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    • 1. 发明专利
    • WATER-BASED PIGMENT COMPOSITION
    • JPH07145289A
    • 1995-06-06
    • JP31911793
    • 1993-11-25
    • PENTEL KK
    • KATO AKIMITSUKOBAYASHI YUICHI
    • C08L33/04C09D5/06C09D167/00C09D167/02
    • PURPOSE:To provide a water-based pigment composition resistant to water, useful as a watercolor paint, poster color, etc., comprising a pigment, primer consisting of an acrylic alkali-soluble resin, thickening agent consisting of a specific acrylic copolymer, high-boiling water-soluble organic solvent and water. CONSTITUTION:The objective composition useful as a water-resistant watercolor paint or poster color, etc., comprising (A) a pigment (e.g. carbon black), (B) a primer consisting of an acrylic alkali-soluble and/or resin dispersion (e.g. acrylic acid-butyl acrylate copolymer ammonium salt), (C) a thickening agent consisting of a copolymer from acrylic acid and a 10-30C alkyl methacrylate (e.g. acrylic acid-dodecyl methacrylate copolymer), (D) a high-boiling water-soluble organic solvent (e.g. glycerin) and (E) water. This pigment composition seldom develops its phase separation with time, being slow in water-resistant film formation on the surface when provided on e.g. a pallet without delaying its dryability when applied.
    • 7. 发明专利
    • LIQUID ERASER
    • JPH04164974A
    • 1992-06-10
    • JP29341890
    • 1990-10-30
    • PENTEL KK
    • YAMADA NORIOKATO AKIMITSU
    • C09D10/00
    • PURPOSE:To obtain a liquid eraser having an excellent adaptability to rewriting such that it is free from a color sinking phenomenon when rewriting is made on the surface treated therewith by mixing a masking agent, an organic solvent, a resin soluble in the organic solvent, and a dicarboxylic acid (anhydride). CONSTITUTION:A liquid eraser is obtained by mixing a masking agent (e.g. preferably titanium oxide), an organic solvent (e.g. xylene), a resin soluble in this solvent (e.g. acrylic resin), and a dicarboxylic acid and/or its anhydride (e.g. phthalic anhydride). It is a liquid eraser having an excellent adaptability to rewriting such that it is free from the so-called color sinking phenomenon, i.e., a decrease in the density of a writing, when rewriting is made on the film of the applied eraser with a marking pen, a ball point pen, a writing brush, etc., using a water-base ink.
    • 10. 发明专利
    • WATER BASE FLUORESCENT PIGMENT COMPOSITION
    • JPH1067963A
    • 1998-03-10
    • JP24558696
    • 1996-08-28
    • PENTEL KK
    • KATO AKIMITSU
    • C09K11/02C09B67/46C09D5/06C09D133/00
    • PROBLEM TO BE SOLVED: To obtain a water base fluorescent pigment composition without thickening even stored at a high temperature and useful as a water-resistant poster color, etc., by containing an acrylic resin-based fluorescent pigment, an acrylic ester-based emulsion and water. SOLUTION: This composition contains (A) an acrylic resin-based fluorescent pigment, (B) an acrylic ester-based emulsion [e.g. an emulsion of a copolymer of an ester such as butyl methacrylate or a (meth)acrylate] and (C) water. As the component A, a composition obtained by mixing a pigment having strong fluorescence such as C.I. basic yellow 44 into a styrene-acrylonitrile-based copolymer is exemplified. Preferably, 10-40wt.% of the component A and 5-30wt.% of a solid fraction of the component B are mixed to the whole amount of the objective composition. A body pigment such as silicone oxide or an organic solvent such as sorbitol can be mixed in the composition, as necessary. A thickener such as carboxymethyl cellulose in an amount of 0.05-2wt.% based on the whole weight of the composition may be mixed.