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1. 发明专利

JPH0539673A REINFORCING METHOD FOR STRUCTURE 失效
公开(公告)号：JPH0539673A
公开(公告)日：1993-02-19
申请号：JP22093691
申请日：1991-08-06
申请人： OHBAYASHI CORP , MITSUBISHI CHEM IND
发明人： SAWANOBORI TAKEO , TANAKA TSUNEO , SATO SHOICHI , SHIMAMOTO KATSUJI , OBATA KATSURO
IPC分类号： B29C63/02 , B29K101/10 , B29K105/08 , E04G23/02
摘要： PURPOSE:To harden a fiber-reinforced composite material in a short time with good workability regardless of the change of the environmental conditions, e.g. temperature in particular, and concurrently attain the storage stability of the fiber-reinforced composite material and the short-time hardening at the site. CONSTITUTION:A fiber-reinforced composite material impregnated with a resin composition material containing thermosetting resin and practically containing no hardening agent of resin into fibers is stuck on the surface of a structure element to be reinforced of a structure. A solution containing the hardening agent of the thermosetting resin and a solvent is coated on the fiber-reinforced composite material, and it is dried and hardened.

2. 发明专利

JPH0539674A REINFORCING METHOD FOR STRUCTURE 失效
公开(公告)号：JPH0539674A
公开(公告)日：1993-02-19
申请号：JP22093791
申请日：1991-08-06
申请人： OHBAYASHI CORP , MITSUBISHI CHEM IND
发明人： SAWANOBORI TAKEO , TANAKA TSUNEO , SATO SHOICHI , SHIMAMOTO KATSUJI , OBATA KATSURO
IPC分类号： B29C63/02 , B29C70/06 , B29K105/08 , E01D19/02 , E01D22/00 , E01D101/40 , E04C5/07 , E04G23/02
摘要： PURPOSE:To efficiently reinforce a structure by sticking a plate bode impregnated with resin into reinforcing fibers and the like on the surface of a structure element to be reinforced of a structure, coating a solution containing a hardening agent and a solvent, and drying and hardening it. CONSTITUTION:Resin such as phenol resin and epoxy resin serving as a matrix is impregnated into a uniaxial orientation object, a woven fabric, and a nonwoven fabric of fibers such as carbon fibers and glass fibers used as reinforcing fibers to form a plate shape with the thickness of about 0.1-2mm. This plate body is stuck on the surface of a structure element to be reinforced of a structure, a solution containing a hardening agent such as hexamethylenetetramine and aliphatic diamine and a solvent such as ethanol is coated, and it is dried and hardened by forced hot-air drying and the like. The solution is hardened in a short time with good workability regardless of the change of temperature, and the structure can be efficiently reinforced.

3. 发明专利

JPH04218179A TAPERED PIPE-LIKE BODY 失效
公开(公告)号：JPH04218179A
公开(公告)日：1992-08-07
申请号：JP7124091
申请日：1991-04-03
申请人： MITSUBISHI CHEM IND
发明人： SAWANOBORI TAKEO , SHINTANI SHUJI , MITOMA MASATAKA
IPC分类号： A63B53/10 , A63B102/32 , B29C70/06 , B29K105/10 , B29L31/52
摘要： PURPOSE:To improve the tortional rupture strength of a shaft by laminating a reinforcing layer on an layer in the tip of a pipe-like body amd then 0 deg. layer thereon in the tip part of the pipe-like body. CONSTITUTION:A reinforcing layer is formed of reinforcing fibers angled at least 30 deg.C preferably 35-45 deg. to the axis of a pipe-like body to improve the tortional strength. Desirably at least 30t/mm , further desirably 35-70t/mm of tension elastic modulus is used for the reinforcing fibers used in the reinforcing layer. An amount and orientation angle of a prepreg body used for the reinforcing layer is determined such that strain generated in an angular layer allowable strain or less of high property fibers when the pipe-like body is twisted with a predetermined force. The obliquely crossing reinforcing layer wound around the tip of the pipe-like body and a thermocontracting tape wound around the pipe-like laminated body wound around in a desired laminating order are set at a temperature necessary to set matrix resin in a heating furnace and then a core is removed to provide a desired pipe-like body.

