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    • 1. 发明专利
    • FORMATION OF ELECTRODE FOR SEMICONDUCTOER DEVICE
    • JPH08236483A
    • 1996-09-13
    • JP5802595
    • 1995-02-22
    • NIPPON STEEL CORP
    • SUZUKI TETSUYATERADA TOSHIYUKIFUJITA YUKIHISAFUJII SATOSHI
    • H01L21/28C25D7/12H01L21/288
    • PURPOSE: To easily obtain an ohmic contact between an electrode film and semiconductor film on a substrate by reductively removing a natural oxide film by applying a first voltage across a platinum electrode and plating electrode while a unit to be plated is dipped in a plating solution in such a state that the patterned part of a semiconductor film on which an electrode is formed is exposed, and then, precipitating gold by applying a second voltage across the electrodes. CONSTITUTION: A unit to be plated is composed of a semiconductor substrate 11, epitaxial layer 12, natural oxide film 13, first insulating film 16 formed in a desired pattern, plating electrode 14, second insulating film 17, etc. When a first voltage, under which the film 13 is reduced, is applied across a platinum electrode and the electrode 14 while the unit is dipped in a plating solution containing gold ions, the film 13 is reduced and the surface of the layer 12 on which a gold electrode is formed is exposed. When a second voltage, under which gold is precipitated on the surface of the layer 12, is applied across the electrodes thereafter, gold is precipitated on the surface of the layer 12 and the ohmic gold electrode 18 is obtained in a desired pattern.
    • 4. 发明专利
    • JPH05251368A
    • 1993-09-28
    • JP8342392
    • 1992-03-05
    • NIPPON STEEL CORP
    • FUJII SATOSHIFUJITA YUKIHISA
    • C30B23/00C30B25/00H01L21/205
    • PURPOSE:To facilitate decomposition of source gas and excitation of a doping gas and obtains a high-quality crystal by applying a plurality of high output laser beams with a wavelength which subject the source gas to photolysis toward a position near a substrate surface. CONSTITUTION:Gallium arsenide substrate B is retained upward and skewly for a susceptor 3 and the substrate B is rotated and at the same time is heated. Then, source gas and doping gas (150 deg.C) are supplied. At this time, a high-output laser beam at ultraviolet region is applied from each light source 4, the source gas is decomposed and at the same time laser plasma is generated at a position A, and then the doping gas is excited. By performing feedback control of each light source 4 according to laser plasma intensity, growth rate and the amount of supply of nitrogen radical to the substrate B can be properly controlled, thus reducing crystal growth temperature and preventing generation of point defect.
    • 5. 发明专利
    • JPH05251367A
    • 1993-09-28
    • JP8342292
    • 1992-03-05
    • NIPPON STEEL CORP
    • FUJII SATOSHIFUJITA YUKIHISA
    • C30B23/00C30B25/00H01L21/205
    • PURPOSE:To facilitate excitation of a doping gas and promote crystal growth by applying a high output laser beam with a wavelength which does not subject source gas to photolysis and then focusing it and then applying a light with an energy which is higher than a forbidden band of an epitaxial crystal growth compound. CONSTITUTION:Gallium arsenide substrate B is retained upward and skewly for a susceptor 3 and the substrate B is rotated and at the same time is heated. Then, source gas and doping gas are supplied. At this time, a high-output laser beam at infrared region is applied from each light source 4, laser plasma is generated at a position A, and then the doping gas is excited. Since laser beam from each light source 4 is an infrared rays with a wavelength which does not subject the source gas to photolysis, control of crystal growth itself is easy. Both gases are supplied into a reaction chamber 2 and at the same time a high-energy light is applied from a lamp 7 toward the substrate B, thus promoting crystal growth of zinc selenide on the surface of the substrate B.
