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1. 发明专利

JP2008163228A Manufacturing method of biodegradable polymer 有权
标题翻译：生物可降解聚合物的制备方法
公开(公告)号：JP2008163228A
公开(公告)日：2008-07-17
申请号：JP2006355437
申请日：2006-12-28
申请人： Mitsui Chemicals Inc , Mitsui Chemicals Polyurethanes Inc , 三井化学ポリウレタン株式会社 , 三井化学株式会社
发明人： SHIMODA MANABU , SUKEGAWA MAKOTO , MITSUZUKA MASAHIKO , TSURUTA MANABU , NOBORI TADAHITO
IPC分类号： C08G18/65 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of a biodegradable polymer which can prepare a biodegradable polymer having a biodegradable moiety and an imine moiety in the form of making pre-molding preparatory processes, such as cutting and crushing, unnecessary and which gives a polymer of a high molecular weight. SOLUTION: Provided is a manufacturing method of the biodegradable polymer having the biodegradable moiety and the imine moiety, characterized by conducting the dispersion polymerization of at least (A) a compound containing a biodegradable moiety, (B) a compound containing an imine moiety and (C) a linking agent in (D) an organic solvent containing a dispersant. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种生物可降解聚合物的制造方法，其可以制备具有生物可降解部分和亚胺部分的可生物降解聚合物，其形式为预成型预备过程，例如切割和破碎，不必要和不必要的其产生高分子量的聚合物。解决方案：提供具有生物可降解部分和亚胺部分的生物可降解聚合物的制造方法，其特征在于进行至少（A）含有可生物降解部分的化合物的分散聚合，（B）含有亚胺的化合物部分和（C）（D）含有分散剂的有机溶剂中的交联剂。版权所有（C）2008，JPO＆INPIT

2. 发明专利

JP2006199834A Photosetting heat-decomposable composition and use thereof 审中-公开
标题翻译：摄影热分解组合物及其用途
公开(公告)号：JP2006199834A
公开(公告)日：2006-08-03
申请号：JP2005013435
申请日：2005-01-21
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： MITSUZUKA MASAHIKO , TSURUTA MANABU , TANEICHI DAIKI
IPC分类号： C08L75/04 , C08G18/28 , C08K3/00 , C08K5/00 , G03F7/004 , G03F7/035
摘要： PROBLEM TO BE SOLVED: To solve the heat-decomposition problems of conventional photosetting heat-decomposable compositions containing cellulose esters such as the generation of heat in heat decomposition and the residue of carbon and provide a photosetting heat-decomposable composition having improved heat-decomposability and usable as a substitute for conventional photosetting heat-decomposable compositions containing a cellulose ester as a binder resin. SOLUTION: The photosetting heat-decomposable resin composition contains a polyurethane resin composed of a repeating unit (a) expressed by formula (1) and a repeating unit (b) expressed by formula (2) and having a molar ratio of the repeating unit (a) of 0.35-0.99 and a molar ratio of the repeating unit (b) of 0.01-0.65, and further contains a photosetting monomer and a solvent. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决的问题：为了解决含有纤维素酯的常规的光固化热分解组合物的热分解问题，如热分解产生热量和碳残余物，并提供具有改进的热量的光固化热分解组合物 - 可分解性，可用作代替含有纤维素酯作为粘合剂树脂的常规光固化热分解组合物。光解热分解树脂组合物含有由式（1）表示的重复单元（a）和由式（2）表示的重复单元（b）组成的聚氨酯树脂，其摩尔比为重复单元（a）为0.35-0.99，重复单元（b）的摩尔比为0.01-0.65，并且还含有光固化性单体和溶剂。版权所有（C）2006，JPO＆NCIPI