4. 发明专利

JPH03121134A THERMOSETTING FIBER-REINFORCED COMPOSITE MATERIAL OF REMARKABLE IMPROVED WEATHERING RESISTANCE 失效
公开(公告)号：JPH03121134A
公开(公告)日：1991-05-23
申请号：JP25816489
申请日：1989-10-03
申请人： MITSUBISHI CHEM IND
发明人： SAWANOBORI TAKEO , TANAKA TSUNEO , SHIMAMOTO KATSUJI
IPC分类号： C08J5/10
摘要： PURPOSE:To obtain the title material improved in weathering resistance by mixing a matrix resin with a long-fiber reinforcement and a short-fiber or particulate carbonaceous material. CONSTITUTION:100 pts.wt. matrix resin (e.g. epoxy resin) is mixed with 10-80vol.%, based on the composite material, long-fiber reinforcement (e.g. glass fiber) and 1.0-30 pts.wt. carbonaceous material which is in the form of a short fiber having a length of 0.1-50mm or a particle having a diameter of 25-100mum, a specific surface area of 20-1000m /g and a DBP absorption of 24-200cc/100g, desirably a short carbon fiber or carbon black.

5. 发明专利

JPH01230655A CONDUCTIVE RESIN COMPOSITION 失效
公开(公告)号：JPH01230655A
公开(公告)日：1989-09-14
申请号：JP5708388
申请日：1988-03-10
申请人： MITSUBISHI CHEM IND
发明人： KOBAYASHI SHIN , MATSUKI AKIHIRO , SATO SHIN , SAWANOBORI TAKEO
IPC分类号： C08K3/04 , C08K3/00 , C08L25/04 , H01B1/24
摘要： PURPOSE:To obtain the title resin composition improved in the balance between conductivity and viscosity, by mixing a PS resin with a mineral oil, a butadiene rubber and a specified carbon black. CONSTITUTION:A PS resin (a) containing 100 pts.wt. PS component is mixed with 1-15 pts.wt. mineral oil (b) of a viscosity (25 deg.C) of 100-400cP, 1-10 pts.wt. butadiene rubber (c) of a butadiene content >=50% and 10-20 pts.wt. carbon black (d) of a DBP absorption >=100ml/100g, desirably, 150-400ml/100g, and the obtained mixture is kneaded at 130-250 deg.C to obtain the title composition of a volume resistivity >=1X10 OMEGA.cm and an MI >=5g/10min.

6. 发明专利

JPH01203443A BELT 失效
公开(公告)号：JPH01203443A
公开(公告)日：1989-08-16
申请号：JP2702888
申请日：1988-02-08
申请人： MITSUBISHI CHEM IND
发明人： SAWANOBORI TAKEO , FURUKI NOBORU
IPC分类号： F16G1/06 , B29D29/00 , C08F220/42 , C08F220/44 , C08F236/04 , C08F236/06 , C08L15/00 , C08L21/00
摘要： PURPOSE:To obtain a belt, having excellent resistance to oils, weather, heat and fatigue, and useful as automotive timing belts, etc., by forming a vulcanized rubber composition prepared by blending a rubber component with a vinylic deterioration inhibitor containing an anilinophenyl skeleton in a specific proportion. CONSTITUTION:The aimed belt, obtained by blending (A) a partially hydrogenated multicomponent copolymer rubber prepared by copolymerizing (i) 100wt.% rubber component consisting of 45-80wt.% butadiene and 20-55wt.% acrylonitrile with (ii) 0.1-10wt.% vinylic deterioration inhibitor containing an anilinophenyl skeleton in the molecular [e.g., a compound expressed by formula I (R and R are H, chlorine, bromine or 1-12C alkyl; X is formulas II, III, IV and V)] and having at least >=70wt.% hydrogenated C-C double bond parts thereof with (B) a filler and (C) a vulcanizing agent and having durability.

