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1. 发明专利

JP2009061136A Method for biological activation of metallic glass and biologically activated metallic glass 审中-公开
标题翻译：金属玻璃和生物活性金属玻璃的生物活化方法
公开(公告)号：JP2009061136A
公开(公告)日：2009-03-26
申请号：JP2007232225
申请日：2007-09-07
申请人： Osaka Univ , Tohoku Univ , Tokyo Institute Of Technology , 国立大学法人大阪大学 , 国立大学法人東京工業大学 , 国立大学法人東北大学
发明人： YOSHIMURA MASAHIRO , ONOKI NORISHIGE , YASUDA EIICHI , WATANABE TOMOSUKE , TANABE YASUHIRO , AKAO MASARU , MATSUSHITA NOBUHIRO , SUGIYAMA NAOHIRO , HOSHIKAWA YASUTO , NAITO MAKIO , TSUKAMOTO MASAHIRO , KOMIZO YUICHI , ABE HIROYA , ABE NOBUYUKI , INOUE AKIHISA , WANG XINMIN , WADA TAKESHI , AKE KATSUTOSHI , HATA FUGA , FUKUHARA MIKIO
IPC分类号： A61L27/00
摘要： PROBLEM TO BE SOLVED: To provide a method for the biological activation of a metallic glass surface and a biologically activated metallic glass.
SOLUTION: A base metallic glass material is filled up in an autoclave for hydrothermal hot press, together with a powder of mixture of calcium II hydrate hydrogenphosphate and calcium hydroxide, and kept pressurized at a temperature of 50 to 300°C for 30 to 720 minutes. The biologically activated metallic glass manufactured by this process includes an intermediate layer between the base metallic glass material and the hydroxyapatite layer.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供金属玻璃表面和生物活化金属玻璃的生物活化的方法。解决方案：将碱金属玻璃材料与用于水热热压的高压釜以及II型二水合磷酸氢钙和氢氧化钙的混合物粉末填充，并在50至300℃的温度下保持加压30 至720分钟。通过该方法制造的生物活化金属玻璃包括在基底金属玻璃材料和羟基磷灰石层之间的中间层。版权所有（C）2009，JPO＆INPIT

2. 发明专利

JP2009061135A Biological activation material 审中-公开
标题翻译：生物活性材料
公开(公告)号：JP2009061135A
公开(公告)日：2009-03-26
申请号：JP2007232224
申请日：2007-09-07
申请人： Osaka Univ , Tohoku Univ , Tokyo Institute Of Technology , 国立大学法人大阪大学 , 国立大学法人東京工業大学 , 国立大学法人東北大学
发明人： YOSHIMURA MASAHIRO , ONOKI NORISHIGE , YASUDA EIICHI , WATANABE TOMOSUKE , TANABE YASUHIRO , AKAO MASARU , MATSUSHITA NOBUHIRO , SUGIYAMA NAOHIRO , HOSHIKAWA YASUTO , NAITO MAKIO , TSUKAMOTO MASAHIRO , KOMIZO YUICHI , ABE HIROYA , ABE NOBUYUKI , INOUE AKIHISA , WANG XINMIN , WADA TAKESHI , AKE KATSUTOSHI , HATA FUGA , FUKUHARA MIKIO
IPC分类号： A61L27/00 , A61F2/28
摘要： PROBLEM TO BE SOLVED: To provide a biological activation material where the metallic glass surface of the material is firmly connected with HAp because of similarities between the network of the metallic glass surface and the network of bio-tissues, and connections with HAp are more strengthened with an oxide as roots and component of interfaces with HAp.
SOLUTION: The inner metallic glass is porous and has an elastic modulus and a high strength similar to those of human bones. The biological activation material surface made of biological ceramics having biological affinity or a material inducing it is deposited on the metallic glass surface through intermediate layers.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种生物活化材料，其中材料的金属玻璃表面与HAp牢固地连接，因为金属玻璃表面的网络和生物组织的网络之间的相似性以及与HAp的连接更加强化了氧化物作为HAp接口的根和组成部分。解决方案：内金属玻璃是多孔的，并且具有类似于人骨的弹性模量和高强度。由具有生物亲和力的生物陶瓷制成的生物活化材料表面或诱导材料的材料通过中间层沉积在金属玻璃表面上。版权所有（C）2009，JPO＆INPIT

