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    • 5. 发明专利
    • CORROSION RESISTING STEEL MEMBER AND MANUFACTURE THEREFOR
    • JPH111760A
    • 1999-01-06
    • JP16353597
    • 1997-06-06
    • NIPPON KOKAN KK
    • TAKADA YOSHIICHININOMIYA HIRONORISHOMURA KATSUMIKURIKI YOSHIRO
    • C23C10/08
    • PROBLEM TO BE SOLVED: To obtain a steel member excellent in corrosion resistance applicable to a high temperature corrosive atmosphere by heating a steel member in an atmosphere of mixture of SiCl4 containing gas and nonoxidizing gas at a high temperature and forming a high Si containing Fe-Si alloy layer on the surface of the steel member through a Si concentration transtion layer. SOLUTION: A steel member is heated at a high temperature in nonoxidizing gases such as nitrogen and the like, and at the same time by gas-solid reaction with a mixture of SiCl4 of >=5 volume % and nonoxidizing gas, a high Si corrosion resisting layer with a thickness of 10-200 μm comprising Fe3 Si of 7-15 wt.% Si is formed through a Si concentration transition layer on the surface of steel member. By gassolid reaction of the steel member and the mixture of SiCl4 containing nonoxidizing gas, a corrosion resistant steel member is obtained applicable to a severe corrosive environment such as boiling sulfuric acid or the like without any restriction of the kind of steel member and the figure, without any complicated layer structure, nor with any deterioration of the surface quality.