    • 6. 发明专利
    • METHOD AND APPARATUS FOR SEMICONDUCTOR SURFACE PASSIVATION DEVICE
    • JPH0372628A
    • 1991-03-27
    • JP7447489
    • 1989-03-27
    • NIPPON STEEL CORP
    • FUJII SATOSHIFUJITA YUKIHISAINAI TORU
    • C23C16/18C23C16/48H01L21/314
    • PURPOSE:To easily form a surface passivation film in the case a photosensitive semiconductor thin film is formed by an MOCVD method or an optical pumping vapor growth method, by a method wherein after the semiconductor thin film is grown on a substrate, an organozinc compound and an organosulfur compound are made to accompany carrier gas and are fed in this reaction tube by a prescribed amount and light having a specified wavelength is irradiated in the vicinity of the substrate or on the substrate itself. CONSTITUTION:A CMT single crystal of a prescribed compositional ratio is grown on the surface of a substrate 13. Raw gas for forming a ZnS passivation film is introduced in a reaction tube 8. As the flow rate of dimethyl zinc (Me2Zn) gas and diethyl sulfur (Et2S) gas, which are used as the raw gas, a flow rate of 1 to 500ml/minute is proper as the flow rate of H2 gas, which is sent in an Me2Zn bubbler 18, a flow rate of 1 to 500ml/minute is proper as the flow rate of H2 gas, which is sent in an Et2S bubbler 19, and a flow rate of 0.1 to 20ml/minute is proper as the flow rate of diluent H2 gas. An organozinc compound and an organosulfur compound, which are introduced in the tube 8, are decomposed by irradiation with light having a wavelength of 190 to 300nm.
    • 7. 发明专利
    • METHOD AND DEVICE FOR VAPOR GROWTH
    • JPH02239187A
    • 1990-09-21
    • JP6181489
    • 1989-03-14
    • NIPPON STEEL CORP
    • FUJII SATOSHIFUJITA YUKIHISATERADA TOSHIYUKI
    • C30B25/14C23C16/18C23C16/44C23C16/455C30B29/48
    • PURPOSE:To obtain many sheets of thin films having large area in the excellent composition ratio and surface state by holding a mercury reservoir with a shaft vertically stood in a vertical reaction tube, specifying the position for supplying the organic metallic compd. of a raw material and rotating a base plate in the case of growing the thin films of mercury-contg. compd. single crystal. CONSTITUTION:In the case of growing a CdxHg1-xTe single crystal thin film, Me2Cd and Et2Te sent from the bubblers 1, 2 are diluted by H2 and then introduced into the vertical reaction tube 11 through the nozzles 9, 10. Mercury vapor is generated by heating a mercury reservoir 12 which is held with the shaft vertically stood from the lower wall surface of the reaction tube 11 and arranged to the central part in the reaction tube 11. In this case, at least Me2Cd decomposable at low temp. is supplied through the nozzle 9 opened in the part upper than the top-end aperture of the mercury reservoir 12. A base plate 16 controlled at the prescribed temp. is arranged to the part upper than the aperture of the nozzle 9. this base plate 16 is rotated for the center axis of the reaction tube 11 by a rotating shaft 18.
    • 8. 发明专利
    • METHOD AND DEVICE FOR VAPOR GROWTH
    • JPH02239186A
    • 1990-09-21
    • JP6181289
    • 1989-03-14
    • NIPPON STEEL CORP
    • FUJII SATOSHIFUJITA YUKIHISATERADA TOSHIYUKI
    • C30B25/14C23C16/18C23C16/44C23C16/455C30B29/48
    • PURPOSE:To obtain many sheets of thin films having large area in the excellent composition ratio and surface state by holding a mercury reservoir with a shaft vertically hung in a vertical reaction tube specifying the position for supplying the organic metallic compd. of a raw material and rotating a base plate in the case of growing the thin films of mercury-contg. compd. single crystal. CONSTITUTION:In the case of growing a CdxHg1-x Te single crystal thin film, Me2Cd and Et2Te sent from the bubblers 1, 2 are diluted by H2 and introduced into the vertical reaction tube 11 through the nozzles 9, 10. Mercury vapor is generated by heating a mercury reservoir 12 which is held with the shaft vertically hung from the upper wall surface of the reaction tube 11 and arranged to the central part in the reaction tube 11. In this case, at least Me2Cd decomposable at low temp. is supplied through the nozzle 9 opened to the part lower than the mercury reservoir 12. A base plate 16 controlled at prescribed temp. is arranged to the part lower than this aperture. This base plate 16 is rotated for the center axis of the reaction tube 11 by a rotating shaft 18.