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    • 1. 发明专利
    • Polyolefin composition
    • 聚烯烃组合物
    • JPS619447A
    • 1986-01-17
    • JP13026984
    • 1984-06-25
    • Nippon Petrochem Co Ltd
    • OKA MASATAKAFURUKAWA MASAMIKOJIMA SHINJIAMATSU TAKEO
    • C08L23/00C08K3/26C08K3/30C08K3/32C08K3/34C08K9/08C08L23/06C08L23/08C08L23/12C08L23/26C08L33/00C08L33/02C08L51/00C08L51/02C08L51/06C08L101/00
    • C08L23/12C08K3/34C08K9/08C08L23/08C08L23/0876C08L51/06C08L2205/03C08L23/02C08L2666/24C08L2666/02
    • PURPOSE: The titled composition having excellent mechanical properties, obtained by incorporating an inorganic filler and a coupling agent comprising a copolymer which contains (meth) acrylic acid into a high-molecular weight polyolefin containing a polyolefin modified with an unsaturated carboxylic acid.
      CONSTITUTION: An inorganic filler (A) such as a silicate, a carbonate or a sulfate, a coupling agent (B) comprising a copolymer (fully or partially neutralized) which has a viscosity-average molecular weight of 15,000 or lower, contains at least 1mol% (meth)acrylic acid, and is selected from among ethylene-(meth)acrylic acid copolymers and ethylene-alkyl (meth)acrylate-(meth)acrylic acid copolymers (of a 1W4C alkyl), and a high-molecular weight polyolefin (C) containing 3W100wt% modified polyolefin which has a viscosity-average molecular weight of 2.6×10
      5 or higher and has been modified with at least 0.01wt% unsaturated caboxylic acid (anhydride ester) are mixed.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过将含有(甲基)丙烯酸的共聚物的无机填料和偶联剂并入含有用不饱和羧酸改性的聚烯烃的高分子量聚烯烃中而得到的具有优异的机械性能的标题组合物。 构成:粘均分子量为15000以下的无机填料(A),如硅酸盐,碳酸盐,硫酸盐,偶联剂(B),含有共聚物(全部或部分中和的),至少含有 1摩尔%(甲基)丙烯酸,并且选自乙烯 - (甲基)丙烯酸共聚物和乙烯 - (甲基)丙烯酸烷基酯 - (甲基)丙烯酸共聚物(1-4C烷基)和高分子 含有粘均分子量为2.6×10 5或更高并已用至少0.01重量%不饱和羧酸(酸酐酯)改性的3-100重量%改性聚烯烃的聚烯烃(C)混合。
    • 2. 发明专利
    • Novel ethylene copolymer
    • 新型乙烯共聚物
    • JPS6185416A
    • 1986-05-01
    • JP20759584
    • 1984-10-03
    • Nippon Petrochem Co Ltd
    • ORIGASA YUICHIKOJIMA SHINJIINOUE TAKASHIYAMAMOTO KAORUSATO ATSUSHIKAWAKAMI SHIGENOBU
    • C08F210/00C08F210/02H01B3/44
    • C08F210/02H01B3/441
    • PURPOSE: To provide the titled copolymer constituted by ethylene unit, a small amount of specific comonomer unit and others, having each specific density and melt index, useful for electrical insulation materials, expansion materials, modification of polymers such as engineering plastics.
      CONSTITUTION: The objective copolymer with a density 0.860W0.970g/cm
      3 and a melt index 0.05W100g/10min made up of (A) 85.0W99.995mol% of ethylene unit, (B) 0.005W5 (pref. 0.01W2) mol% of comonomer unit of formula I (Ar is of formula II or III; R
      1 is 1W2C alkylene; R
      2 and R
      3 are each H, Cl, or 1W4C alkyl) (pref. allylbenzene, allyl biphenyl or 4-phenylbutene-1) and (C) 0W10 (pref. 0W5) mol% of an ethylenic unsaturated monomer unit (e.g., propylene, styrene). This copolymer can preferably be obtained by high pressure radical polymerization at 50W400°C under a pressure of 500W4,000kg/cm
      2 .
