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1. 发明专利

JP2012255179A Method for producing useful substance from carbon dioxide 审中-公开
标题翻译：从二氧化碳生产有用物质的方法
公开(公告)号：JP2012255179A
公开(公告)日：2012-12-27
申请号：JP2011127760
申请日：2011-06-07
申请人： National Institutes Of Natural Sciences , 大学共同利用機関法人自然科学研究機構 , Kyoto Univ , 国立大学法人京都大学 , Kuraray Co Ltd , 株式会社クラレ , Showa Denko Kk , 昭和電工株式会社 , Toyobo Co Ltd , 東洋紡株式会社 , Shoei Chem Ind Co , 昭栄化学工業株式会社
发明人： TANAKA KOJI , KOBAYASHI KATSUAKI , KOBAYASHI HIROKAZU , KITAGAWA HIROSHI , KITAGAWA SUSUMU , INUBUSHI YASUTAKA , KISHIDA KEISUKE , NISHIGUCHI YASUKO
IPC分类号： C25B3/04 , B01J31/22
CPC分类号： Y02P20/121
摘要： PROBLEM TO BE SOLVED: To provide a method for producing formic acid as a useful substance from carbon dioxide which is excellent in an environmental aspect and energy efficiency.SOLUTION: A process for producing the formic acid by electrolytically reducing the carbon dioxide is performed in an aqueous medium which includes a porous metal complex capable of storing carbon dioxide, an amphiphilic electron donor such as 1, 1'-dimethyl-4, 4'-piperidinium and a trinuclear transition metal sulfur cluster catalyst such as [(C5H5Co)3S2] obtained by complexation with the porous metal complex.
摘要翻译：待解决的问题：提供从环境方面和能量效率优异的二氧化碳生产甲酸作为有用物质的方法。解决方案：通过电解还原二氧化碳来生产甲酸的方法是在水性介质中进行的，所述水性介质包括能够储存二氧化碳的多孔金属络合物，两亲电子给体如1,1'-二甲基-4 ，4'-哌啶鎓和通过与多孔金属络合物络合获得的[（C 5 H 5 Co）3S 2]三核过渡金属硫簇催化剂。版权所有（C）2013，JPO＆INPIT

2. 发明专利

JP2012017268A Metal complex and production method thereof 有权
标题翻译：金属复合材料及其生产方法
公开(公告)号：JP2012017268A
公开(公告)日：2012-01-26
申请号：JP2010153928
申请日：2010-07-06
申请人： Kuraray Co Ltd , Kyoto Univ , Shoei Chem Ind Co , Showa Denko Kk , Toyobo Co Ltd , 国立大学法人京都大学 , 昭和電工株式会社 , 昭栄化学工業株式会社 , 東洋紡績株式会社 , 株式会社クラレ
发明人： INUBUSHI YASUTAKA , MITSUYA YOSHIKO , KISHIDA KEISUKE , NISHIGUCHI YASUKO , KITAGAWA SUSUMU , HORIKE SATOSHI , FUKUSHIMA TOMOHIRO
IPC分类号： C07C63/24 , B01J20/22 , B01J20/30 , C07C7/12 , C07C9/04 , C07C15/06 , C07C51/41 , C07D213/22 , C07F3/06
摘要： PROBLEM TO BE SOLVED: To provide a metal complex which has outstanding gas adsorption performance.SOLUTION: The metal complex whose composition is expressed by formula (1) consists of: a dicarboxylic acid compound (A) expressed by general formula (I) (wherein, X represents an alkyl group); at least one type of metal (M) selected from the group consisting of magnesium, aluminum, chromium, iron, nickel and zinc; and an organic ligand (B) which can bidentately coordinate to the metal. In formula (1), M represents at least one type of metal selected from the group consisting of magnesium, calcium, aluminum, chromium, molybdenum, tungsten, manganese, iron, ruthenium, rhodium, nickel, palladium, zinc and cadmium, A represents a dicarboxylic acid compound (I), and B represents an organic ligand which can bidentately coordinate.
摘要翻译：要解决的问题：提供具有优异气体吸附性能的金属络合物。解决方案：组成由式（1）表示的金属络合物包括：由通式（I）表示的二羧酸化合物（A）（其中X表示烷基）; 至少一种选自镁，铝，铬，铁，镍和锌的金属（M）; 和可以与金属相互配位的有机配体（B）。在式（1）中，M表示选自镁，钙，铝，铬，钼，钨，锰，铁，钌，铑，镍，钯，锌和镉中的至少一种金属。二元羧酸化合物（I），B表示可以双键配位的有机配体。版权所有（C）2012，JPO＆INPIT