3. 发明专利

JP2009034369A Biomaterial 有权
标题翻译：生物材料
公开(公告)号：JP2009034369A
公开(公告)日：2009-02-19
申请号：JP2007201691
申请日：2007-08-02
申请人： Tohoku Univ , Tokyo Institute Of Technology , 国立大学法人東京工業大学 , 国立大学法人東北大学
发明人： INOUE AKIHISA , WANG XINMIN , AKE KATSUTOSHI , KIMURA HISAMICHI , YOSHIMURA MASAHIRO , ONOKI NORISHIGE
IPC分类号： A61L27/00
摘要： PROBLEM TO BE SOLVED: To provide a biomaterial having low rigidity, high strength, and excellent corrosion resistance.
SOLUTION: The biomaterial contains a metallic glass alloy having a composition of formula: (Ti
1-a-b-c Cu
a Zr
b Pd
c )
100-x M
x (wherein a, b and c are atomic ratios: a is 0.3-0.5; b is 0.005-0.2, and c is 0.005-0.2; x is atomic percent and is 0.5-2 atomic percent; M is an element selected from at least one of HA, CaTiO
3 and CaZrO
3 ). Alternatively, the biomaterial contains a metallic glass alloy having a composition of formula: (Ti
1-a-b-c Cu
a Zr
b Pd
c )
100-x Ca
x (wherein a, b and c are atomic ratios: a is 0.3-0.5, b is 0.005-0.2, and c is 0.005-0.2 and x is atomic percent and is 0.5-10 atomic percent).
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供刚性低，强度高，耐腐蚀性优异的生物材料。解决方案：生物材料包含具有下式的组成的金属玻璃合金：（Ti <1> a> b> （其中a，b和c是原子比：a是0.3-0.5; b是0.005-0.2，其中a，b和c是原子比：a是0.3-0.5; b是0.005-0.2， c为0.005〜0.2; x为原子百分数，为0.5〜2原子％; M为选自HA，CaTiO 3，SB 3，Ca 3 O 3，SB 3，）。或者，生物材料含有具有下列组成的组成的金属玻璃合金：（Ti 1-abc （其中a，b和c为原子比：a为0.3-0.5，b为0.005-0.2，c为 0.005-0.2，x为原子百分数，为0.5-10原子％）。版权所有（C）2009，JPO＆INPIT

4. 发明专利

JP2010279905A Compound hydrogen permeable membrane 审中-公开
标题翻译：化合物渗透膜
公开(公告)号：JP2010279905A
公开(公告)日：2010-12-16
申请号：JP2009135581
申请日：2009-06-04
申请人： Tohoku Univ , Tokyo Institute Of Technology , 国立大学法人東京工業大学 , 国立大学法人東北大学
发明人： YAMAURA SHINICHI , CHO ISAMU , INOUE AKIHISA , TAWARAYAMA HIROMASA , HOSONO HIDEO
IPC分类号： B01D71/02 , B01D69/12 , B01J23/755 , C01B3/16
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a compound hydrogen permeable membrane whose hydrogen permeating speed is comparable to that of a Pd membrane. SOLUTION: The compound hydrogen permeable membrane 1 includes a metal alloy substrate 2 having hydrogen permeability, oxide glass layers 3, 5 covering the metal alloy substrate 2, and catalyst layers 4, 6 covering the oxide glass layers 3, 5. The metal alloy substrate 2 consists of a Ni-Nb-Zr alloy, the oxide glass layers 3, 5 consist of tungsten oxide-containing phosphate glass having mixed conductivity of protons and electrons, and the catalyst layers 4, 6 consist of a transition metal such as Ni and Pd. The compound hydrogen permeable membrane 1 has high mechanical strength and stably functions for a long period of time. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供氢透过速度与Pd膜相当的复合氢透过膜。解决方案：复合氢透过膜1包括具有透氢性的金属合金基板2，覆盖金属合金基板2的氧化物玻璃层3,5和覆盖氧化物玻璃层3,5的催化剂层4,6。金属合金基板2由Ni-Nb-Zr合金构成，氧化物玻璃层3,5由具有质子和电子的导电性的混合物的含氧化钨的磷酸盐玻璃组成，催化剂层4,6由过渡金属作为Ni和Pd。复合氢渗透膜1具有高的机械强度并且长时间稳定地起作用。版权所有（C）2011，JPO＆INPIT