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:提供由乙烯单元,少量特定共聚单体等构成的具有各种比重和熔体指数的标题共聚物,可用于电绝缘材料,膨胀材料,改性聚合物如工程塑料。 构成:由(A)85.0-99.995mol%的乙烯单元组成的目标共聚物,密度为0.860-0.970g / cm 3,熔体指数为0.05-100g / 10min,(B)0.005-5 0.01-2摩尔%的式I的共聚单体单元(Ar为式II或III; R 1为1-2C亚烷基; R 2和R 3各自为H,Cl或1-4C烷基)(优选烯丙基苯,烯丙基联苯 或4-苯基丁烯-1)和(C)0-10(优选0-5)摩尔%的烯属不饱和单体单元(例如丙烯,苯乙烯)。 该共聚物优选通过在500-4000kg / cm 2的压力下在50-400℃的高压自由基聚合获得。
    • 3. 发明专利
    • Production of ethylene copolymer crosslinked by ionic bond
    • 生产由离子键交联的乙烯共聚物
    • JPS59102901A
    • 1984-06-14
    • JP21168782
    • 1982-12-02
    • Nippon Petrochem Co Ltd
    • KOJIMA SHINJIORIGASA YUUICHIKANAZAWA SHIYUUJI
    • C08F8/00C08F8/12C08F8/44C08F210/02C08F220/10
    • PURPOSE: To obtain the titled copolymer by a simple operation inexpensively with preventing corrosion of a device, by saponifying a copolymer of ethylene and an α, β-unsaturated carboxylic acid with a basic metallic compound in a mixed solvent containing an aromatic alcohol.
      CONSTITUTION: A copolymer of ethylene and an α, β-ethylenic unsaturated carboxylic acid ester (e.g., ethyl acrylate, etc.) is saponified with a basic metallic compound (e.g., sodium hydroxide, etc.) in an organic solvent (e.g., xylene, etc.) containing an aromatic alcohol, to give the desired copolymer. A ratio of the aromatic alcohol contained in the mixed solvent is preferably 1W70wt%.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过简单的操作,通过简单的操作获得标题共聚物,通过在含有芳族醇的混合溶剂中将碱性金属化合物与碱金属化合物皂化而使乙烯与α,β-不饱和羧酸的共聚物皂化,从而廉价地防止器件的腐蚀。 构成:乙烯与α,β-烯属不饱和羧酸酯(如丙烯酸乙酯等)的共聚物在有机溶剂(例如二甲苯)中用碱性金属化合物(如氢氧化钠等)皂化 等),得到所需的共聚物。 混合溶剂中所含的芳香醇的比例优选为1-70重量%。
    • 4. 发明专利
    • Ethylene copolymer
    • 乙烯共聚物
    • JPS61111312A
    • 1986-05-29
    • JP23395184
    • 1984-11-06
    • Nippon Petrochem Co Ltd
    • ORIGASA YUICHIKOJIMA SHINJIINOUE TAKASHIYAMAMOTO KAORUSATO ATSUSHIKAWAKAMI SHIGENOBU
    • C08F210/00C08F210/02H01B3/44
    • C08F210/02H01B3/441
    • PURPOSE: To improve the withstand voltage of an ethylene copolymer as an electrical insulation material or its properties as a cellular material or as a modifier for polymers, by forming a copolymer of ethylene with a specified comonomer and an ethylenically unsaturated monomer.
      CONSTITUTION: A copolymer comprising 85.0W99.995mol% ethylene units, 0.005W5mol% comonomer units of formula I (wherein Ar is formula II or III, R is H or methyl, R
      2 and R
      3 are each H, Cl, a 1W4C linear or branched alkyl) and 0W10mol% ethylenically unsaturated monomer units. This copolymer has a density of 0.860W0.970g/cm
      3 and a melt index of 0.05W100g/10min. As the comonomer of formula I, benzyl (meth)acrylate is particularly preferable. When this ethylene copolymer is used as an electrical insulation material, it is preferable that the copolymer is produced by high-pressure radical polymerization (at 50W400°C and about 500W4,000kg/cm
      2 ) freed from a problem of catalyst residues.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过形成乙烯与特定共聚单体和烯键式不饱和单体的共聚物,提高作为电绝缘材料的乙烯共聚物的耐电压或其作为多孔材料的性质或作为聚合物的改性剂。 构成:包含85.0-99.995mol%乙烯单元,0.005-5mol%式I共聚单体单元的共聚物(其中Ar为式II或III,R为H或甲基,R2和R3各自为H,Cl,1-4C 直链或支链烷基)和0-10mol%烯属不饱和单体单元。 该共聚物的密度为0.860-0.970g / cm 3,熔体指数为0.05-100g / 10min。 作为式I的共聚单体,特别优选(甲基)丙烯酸苄酯。 当该乙烯共聚物用作电绝缘材料时,优选通过高压自由基聚合(在50-400℃和约500-4,000kg / cm 2)下产生共聚物,从而避免了问题 的催化剂残留物。
    • 5. 发明专利
    • Ethylene copolymer
    • 乙烯共聚物
    • JPS6185419A
    • 1986-05-01
    • JP20759884
    • 1984-10-03
    • Nippon Petrochem Co Ltd
    • ORIGASA YUICHIKOJIMA SHINJIINOUE TAKASHIYAMAMOTO KAORUSATO ATSUSHIKAWAKAMI SHIGENOBU
    • C08F210/00C08F210/02C08F212/32
    • PURPOSE: To provide the titled copolymer made up of specific proportion of ethylene, 2,4-diphenyl-4-methylpentene-1 and ethylenic unsaturated monomer units, having each specific density and melt index, suitable for electrical insulation and expansion materials, etc.