3. 发明专利

JP2012254398A Method for producing composite catalyst 有权
标题翻译：生产复合催化剂的方法
公开(公告)号：JP2012254398A
公开(公告)日：2012-12-27
申请号：JP2011127922
申请日：2011-06-08
申请人： Shoei Chem Ind Co , 昭栄化学工業株式会社 , Kuraray Co Ltd , 株式会社クラレ , Showa Denko Kk , 昭和電工株式会社 , Toyobo Co Ltd , 東洋紡株式会社
发明人： MITSUYA YOSHIKO , NAGASHIMA KAZUO , KITAGAWA HIROSHI , KOBAYASHI HIROKAZU , INUBUSHI YASUTAKA , KISHIDA KEISUKE , NISHIGUCHI YASUKO
IPC分类号： B01J31/22 , B01J37/04 , B01J37/08
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a composite catalyst, with which the composite catalyst comprising a porous metal complex and a functional material having catalysis can be produced within a time shorter than the conventional method.SOLUTION: The complex catalyst includes the porous metal complex which is formed by accumulating an organic metal complex comprising a central metal and an organic ligand to be coordinated with the central metal and has a porous structure, and the functional material having catalysis. The method for producing the composite catalyst includes steps of: preparing a raw material solution which contains a compound comprising the central metal constituting the porous metal complex, another compound becoming the organic ligand, and the functional material or a precursor thereof and in which the seed of the porous metal complex and/or the composite catalyst is uniformly dispersed; atomizing the prepared raw material solution in a gas phase to produce a liquid droplet; and heating the produced liquid droplet to grow the seed to the composite catalyst.
摘要翻译：待解决的问题：提供一种复合催化剂的制备方法，其中可以在比常规方法短的时间内制备包含多孔金属络合物的复合催化剂和具有催化功能材料的方法。解决方案：复合催化剂包括多孔金属络合物，其通过积聚包含中心金属和有机配体的有机金属络合物形成，与中心金属配位并具有多孔结构，以及具有催化作用的功能材料。制备复合催化剂的方法包括以下步骤：制备含有构成多孔金属络合物的中心金属，成为有机配体的另一种化合物和功能材料或其前体的化合物的原料溶液，其中种子的多孔金属络合物和/或复合催化剂均匀分散; 在气相中雾化制备的原料溶液以产生液滴; 并加热生成的液滴以将种子生长至复合催化剂。版权所有（C）2013，JPO＆INPIT

4. 发明专利

JP2012250946A Method for producing porous metal complex 有权
标题翻译：生产多孔金属复合材料的方法
公开(公告)号：JP2012250946A
公开(公告)日：2012-12-20
申请号：JP2011126091
申请日：2011-06-06
申请人： Shoei Chem Ind Co , 昭栄化学工業株式会社 , Kuraray Co Ltd , 株式会社クラレ , Showa Denko Kk , 昭和電工株式会社 , Toyobo Co Ltd , 東洋紡株式会社
发明人： MITSUYA YOSHIKO , NAGASHIMA KAZUO , KITAGAWA HIROSHI , KOBAYASHI HIROKAZU , INUBUSHI YASUTAKA , KISHIDA KEISUKE , NISHIGUCHI YASUKO
IPC分类号： C07D213/22 , C07D233/58 , C07F3/06
摘要： PROBLEM TO BE SOLVED: To provide a production method that can synthesize a porous metal complex in a short time.SOLUTION: The method for producing a porous metal complex having a porous structure formed by the accumulation of central metal and an organic metal complex including an organic ligand coordinated to the central metal, includes: a step of preparing raw material solution in which a compound including the central metal composing the porous metal complex and a compound composed of the organic ligand are dissolved, and seeds for the porous metal complex are dispersed evenly; a step of spraying the raw material into gas phase to produce liquid droplets; and a step of heating the liquid droplets to grow the seeds into the porous metal complex.
摘要翻译：待解决的问题：提供能够在短时间内合成多孔金属络合物的制造方法。解决方案：制备具有由中心金属和包含与中心金属配位的有机配体的有机金属络合物形成的多孔结构的多孔金属络合物的方法包括：制备原料溶液的步骤，其中包含构成多孔金属络合物的中心金属和由有机配体构成的化合物的化合物溶解，多孔金属络合物的种子均匀分散，将原料喷入气相以产生液滴的步骤; 以及加热液滴以将种子生长成多孔金属络合物的步骤。版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2012020956A Metal complex and method of producing the same 审中-公开
标题翻译：金属复合物及其制备方法
公开(公告)号：JP2012020956A
公开(公告)日：2012-02-02
申请号：JP2010159362
申请日：2010-07-14
申请人： Kuraray Co Ltd , Kyoto Univ , Showa Denko Kk , 国立大学法人京都大学 , 昭和電工株式会社 , 株式会社クラレ
发明人： INUBUSHI YASUTAKA , KISHIDA KEISUKE , KITAGAWA HIROSHI
IPC分类号： C07D213/22 , B01D53/02 , B01J20/22 , B01J20/30 , C07F1/08 , C07F15/04 , C07F15/06
CPC分类号： Y02C10/08 , Y02P20/152
摘要： PROBLEM TO BE SOLVED: To provide a metal complex having excellent carbon dioxide-separating performance.SOLUTION: The metal complex comprises: at least one metal ion selected from metals that belong to Group II and Group VII to XII of the periodic table; a lewis-base anion; and an organic ligand capable of bidentate coordination to the metal ion, wherein the organic ligand is expressed by the general formula (I).
摘要翻译：要解决的问题：提供具有优异的二氧化碳分离性能的金属络合物。金属络合物包括：选自属于周期表第II族和第VII至Ⅻ族的金属的至少一种金属离子; 路易威因阴离子; 和能够与金属离子双齿配位的有机配体，其中有机配体由通式（I）表示。版权所有（C）2012，JPO＆INPIT