5. 发明专利

JP2008214704A Amorphous metal or metal glass joined body 审中-公开
标题翻译：非晶金属或金属玻璃接合体
公开(公告)号：JP2008214704A
公开(公告)日：2008-09-18
申请号：JP2007055093
申请日：2007-03-06
申请人： Osaka Univ , Tohoku Univ , 国立大学法人大阪大学 , 国立大学法人東北大学
发明人： NOSHIRO KIYOSHI , NAKADA KAZUHIRO , KURODA TOSHIO , TAKEMOTO TADASHI , FUJII HIDETOSHI , ABE HIROYA , TSUMURA TAKUYA , MAEDA MASAKATSU , TERAJIMA TAKESHI , NISHIKAWA HIROSHI , INOUE AKIHISA , KIMURA HISAMICHI , CHO ISAMU , DMITRI LOUZGUINE , FUKUHARA MIKIO , WANG XINMIN , WADA TAKESHI , SHA KOKUKYO , SEKI ICHIRO
IPC分类号： C22C45/00 , B23K1/19 , B23K11/16 , B23K20/00 , B23K20/10 , B23K20/12 , B23K26/32 , B23K103/18
摘要： PROBLEM TO BE SOLVED: To provide a joined body which is small in ΔT(=Tx-Tg) (Tx: crystallization temperature, Tg: glass point) and in which a joined surface is not crystallized in an amorphous metal or metal glass. SOLUTION: There is provided the amorphous metal joined body obtained by joining the amorphous metal having an irregular crystal structure by a thermal method or a method using plastic deformation. Particularly, the joined body has a nanocrystal precipitated in a joint portion. Also, the metal glass having an extensive supercooling liquid region and a distinct glass transition point is joined by the thermal method or the method using the plastic deformation. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供ΔT（= Tx-Tg）（Tx：结晶温度，Tg：玻璃点）小的接合面在非晶金属或金属中未结晶的接合体玻璃。解决方案：提供通过热法或使用塑性变形的方法将具有不规则晶体结构的非晶态金属接合而获得的非晶金属接合体。特别是，接合体具有在接合部分析出的纳米晶体。另外，通过热法或使用塑性变形的方法将具有广泛的过冷液体区域和不同的玻璃化转变点的金属玻璃接合。版权所有（C）2008，JPO＆INPIT

6. 发明专利

JP2012158794A Cu-FREE, Zr-BASED METAL GLASS ALLOY 有权
标题翻译：无铜，基于Zr的金属玻璃合金
公开(公告)号：JP2012158794A
公开(公告)日：2012-08-23
申请号：JP2011018717
申请日：2011-01-31
申请人： Tohoku Univ , 国立大学法人東北大学
发明人： CHO ISAMU , INOUE AKIHISA
IPC分类号： C22C45/10
摘要： PROBLEM TO BE SOLVED: To provide a Cu-free, Zr-based metal glass alloy that has a large amorphous-forming ability and is excellent in mechanical properties, workability and corrosion resistance.SOLUTION: The Cu-free, Zr-based metal glass alloy includes a composition represented by the formula: ZrAlNiMB(wherein x and y satisfy the relations: 10≤x≤19 and 15≤y≤28, respectively; M is Nb or Ta; z satisfies the relation: 0 0.54 and a γ value of ≥0.38, is in a rod shape with a diameter of ≥2 mm and has compression fracture strength of ≥1,650 MPa. The Cu-free, Zr-based metal glass alloy is superior to conventional ternary to penternary Zr-based metal glass alloys in terms of resistance to corrosion against HCl and NaCl solutions.
摘要翻译：要解决的问题：提供一种具有大的非晶形成能力且机械性能，加工性和耐腐蚀性优异的无Cu的Zr基金属玻璃合金。解决方案：无Cu的Zr基金属玻璃合金包括由下式表示的组成：Zr 75-xyz A1 x a Ni Ni Ni Ni Ni y y y y y y y y y y y y y y>>>>>>>>>>>>>>>>>>>>>>>>>>>>> y满足关系：10≤x≤19和15≤y≤28; M为Nb或Ta; z满足关系：0 0.54，γ值≥0.38，直径≥2mm的棒状，具有压缩断裂强度≥1650MPa。对于HCl和NaCl溶液的耐腐蚀性，无Cu，Zr基金属玻璃合金优于常规三元Zr基金属玻璃合金。版权所有（C）2012，JPO＆INPIT