      CONSTITUTION: The objective copolymer with a density 0.860W0.970g/cm
      3 and a melt index 0.05W100g/10min made up of (A) 85.0W99.995mol% of ethylene unit, (B) 0.005W5 (pref. 0.01W2) mol% of comonomer unit comprising 2,4- diphenyl-4-methylpentene-1 and (C) 0W10 (pref. 0W5) mol% of an ethylenic unsaturated monomer (e.g., ethyl acrylate) unit can preferably be obtained by high-pressure radical polymerization at 100W350°C under a pressure of 1,000W3,500kg/cm
      2 .
      USE: Also suitable as a polymer modifier.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:提供具有比重密度和熔体指数的乙烯,2,4-二苯基-4-甲基戊烯-1和烯属不饱和单体单元的特定比例的标准共聚物,适用于电气绝缘和膨胀材料等。 构成:由(A)85.0-99.995mol%的乙烯单元组成的目标共聚物,密度为0.860-0.970g / cm 3,熔体指数为0.05-100g / 10min,(B)0.005-5 0.01-2摩尔%的包含2,4-二苯基-4-甲基戊烯-1和(C)0-10(优选0-5)摩尔%的烯属不饱和单体(例如丙烯酸乙酯)单元的共聚单体单元可以 优选通过在100-350℃,1000-3500kg / cm 2的压力下的高压自由基聚合获得。 用途:也适合作为聚合物改性剂。
    • 6. 发明专利
    • Deodorization of odoriferous resin
    • 臭氧树脂的脱除
    • JPS60210605A
    • 1985-10-23
    • JP6808184
    • 1984-04-05
    • Nippon Petrochem Co Ltd
    • KOJIMA SHINJIKIYOTA TAKASHIAMATSU TAKEO
    • C08F6/00B29C71/00B29C71/02C08J7/00
    • B29B2017/0224Y02W30/523Y02W30/622
    • PURPOSE: To deodorize an odoriferous resin effectively without detriment to the properties of the resin, by bringing the odoriferous resin into contact with a deodorant selected from among 3C or lower alkenes or alkanes and carbon dioxide at a temperature higher than the critical temperature of the deodorant and a pressure higher than its critical pressure.
      CONSTITUTION: An odoriferous resin containing odorants (e.g., ethylene/ethyl acrylate copolymer or ethylene/vinyl acetate copolymer) is brought into contact with a deodorant selected from among 3C or lower alkenes (e.g., ethylene or propylene), 3C or lower alkanes (e.g., methane or ethane) and carbon dioxide at a temperature higher than the critical temperature of the deodorant and a pressure higher than its critical pressure to remove the odorants from the resin. By using a cosolvent selected from among 1W3C alcohols (e.g. methanol), ethers, and ketones, it is possible to enhance an effect of extracting the odorants to thereby reduce the amount of a deodorant used.
