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1. 发明专利

JP2519955B2 失效
公开(公告)号：JP2519955B2
公开(公告)日：1996-07-31
申请号：JP30702487
申请日：1987-12-04
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： OOMIKA HIROYOSHI , KUROKI TERUHISA , NARAHARA HISAO , MYAZAKI KAZUO , ITO AKIO
IPC分类号： C09D5/44 , C09D147/00 , C09D191/00

2. 发明专利

JPS63120195A PAPER COATING MATERIAL 失效
公开(公告)号：JPS63120195A
公开(公告)日：1988-05-24
申请号：JP26240486
申请日：1986-11-04
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： KUROKI TERUHISA , MIYAZAKI KAZUO , ITO AKIO , OMIKA HIROYOSHI
IPC分类号： C09D123/02 , C09D161/04 , D21H19/00 , D21H19/58

3. 发明专利

JP2519989B2 失效
公开(公告)号：JP2519989B2
公开(公告)日：1996-07-31
申请号：JP21272688
申请日：1988-08-27
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： OOMIKA HIROYOSHI , KUROKI TERUHISA , NARAHARA HISAO , MYAZAKI KAZUO , ITO AKIO
IPC分类号： C09D5/44 , C09D109/00 , C09D121/00 , C09D147/00 , C09D191/00

4. 发明专利

JPH0260973A COMPOSITION FOR ELECTRODEPOSITION COATING 失效
公开(公告)号：JPH0260973A
公开(公告)日：1990-03-01
申请号：JP21272688
申请日：1988-08-27
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： OMIKA HIROYOSHI , KUROKI TERUHISA , NARAHARA HISAO , MIYAZAKI KAZUO , ITO AKIO
IPC分类号： C09D5/44 , C09D109/00 , C09D121/00 , C09D147/00 , C09D191/00
摘要： PURPOSE:To obtain the title composition improved in low-temperature curability and tackpreeness without detriment to the performances required of an electrodeposition coating material by adding a wax to a specified resin composition used as an anode deposition type electrodeposition coating material. CONSTITUTION:The title composition is obtained by mixing 100 pts.wt. modified resin having 10-300mgKOH/g (in terms of an acid value per g of the modified resin) of free carboxylic acid residues and at least 10 milliequivalent, per 100g of the modified resin, alpha,beta-unsaturated monocarboxylic acid residues of the formula (wherein R1 and R2 are each H or CH3) in the side chains and/or the main chain and prepared by modifying a drying oil of a number-average MW of 500-10000 or a conjugated diene polymer or copolymer of a number-average MW of 500-10000 with 0.001-1.0 pt.wt. (in terms of the metal atom) organic compound or inorganic compound of at least one metal of Co, Mn, Fe, Ni, Pb, Zn or Cr and 0.2-10 pts.wt. wax, neutralizing at least part of the free carboxyl groups of the modified resin with a base and dispersing or dissolving the neutralized product in water.

5. 发明专利

JPH01146971A ELECTRODEPOSITION PAINT COMPOSITION 失效
公开(公告)号：JPH01146971A
公开(公告)日：1989-06-08
申请号：JP30702487
申请日：1987-12-04
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： OMIKA HIROYOSHI , KUROKI TERUHISA , NARAHARA HISAO , MIYAZAKI KAZUO , ITO AKIO
IPC分类号： C09D5/44 , C09D147/00 , C09D191/00
摘要： PURPOSE:To obtain the title anode-depositing composition excellent in low- temperature curability, by dispersing a mixture of a specified modified resin with an organic or inorganic compound of a metal selected from among Co, Mn, Fe, Ni, Pb, Zn and Cr in water. CONSTITUTION:A drying oil and/or a conjugated diene (co)polymer (A) of an iodine value >=80 and a number average MW of 500-10000 is subjected to an addition reaction with an alpha,beta-unsaturated dicarboxylic acid (anhydride) (B), and the adduct is reacted with a conjugated diene bond-containing alcohol (C) and an alpha,beta-unsaturated monocarboxylic acid hydroxyalkyl ester (D) of formula I to obtain a modified resin (A) containing 10-300mgKOH/g (in terms of an acid value), per g of the modified resin, free carboxyl groups, at most 10 milliequivalents of conjugated diene bonds per 100g of the modified resin, and at least 10 milliequivalents of alpha,beta-unsaturated monocarboxylic acid residues of the formula II, per 100g of the modified resin, in the side chains and/or the main chain. A mixture of 100 pts.wt. component A with 0.001-1.0 pt.wt. (in terms of the metal) of organic or inorganic compound of a metal selected from along Co, Mn, Fe, Ni, Pb, Zn and Cr is neutralized with a base, and the product is dispersed or dissolved in water.