7. 发明专利

JP2011231351A Co-BASED METALLIC GLASS ALLOY, MAGNETIC CORE, ELECTRO-MAGNETIC TRANSDUCER AND CLOCK 有权
标题翻译：共基金属玻璃合金，磁芯，电磁传感器和时钟
公开(公告)号：JP2011231351A
公开(公告)日：2011-11-17
申请号：JP2010100625
申请日：2010-04-26
申请人： Seiko Epson Corp , Tohoku Univ , セイコーエプソン株式会社 , 国立大学法人東北大学
发明人： MASAI SATOSHI , TSUCHIYA KAZUHIRO , INOUE AKIHISA , KATO HIDEMI
IPC分类号： C22C45/04 , B22F3/105 , C22C1/04 , H01F1/153 , H01F1/22 , H01F27/24
摘要： PROBLEM TO BE SOLVED: To provide a Co-based metallic glass alloy which stably exists as a metallic glass having a wide supercooled liquid temperature region ΔTx and a large conversion glass transition temperature Tg/Tl.SOLUTION: The Co-based metallic glass alloy has high magnetic permeability and contains Fe, Ni, B, Si, Nb, Mo, and Cr in a content by atom% of, 2-6, 4 or less, 15-20, 8-13, 3 or less, 0.1-1, and 2 or less, respectively, and the balance being Co. The content ratio of Co and Fe is Co:Fe=95.2:4.8, and the allowable range of each value of Co and Fe which shows the content ratio is ±0.3 or less, respectively.
摘要翻译：要解决的问题：提供一种作为金属玻璃稳定存在的Co基金属玻璃合金，其具有宽的过冷液体温度区域ΔTx和大的转化玻璃化转变温度Tg / T1。解决方案：Co基金属玻璃合金具有高磁导率，含有原子％为2-6,4或15以下的Fe，Ni，B，Si，Nb，Mo和Cr， 20,8-13,3或更低，0.1-1和2以下，余量为Co。Co和Fe的含量比为Co:Fe = 95.2：4.8，各值的容许范围的含量比分别为±0.3以下的Co和Fe。版权所有（C）2012，JPO＆INPIT

8. 发明专利

JP2011144416A Highly conductive amorphous alloy, highly conductive amorphous alloy for light electric application and highly conductive amorphous alloy for power application 审中-公开
标题翻译：高导电非晶合金，用于轻电力的高导电非晶合金和用于电力应用的高导电非晶合金
公开(公告)号：JP2011144416A
公开(公告)日：2011-07-28
申请号：JP2010005380
申请日：2010-01-14
申请人： Tohoku Univ , 国立大学法人東北大学
发明人： FUKUHARA MIKIO , INOUE AKIHISA
IPC分类号： C22C45/10 , B82B1/00 , C22C45/04 , H01B1/02 , H01L21/3205 , H01L23/52
摘要： PROBLEM TO BE SOLVED: To provide a highly conductive amorphous alloy operable at a temperature ranging from low temperature to room temperature using single electron tunneling, a highly conductive amorphous alloy for light electric application, and a highly conductive amorphous alloy for power application.
SOLUTION: The highly conductive amorphous alloy has an integrated nanostructure in which a plurality of isolated metal clusters having conducting islands are continuously aligned via sub-nanoscale insulating layers. The highly conductive amorphous alloy is composed so that electrons can perform tunneling between individual metal clusters via the conducting islands at a temperature ranging from extremely low temperature to 500°C and exerts ballistic conductivity for both direct current and alternating current. Here, sub-nanoscale atomic vacancies are uniformly distributed between individual metal clusters. The highly conductive amorphous alloy may comprise an Ni-Nb-Zr amorphous alloy or a Ti-Ni-Cu amorphous alloy wherein hydrogen atoms invade and are solid-dissolved in gaps between the individual metal clusters.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种可在低温至室温范围内使用单电子隧道工作的高导电非晶合金，用于光电应用的高导电非晶态合金和用于电力应用的高导电非晶合金。解决方案：高导电非晶合金具有集成的纳米结构，其中多个具有导电岛的隔离金属簇通过亚纳米级绝缘层连续排列。高导电性非晶合金构成为使电子能够在极低温至500℃的温度范围内经由导电岛进行各金属簇之间的隧道化，并对直流电和交流电都施加弹道导电性。这里，亚纳米级原子空位均匀分布在各个金属簇之间。高导电性非晶合金可以包含Ni-Nb-Zr非晶合金或Ti-Ni-Cu非晶合金，其中氢原子侵入并固体溶解在各个金属簇之间的间隙中。版权所有（C）2011，JPO＆INPIT