6. 发明专利

JP2013107826A Metal complex, method for producing the metal complex and separation material 审中-公开
标题翻译：金属复合材料，生产金属复合材料和分离材料的方法
公开(公告)号：JP2013107826A
公开(公告)日：2013-06-06
申请号：JP2011251395
申请日：2011-11-17
申请人： Showa Denko Kk , 昭和電工株式会社 , Kuraray Co Ltd , 株式会社クラレ , Kyoto Univ , 国立大学法人京都大学
发明人： KISHIDA KEISUKE , WATANABE TADAHIRO , INUBUSHI YASUTAKA , KITAGAWA SUSUMU , HORIKE SATOSHI
IPC分类号： C07C63/24 , B01D53/02 , B01D53/62 , B01J20/22 , B01J20/30 , C07C51/43 , C07D213/38 , C07F3/06
CPC分类号： Y02A50/2341 , Y02C10/08 , Y02P20/152
摘要： PROBLEM TO BE SOLVED: To provide a metal complex which more selectively adsorbs carbon dioxide than conventional materials.SOLUTION: The metal complex includes a structure in which pseudo-diamond skeletons each comprising the ion of at least one metal selected from zinc, or the like, a dicarboxylic acid compound represented by formula (I) (wherein, R, R, Rand X are each H or the like), and an organic ligand which is represented by formula (II) (wherein, R, R, R, R, R, R, Rand Rare each H or the like) and can form a bidentate with the metal ion are mutually intruded.
摘要翻译：要解决的问题：提供比常规材料更有选择地吸附二氧化碳的金属络合物。解决方案：金属络合物包括其中每个包含至少一种选自锌等金属的离子的假金刚石骨架的结构，由式（I）表示的二羧酸化合物（其中R 1 ，R 2 ，R 3 ，X分别为H等），和由式（II）表示的有机配体（其中，R 4 ，R 6 ，R 7 ，R 8 ，R 9 ，R 10 和R 11 均为H等），并可与金属形成双齿离子相互侵入。版权所有（C）2013，JPO＆INPIT

7. 发明专利

JP2012180321A Metal complex, and separation material comprising the same 审中-公开
标题翻译：金属复合材料及其分离材料
公开(公告)号：JP2012180321A
公开(公告)日：2012-09-20
申请号：JP2011045232
申请日：2011-03-02
申请人： Kuraray Co Ltd , Showa Denko Kk , Kyoto Univ , 国立大学法人京都大学 , 昭和電工株式会社 , 株式会社クラレ
发明人： INUBUSHI YASUTAKA , HORI KEIJI , KISHIDA KEISUKE , WATANABE TADAHIRO , KITAGAWA SUSUMU , HORIKE SATOSHI
IPC分类号： C07D213/22 , B01D53/02 , B01J20/22 , B01J20/30 , C07F15/04
CPC分类号： Y02C10/08
摘要： PROBLEM TO BE SOLVED: To provide a metal complex having excellent gas separation capability.SOLUTION: This metal complex includes 5-nitroisophthalic acid, a nickel ion and a compound expressed by general formula (I), wherein R, R, R, R, R, R, Rand Reach the same or different and represents a hydrogen atom, a (substituted) alkyl group or a halogen atom, or Rand R, or Rand Rmay get together and form an alkenylene group which may have a substituent.
摘要翻译：要解决的问题：提供具有优异气体分离能力的金属络合物。解决方案：该金属络合物包括5-硝基间苯二甲酸，镍离子和由通式（I）表示的化合物，其中R 1 ，R 2 ，R 3 ，R 4 ，R 5 < / SP>，R 6 ，R 7 和R 8 相同或不同，表示氢原子，（取代的）烷基或卤素原子，或者R 3 ，或者R 6 和R 7 可以合并形成可以具有取代基的亚烯基。版权所有（C）2012，JPO＆INPIT

