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    • 1. 发明专利
    • COMPOSITE SEMICONDUCTOR SUBSTRATE AND MANUFACTURE THEREOF
    • JPH02194519A
    • 1990-08-01
    • JP1199589
    • 1989-01-23
    • NIPPON TELEGRAPH & TELEPHONE
    • YAMAGUCHI MASASHISUGO MITSURU
    • H01L21/02H01L21/20
    • PURPOSE:To form a semiconductor single-crystal growth layer whose dislocation density is extremely small by a method wherein faces of a first substrate and a second substrate in which a single-crystal growth layer composed of at least one kind selected from group IV elements, III-V compound semiconductors and II-VI compound semiconductors or of these elements or compound semiconductors has been formed and whose constitutive elements or constitution ratios of the elements are different from each other are bonded directly at a temperature of a critical temperature or lower causing a dislocation. CONSTITUTION:For example, the following are prepared: a first single-crystal substrate 1 whose surface has been cleaned and which is composed of Si or Ge; a second single-crystal substrate composed of a single-crystal growth layer 2' constituted of a compound semiconductor composed of group III elements and group V elements the periodic table such as GaAs, InP and the like which are different from those of the substrate 1 and constituted of a compound semiconductor composed of group II elements and group VI elements such as ZnSe or a single-crystal substrate 4' composed of these III-V and II-VI compound semiconductors. Then, the surface of these substrates are cleaned; after that, these substrates are bonded directly in a clean atmosphere at a temperature of 450 deg.C or lower; alternatively, after these substrates have been bonded directly, they are heat-treated at the temperature of 450 deg.C and completed.
    • 8. 发明专利
    • PACKAGING METHOD FOR OPTICAL WAVEGUIDE PARTS
    • JPH0375608A
    • 1991-03-29
    • JP21167589
    • 1989-08-17
    • NIPPON TELEGRAPH & TELEPHONE
    • HANAWA FUMIAKIKOBAYASHI SOICHIYAMAGUCHI MASASHIKITO TSUTOMUSUDA HIROYUKI
    • G02B6/30
    • PURPOSE:To obtain the optical waveguide parts which are low in loss and have excellent long-term reliability by applying heat and voltage between a silicon substrate provided with an optical waveguide chip and a glass mount covering this substrate and between a silicon substrate formed with V-grooves and a glass mount covering this, respectively and fixing the contact surfaces by chemical bonding. CONSTITUTION:The heat and voltage are applied between the silicon substrate 3 provided with the optical waveguide chip made of a quartz system and the glass mount 8 covering this substrate and between the silicon substrate 5 formed with the V-grooves 6 and the glass mount 8 covering this, respectively, to generate the chemical bond. The contact surfaces of the respective silicon substrates 3, 5 and the glass mounts 4, 8 are thus fixed by the chemical bonding. The surfaces of the two material are first heated to about 300 deg.C and are tightly adhered and then, while these two materials are pressed to each other, 500 to 1,000V voltage is impressed thereto. The phenomenon that the connection loss is increased by the external environment, such as heat-cycle tests, is prevented in this way and the optical waveguide parts having the high reliability are obtd.
    • 9. 发明专利
    • MANUFACTURE OF SEMICONDUCTOR SUBSTRATE
    • JPH02174220A
    • 1990-07-05
    • JP32969488
    • 1988-12-27
    • NIPPON TELEGRAPH & TELEPHONE
    • YAMAGUCHI MASASHIITO YOSHIOKONDO SUSUMU
    • H01L21/205H01L21/20H01L21/324
    • PURPOSE:To decrease dislocation density and shorten manufacturing hours by causing a rear layer consisting of a thin film material which has thermal expansion coefficient that is larger than that of a substrate to be deposited at the rear of the single crystal substrate and treating its layer with heat at a high temperature of 700-900 deg.C. CONSTITUTION:After an Si3N4 film 4 amounting to about 5000Angstrom is formed on the rear of an Si single crystal substrate 1 with a plasma CVD process, an intermediate layer 3 consisting of a low temperature growth layer at a growth temperature of the order of 400 deg.C as well as of a high temperature growth layer at a growth temperature of the order of 700 deg.C and amounting to about 1.5mum is formed with an organic metal vapor phase epitaxy(OMVPE) process on the Si single crystal substrate 1. After that, its layer is treated with heat at a temperature 800 deg.C in an atmosphere of arsine (AsH3) for 1-10 hours. Further, a GaAs single crystal layer 2 amounting to 1mum is formed at a temperature 700 deg.C. Dislocation density in the GaAs single crystal at a semiconductor substrate which is treated with heat for 1-10 hours is about 10 cm and 10 cm respectively. In this way, heat treatment time is lessened by approximately 1/10 or less in comparison with its time required by conventional processes or dislocation density decreases with a high reduction of more than one digit.
    • 10. 发明专利
    • MANUFACTURE OF COMPOSITE SEMICONDUCTOR SUBSTRATE
    • JPH01220819A
    • 1989-09-04
    • JP4658588
    • 1988-02-29
    • NIPPON TELEGRAPH & TELEPHONE
    • SUGO MITSURUYAMAMOTO AKIISAYAMAGUCHI MASASHI
    • H01L21/28H01L21/20H01L21/36
    • PURPOSE:To enable integrated circuits or the like to be produced finely and precisely by forming a metallic layer on a second principal face of a semiconductor substrate opposite to the first one as a temperature higher than ordinary temperature is given to the substrate such that the metallic layer has a sufficiently large thickness that is determined in view of the temperature given to the substrate so that a composite semiconductor substrate obtains an inverse number of radius of curvature of warpage that is smaller than one tenth of that of the substrate. CONSTITUTION:On one principal face 2a of a semiconductor substrate body 1, a semiconductor layer 3 having a coefficient of thermal expansion higher than that of the substrate 1 is formed as a temperature higher than ordinary temperature is given to the semiconductor substrate 1, so that a semiconductor substrate 1 is produced. Then, a metallic layer 5 is formed on the other principal face 2b of the substrate 1 by vapor deposition, whereby a composite semiconductor substrate 6 is produced. The metallic layer 5 is formed, as a temperature higher than ordinary temperature is given to the semiconductor substrate 1, into a thickness which is large enough to enable the composite semiconductor substrate 6 to be produced to have only an inverse number of radius of curvature of warpage that is smaller than one tenth of that of the semiconductor substrate. Further, the temperature given to the semiconductor substrate 1 should be taken into consideration when such a thickness is determined.