839A PREPARATION OF 22*2*22DIHALOVINYL* CYCLOPROPANE CRBOXYLIC ACIDS 失效
公开(公告)号：JPS5253839A
公开(公告)日：1977-04-30
申请号：JP13125475
申请日：1975-10-30
申请人： SAGAMI CHEM RES , SUMITOMO CHEMICAL CO
发明人： KONDOU SEI , MATSUI KIYOHIDE , NEGISHI AKIRA , TAKAHATA YURIKO , SUGIMOTO KIKUO
IPC分类号： C07C61/40 , A01N53/00 , C07C51/00 , C07C67/00
摘要： PURPOSE:An alpha-acyl-UPSILON-halocarboxylic acid derivative or it reaction product with a base is allowed to react with an alkali (ne earth) metal hydroxide in ether to form a title compound useful as an intermediate for insecticides.

3. 发明专利

JPS5257142A PROCESS FOR PREPARING DIHALOVINYLLCYCLOPROPANECARBOXYLIC ACID DERIVATI VES 失效
公开(公告)号：JPS5257142A
公开(公告)日：1977-05-11
申请号：JP13125575
申请日：1975-10-30
申请人： SAGAMI CHEM RES , SUMITOMO CHEMICAL CO
发明人： KONDOU SEI , MATSUI KIYOHIDE , NEGISHI AKIRA , TAKAHATA YURIKO , SUGIMOTO KIKUO
IPC分类号： C07C69/738 , A01N53/02 , B01J31/00 , C07B61/00 , C07C67/00 , C07C69/743 , C07C253/00 , C07C255/38 , C07C313/00 , C07C319/20 , C07C323/19 , C07D307/45 , C07D307/54 , C07D333/16
摘要： PURPOSE:To obtain dihalovinylcyclopropanecarboxylic acid esters useful as intermediates for the synthesis of insecticides from easily available alpha-acri-UPSILON -unsaturated-carboxylic acid esters as starting materials via reaction of two steps.

4. 发明专利

JPH02160777A CYCLIC SULFOXIDE DERIVATIVE AND PERCUTANEOUS ABSORPTION-ACCELERATING AGENT 失效
公开(公告)号：JPH02160777A
公开(公告)日：1990-06-20
申请号：JP31395088
申请日：1988-12-14
申请人： SAGAMI CHEM RES
发明人： AOYANAGI TAKAO , YAMAMURA MARIKO , MATSUI KIYOHIDE
IPC分类号： C07D331/04 , A61K31/38 , A61K31/381 , A61K31/382 , A61P17/00 , C07D333/48 , C07D335/02 , C07D337/04
摘要： NEW MATERIAL:A cyclic sulfoxide derivative of formula I (R is H, lower alkyl or lower alkenyl; R is >=8C hydrocarbon group; n is 1-4). EXAMPLE:2-Hexadecyltetramethylene sulfoxide. USE:A drug. A percutaneous absorption-accelerating agent. The drug or agent is preferably applied directly to an injured portion of a near portion thereof for the total treatment of an injury, skin sore, muscle pain, arthritis, etc., or applied to an easily medical ingredient-absorbing site for the general treatment of organs, etc., in the body. The agent is further used in cosmetics for skin cleansing, face packing, sunburn measures, skin irritation measures, moisture treatment, etc. PREPARATION:A cyclic sulfoxide of formula II is reacted with an alkylating agent of formula: R X (X is halogen, tosyloxy, mesyloxy or trifluoromethanesulfonyloxy) preferably in a solvent such as tetrahydrofuran in the presence of a base such as NaH to readily provide the compound of formula I.

