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    • 3. 发明专利
    • CONTINUOUS PROCESS FOR DETOXIFICATION OF FLY ASH, SEPARATION OF SALT AND RECYCLING
    • JPH11226558A
    • 1999-08-24
    • JP3710998
    • 1998-02-19
    • TECHNO FRONTIER KK
    • HIROSE TOMOHIROYAMAMOTO YOICHIYOKU KAZUHIKO
    • B09B3/00B09B5/00
    • PROBLEM TO BE SOLVED: To make fly ash nontoxic, to change it to a resource, to prolong the life of a final disposal space, of which the site is now extremely difficult to secure and to reduce the size required for it, by classifying fly ash into components and organically integrating their treatments. SOLUTION: Heating fly ash carries out oxidation and removal of free carbon and decomposition and detoxification of an offensive odor. Supplying this fly ash to a washing tank 3 separates the contents therein to a mud-like layer composed of precipitated water-insoluble materials and supernatant water. Water is added again to the mud-like layer which remains in the washing tank 3 again to make it slurry, then it is fed to a decomposition tank 5, and sulfuric acid is injected therein to decompose the remaining fly ash component. A liquid, which overflows the decomposition tank 5, flows into a growth tank 6 to form crystals of a solid phase therein, and a liquid, which overflows the growth tank 7, flows into a separation tank 6 to separate materials with high settling velocity from the slurry liquid. Aqueous solutions having different concentrations discharged by a solid-liquid separator 8 or the like are stored in a circulating liquid tank 10, a part of the stored solution is moved to the washing tank 3 to dissolve water-soluble materials in the fly ash, then it is discharged to a filtration and circulation tank 12 outside a circulatory system of a main liquid, and the remainder of the solution is reused as water for slurry.
    • 5. 发明专利
    • PREPARATION OF GYPSUM DIHYDRATE FROM FLY ASH AND DEVICE THEREFOR
    • JPH11343117A
    • 1999-12-14
    • JP15158198
    • 1998-06-01
    • TECHNO FRONTIER KK
    • KATSURA KAZUNARIYAMAMOTO YOICHIYOKU KAZUHIKO
    • C01F11/46B09B3/00B09B5/00
    • PROBLEM TO BE SOLVED: To reuse fly ash discarded and reclaimed at a final processing field from an incinerator as a raw material for gypsum dihydrate by combining fly ash heat processing step, fly ash slurry washing step, solid-liquid separation step, hemihydrate gypsum generating step, gypsum dihydrate generating step, slurry classification step and gypsum dihydrate separating step in this order. SOLUTION: A processing step in a fly ash heater 2 conducts to remove free carbons and org. materials being harmful or generating a malodor by oxidizing and decomposing. A washing step of the fly ash slurry conducts to make the fly ash into slurry with a part of filtrate from solid-liquid separation and water and to wash it in a cleaning vessel 5. A hemihydrate gypsum generating step conducts to generate the hemihydrate gypsum by adding water or a liquid filterate, a gypsum dihydrate slurry cooled with a cooler and sulfuric acid to a cake from the solid-liquid separation in a reactor 8. A slurry classification step conducts to classify the slurry into a slurry having smaller particle size and a slurry having larger particle size in a crystal classification vessel 12. A gypsum dihydrate separating step conducts to separate the gypsum dihydrate from the slurry enriched with larger size particles in a solid-liquid separating equipment 13.