3. 发明专利

JP2014008694A Laminate and formed article including the same 有权
标题翻译：包括其中的层压和成型品
公开(公告)号：JP2014008694A
公开(公告)日：2014-01-20
申请号：JP2012147460
申请日：2012-06-29
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： HIROTA YOSHITO , TSURUTA MANABU , ITO YUICHI
IPC分类号： B32B27/32 , C09J7/00 , C09J109/00 , C09J123/10 , C09J123/20 , C09J135/00 , C09J153/02 , C09J157/02 , C09J201/00
摘要： PROBLEM TO BE SOLVED: To provide: a laminate that adheres excellently to polyolefin base materials the surface of which is not treated by preliminary treatment such as corona treatment and satisfactorily to highly polar base materials such as polyester resins and acrylic resins and that is less tacky and easy to handle; a formed article including the laminate; and, additionally, primers and hot-melt adhesive films including the laminate as a main component; as well as decorative films including the hot-melt adhesive films as a main component.SOLUTION: The laminate has a layer having the following polyolefin adhesion resin (A) on a layer having the following polar adhesive resin (B): (A) is a copolymer of propylene and 1- butene and derivatives thereof comprising 50-95 mol% of propylene and 5-50 mol% of 1-butene and having melting points of 50-120°C; (B) is a resin satisfying all of the following three requirements (i) to (iii): (i) the resin includes a structure derived from either or both of alkene and diene; (ii) the resin has at least one functional group selected from the group consisting of epoxy, hydroxy, carboxylic acid, acid anhydride, amino, imido, amide, nitrile, thiol, isocyanate; (iii) the resin has at least one structure derived from predetermined monomers not including functional groups described in (ii). The laminate adheres to polyolefin base materials excellently and to highly polar base materials such as polyester resins and acrylic resins satisfactorily.
摘要翻译：要解决的问题：提供：非常适合于聚烯烃基材的层压体，其表面未经电晕处理的预处理而令人满意地对高极性基材如聚酯树脂和丙烯酸树脂进行处理，并且粘性较差易于处理; 包括层压体的成形制品; 以及包含层叠体作为主要成分的底漆和热熔粘合剂膜; 以及包括热熔粘合膜作为主要成分的装饰膜。方案：层压板在具有以下极性粘合剂树脂（B）的层上具有下列聚烯烃粘合树脂（A）的层：（A）为丙烯和1-丁烯的共聚物及其衍生物，其包含50-95摩尔％丙烯和5-50摩尔％1-丁烯，熔点为50-120℃; （B）是满足以下三个要求（i）至（iii）的所有树脂：（i）树脂包括衍生自烯烃和二烯烃之一或两者的结构; （ii）树脂具有至少一种选自环氧基，羟基，羧酸，酸酐，氨基，亚氨基，酰胺，腈，硫醇，异氰酸酯的官能团; （iii）树脂具有至少一种衍生自不包括（ⅱ）中所述的官能团的预定单体的结构。该层压板极好地粘附到聚烯烃基材上，并且令人满意地粘附到高极性基材如聚酯树脂和丙烯酸树脂上。

4. 发明专利

JP2013043789A Coking assistant for firing 审中-公开
标题翻译：烧焦助手
公开(公告)号：JP2013043789A
公开(公告)日：2013-03-04
申请号：JP2011180986
申请日：2011-08-22
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： ITO YUICHI , YOSHIDA MASAKO , SAITO YOSHITOMO , TSURUTA MANABU , HIROTA YOSHITO
IPC分类号： C04B35/632 , B22F3/02
摘要： PROBLEM TO BE SOLVED: To provide a coking assistant for firing capable of dispersing sufficiently raw material powder in ceramics production or in sintered metal production (powder metallurgy) and binding each raw material powder, and further keeping moldability which is necessary for post processing, and having a property of low carbon residue for keeping a characteristic after firing.SOLUTION: This coking assistant for firing contains a propylene-based copolymer (A). The propylene-based copolymer (A) preferably contains 1-butene, or may contain another olefin-based resin (B) and/or a styrene-based elastomer (C). When being used for ceramics component production or sintered metal component production (powder metallurgy), the coking assistant for firing can disperse sufficiently raw material powder (metal powder, graphite powder, inorganic raw material powder) and bind each raw material powder, and further keep moldability which is necessary for post processing, and has the property of low carbon residue for keeping the characteristic after firing, to thereby enable production of a ceramics component or a sintered metal component which is more excellent compared with hitherto. Further, when being formed into a green tape, high strength and extension can be maintained.
摘要翻译：要解决的问题：提供一种用于焙烧的焦化助剂，其能够在陶瓷生产或烧结金属生产（粉末冶金）中分散足够的原料粉末并结合每种原料粉末，并进一步保持柱子所需的成型性加工，具有低碳残渣性能，以保持焙烧后的特性。解决方案：该烧焦助熔剂含有丙烯类共聚物（A）。丙烯类共聚物（A）优选含有1-丁烯，或者可以含有另一种烯烃系树脂（B）和/或苯乙烯系弹性体（C）。当用于陶瓷部件生产或烧结金属部件生产（粉末冶金）时，焦化焦化助剂可以充分分散原料粉末（金属粉末，石墨粉末，无机原料粉末）并结合每种原料粉末，并进一步保持后处理所需的成型性，并且具有保持烧成后的特性的低碳残渣的性质，从而能够生产比迄今更优异的陶瓷成分或烧结金属成分。此外，当形成绿色带时，可以保持高强度和延伸。版权所有（C）2013，JPO＆INPIT

