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    • 1. 发明专利
    • Coating liquid for p-type diffusion layer
    • 用于P型扩散层的涂层液
    • JP2013153052A
    • 2013-08-08
    • JP2012013013
    • 2012-01-25
    • Naoetsu Electronics Co Ltd直江津電子工業株式会社Japan Vam & Poval Co Ltd日本酢ビ・ポバール株式会社
    • ISOTANI KATSUYUKIWATANABE SHIROYASUKOBAYASHI TAKASHIMATSUOKA TOSHIFUMI
    • H01L21/225
    • PROBLEM TO BE SOLVED: To provide a coating liquid for boron and aluminum diffusion which: allows the density of a boron compound to be controlled to a desired one while using a propyleneglycol-based solvent as a solvent of a coating liquid for impurity diffusion; contains an aluminum compound used as a second impurity; enables boron and aluminum to be uniformly diffused into a semiconductor silicon substrate; causes neither variation in the surface specific resistance of the semiconductor silicon substrate after the diffusion, nor impurity crystalline precipitation; and allows the boron and aluminum to be diffused at desired densities.SOLUTION: The coating liquid for diffusion for forming a P-type diffusion layer in a semiconductor silicon substrate comprises: (a)a boron compound and (b)an aluminum compound which are used as materials for forming a P-type diffusion layer in a silicon substrate; a solvent including (c)a propyleneglycol derivative and (d)water; and a coating film forming agent consisting of (e)a polyvinyl alcohol-based resin having a saponification degree of 96 mol% or less. The content of sodium in (e) the polyvinyl alcohol-based resin is 0.2 mass% or less to the mass of the polyvinyl alcohol-based resin. The coating liquid for diffusion is arranged for the purpose of diffusing boron and aluminum into a semiconductor silicon substrate.
    • 要解决的问题:提供一种用于硼和铝扩散的涂布液,其可以使用丙二醇基溶剂作为用于杂质扩散的涂布液的溶剂,将硼化合物的密度控制为所需的浓度; 含有用作第二杂质的铝化合物; 使硼和铝均匀地扩散到半导体硅衬底中; 扩散后不会导致半导体硅衬底的表面电阻率的变化,也不会造成杂质结晶析出; 并且允许硼和铝以所需的密度扩散。溶液:用于在半导体硅衬底中形成P型扩散层的用于扩散的涂布液包括:(a)硼化合物和(b)铝化合物,其为 用作在硅衬底中形成P型扩散层的材料; 溶剂,包括(c)丙二醇衍生物和(d)水; 和(e)皂化度为96摩尔%以下的聚乙烯醇类树脂组成的涂膜成膜剂。 (e)聚乙烯醇系树脂中的钠的含量相对于聚乙烯醇类树脂的质量为0.2质量%以下。 用于扩散的涂布液用于将硼和铝扩散到半导体硅衬底中。
    • 2. 发明专利
    • P-type diffusion layer coating liquid
    • P型扩散层涂层液
    • JP2014011379A
    • 2014-01-20
    • JP2012148323
    • 2012-07-02
    • Naoetsu Electronics Co Ltd直江津電子工業株式会社Japan Vam & Poval Co Ltd日本酢ビ・ポバール株式会社
    • NISHIMAKI KOICHIISOTANI KATSUYUKIMATSUOKA TOSHIFUMI
    • H01L21/225
    • PROBLEM TO BE SOLVED: To provide a boron diffusion coating liquid for forming a P-type diffusion layer on a semiconductor silicon substrate capable of adjusting a boron compound to a desired concentration by using a propylene glycol derivative as a solvent, uniformly dispersing boron in the semiconductor silicon substrate, and diffusing the boron to a desired concentration without any variation on the surface resistance value of the semiconductor silicon substrate after the diffusion and without any impurity crystal deposition.SOLUTION: Provided is a diffusion coating liquid for forming a P-type diffusion layer in a semiconductor silicon substrate. The diffusion coating liquid for diffusing boron in the semiconductor silicon substrate is characterized in that (a) a bron compound as a substance for forming the P-type diffusion layer in the silicon substrate, (b) a propylene glycol derivative as a solvent, and (c) water are contained, (d) a polyvinyl alcohol resin having a saponification degree set less than 96 mol% is contained as a film forming agent, and the addition amount of the (d) polyvinyl alcohol resin is within the range of 1.5 to 3.0 mass times larger than the mass of the (a) boron compound.
    • 要解决的问题:为了提供一种用于在能够通过使用丙二醇衍生物作为溶剂将硼化合物调节至所需浓度的半导体硅衬底上形成P型扩散层的硼扩散涂布液,将硼均匀分散在 半导体硅衬底,并且将硼扩散到期望的浓度,而在扩散之后并且没有任何杂质晶体沉积,半导体硅衬底的表面电阻值没有任何变化。解决方案:提供一种用于形成P型扩散的扩散涂覆液 在半导体硅衬底中。 用于在半导体硅衬底中扩散硼的扩散涂布液的特征在于(a)作为在硅衬底中形成P型扩散层的物质的支化合物,(b)作为溶剂的丙二醇衍生物,以及 (c)含有水,(d)作为成膜剂含有皂化度小于96摩尔%的聚乙烯醇树脂,(d)聚乙烯醇树脂的添加量在1.5以下 比(a)硼化合物的质量大3.0质量倍。
    • 10. 发明专利
    • Coating liquid for boron diffusion
    • 涂料液用于硼的扩散
    • JP2012227287A
    • 2012-11-15
    • JP2011092443
    • 2011-04-18
    • Japan Vam & Poval Co Ltd日本酢ビ・ポバール株式会社
    • MATSUOKA TOSHIFUMI
    • H01L21/225
    • PROBLEM TO BE SOLVED: To provide a coating liquid for boron diffusion capable of diffusing boron at high concentration even using a propylene glycol-based solvent having inferior solubility in a boron compound.SOLUTION: A coating liquid for boron diffusion contains (a) a boron compound, (b) an alcoholic hydroxyl group-containing polymer compound, (c) a propylene glycol derivative, (d) ethylene glycol and (e) water, and is characterized in that the content of the above (a) boron compound is 5 mass% or more and 20 mass% or less in the case of boron oxide (BO).
    • 要解决的问题:即使使用在硼化合物中溶解性差的丙二醇类溶剂,也可以提供能够高浓度硼扩散的硼扩散用涂布液。 解决方案:硼扩散用涂布液含有(a)硼化合物,(b)含醇羟基的高分子化合物,(c)丙二醇衍生物,(d)乙二醇和(e)水, 其特征在于,在氧化硼的情况下,上述(a)硼化合物的含量为5质量%以上至20质量%以下(B 2 SB POS =“POST”> 3 )。 版权所有(C)2013,JPO&INPIT