6. 发明专利

JPS63288295A PAPER COATING MATERIAL 失效
公开(公告)号：JPS63288295A
公开(公告)日：1988-11-25
申请号：JP12276287
申请日：1987-05-20
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： KUROKI TERUHISA , ITO AKIO , MIYAZAKI KAZUO , OMIKA HIROYOSHI
IPC分类号： C08L15/00 , C08L21/00 , C08L61/00 , C08L61/04 , C08L61/20 , D21H19/24 , D21H19/58

7. 发明专利

JP2519956B2 失效
公开(公告)号：JP2519956B2
公开(公告)日：1996-07-31
申请号：JP30702587
申请日：1987-12-04
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： OOMIKA HIROYOSHI , KUROKI TERUHISA , NARAHARA HISAO , MYAZAKI KAZUO , ITO AKIO
IPC分类号： C09D5/44 , C09D147/00 , C09D191/00

8. 发明专利

JPH0261198A COATING MATERIAL FOR PAPER 失效
公开(公告)号：JPH0261198A
公开(公告)日：1990-03-01
申请号：JP20805388
申请日：1988-08-24
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： MIYAZAKI KAZUO , KUROKI TERUHISA , ITO AKIO , OMIKA HIROYOSHI
IPC分类号： D21H19/20
摘要： PURPOSE:To obtain the subject material having excellent coating property, impregnation property, water-repellence, wet strength, gloss, etc., by neutralizing a polymer such as butadiene having a specific iodine value, etc., and reacting with a radically polymerizable monomer. CONSTITUTION:The objective material can be produced by reacting a low- polymer such as butadiene or isoprene with e.g., peracetic acid to introduce epoxy group to the polymer, reacting the product with a primary or secondary amine to form a polymer (A) containing 0.02-1.3mol (based on 100g of the polymer) of a basic group expressed by formula (R1 and R2 are H or methyl; R3 and R4 are H or 1-10C organic group; X is H, etc.) and having a number-average molecular weight of 500-10,000 and an iodine value of 100-500, dispersing the component A in water, neutralizing with (B) an organic acid or an inorganic acid, added with (C) a radically polymerizable monomer (e.g., methyl acrylate) and then (D) a radical polymerization initiator and finally polymerizing the monomer.

9. 发明专利

JPH01146972A ELECTRODEPOSITION PAINT COMPOSITION 失效
公开(公告)号：JPH01146972A
公开(公告)日：1989-06-08
申请号：JP30702587
申请日：1987-12-04
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： OMIKA HIROYOSHI , KUROKI TERUHISA , NARAHARA HISAO , MIYAZAKI KAZUO , ITO AKIO
IPC分类号： C09D5/44 , C09D147/00 , C09D191/00
摘要： PURPOSE:To obtain the title anode-depositing composition excellent in low-temperature curability, by neutralizing a mixture of two specified modified resins with an organic or inorganic compound of a metal such as Co, Mn, Fe or Ni and dispersing or dissolving the product of neutralization in water. CONSTITUTION:A mixture of 100 pts.wt. composition comprising 10-90 pts.wt. modified resin (A) obtained by reacting a drying oil or a conjugated diene (co)polymer (a) of a number-average MW of 500-10000 with an alpha,beta-unsaturated dicarboxylic acid anhydride (b) and a conjugated bond-containing alcohol (c) and having 10-300mgKOH/g (in terms of an acid value) free carboxylic acid groups per g of the resin, and at least 10 milliequivalents of conjugated diene bonds per 100g of the resin and 10-90 pts.wt. modified resin (B) obtained by reacting component (a) with component (b) and an alpha,beta-unsaturated monocarboxylic acid hydroxyalkyl ester (d) and having 10-30mgKOH/g (in terms of an acid value) free carboxyl groups per g of the resin and at least 10 milliequivalents of alpha,beta-unsaturated monocarboxylic acid residues of the formula I (wherein R1-2 are each H or CH3) per 100g of the resin with 0.001-1.0 pt.wt. (in term of the metal) organic or inorganic compound of a metal (C) such as Co or Ni is neutralized, and the product of neutralization is dispersed or dissolved in water.

10. 发明专利

JPS6392798A PAPER COATING MATERIAL 失效
公开(公告)号：JPS6392798A
公开(公告)日：1988-04-23
申请号：JP23258786
申请日：1986-09-30
申请人： NIPPON PETROCHEMICALS CO LTD
发明人： MIYAZAKI KAZUO , KUROKI TERUHISA , ITO AKIO , OMIKA HIROYOSHI
IPC分类号： D21H19/20

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