5. 发明专利

JP2008095090A Method for producing water-disintegratable block copolymer and water-disintegratable block copolymer obtained by the method 有权
标题翻译：用于生产可消毒嵌段共聚物和由该方法获得的水不溶性嵌段共聚物的方法
公开(公告)号：JP2008095090A
公开(公告)日：2008-04-24
申请号：JP2007238051
申请日：2007-09-13
申请人： Mitsui Chemicals Inc , Mitsui Chemicals Polyurethanes Inc , 三井化学ポリウレタン株式会社 , 三井化学株式会社
发明人： OBATA ATSUO , OTANI RIEKO , WATANABE AKITO , OOKUBO HIDEKAZU , MITSUZUKA MASAHIKO , TSURUTA MANABU
IPC分类号： C08G18/48 , C08G18/42 , C08G63/91
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a block copolymer usable as a novel plastic material having a rapid decomposability in a large amount of water (water disintegratability) while maintaining a certain form in the air and absorbing a certain amount of moisture content.
SOLUTION: A method for producing a water-disintegratable block copolymer comprising a step of reacting (a): (a1) a polyalkylene glycol and/or (a2) an aliphatic polyester having a hydroxy group at both ends obtained by esterification of a polyalkylene glycol and an aliphatic dicarboxylic acid or its anhydride, (b) an aliphatic polyester having a hydroxy group at both ends not including a polyoxyalkylene group, and (c) a chain extending agent having a plurality of functional groups to react with a hydroxy group is provided.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一种在大量水分上具有快速分解性（水崩解性）的新型塑料材料的制造方法，同时保持一定形式在空气中并吸收一定量的含水量。解决方案：一种生产水解性嵌段共聚物的方法，包括以下步骤：（a）：（a1）聚亚烷基二醇和/或（a2）在两端具有羟基的脂族聚酯，其通过酯化聚亚烷基二醇和脂肪族二羧酸或其酸酐，（b）在两端不具有聚氧化烯基的羟基的脂肪族聚酯，（c）具有多个与羟基反应的官能团的扩链剂组提供。版权所有（C）2008，JPO＆INPIT

6. 发明专利

JP2012179891A Decorating method of metal material and decorative molded product by the decorating method 审中-公开
标题翻译：通过装饰方法制作金属材料和装饰成型品的装饰方法
公开(公告)号：JP2012179891A
公开(公告)日：2012-09-20
申请号：JP2011206731
申请日：2011-09-22
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： HIROTA YOSHITO , TSURUTA MANABU , ITO YUICHI
IPC分类号： B29C51/10 , B29C65/54 , B29C65/70 , B32B15/08 , B32B37/16
摘要： PROBLEM TO BE SOLVED: To obtain a beautiful decorative molded product at a low cost by an economically superior method to a metal base material, which is capable of achieving decoration having high designability, and of decorating even a member obtained by composition of a plastic member such as PP, ABS, polycarbonate, vinyl chloride or the like and a metal part at a time.SOLUTION: In the decorating method for laminating a decorative film on the metal base material by vacuum pressure molding, an adhesive layer for the decorative film in contact with the metal material has at least a propylene base copolymer (A) having a polar group. The propylene based copolymer (A) preferably contains 1-butene.
摘要翻译：要解决的问题：通过经济上优越的方法获得美丽的装饰成型产品，能够实现具有高设计性的装饰的金属基材，并且甚至通过组合获得的构件诸如PP，ABS，聚碳酸酯，氯乙烯等的塑料部件和金属部件。解决方案：在通过真空压力成型在金属基材上层压装饰膜的装饰方法中，与金属材料接触的装饰膜的粘合剂层至少具有极性的丙烯基共聚物（A）组。丙烯类共聚物（A）优选含有1-丁烯。版权所有（C）2012，JPO＆INPIT