7. 发明专利

JPH01121304A OIL-RESISTANT HYDROGENATED ACRYLONITRILE-BUTADIENE RUBBER AND VULCANIZED RUBBER COMPOSITION HAVING IMPROVED HEAT RESISTANCE 失效
公开(公告)号：JPH01121304A
公开(公告)日：1989-05-15
申请号：JP28003987
申请日：1987-11-05
申请人： MITSUBISHI CHEM IND
发明人： SAWANOBORI TAKEO , FURUKI NOBORU
IPC分类号： C08L15/00 , C08C19/02 , C08F8/04 , C08L21/00
摘要： PURPOSE:To obtain the titled rubber, having improved heat resistance and oil, weather resistance, etc., and useful as industrial belts, etc., by hydrogenating butadiene parts of acrylonitrile-butadiene rubber prepared by binding a specific vinyl based deterioration inhibitor as the third component thereto. CONSTITUTION:The aimed rubber obtained by copolymerizing 100wt.% rubber component consisting of 45-80wt.% butadiene and 20-55wt.% acrylonitrile with 0.1-10wt.% vinyl based deterioration inhibitor containing anilinophenyl skeletons in the molecule {e.g. a compound expressed by formula I or II [R1 and R2 are H, Cl, Br or 1-12C alkyl; R3 is H or 1-4C alkyl; R4 is H, 1-4C alkyl or 6-12C aryl; X is a group expressed by formula III (R5 is H or 1-4C alkyl), etc.; Y is -N=CH-, etc.]} and hydrogenating >=70wt.% carbon-carbon double bond parts of the resultant multielement based copolymer. Furthermore, carbon black, a vulcanizing agent or vulcanization accelerator is blended with the afore-mentioned rubber to provide a vulcanized rubber composition.

8. 发明专利

JPS6440327A CALCIUM SILICATE MOLDED BODY AND MANUFACTURE THEREOF 失效
公开(公告)号：JPS6440327A
公开(公告)日：1989-02-10
申请号：JP19663587
申请日：1987-08-06
申请人： MITSUBISHI CHEM IND
发明人： SAWANOBORI TAKEO , AWATA MITSURU , NOGUCHI YUJI
IPC分类号： B32B13/00 , B28B1/52 , B32B5/14 , B32B13/02
摘要： PURPOSE:To obtain a lightweight molded body excellent in bending strength, toughness, incombustibility, heat resistance and water resistance by a method wherein slurry stock containing one kind of fiber and slurry containing another kind of fiber are alternately laminated to each other and integrally formed without disturbing the interface between respective slurries. CONSTITUTION:Aqueous slurry, which is formed by preparing calcareous stock and siliceous stock so as to have the same molar ratio of CaO and SiO2, is brought into reaction under pressure by heating up to 160 deg.C or higher. Next, as reinforcing fiber, fiber, the ILSS (interlaminar shear strength) value by ASTM method of which is 400kg/cm or more, and fiber, the ILSS value of which is 300kg/cm or less, are used in combination. Two kinds or more of fibers as mentioned above are respectively added to and mixed with calcium silicate slurries. After slurry containing one kind of fiber is fed in the mold for a filter press, slurry containing another kind of fiber is fed above said slurry in such a manner not to disturb the interface between the two slurries so as to alternately laminate the two slurries to each other and, after that, pressed as they are to obtain an integral forming.

9. 发明专利

JPS6438227A CALCIUM SILICATE MOLDED OBJECT AND ITS MANUFACTURE 失效
公开(公告)号：JPS6438227A
公开(公告)日：1989-02-08
申请号：JP19482687
申请日：1987-08-04
申请人： MITSUBISHI CHEM IND
发明人： SAWANOBORI TAKEO , AWATA MITSURU , NOGUCHI YUJI
IPC分类号： B28B1/52 , B32B13/00 , B32B13/02
摘要： PURPOSE:To make a molded object light-weight by providing the multilayer construction in which the matrix layers with different fiber contents are alternately laminated and are integrally molded. CONSTITUTION:In the manufacture of the calcium silicate molded object having multilayer construction in which the matrix layers containing reinforcing fiber are laminated in multilayer, the raw material slurries of different fiber contents are laminated in multilayer in the mold of the molding machine such as a water filtration molding machine, etc. While the interface of the slurries is kept practically, said slurries are pressurized and dehydrated, and after they have been integrally molded, it is dried. As the reinforcing fiber, nylon, polyestervinylon, rayon and aramid etc. of organic fiber are used. An inorganic fiber, steel, glass fiber, carbon fiber, SiC fiber, alumina fiber, etc. are used. Consequently, the calcium silicate molded object excellent in bending strength may be obtained without lowering incombustibility, heat resistance and water resistance.

10. 发明专利

JPS63260847A FIBER-REINFORCED CALCIUM SILICATE FORMED MATTER 失效
公开(公告)号：JPS63260847A
公开(公告)日：1988-10-27
申请号：JP9379687
申请日：1987-04-16
申请人： MITSUBISHI CHEM IND
发明人： SAWANOBORI TAKEO , AWATA MITSURU , NOGUCHI YUJI
IPC分类号： C04B14/38 , C04B24/24 , C04B28/18

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