      COPYRIGHT: (C)1985,JPO&Japio
    • 目的:通过在高于除臭剂的临界温度的温度下使有气味的树脂与选自3C或低级烯烃或烷烃和二氧化碳的除臭剂接触,以有效地对有机树脂进行除臭,而不损害树脂的性能 并且压力高于其临界压力。 构成:将含有气味的气味树脂(例如乙烯/丙烯酸乙酯共聚物或乙烯/乙酸乙烯酯共聚物)与选自3C或低级烯烃(例如乙烯或丙烯),3C或低级烷烃(例如乙烯/乙酸乙烯酯共聚物)的除臭剂接触。 ,甲烷或乙烷)和二氧化碳,其温度高于除臭剂的临界温度,并且压力高于其临界压力以从树脂中除去气味剂。 通过使用选自1-3C醇(例如甲醇),醚和酮的共溶剂,可以提高提取气味剂的效果,从而减少所用的除臭剂的量。
    • 7. 发明专利
    • Thermoplastic resin composition
    • 热塑性树脂组合物
    • JPS61120853A
    • 1986-06-07
    • JP24154684
    • 1984-11-15
    • Mitsubishi Gas Chem Co IncNippon Petrochem Co Ltd
    • SONODA SHINJIKOJIMA SHINJIAMATSU TAKEOONISHI HIROYUKI
    • C08L69/00C08L23/00C08L23/08C08L67/00C08L101/00
    • PURPOSE: To provide the titled resin compsn. excellent in chemical resistance, impact resistance at low temp., moldability, etc., and well suited for automobile parts, by incorporating an arom. polycarbonate resin and ethylene/arom. monovinyl copolymer in a specific wt. ratio.
      CONSTITUTION: 70W99wt% arom. polycarbonate resin yielded by the reaction of an arom. dihydroxy compd. (e.g., bisphenol A) with phosgene or a carbonic acid diester and 30W1wt% ethylene/arom. monovinyl copolymer (e.g., ethylene- styrene copolymer) are mixed by means of melt-blend, etc., to yield the intended thermoplastic resin compsn. If necessary, stabilizers, pigments, flame retardants, reinforcers, fillers, etc., can be incorporated Furthermore, heat-resistant polyesters such as polyester carbonates or polyarylates may be incorporated to improve heat resistance.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:提供标题树脂制品。 优异的耐化学性,低温下的耐冲击性,成型性等,并且通过加入芳香剂非常适合于汽车部件。 聚碳酸酯树脂和乙烯/芳香剂。 单乙烯基共聚物。 比。 构成:70-99wt%芳香。 通过芳香反应产生的聚碳酸酯树脂。 二羟基化合物 (例如,双酚A)与光气或碳酸二酯和30-1重量%乙烯/芳烃。 单乙烯基共聚物(例如乙烯 - 苯乙烯共聚物)通过熔融共混物等混合,得到所需的热塑性树脂组合物。 如果需要,可以加入稳定剂,颜料,阻燃剂,增强剂,填料等。此外,可以引入耐热聚酯如聚酯碳酸酯或多芳基化合物以改善耐热性。
    • 8. 发明专利
    • Thermoplastic resin composition
    • 热塑性树脂组合物
    • JPS61120852A
    • 1986-06-07
    • JP24154584
    • 1984-11-15
    • Mitsubishi Gas Chem Co IncNippon Petrochem Co Ltd
    • SONODA SHINJIKOJIMA SHINJIAMATSU TAKEOONISHI HIROYUKI
    • C08L69/00C08L23/00C08L23/08C08L33/00C08L33/02C08L67/00C08L101/00
    • PURPOSE: To improve resistance to chemicals and impact, moldability, etc., by incorporating an arom. polycarbonate resin with ethylene/vinyl carboxylate/ alkyl (meth)acrylate copolymer in a specific wt. ratio.
      CONSTITUTION: 70W99wt% arom. polycarbonate resin yielded by the reaction of an arom. dihydroxy compd. (e.g., bisphenol A) with phosgene or a carbonic acid diester and 30W1wt% ethylene/vinyl carboxylate/alkyl (meth)acrylate copolymer (e.g., ethylene/vinyl acetate/methyl acrylate copolymer) are mixed by means of melt-blend, etc. to yield the intended thermoplastic resin compsn. Stabilizers, pigments, retardants, reinforcers, fillers, and other resin components such as heat-resistance polyesters can be incorporated if necessary.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过加入芳香剂来提高耐化学品和抗冲击性,成型性等。 具有乙烯/羧酸乙烯酯/(甲基)丙烯酸烷基酯共聚物的聚碳酸酯树脂。 比。 构成:70-99wt%芳香。 通过芳香反应产生的聚碳酸酯树脂。 二羟基化合物 (例如双酚A)与光气或碳酸二酯和30-1wt%乙烯/羧酸乙烯酯/(甲基)丙烯酸烷基酯共聚物(例如乙烯/乙酸乙烯酯/丙烯酸甲酯共​​聚物)通过熔融共混物混合, 以产生所需的热塑性树脂组合物。 如果需要,可以加入稳定剂,颜料,阻燃剂,增强剂,填料和其它树脂组分如耐热聚酯。
    • 9. 发明专利
    • Novel ethylene copolymer
    • 新型乙烯共聚物
    • JPS6185418A
    • 1986-05-01
    • JP20759784
    • 1984-10-03
    • Nippon Petrochem Co Ltd
    • ORIGASA YUICHIKOJIMA SHINJIINOUE TAKASHIYAMAMOTO KAORUSATO ATSUSHIKAWAKAMI SHIGENOBU
    • C08F210/00C08F210/02C08F212/32
    • PURPOSE: To provide the titled copolymer constituted by ethylene unit, a small amount of specific comonomer unit and others having each specific density and melt index, useful for electrical insulation materials, expansion materials, modification of polymers such as engineering plastics.