5. 发明专利

JPS6481823A POLYSULFONE BASED GRAFT COPOLYMER AND SEPARATION MEMBRANE 失效
公开(公告)号：JPS6481823A
公开(公告)日：1989-03-28
申请号：JP23742687
申请日：1987-09-24
申请人： SAGAMI CHEM RES
发明人： MATSUI KIYOHIDE , NAGASE YUTAKA
IPC分类号： B01D53/22 , B01D71/68 , B01D71/70 , B01J47/12 , C08G75/00 , C08G75/23 , C08G81/00 , C08J5/18
摘要： PURPOSE:To obtain the titled copolymer, having a structure in which hydrogens on the backbone chain aromatic ring are partially substituted by a specific polyorganosiloxane chain, specific composition and molecular weight, excellent film-forming properties and strength and high gas and liquid permeability and useful as separation membranes, etc. CONSTITUTION:The aimed copolymer, obtained by reacting a polysulfone expressed by formula I (A is bifunctional organic group having 1-2 aromatic rings) with dimethylvinylchlorosilane in the presence of n-butyllithium in a solvent to provide a dimethylvinylsilylated polysulfone, subjecting one terminated hydrosilylpolyorganopolysiloxane expressed by formula II (m is an integer of >=1), etc., to grafting reaction therewith and having a structure in which hydrogens on the backbone chain aromatic ring of the polysulfone having recurring units expressed by formula I are partially substituted by an organopolysiloxane chain expressed by formula III (R -R are alkyl, phenyl, etc.; B is O or bifunctional organic group) at 70/30-1/99 molar ratio of the recurring units expressed by formula I to the recurring units expressed by formula III and >=10,000 average molecular weight.

6. 发明专利

JPS6452728A AGENT FOR PROMOTING PERCUTANEOUS ABSORPTION 失效
公开(公告)号：JPS6452728A
公开(公告)日：1989-02-28
申请号：JP20936287
申请日：1987-08-25
申请人： SAGAMI CHEM RES
发明人： MATSUI KIYOHIDE , AOYANAGI TAKAO , SUZUKI KAZUMI
IPC分类号： A61K47/32 , A61K47/00
摘要： PURPOSE:To obtain an agent for promoting percutaneous absorption of medicine consisting of a specific polymer having pyridinium group and having extremely excellent percutaneous absorption-containing promoting effect. CONSTITUTION:An agent for promoting percutaneous absorption of medicine consisting of a polymer containing >=10mol.%, preferably >=30mol.% recurring unit expressed by the formula (R is H or lower alkyl; R is >=6C, preferably >=8C, especially >=10C hydrocarbon group; X is pair ion such as halogen anion, organic acid anion, 1/2 SO , NO or 1/2 PO ) in total recurring units and having >=800, preferably

7. 发明专利

JPS61252214A PRODUCTION OF GRAFT COPOLYMER 失效
公开(公告)号：JPS61252214A
公开(公告)日：1986-11-10
申请号：JP9334585
申请日：1985-04-30
申请人： SAGAMI CHEM RES , TOYO SODA MFG CO LTD
发明人： MATSUI KIYOHIDE , NAGASE YUTAKA , UEDA TOMOKO , UCHIKURA MASAKI
IPC分类号： C08F283/00 , C08F283/06 , C08F283/08
摘要： PURPOSE:To produce the titled copolymer of excellent gas permeability, by reacting a reaction product between a polyphenylene oxide and a strong base with a polyorganosiloxane having a reactive group on one end. CONSTITUTION:A reaction product is obtained by reacting polyphenylene oxide having repeating units of formula I (wherein A is a halogen, methyl or alkoxy) with 0.01-4 equivalent of a strong base (e.g., n-butyllithium) at 40-150 deg.C in the presence of a diamine such as N,N,N',N'-tetramethylethylenediamine. This reaction product is reacted with a polyorganosiloxane having a reactive group on one end of formula II [wherein X is a halogen, Y is 0 or a bivalent organic group, Z is an organosiloxane chain, R are ach (substituted) alkyl or (substituted) phenyl] at 0-150 deg.C to obtain a polyphenylene oxide/ polyorganosiloxane graft copolymer of formula III (wherein B are each H or formula IV and A is methyl or formula V wherein A is methyl).