8. 发明专利

JP2013154302A Adsorption sheet 审中-公开
标题翻译：吸附片
公开(公告)号：JP2013154302A
公开(公告)日：2013-08-15
申请号：JP2012017193
申请日：2012-01-30
申请人： Showa Denko Kk , 昭和電工株式会社 , Toyobo Co Ltd , 東洋紡株式会社
发明人： WATANABE TADAHIRO , KISHIDA KEISUKE
IPC分类号： B01J20/22 , B01D53/04 , B01J20/30
摘要： PROBLEM TO BE SOLVED: To provide an adsorption sheet that can provide adsorption and desorption performance originating in a porous metal complex even in a case where the structure of the porous metal complex changes as a result of adsorption and desorption of gases.SOLUTION: An adsorption sheet includes: a porous metal complex (A) with a porous structure resulting from the bonding of metal ions and organic ligands that can bond with the metal ions; and organic fibers (B).
摘要翻译：要解决的问题：即使在多孔金属配合物的结构由于气体的吸附和解吸附而发生变化的情况下，也可提供能够提供多孔金属络合物的吸附和解吸性能的吸附片。溶解性：吸附片材包括：多孔金属络合物（A），其具有由金属离子和可与金属离子键合的有机配体结合而产生的多孔结构; 和有机纤维（B）。

9. 发明专利

JP2013040130A Metal complex, and adsorbing material, occluding material and separating material each comprising the same 审中-公开
标题翻译：金属复合材料，吸附材料，封装材料和分离材料
公开(公告)号：JP2013040130A
公开(公告)日：2013-02-28
申请号：JP2011178073
申请日：2011-08-16
申请人： Kuraray Co Ltd , 株式会社クラレ , Showa Denko Kk , 昭和電工株式会社
发明人： INUBUSHI YASUTAKA , IKEDA CHIKAKO , KISHIDA KEISUKE
IPC分类号： C07C65/21 , B01D53/02 , B01J20/22 , B01J20/30 , C07C51/347 , C07C51/43 , C07D213/38 , C07F3/06
CPC分类号： Y02C10/08
摘要： PROBLEM TO BE SOLVED: To provide a metal complex that exhibits excellent gas-adsorbing performance, excellent gas-occluding performance and excellent gas-separating performance.SOLUTION: The metal complex comprises an aromatic dicarboxylic acid compound represented by general formula (I), represented by 2-methoxyterephthalic acid, at least one metal ion selected from among ions of metals belonging to groups 2 and 7 to 12 of the periodic table, represented by a zinc ion, and a nitrogen-atom-containing aromatic heterocyclic compound bidentately coordinatable to the metal ion, represented by 1,2-bis(4-pyridyl)ethane.

10. 发明专利

JP2012232928A Metal complex, and adsorbent and separation material comprising the same 审中-公开
标题翻译：金属复合物，以及包含它们的吸附和分离材料
公开(公告)号：JP2012232928A
公开(公告)日：2012-11-29
申请号：JP2011102672
申请日：2011-05-02
申请人： Kuraray Co Ltd , 株式会社クラレ , Showa Denko Kk , 昭和電工株式会社
发明人： INUBUSHI YASUTAKA , IKEDA CHIKAKO , KISHIDA KEISUKE
IPC分类号： C07D213/38 , B01D53/02 , B01J20/22 , B01J20/30 , C07F3/06
CPC分类号： Y02C10/08
摘要： PROBLEM TO BE SOLVED: To provide a metal complex having gas adsorption performance and gas separation performance.SOLUTION: This metal complex comprises an alkenylene dicarboxylic acid compound, at least one kind of metal ion selected from metal ions belonging to groups 2, 7-10 and 12 in the periodic table, and an organic ligand capable of bidentate coordination to metal ion represented by general formula (I). (In the formula, X and T each represent CH, CH(OH) or the like, which may be the same or different).

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