      CONSTITUTION: The objective copolymer with a density 0.860W0.970g/cm
      3 and a metal index 0.05W100g/10min made up of (A) 85.0W99.995mol% of ethylene unit, (B) 0.005W5 (pref. 0.01W2) mol% of comonomer unit of formula (R
      1 is 1W4C alkylene; R
      2 and R
      3 are each H, Cl, or 1W4C alkyl) (pref. 1-phenyl-1- styrlethane) and (C) 0W10 (pref. 0W5) mol% of an ethylenic unsaturated monomer unit (e.g., propylene, styrene). This copolymer can preferably be obtained by high-pressure radical polymerization at 50W400°C under a pressure of 500W4,000kg/cm
      2 .
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:提供由乙烯单元,少量特定共聚单体单元等具有各种比重和熔体指数的共聚物,用于电绝缘材料,膨胀材料,聚合物如工程塑料的改性。 构成:由(A)85.0-99.995mol%的乙烯单元组成的目标共聚物,密度为0.860-0.970g / cm 3,金属指数为0.05-100g / 10min,(B)为0.005-5(优选)。 0.01-2摩尔%的共聚单体单元(R1为1-4C亚烷基; R2和R3分别为H,C1或1-4C烷基)(优先1-苯基-1-苯乙烯)和(C)0 -10(优选0-5)mol%的烯属不饱和单体单元(例如丙烯,苯乙烯)。 该共聚物优选通过在500-4000kg / cm 2的压力下在50-400℃的高压自由基聚合获得。
    • 10. 发明专利
    • Novel ethylene copolymer
    • 新型乙烯共聚物
    • JPS6185417A
    • 1986-05-01
    • JP20759684
    • 1984-10-03
    • Nippon Petrochem Co Ltd
    • ORIGASA YUICHIKOJIMA SHINJIINOUE TAKASHIYAMAMOTO KAORUSATO ATSUSHIKAWAKAMI SHIGENOBU
    • C08F210/00C08F210/02C08F212/32
    • PURPOSE: To provide the titled copolymer constituted by ethylene unit, a small amount of specific comonomer unit and others, having each specific density and melt index, useful for electrical insulation materials, expansion materials, modification of polymers such as engineering plastics.
      CONSTITUTION: The objective copolymer with a density 0.860W0.970g/cm
      3 and a melt index 0.05W100g/10min made up of (A) 85.0W99.995% of ethylene unit, (B) 0.005W5 (pref. 0.01W2) mol% of comonomer unit of formula (R
      1 and R
      2 are each H, Cl or 1W4C alkhl) (pref. 1,1'-diphenylethylene) and (C) 0W10 (pref. 0W5) mol% of an ethylenic unsaturated monomer unit (e.g., butene-1, styrene). This copolymer can preferably be obtained by high-pressure radical polymerization at 50W400°C under a pressure of 500W4,000kg/cm
      2 .
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:提供由乙烯单元,少量特定共聚单体等构成的具有各种比重和熔体指数的标题共聚物,可用于电绝缘材料,膨胀材料,改性聚合物如工程塑料。 构成:由(A)85.0-99.995%的乙烯单元,(B)0.005-5(优选0.01)构成的目标共聚物,密度为0.860-0.970g / cm 3,熔体指数为0.05-100g / 10min -2)mol%的式(R1和R2各自为H,Cl或1-4C烷基)(优选1,1'-二苯基乙烯)和(C)0-10(优选0-5)摩尔的共聚单体单元 %的不饱和单体单元(例如,丁烯-1,苯乙烯)。 该共聚物优选通过在500-4000kg / cm 2的压力下在50-400℃的高压自由基聚合获得。