8. 发明专利

JPS61249522A SELECTIVE GAS SEPARATING MEMBRANE 失效
公开(公告)号：JPS61249522A
公开(公告)日：1986-11-06
申请号：JP9334485
申请日：1985-04-30
申请人： SAGAMI CHEM RES , TOYO SODA MFG CO LTD
发明人： MATSUI KIYOHIDE , NAGASE YUTAKA , UEDA TOMOKO , UCHIKURA MASAKI
IPC分类号： B01D53/22 , B01D71/52 , B01D71/70
摘要： PURPOSE:To obtain a membrane excellent in the separation and the concentration of a gaseous mixture which has the sufficient membrane strength in a state keeping or increasing the high substance permeability and the selective separability by using polyphenyleneoxide substituted with silyl. CONSTITUTION:Polyphenyleneoxide substituted with silyl having a repeated unit shown in a formula is used. The weight mean mol.wt. of this polymer is preferably >=0.01 million. A thin membrane having 0.01-100mum thickness can be obtained by dissolving this polymer in a hydrocarbon series or ether series solvent and developing it and thereafter evaporating slowly the solvent.

9. 发明专利

JPS61178002A SEPARATION MEMBRANE OF LIQUID MIXTURE 失效
公开(公告)号：JPS61178002A
公开(公告)日：1986-08-09
申请号：JP1666785
申请日：1985-02-01
申请人： SAGAMI CHEM RES
发明人： MATSUI KIYOHIDE , ISHIHARA KAZUHIKO , SHINOHARA ISAO , NISHIDE HIROYUKI
摘要： PURPOSE:To separate a liquid mixture containing an aromatic compound having no substituent or having an electron donating nucleus substitution group from a liquid mixture containing an aromatic compound, by introducing an electron acceptive group into a polymer. CONSTITUTION:An electron acceptive group such as an aromatic group, a pyridinium group or an aromatic quinonyl group, of which the nucleus was substituted with an electron withdrawing group such as a nitro group, a cyano group, a carbonyl group, a sulfonyl group, an ammonium group or a halogen atom, is introduced into a polymer in an introducing ratio of 1-100% on the basis of a monomer mol percentage and the MW of said polymer is pref. 10,000 or more. This polymer is formed into a membrane with a thickness of 0.01-200mum. Crosslinking treatment is pref. not performed. As the separable aromatic compound, benzene, naphthalene, anthracene, furan or pyrrole having an electron donating group such as an alkyl group, a vinyl group, an aryl group or amino group as a nucleus substitution group are designated.

10. 发明专利

JPS61176608A COPOLYMER HAVING NITROPHENYL GROUP 失效
公开(公告)号：JPS61176608A
公开(公告)日：1986-08-08
申请号：JP1666885
申请日：1985-02-01
申请人： SAGAMI CHEM RES
发明人： MATSUI KIYOHIDE , ISHIHARA KAZUHIKO , SHINOHARA ISAO , NISHIDE HIROYUKI
IPC分类号： C08F20/00 , B01D71/40 , B01D71/82 , C08F8/30 , C08F20/34 , C08F20/52 , C08F220/36 , C08F220/60
摘要： PURPOSE:A novel copolymer, containing specific repeating units and nitrophenyl groups, and giving a separation membrane capable of separating a liquid mixture containing an aromatic compound effectively by forming the membrane. CONSTITUTION:A novel copolymer, obtained by radically copolymerizing for example an ethylene derivative expressed by formula I (R is H, halogen or lower alkyl; R is H, lower alkyl, phenyl, cyano, halogen OH, etc.) with an ethylene derivative, having OH or NH2, and expressed by formula II (R has the same definition as R ; R is alkylene, phenylene, phenylenealkyl or polymethylene; X and X are O or NH; p and q are 0 or 1, provided that p and q are not 0 at the same time), and reacting a nitro-substituted benzoic acid derivative with the resultant copolymer, and having repeating units expressed by formulas III and IV (n is an integer 1-3).

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