9. 发明专利

JP2010255053A Metallic glass composite structure and method for producing metallic glass composite structure 有权
标题翻译：金属玻璃复合结构和金属玻璃复合结构生产方法
公开(公告)号：JP2010255053A
公开(公告)日：2010-11-11
申请号：JP2009107145
申请日：2009-04-24
申请人： Tohoku Univ , 国立大学法人東北大学
发明人： SHA KOKUKYO , INOUE AKIHISA , LOUZGUINE DMITRI VALENTINOVICH , KIMURA HISAMICHI , RI MATSU
IPC分类号： C22C45/00 , B22F3/14 , B22F9/08 , C22C45/02 , C22C45/04
摘要： PROBLEM TO BE SOLVED: To provide a metallic glass composite structure that can easily achieve various characteristics such as ductility and to provide a method for easily producing a metallic glass composite structure in a large dimension.
SOLUTION: The metallic glass composite structure 30 has a structure containing a plurality of metallic glass phases having different structural metal elements. The structure is produced by preparing a metallic glass particle mixture 10 comprising a mixture of a plurality of kinds of metallic glass particles 11, 12 and sintering the mixture by a discharge plasma sintering method or the like.
COPYRIGHT: (C)2011,JPO&INPIT

10. 发明专利

JP2010184284A Method and structure for joining aluminum base material 有权
标题翻译：接合铝基材料的方法与结构
公开(公告)号：JP2010184284A
公开(公告)日：2010-08-26
申请号：JP2009031539
申请日：2009-02-13
申请人： Nissan Motor Co Ltd , Tohoku Univ , 国立大学法人東北大学 , 日産自動車株式会社
发明人： MIYAMOTO KENJI , NAKAJIMA YASUSHI , NAKAGAWA NARIYUKI , SAKAMOTO HIRONORI , INOUE AKIHISA , KIMURA HISAMICHI , SEKI ICHIRO
IPC分类号： B23K20/00
摘要： PROBLEM TO BE SOLVED: To provide a joining method for aluminum base material by which the aluminum base materials are joined with high strength at low temperature without using a flux for removing an oxidized coating film, and the cost is reduced by eliminating the need of a flux cleaning stage after joining, and to provide a joining structure by the joining method.
SOLUTION: In the state that an intermediate material 3 composed of metallic glass containing an element, for example La, whose standard generated free energy of oxidation is smaller than aluminum and having the melting point lower than that of the materials to be joined is interposed between materials 1, 2 to be joined consisting of aluminum or an aluminum alloy, the intermediate material 3 is heated to the temperature to the melting point or above of the intermediate material 3 and the melting point or below of the materials 1, 2 to be joined, so that the materials 1, 2 to be joined are joined without using the flux.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了提供铝基材料的接合方法，铝基材料在低温下以高强度接合而不使用用于除去氧化涂膜的助熔剂，并且通过消除在接合之后需要焊剂清洁级，并且通过接合方法提供接合结构。解决方案：在由含有标准产生氧化自由能小于铝并且熔点低于待接合材料的熔点的金属玻璃构成的中间材料3的状态下，介于由铝或铝合金构成的待连接的材料1,2之间，将中间材料3加热至中间材料3的熔点或高于熔点或熔点以下的材料1,2 以使待接合的材料1,2不使用助焊剂而接合。版权所有（C）2010，JPO＆INPIT

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