7. 发明专利

JP2011006382A Method for producing trans-1,4-bis(aminomethyl)cyclohexane 有权
标题翻译：生产反式-1,4-双（氨基甲基）环己酮的方法
公开(公告)号：JP2011006382A
公开(公告)日：2011-01-13
申请号：JP2010089861
申请日：2010-04-08
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YOSHIMURA SHIGETOSHI , KIYONO SHINJI , KUNIHIRO TAMOTSU , TSURUTA MANABU , HAMADA TETSUYA , WATABE EIJI , MOROOKA SAIKO
IPC分类号： C07C209/48 , C07B61/00 , C07C211/18
摘要： PROBLEM TO BE SOLVED: To provide a method for producing trans-1,4-bis(aminomethyl)cyclohexane excellent in facility, safety and economical aspects.SOLUTION: The method includes: performing the nucleus hydrogenation of at least one terephthalic acid or derivative thereof selected from the group consisting of terephthalic acid, terephthalates and terephthalamide to obtain a hydrogenated terephthalic acid or derivative thereof; obtaining trans-1,4-dicyanocyclohexane from 1,4-dicyanocyclohexane obtained by bringing the hydrogenated terephthalic acid or derivative thereof into contact with ammonia; and then bringing the obtained trans-1,4-dicyanocyclohexane into contact with hydrogen to produce trans-1,4-bis(aminomethyl)cyclohexane.
摘要翻译：要解决的问题：提供在设备，安全性和经济方面优异的反式-1,4-双（氨基甲基）环己烷的制备方法。方法：该方法包括：进行至少一种对苯二甲酸或其衍生物的核氢化选自对苯二甲酸，对苯二甲酸酯和对苯二甲酰胺，得到氢化对苯二甲酸或其衍生物; 通过使氢化对苯二甲酸或其衍生物与氨接触而获得的1,4-二氰基环己烷获得反式-1,4-二氰基环己烷; 然后使所得到的反式-1,4-二氰基环己烷与氢接触以产生反式-1,4-双（氨基甲基）环己烷。

8. 发明专利

JP2002265557A MANUFACTURING METHOD OF WATER-SOLUBLE POLYURETHANE RESIN HAVING COMB-LIKE HYDROPHOBIC GROUP 失效
公开(公告)号：JP2002265557A
公开(公告)日：2002-09-18
申请号：JP2001070630
申请日：2001-03-13
申请人： MITSUI CHEMICALS INC
发明人： TSURUTA MANABU , OGA AKIHITO , MITSUZUKA MASAHIKO , TANAKA YONEZO , NAKAMURA YASUGO
IPC分类号： C08K3/34 , C08G18/66 , C08G18/82 , C08L75/08
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing a water-soluble polyurethane resin having a comb-like hydrophobic group wherein the productivity of the water-soluble polyurethane resin having new structure and function can be greatly improved, and the dissolving speed into a mortar or the like can be improved owing to its smaller particle size realized by the improved pulverization process. SOLUTION: This method of manufacturing a water-soluble polyurethane resin is characterized in that a water-soluble polyalkylene glycol, a diisocyanate, and a diol having a comb-like hydrophobic group are supplied through a screw extruder and subjected to the reaction.

9. 发明专利

JP2001348256A THICKENER FOR MORTAR 失效
公开(公告)号：JP2001348256A
公开(公告)日：2001-12-18
申请号：JP2000313463
申请日：2000-10-13
申请人： MITSUI CHEMICALS INC
发明人： MITSUZUKA MASAHIKO , TSURUTA MANABU , GO UNSHI
IPC分类号： C04B24/14 , C04B28/02 , C08G18/65
摘要： PROBLEM TO BE SOLVED: To solve the problem that thickeners for mortar consisting of cellulose ethers retard setting. SOLUTION: This new thickener for mortar is manufactured from polyalkylene glycol, novel comb-shaped hydrophobic diol and polyisocyanate.

10. 发明专利

JP2000355618A BINDER FOR MOLDING CERAMICS 失效
公开(公告)号：JP2000355618A
公开(公告)日：2000-12-26
申请号：JP16773399
申请日：1999-06-15
申请人： MITSUI CHEMICALS INC
发明人： MITSUZUKA MASAHIKO , TSURUTA MANABU , GO UNSHI
IPC分类号： B28B3/20 , C08G18/50
摘要： PROBLEM TO BE SOLVED: To obtain a binder which, when degreased, slowly generates a small quantity of heat and leaves little carbide by selecting a polyurethane having comb hydrophobic diol groups as the hydrophobic groups and having a molecular weight in a specified range. SOLUTION: This binder comprises a polymer comprising repeating units of formula I and repeating units of formula II, having a molar fraction of repeating units of formula I of 0.5-0.99 and a molar fraction of repeating units of formula II of 0.01-0.5, and having a weight-average molecular weight of 10,000-1,000,000 as measured by GPC. In the formulae, A is such a divalent group that HO-A-OH is a water-soluble polyalkylene polyol having OH groups on at least both terminals and having a number-average molecular weight of 400-100,000; B is such a divalent group that OCN-B-NCO is a polyisocyanate compound selected from 3-18C polyisocyanates; D is such a divalent group that HO-D-OH is a comb hydrophobic diol of any one of formulae III to V; R1 to R6 and R8 to R11 are each a hydrocarbon group; R7 and R12 are each an alkylene; Y and Y' are each H, CH3 or the like; Z and Z' are each O, S or CH2; and (n), (n'), and (k) are each 0-15.

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