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    • 3. 发明专利
    • FORMATION OF SILICON SINGLE CRYSTALLINE FILM
    • JPH03283610A
    • 1991-12-13
    • JP8447490
    • 1990-03-30
    • OKI ELECTRIC IND CO LTD
    • ARAKAWA TOMIYUKIFUKUDA HISASHI
    • H01L21/205
    • PURPOSE:To acquire an Si single crystalline film of little defect by attracting an element of organic raw gas including Si to a foundation in a first heating treatment process and by forming Si on the foundation making Si remain on the foundation in a second heating treatment process. CONSTITUTION:A valve 27 is closed, valves 28, 53, 55 are opened, and heat treatment is carried out in an organic raw gas atmosphere including Si by a heating part 12; thereby, organic raw gas element including Si is attracted on a surface of a substrate 15 by monoatomic layer. Then, the valve 55 is closed to stop supply of raw gas, and the valves 28, 53 are closed and the valve 27 is opened to carry out second heating; thereby, Si alone of element including Si remains and Si of monoatomic layer is formed. Since an Si single crystalline film of a desired thickness is formed by repeating the attraction and release, it is possible to control a film thickness on an atomic layer level and to form an Si single crystalline film of little defect. It is desirable to heat the substrate 15 by infrared irradiation.
    • 4. 发明专利
    • FORMATION OF INSULATING FILM
    • JPH03160720A
    • 1991-07-10
    • JP29954689
    • 1989-11-20
    • OKI ELECTRIC IND CO LTD
    • ARAKAWA TOMIYUKIFUKUDA HISASHI
    • H01L21/316H01L21/28H01L21/306H01L21/314H01L29/51
    • PURPOSE:To improve controllability with respect to film thickness and dielectric breakdown strength by performing heat treatment in an atmosphere of an oxidizing gas which does not contain nitrogen after performing heat treatment one after another in an atmosphere of a reduction gas or in an atmosphere of a reactive gas as a cleaning measure for a silicon substrate and then, forming a 2nd insulating film on a 1st insulating film by treating the insulating film with heat in an atmosphere of dinitrogen monoxide. CONSTITUTION:Heat treatment is performed in an atmosphere of a reduction gas as a cleaning measure for a silicon substrate and then, a natural oxidation film is reduced by the reduction gas. As heat treatment is performed in an atmosphere of a reactive gas, the reactive gas that is thermally activated chemically reacts to impurities attached to the substrate and then, volatilization of its gas is performed. Since 1st and 2nd insulating films, further, are formed on the silicon substrate, for free bonds existing in the oxide film, i.e., the 1st insulating film, nitrogen atoms which exist in nitrogen oxide film, i.e., the 2nd insulating film enter into the oxide film, then newly Si-N bonding and O-N bonding are generated and the free bonds decrease. In this way, the insulating films which are superior in controllability with respect to film thickness, dielectric breakdown strength, and thin film quality are obtained.
    • 5. 发明专利
    • FORMATION OF INSULATING FILM
    • JPH03154340A
    • 1991-07-02
    • JP29367089
    • 1989-11-10
    • OKI ELECTRIC IND CO LTD
    • ARAKAWA TOMIYUKIFUKUDA HISASHI
    • H01L21/316
    • PURPOSE:To form an insulating film that is superior in film quality by forming the insulating film which has specific film thickness at a base after performing heat treatment in an atmosphere of an oxidizing gas and after that, in a state that a certain heat treatment temperature is maintained, by performing heat treatment continuously in an atmosphere of an inactive gas. CONSTITUTION:An oxidizing gas, e.g. an oxygen gas is supplied in a reaction furnace 10 in order to form an insulating film having a film thickness of less than about 100Angstrom on a substrate 18 by performing heat treatment in an atmo sphere of the oxidizing gas and an oxide film is formed on the surface of the substrate after heating the substrate 18 by giving heat treatment to a heating part 16. Then, an inactive gas, e.g. an Ar gas is supplied in the reaction furnace 10 in a state that a certain heat treatment temperature in the case of forming the oxide film is maintained for the substrate 18 on which the oxide film is formed and heat treatment is carried out for hours desired. As a result, after insulating films are formed, the insulating films which are not bonded yet and have weak bonding are lessened by heat treatment in an atmosphere of the inactive gas. Each insulating film which has the film thickness of less than about 100Angstrom and is superior in film quality is thus formed.
    • 7. 发明专利
    • MANUFACTURE OF OPTICAL WAVEGUIDE
    • JPH11231160A
    • 1999-08-27
    • JP5290298
    • 1998-02-17
    • OKI ELECTRIC IND CO LTD
    • ARAKAWA TOMIYUKI
    • G02B6/13
    • PROBLEM TO BE SOLVED: To provide an optical waveguide manufacturing method which can easily embed an upper clad even when the ratio of the height of a core and the distance between the cores is large and can manufacture a high-precision optical waveguide. SOLUTION: This method for manufacturing the optical waveguide in which cores and a clad layer surrounding the cores are formed on a substrate includes a process for forming a lower clad layer on the substrate 11, a process for forming the core layer over the entire top surface of the lower clad layer, a process for forming the cores of the core layer, a process for forming a 1st upper clad layer 16 of specific thickness over the entire top surface of the lower clad layer and cores, a process for forming an inorganic SOG(spin on glass) film 17 in a groove 16a formed between the cores, and a process for forming a 2nd upper clad layer 18 over the entire top surface of the 1st upper clad layer and inorganic SOG film. Since the inorganic SOG film is formed, the ratio of the width and height of the groove is decreased to reduce the tilt of a side wall part.
    • 10. 发明专利
    • METHOD AND DEVICE FOR FORMING OXIDE FILM
    • JPH03134153A
    • 1991-06-07
    • JP26975989
    • 1989-10-17
    • OKI ELECTRIC IND CO LTD
    • FUKUDA HISASHIARAKAWA TOMIYUKI
    • C23C8/12F27D7/02H01L21/31H01L21/316
    • PURPOSE:To form an oxide film having excellent film quality at a desired film thickness by incorporating gaseous ozone into an oxidating gas at the time of introducing the oxidizing gas into a reaction furnace and subjecting a substrate to a rapid heating treatment. CONSTITUTION:The gas for purging (inert gas, etc.) is introduced from a gas source 14a into the reaction furnace 10 and the substrate 18 subjected to cleaning after oxidizing is is fixed onto a base 20 of a lifting member 10c. The inside of the reaction chamber 10 is evacuated to a vacuum by a discharge means 12 and an ozone generator 51 is operated to supply gaseous oxygen from an oxidizing gas source 14b to introduce the oxidizing gas contg. the gaseous ozone into the reaction furnace 10, by which the prescribed reduced pressure state is maintained. The substrate 18 is heated in this state by an IR lamp 16a of a heating section 16 to form the oxide film on the surface of the substrate 18; thereafter, the heating of the substrate 18 is stopped and the substrate is cooled. The substrate is then taken out of the reaction furnace 10. The desired oxide film is obtd. at about 1000 deg.C and the generation of a slip in the substrate 18 is obviated.